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Title:
ELECTROCHEMICAL PROCESSING POWER DEVICE
Document Type and Number:
WIPO Patent Application WO/2002/033150
Kind Code:
A2
Abstract:
The present invention discloses a power supply device, particularly for supplying a controlled electrical signal in an electrochemical process, e.g. plating, etching, etc. The power delivery device provides an electrical signal with optimal characteristics and setting for processing one or more surfaces in an electrochemical process. The power delivery device comprises a power stage having an input for receiving a power signal and an output being operably connected to the object. A sensor is operably connected to the output. A controller is operably connected to the output and responsive to the sensor. A modulator is operably connected between the controller and the power stage wherein the power stage outputs the electrical signal to the object in response to the modulator and the controller.

Inventors:
GUTIERREZ ENRIQUE JR
DIAZ BONIFACIO
Application Number:
PCT/US2001/032534
Publication Date:
April 25, 2002
Filing Date:
October 18, 2001
Export Citation:
Click for automatic bibliography generation   Help
Assignee:
TECNU INC (US)
International Classes:
C25D5/18; C25D21/12; H02M3/28; (IPC1-7): C25B/
Domestic Patent References:
WO2000036737A22000-06-22
WO1996023090A11996-08-01
Foreign References:
US3983014A1976-09-28
EP1020982A12000-07-19
US4338176A1982-07-06
DE1421984A11968-11-07
Other References:
A.J. BARD AND L.R. FAULKNER: "Electrochemical Methods. Fundamentals and Applications." 1980, JOHN WILEY & SONS INC. , NEW YORK , XP002330974 pages 136-140 pages 249-251
DATABASE WPI Section Ch, Week 198024 Derwent Publications Ltd., London, GB; Class M11, AN 1980-42708C XP002330790 & JP 55 018789 B (GAKKO HOJIN WASEDA) 21 May 1980 (1980-05-21)
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 06, 28 June 1996 (1996-06-28) -& JP 08 053796 A (NIKKO GOULD FOIL KK), 27 February 1996 (1996-02-27)
Attorney, Agent or Firm:
Morneault, Monique A. (311 South Wacker Drive - 530, Chicago IL, US)
Download PDF:
Claims:
CLAIMS What is claimed is:
1. A power delivery device for providing an electrical signal in an electrochemical process involving an object, the power delivery device comprising: a power stage having an input and an output, the input for receiving a power signal, the output being operabty connected to the object ; a sensor being operably connected to the output : a controller being operably connected to the output and responsive to the sensor; and, a modulator being operably connected between the controller and the power stage wherein the power stage outputs the electrical signal to the object in response to the modulator and the controller.
2. The power delivery device of Claim 1 wherein the electrical signal includes an AC ripple component and a DC component.
3. The power delivery device of Claim 1 wherein the electrical signal includes a dynamic power, the dynamic power being operabty responsive to the specific features of the object.
4. The power delivery device of Claim 1 further comprising a user interface being operably connected to the controller.
5. The power delivery device of Claim 1 wherein the controller is a digital signa) processor having an A/D converter and a D/A converter.
6. The power delivery device of Claim 1 wherein the modulator is a pulse width modulator.
7. The power delivery device of Claim 1 wherein the modulator is a Frequency modulator.
8. The power delivery device of Claim I wherein the sensor is a current sensor.
9. The power delivery device of Claim 1 wherein the sensor is a voltage sensor.
10. The power delivery device of Claim 1 wherein the sensor is a power sensor.
11. The power delivery device of Claim 1 wherein the electrical signal output by the power stage includes a constant power.
12. The power delivery device of Claim 1 wherein the electrical signal output by the power stage includes a power gradient waveform,.
13. The power delivery device of Claim 1 wherein the electrical signal output by the power stage includes a voltage gradient waveform.
14. The power delivery device of Claim I wherein the electrical signal output by the power stage includes a current gradient waveform. I 5.
15. The power delivery device of Claim 1 wherein the electrical signal output by the power stage includes a frequency gradient waveform.
16. The power delivery device of Claim 1 wherein the electrical signal output by the power stage includes a unipolar waveform.
17. The power delivery device otClaim I wherein the etectricat signat output bv the power stage inctudcs a bipotar Waverbrm,.
18. The power delivery device of Claim 1 wherein the electrical signal output by the power stage has a dynamic power, the dynamic power being operably responsive to the specific features of the object.
19. The power delivery device of Claim 18 wherein the electrical signal further being operably responsive to a process condition.
20. A power delivery device for providing an electrical signal for an electrochemical process wherein an object is operably connected to the power delivery device, the power delivery device comprising: a tracking power stage being operably connected to the object, an output power stage providing the electrical signal having an AC component and a OC component to the object, the output power stage being operably responsive to the tracking power stage wherein a dynamic power dissipated by the output power stage is minimized.
21. The power delivery device of Claim 20 wherein the tracking power stage comprises : I controller being operably connected to the output power stage, the controller having a reference parameter input wherein the controller provides an input signal to the output power stage in response to the reference parameter and the electrical signal.
22. The power delivery device of Claim 21 wherein the reference parameter input is a voltage.
23. The power delivery device of Claim 22 wherein the reference parameter input is a current.
24. The power delivery device of Claim 21 wherein the reference parameter input is power.
25. The power delivery device of Claim 21 further comprising: a frequency modulator being operably connected to the controller and the object. the frequency modulator having u first input being operably connected to the output power stage and a second input being operably connected to a ripple reference for an AC signal parameter wherein the controller is operably responsive to the output of the frequency modulator.
26. The power delivery device of Claim 25 wherein the ripple reference is approximately equal to or greater than 10KHz.
27. The power delivery device of C) aim 25 wherein the ripple reference is approximately equal to or less than I MHz.
28. A method of providing power to a plating process for plating an object, the method comprising the steps of providing an electrical signal to the object, the electrical signal comprising an AC component and a DC component : sensing a parameter of the electrical signal; and, adjusting the AC component of the electrical signal in response to the sensed parameter.
29. method of Claim 28 further comprising: adjusting the DC component of the electric signal in response to the sensed parameter.
30. The method of Claim 28 wherein the sensed parameter is current,.
31. The method of Claim 28 wherein the sensed parameter is voltage.
32. The method of Claim 28 wherein the sensed parameter is power.
33. The method of Claim 28 wherein the electrical signat provided to the object includes a constant power.
34. The method of Claim 28 wherein the electrical signal provided to the object includes a power gradient waveform.
35. The method of Claim 28 wherein the electrical signal provided to the object includes a frequency gradient waveform,.
36. The method of Claim 28 wherein the electrical signal provided to the object includes a unipolar waveform.
37. The method of Claim 28 wherein the electrical signal provided to the object includes a bipolar waveform.
38. The method of Claim 28 wherein the electrical signal provided to the object includes a dynamic power, the dynamic power being operably responsive to the specific features of the object.
39. The method of Claim 28 wherein the electrical signal being operably responsive to a process condition.
40. The method of Claim 38 wherein the electrical signal further being operably responsive to a process condition.
Description:
ELECTROCHEMICAL PROCESSING POWER DEVICE

Related Applications This application claims the benefit of U. S. Provisional Application No.

60/241,343, filed October 18, 2000.

Technical Field The present invention relates to power delivery devices. and more particularly to a power supply that delivers controlled electrical signals for use in electrochemical processes, including material deposition and removal.

Background of the Invention Various processes for depositing and removing material. i. e plating and etching. are known. For example, chemical plating involves platiy via chemical reaction. In this type ofchemicahy mediated process, the plating is controlled via control ofthe chemical reaction during the plating process. While this process tends to provide a robust plating, it also provides a lesser degree of control over the plating process, furthermore. l. PA regulations make this type of processing more costly and complex because the purely chemicaity mediated plating process requires controtting targe quantities of EPA-regulated chemicals.

Electrical plating, or electrolytic plating, involves providing a potential across the object to be plated while the object is in contact with the plating material. This can be

done. for example, by submersing the object within a bath of plating material. The plating material builds up upon the object due to the electrical potential at the outer surface of the object. However, because a greater build-up of electrical charge occurs at these locations, the plating tends to build up around edges and sharp prostrusions in this type of process, the more irregularly shaped the object, the more difficult it is to apply a uniform layer of plating. Furthermore, the effective depth of the plating on the object is also limited by this process. While this type of process tends to be more controllable than chemical plating processes, it is still somewhat limited by complex geometry of the object that is difficult to reach during processing.

Due to the drawbacks of the aforementioned plating processes, electrochemical plating has gained increased acceptance. This process combines the benefits of controllability of electrolytic plating and the quality of chemical plating, Electrochemical processing includes electroplating, deposition by electrochemical means, electromachimng, etching by electrochemical means and anodizing Since the process also relies on electrolytic plating, lesser quantities of chemicals are required to effectuate the plating process. However, control of the electrical characteristics of the plating process has become increasingly important.

Control of the electrochemical plating process can be achieved through control of the power supply signal to the plating electrodes. Due to increasing complexity of objects requiring plating, particularly in the micro-electronics industry, the need for power supplies allowing for precise control over the signals produced has grown.

Signals that produce pulses having varying positive and negative magnitudes are needed to gradually build up metal layers on surfaces, and to remove excess build-up in problematic areas are a necessity. Furthermore, more precise control and optimization of the electrical signal can help overcome limitations of specific process conditions including, but not limited to chemistries between two or more substances, current, voltage, power, and impendance.

Therefore, there is a need for a power supply device that optimizes the resulting plating of an object during the electrochemical plating process while also offering precise control of the plating process through control of electrical signals produced by the power supply.

Summary of the Invention The present invention is directed to a power supply device, particularly for supplying a controlled electrical signal in an electrochemical process. One embodiment of the present invention is a power delivery device providing an electrical signal in an electrochemical process involving an objcct.-IAhe power delivery device comprises a power stage having an input for receiving a power signal and an output being operably connected to the object. A sensor is operably connected to the output. A controller is operably connected to the output and responsive to the sensor. A modulator is operably connected between the controller and the power stage wherein the power stage outputs the electrical signal to the object in response to the modulator and the controller.

Another aspect of'the present invention is directed to a power delivery device for providing an electrical signal for an electrochemical process wherein an object is operably connected to the power delivery device. The power delivery device comprises a tracking power stage being operably connected to the object. An output power stage provides the electrical signal to the object The output power stage is operably responsive to the tracking power stage wherein a dynamic power dissipated by the output power stage is minimized.

In another aspect of the invention, a power supply device is provided that generates a controlled AC'"ripple"content on a OC @ signal for the purpose of electrochemical processing.

In another aspect of the invention, a device is provided that modulates and controls the power signal in a constant power mode or a dynamic power mode, in

addition to constant voltage/constant current mode, for the purpose of electrochemical processing.

In yet another aspect of the present invention, a device is provided that utilizes one or more digital signal processors (DSP) for the purpose of controlling and/or modulating an electrical signal based on a feedback signal from one or more sensors of a plating or etching apparatus for the purpose of real-time operation, e.g., control, of an electrochemical processing.

Other features and advantages of the invention will be apparent from the following specification taken in conjunction with the following drawings.

Brief Description of the Drawings FIGURE I is a graph depicting a first example ofa controlled AC ripple on a DC signal generated by a power supply device of the present invention; FIGURE 2 is a graph depicting a second example ofa controlled AC ripple on a DC signal generated by a power supply device of the present invention; FIGURE 3 is a graph depicting a first example of a controlled AC ripple on a pulse signal generated by a power supply device of the present invention ; FIGURE 4 is a graph depicting a second example of a controlled AC ripple on a pulse signal generated by a power supply device of the present invention; FIGURE 5 is a graph of a decreasing amplitude gradient waveform utilized to modify the DC level of periodic or non-periodic pulse waveforms generated by a power supply device of the present invention ; FIGURE 6 is a graph of an increasing amplitude gradient waveform utilized to modify the DC leve) of periodic or non-periodic pulse waveforms generated by a power supply device of the present invention;

FIGURE 7 is a graph of a decreasing frequency gradient waveform utilized to modify the DC level of periodic or non-periodic pulse waveforms generated by a power supply device of the present invention: FIGURE 8 is a graph oman increasing Frequency gradient waveform utilized to modify the DC level of periodic or non-periodic pulse waveForms generated by a power supply device ot the present invention ; FIGURE 9 is a graph of a waveForm optimized Cor a speciFic ratio of pulse to reverse pulse amplitude, the ratio being 1 : X; FIGURE 10 is a graph of a waveform optimized for a specific ratio of pulse to reverse pulse amplitudes the ratio being 1 : <X FIGURE It is a graph of a waveform optimized for a specific ratio oF pulse to reverse pulse amplitude, the ratio being I >X ; FIGURE 12 is a graph depicting voltage versus current in a traditional constant voltage/constant current power supply; FIGURE 13 is a graph depicting voltage versus current in a "constant power" power supply according to the present invention ; FIGURE 14 is a graph depicting voltage versus current for a first example of a dynamic power mode of"a power supply of the present invention: FIGURE 15 is a graph depicting voltage versus current for a second example of a dynamic power mode of a power supply of the present invention: FIGURE 16 is a graph depicting voltage versus current for a third example of a dynamic power mode of'a power supply of the present invention, FIGURE 17 is a graph depicting voltage versus current tor a Fourth example of' a dynamic power mode of a power supply otthe present invention : FIGURE 18 is a graph depicting voltage versus current for a first example of a pulse reverse waveform generated by a power supply in dynamic power mode;

FIGURE 19 is a graph depicting voltage versus current for a second example of a pulse reverse waveform generated by a power supply in dynamic power mode; FIGURE 20 is a schematic diagram depicting a dual power stage approach of the present invention that provides increased power resolution over a broader operating range, FIGURE 21 is a schematic diagram of a first embodiment of a power supply device capable of generating an amplitude gradient signal according to the present invention ; FIGURE 22 is a schematic diagram of a second embodiment of a power supply device capable of generating ri controlled AC ripple on a DC signal according to the present invention ; and, FIGURE 23 is a schematic diagram of a signal feedback arrangement that utilizes a digital signal processor to provide feedback and adjustment of a power supply device according to the present invention.

Detailed Description of the Preferred Embodiments While this invention is susceptible of embodiments in many different forms, there is shown in the drawings and wit) herein be described in detail preferred embodiments of the invention with the understanding that the present disclosure is to be considered as an exemplification of the principles of'the invention and is not intended to limit the broad aspect of the invention to the embodiments illustrated The present invention is t power delivery device ! 0, which generates a controlled electrical signal for the purpose of electrochemical processing. Electrochemical processing includes electroplasting, deposition by electrocllemical means, electromachining, etching by electrochemical means and anodizing. However, it is to be understood that the power power delivery device of 10 the present invention can also be utilized in electrical or electrolytic plating applications, or any other plating or etching application

requiring precise control of an electrical signal. By controlling the electrical signal, the electrochemical process can be controlled. This, in turn, allows for plating of complex geometric parts in a uniform manner (geometric leveling) and also overcomes limitations of-process conditions, e. g., chemistries between various substances involved in the platinS, or etching process, current, voltage, power, impedavce. etc, In a first aspect of the present invention, the power delivery device 10 is capable of controlling the AC content of an electrical signal for the purpose of controlling the electrochemical process. The input power for the power supply device of the present invention is typically AC power single phase, or three phase. The power delivery device 10 typically includes a rectifier portion 12 that converts the AC input to a DC signal. The l) signal is then modified for output to the plating, electrodes of the plating apparatus. picallyS the DC signal is modified into high frequency pulses (HFPs) by a full bridge inverter. An AC component, or "ripple," remains on the modified DC signal. In typical power supply applications, this AC component that "rides on" the DC signal is further filtered or "smoothed" out. The present invention contemplates utilizing this AC component instead of filtering it out of the power It has been discovered by the inventors of the present invention that a power signal that includes an AC"ripple"having a frequency greater than approximately 10KHz, and preferably less than approximately 1 MHz, produces a superior deposit in a variety of electrochemical applications, including Chromium electroplating. Thus, the power delivery device 10 can actually provide control of the "ripple effect" for purposes of controlling the electrochemical process.

Multiple AC signals can be simultaneously included and controlled with individual <BR> <BR> amplitude content. Examples of controlled AC components of DC signals as contemplated by the present invention are depicted in FIGURES 1-4. However, the present invention is not limited to the signals depicted in these figures as there are numerous other signals that can incorporate the AC "ripple" component. The AC

component can be controlled and modulated by electronic circuit methods that are well known in the electronic arts.

In another aspect of the present invention, the power delivery device 10 is capable of creating gradient waveforms for the purpose of controlling the clectrochemical process, Gradient waveforms modify the DC power level of periodic or non-periodic pulse waveforms, as shown in FIGURES 5 and 6 ; or modify the frequency content as shown in FIC ES 7 and 8. By controlling the power level in this way, the electrochemical process can be controlled to allow for the plating ofcomplex geometric parts and to geometric leveling. An increasing amplitude gradient waveform initially alloN~s the plating surface to be etched (removal of material), then allows for materiat to be deposited. Converseiy. a decreasing amplitude gradient waveform initially begins by over-ptating and then subsequently etching to achieve improved leveling and deposit characteristics for complex geometries. An increasing or decreasing frequency gradient waveform may be used in electroplating, electromachining, or electropolishing wherein the specific frequencies in the varying frequency range remove burs of varying sizes. This bur removal results in a smooth surface.

In yet another aspect of the present invention, the power delivery device 10 is capable of creating uni-polar or bi-polar, e.g., reverse waveform, pulses optimized for a specific forward pulse to reverse pulse amplitude ratio. In this embodiment, the power level is determined by the pulse amplitude ratio as shown in FIGURES 9-IGURE 9 demonstrates a waveform set for an optimal 1:X ratio. FIGURES 10 and 11 show a waveform set for a ratio other than an optimal 1:X ratio. The forward pulse to reverse pulse amplitude @ ratio can be adjusted and fixed by electronic circuitry that is well known in the electronic arts.

In yet another aspect of the present invention, the power delivery device 10 provides a "constant power" power mode in addition to the traditional constant voltage/constant current modes (the outputs of which are depicted in FIGURES 12 and

. 11 illl f) F1I'1C11131' I710CC, 1C " (l (zlC 111C tl CLII'ICII ll VilI'ICt O I17r1117E1111 V : CUlS1111 power.

In yet another aspect of the present invention, the power delivery device 10 provides a "dynamic power mode." It has been found that controlling and modulating the power signal in a dynamic power mode (independent of voltage and current) provides a superior deposit and a more uniform plating for complex geometries and an increase in control over the pulsating diffusion layer which can be modeled as an RC circuit. The modulation of the power signal and the control of the powei-level allows the electrochemical process to be varied and customized according to process requirements or for specific geometric profiles. The dynamic power mode allows for customizing various portions, or zones, of the electrical signal supplied to the object to provide a more effective deposition or removal process. For example, if certain features of an object require a certain set of parameters for plating while other features require other parameters, the signal portions can each be optimized for certain specific features of the object. The electrica ! signats can include any number of customized portions. Examples of such signals are depicted in FIGURES 14-17. In addition, the electrical signals of the dynamic power mode may also include uni-polar and bi-polar, e.g., reverse waveform, pulses as shown in FIGURES 18 and 19. These particular waveforms allow for even greater control of an electrochemical process in certain applications. However, the present invention is not limited to the signals depicted in these figures as there are numerous other power mode variations that can be incorporated into the power supply device 10 In a preferred embodiment of Hie dynamic power mode, the power delivery device 10 includes two internal stages, a tracking stage 16 and an output power stage 18, as graphically depicted in FIGURE 20. The first stage 16 tracks the output vottageofthe second stage t8 in a feedback configuration. The first stage 16 then feeds the second stage 18 a signal that minimizes the power dissipation of the second stage. The feedback

configuration allows for greater control of the electrochemical process and also provides u wider operating dynamic range of the power supply device 10 while offering increased resolution and an improved signal at the low output range. Preferably, the tracking stage 16 comprises a controller 17 and a modulator 19 A sensor 20 is operably connected to the output. The controller 17, e. g) DSP, is operably connected to the output and responsive to the sensor 20. The modulator 19 is operably connected between the controller 17 and the power stage 18 wherein the power stage outputs the electrical signal to the object in response to the modulator and the controller. Preferably, the modulator 19 is capable of modifying amplitude and frequency.

Since the power delivery device 10 utilizes a dual power stage approach, high resolution and high power can be achieved In the preferred embodiment, the power output resolution is provided with 1000 step increments in the high range and 1000 step increments in the low range. This increased resolution allows the same power delivery device 10 to be used for both small and large lating applications. For example, with this type of resolution, the same power delivery device) 0 can be used in a plating application requiring only 0. 43 amps for a small surface area as well as a plating application requiring 1340 amps for a large surface area. The dual power stage configuration can be implemented by electronic circuitry methods that are welt known in the electronic arts.

Two particular embodiments of the power delivery device 10 of'the present invention are schematically depicted in FIGURES 21 and 22.

In yet another embodiment, the power delivery device 10 utilizes digital signal processor (DSP) technology for controlling the output signal and/or modulating the power signal based on feedback from the electrochemical process. An embodiment of the DSP feedback portion of the power delivery device 10 is schematically depicted in FIGURE 23. A feedback control loop can be implemented between one or more sensors 20 of the plating apparatus and the power delivery device 10. Various plating and process parameters can be measured and then fed back to the power delivery device 10.

By utilizing a DSP 22, the power signal can be constantly adjusted and controlled in response to the actual sensor readings to provide more precise "real-time" control over the electrochemical process. For example, the signal can be modified i'or contt-ollcti leveling over various geometries of the object, and to address process conditions, chemical imitations during polarity changes of the signal; or to deposit out specific alloys in a single bath composed of multiple alloys. This OSP 22 control configuration can be implemented by electronic circuitry methods that are well known in the electronic arts.

The methods and devices of the present invention provide more precise control of the electrochemical process through power control and modulation methods. Thus, the methods and devices of the present invention allow for process control and adjustment in response to the plating of complex geometries, limitations of specific chemistries of various substances, the deposit and/or removal properties of various substances and control over deposit properties.

While the specific embodiments have been illustrated and described, numerous modifications come to mind without significantly departing from the spirit of the invention and the scope of protection is only limited by the scope of the accompanying Claims.