Title:
ELECTRO-SYNTHESIS OF ALCOHOLS AND CARBOXYLIC ACIDS FROM CORRESPONDING METAL SALTS
Document Type and Number:
WIPO Patent Application WO1992007648
Kind Code:
A3
Abstract:
A preferred electrochemical process for producing an alcohol or carboxylic acid from a corresponding metal salt while also recovering metal cation residues is described. The preferred process does not require a three-compartment desalination cell but rather can be performed in a standard two-compartment cell divided by a cation-permeable membrane. The process comprises the step of electrolyzing an aqueous medium containing the metal salt in the anolyte of the cell to thereby yield alcohol or carboxylic acid in the anolyte and pass the metal cation into the catholyte. In one particularly preferred mode, the process provides a highly effective recovery of valuable materials from byproduct streams of base-catalyzed syntheses of polyols such as such as trimethylolpropane or pentaerythritol from aldehydes, and in another provides an efficient recovery of phenol.
Inventors:
TOOMEY JOSEPH E (US)
Application Number:
PCT/US1991/007960
Publication Date:
November 26, 1992
Filing Date:
October 28, 1991
Export Citation:
Assignee:
REILLY IND INC (US)
International Classes:
B01D61/44; C07C29/88; C07C51/02; C25B3/00; (IPC1-7): B01D61/44; C25B3/00
Foreign References:
| DE99225C | ||||
| FR1075773A | 1954-10-20 | |||
| GB739722A | 1955-11-02 | |||
| US2967806A | 1961-01-10 | |||
| EP0201925A1 | 1986-11-20 | |||
| CH242151A | 1946-04-30 | |||
| DE637772C | 1936-11-04 |
Download PDF:
Previous Patent: DEVICE FOR REGENERATING ORGANIC SOLVENT
Next Patent: COMPOSITE MEMBRANE FOR FACILITATED TRANSPORT PROCESSES
Next Patent: COMPOSITE MEMBRANE FOR FACILITATED TRANSPORT PROCESSES