Selectively Reflect UV Radiation

RELATED APPLICATIONS

[0001] This application claims the benefit of priority of U.S. Provisional Application No. 62/236,704 filed on October 2, 2015 the entire content of the foregoing

application is incorporated herein by reference.

FIELD

[0002] The present invention is generally directed to electrochromic devices including distributed Bragg reflectors configured to selectively reflect UV radiation, and more particularly to the electrochromic devices containing metal oxide

nanoparticle electrodes and distributed Bragg reflectors.

BACKGROUND OF THE INVENTION

[0003] Residential and commercial buildings represent a prime opportunity to improve energy efficiency and sustainability in the United States. The buildings sector alone accounts for 40% of the United States' yearly energy consumption (40 quadrillion BTUs, or "quads", out of 100 total), and 8% of the world's energy use. Lighting and thermal management each represent about 30% of the energy used within a typical building, which corresponds to around twelve quads each of yearly energy consumption in the US. Windows cover an estimated area of about 2,500 square km in the US and are a critical component of building energy efficiency as they strongly affect the amount of natural light and solar gain that enters a building.

Recent progress has been made toward improving window energy efficiency through the use of inexpensive static coatings that either retain heat in cold climates (low emissive films) or reject solar heat gain in warm climates (near-infrared rejection films).

[0004] Currently, static window coatings can be manufactured at relatively low cost. However, these window coatings are static and not well suited for locations with varying climates. An electrochromic (EC) window coating overcomes these limitations by enhancing the window performance in all climates. EC window coatings undergo a reversible change in optical properties when driven by an applied potential. Traditional EC materials, such as WO ₃ , Nb ₂ O ₅ , and NiO, primarily modulate radiation in the visible spectral region, while radiation in the near-infrared (NIR) spectral region remains either unchanged or switches simultaneously with visible region of light. Further, performance of electrochromic materials may degrade from use over time as a result of repeated exposure to radiation in the ultraviolet (UV) spectral region.

SUMMARY OF THE INVENTION

[0005] According to various embodiments, an electrochromic device includes a light transmissive first substrate; a working electrode disposed over the first substrate; a counter electrode; a solid state electrolyte layer disposed between the counter electrode and the working electrode; a light transmissive second substrate disposed over the counter electrode; and a Bragg reflector configured to selectively reflect UV radiation away from the working electrode.

[0006] According to various embodiments, a method of operating an electrochromic device which includes a working electrode, a counter electrode, a solid state

electrolyte layer disposed between the counter electrode and the working electrode, and a Bragg reflector, comprises operating the electrochromic device in a bright mode, such that the electrochromic device transmits at least 50% of received visible light; and operating the electrochromic device in a dark mode, such that the electrochromic device transmits 5% or less of received visible light, wherein the Bragg reflector selectively reflects a majority of UV radiation and transmits a majority of received visible light.

BRIEF DESCRIPTION OF THE DRAWINGS

[0007] FIGS. 1A-1C are schematic representations of electrochromic devices according to various embodiments. [0008] FIGS. 2A-2C are schematic diagrams of electrochromic devices including distributed Bragg reflectors, according to various embodiments of the present disclosure.

[0009] FIG. 2D is a top schematic view of an electrochromic window 250 including one of the electrochromic devices of FIGS 2A-2C, according to various embodiments of the present disclosure.

[0010] FIG. 3 is a sectional view of a distributed Bragg reflector, according to various embodiments of the present disclosure.

DETAILED DESCRIPTION OF THE EMBODIMENTS

[0011] The invention is described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the exemplary embodiments set forth herein. Rather, these exemplary embodiments are provided so that this disclosure is thorough, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the size and relative sizes of layers and regions may be exaggerated for clarity. Like reference numerals in the drawings denote like elements.

[0012] It will be understood that when an element or layer is referred to as being disposed "on" or "connected to" another element or layer, it can be directly on or directly connected to the other element or layer, or intervening elements or layers may be present. In contrast, when an element is referred to as being disposed "directly on" or "directly connected to" another element or layer, there are no intervening elements or layers present. It will be understood that for the purposes of this disclosure, "at least one of X, Y, and Z" can be construed as X only, Y only, Z only, or any combination of two or more items X, Y, and Z (e.g., XYZ, XYY, YZ, ZZ).

[0013] Various embodiments disclosed herein provide electrochromic

nano structured materials capable of selectively modulating radiation in near-infrared

(NIR) and visible spectral regions. The material may include nano structured doped transition metal oxides with ternary compounds of the type A _x M _z O _y . In various embodiment A _x M _z O _y compounds, if it is assumed that z = 1, then 0.08 < x < 0.5 (preferably 0.25 < x < 0.35), and 2 < y <3. In various embodiments, since the nanostructures may be non-uniform as a function of depth, x may represent an average doping content. To operate, the subject material may be fabricated into an electrode that will change optical properties after driven by an applied voltage.

[0014] In order to improve the performance of EC window coatings, selective modulation of NIR and visible spectra radiation, and avoidance of degrading effects of UV radiation, may be desired. Various embodiments may provide single-component electrochromic nano structured materials capable of selectively modulating NIR and visible spectral regions. Further, since certain spectral regions may damage the electrochromic nano structured material, the various embodiments may incorporate at least one protective material and/or protective layer to prevent such damage.

[0015] The various embodiments provide devices and methods for enhancing optical changes in windows using electrochromic nanostructured materials fabricated into an electrode to form an electrochromic device. In various embodiments, the material may undergo a reversible change in optical properties when driven by an applied potential. Based on the applied potential, the electrochromic nanostructured materials may modulate NIR radiation (wavelength of around 780-2500 nm), as well as visible radiation (wavelength of around 400-780 nm). In an example, the device may include a first nanostructured material that modulates radiation in a portion of the NIR spectral region and in the visible spectral region, and a second nanostructured material that modulates radiation in an overlapping portion of the NIR spectral region such that the NIR radiation modulated by the device as a whole is enhanced and expanded relative to that of just the first nanostructured material. In various embodiments, the material may operate in multiple selective modes based on the applied potential.

[0016] Further, the various embodiments may include at least one protective material to prevent or reduce damage to an electrochromic nanostructured material that may result from repeated exposure to radiation in the UV spectral region. In an example, a protective material may be used to form at least one barrier layer in the device that is positioned to block UV radiation from reaching the first nano structured material and electrolyte. In another example, a protective material may be used to form a layer that is positioned to block free electron or hole charge carriers created in the electrolyte due to absorption of UV radiation by the nano structured electrode material from migrating to that material, while allowing conduction of ions from the electrolyte (i.e., an electron barrier and ion conductor).

[0017] In various embodiments, control of individual operating modes for

modulating absorption/transmittance of radiation in specific spectral regions may occur at different applied biases. Such control may provide users with the capability to achieve thermal management within buildings and other enclosures (e.g., vehicles, etc.), while still providing shading when desired.

[0018] FIGS. 1 A-1C illustrate embodiment electrochromic devices. It should be noted that such electrochromic devices may be oriented upside down or sideways from the orientations illustrated in FIGS. 1A-1C. Furthermore, the thickness of the layers and/or size of the components of the devices in FIGS. 1A-1C are not drawn to scale or in actual proportion to one another other, but rather are shown as

representations.

[0019] In FIG. 1 A, an embodiment electrochromic device 100 may include a first transparent conductor layer 102a, a working electrode 104, a solid state electrolyte 106, a counter electrode 108, and a second transparent conductor layer 102b. Some embodiment electrochromic devices may also include first and second light

transmissive substrates 110a, 110b respectively positioned in front of the first transparent conductor layer 102a and/or positioned behind the second transparent conductor layer 102b. The first and second substrates 110a, 110b may be formed of a transparent material such as glass or plastic.

[0020] The first and second transparent conductor layers 102a, 102b may be formed from transparent conducting films fabricated using inorganic and/or organic materials. For example, the transparent conductor layers 102a, 102b may include inorganic films of transparent conducting oxide (TCO) materials, such as indium tin oxide (ITO) or fluorine doped tin oxide (FTO). In other examples, organic films in transparent conductor layers 102a, 102b may include graphene and/or various polymers.

[0021] In the various embodiments, the working electrode 104 may include nanostructures 112 of a doped transition metal oxide bronze, and optionally

nanostructures 113 of a transparent conducting oxide (TCO) composition shown schematically as circles and hexagons for illustration purposes only. As discussed above, the thickness of the layers of the device 100, including and the shape, size and scale of nanostructures is not drawn to scale or in actual proportion to each other, but is represented for clarity. In the various embodiments, nanostructures 112, 113 may be embedded in an optically transparent matrix material or provided as a packed or loose layer of nanostructures exposed to the electrolyte.

[0022] In the various embodiments, the doped transition metal oxide bronze of nanostructures 112 may be a ternary composition of the type AxMzOy, where M represents a transition metal ion species in at least one transition metal oxide, and A represents at least one dopant. Transition metal oxides that may be used in the various embodiments include, but are not limited to any transition metal oxide which can be reduced and has multiple oxidation states, such as niobium oxide, tungsten oxide, molybdenum oxide, vanadium oxide, titanium oxide and mixtures of two or more thereof. In one example, the nanostructured transition metal oxide bronze may include a plurality of tungsten oxide (WO ₃ _ _x ) nanoparticles, where 0 < x < 0.33, such as 0 < x < 0.1.

[0023] In various embodiments, the at least one dopant species may be a first dopant species that, upon application of a particular first voltage range, causes a first optical response. The applied voltage may be, for example, a negative bias voltage.

Specifically, the first dopant species may cause a surface plasmon resonance effect on the transition metal oxide by creating a significant population of delocalized electronic carriers. Such surface plasmon resonance may cause absorption of NIR radiation at wavelengths of around 780-2000 nm, with a peak absorbance at around 1200 nm. In various embodiments, the specific absorbances at different wavelengths may be varied/adjusted based other factors (e.g., nanostructure shape, size, etc.), discussed in further detail below. In the various embodiments, the first dopant species may be an ion species selected from the group of cesium, rubidium, and lanthanides (e.g., cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium).

[0024] In various embodiments, the dopant may include a second dopant species that causes a second optical response based upon application of a voltage within a different, second particular range. The applied voltage may be, for example, a negative bias voltage. In an embodiment, the second dopant species may migrate between the solid state electrolyte 106 and the nano structured transition metal oxide bronze of the working electrode 104 as a result of the applied voltage. Specifically, the application of voltage within the particular range may cause the second dopant species to intercalate and deintercalate the transition metal oxide structure. In this manner, the second dopant may cause a change in the oxidation state of the transition metal oxide, which may cause a polaron effect and a shift in the lattice structure of the transition metal oxide. This shift may cause absorption of visible radiation, for example, at wavelengths of around 400-780 nm.

[0025] In various embodiments, the second dopant species may be an intercalation ion species selected from the group of lanthanides (e.g., cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium), alkali metals (e.g., lithium, sodium, potassium, rubidium, and cesium), and alkali earth metals (e.g., beryllium, magnesium, calcium, strontium, and barium). In other embodiments, the second dopant species may include a charged proton species.

[0026] In various embodiments, nanostructures 113 may optionally be mixed with the doped transition metal oxide bronze nanostructures 112 in the working electrode 104. In the various embodiments, the nanostructures 113 may include at least one TCO composition, which prevents UV radiation from reaching the electrolyte and generating electrons. In an example embodiment, the nanostructures 113 may include an indium tin oxide (ITO) composition, which may be a solid solution of around 60- 95 wt% (e.g., 85-90 wt%) indium(III) oxide (In ₂ O ₃ ) and around 5-40 wt% (e.g., 10- 15 wt%) tin(IV) oxide (SnO ₂ ). In another example embodiment, the nanostructures 113 may include an aluminum-doped zinc oxide (AZO) composition, which may be a solid solution of around 99 wt% zinc oxide (ZnO) and around 2 wt% aluminum(III) oxide (Al ₂ O3). Additional or alternative TCO compositions that may be used to form nanostructures 113 in the various embodiments include, but are not limited to, indium oxide, zinc oxide and other doped zinc oxides such as gallium-doped zinc oxide and indium-doped zinc oxide.

[0027] The TCO composition of nanostructures 113 may be transparent to visible light and, upon application of the first voltage, may modulate absorption of NIR radiation at wavelengths of around 1200-2500 nm, with peak absorbance around 2000 nm (e.g., at a longer peak wavelength than the bronze nanoparticles 112, but with overlapping absorption bands). In particular, application of the first voltage may cause an increase in free electron charge carriers, and therefore cause a surface plasmon resonance effect in at least one TCO composition of nanostructures 113. In an embodiment in which the TCO composition is ITO, the surface plasmon resonance effect may be caused by oscillation of free electrons produced by the replacement of indium ions (In ³⁺ ) with tin ions (Sn ⁴⁺ ). Similar to the transition metal oxide bronze, such surface plasmon resonance may cause a change in absorption properties of the TCO material. In some embodiments, the change in absorption properties may be an increase in absorbance of NIR radiation at wavelengths that overlaps with that of the nanostructures 112. Therefore, the addition of TCO composition nanostructures 113 to the working electrode 104 may serve to expand the range of NIR radiation absorbed (e.g., at wavelengths of around 780-2500 nm) compared to that of the nanostructures 112 alone (e.g., at wavelengths of around 780-2000 nm), and to enhance absorption of some of that NIR radiation (e.g., at wavelengths of around 1200-2000 nm). [0028] Based on these optical effects, the nanostructure 112 and optional nanostructure 113 of the working electrode may progressively modulate transmittance of NIR and visible radiation as a function of applied voltage by operating in at least three different modes. For example, a first mode may be a highly solar transparent ("bright") mode in which the working electrode 104 is transparent to NIR radiation and visible light radiation. A second mode may be a selective-IR blocking ("cool") mode in which the working electrode 104 is transparent to visible light radiation but absorbs NIR radiation. A third mode may be a visible blocking ("dark") mode in which the working electrode 104 absorbs radiation in the visible spectral region and at least a portion of the NIR spectral region. In an example, application of a first voltage having a negative bias may cause the electrochromic device to operate in the cool mode, blocking transmittance of NIR radiation at wavelengths of around 780-2500 nm. In another example, application of a second negative bias voltage having a higher absolute value than the first voltage may cause the electrochromic device to operate in the dark state, blocking transmittance of visible radiation (e.g., at wavelengths of around 400-780 nm) and NIR radiation at wavelengths of around 780-1200 nm. In another example, application of a third voltage having a positive bias may cause the electrochromic device to operate in the bright state, allowing transmittance of radiation in both the visible and NIR spectral regions. In various embodiments, the applied voltage may be between -5V and 5V, preferably between -2V and 2V. For example, the first voltage may be -0.25V to -0.75V, and the second voltage may be -IV to -2V. In another example, the absorbance of radiation at a wavelength of 800- 1500 nm by the electrochromic device may be at least 50% greater than its absorbance of radiation at a wavelength of 450-600 nm.

[0029] Alternatively, the nanostructure 112 and optional nanostructure 113 of the working electrode may modulate transmittance of NIR and visible radiation as a function of applied voltage by operating in two different modes. For example, a first mode may be a highly solar transparent ("bright") mode in which the working electrode 104 is transparent to NIR radiation and visible light radiation. A second mode may be a visible blocking ("dark") mode in which the working electrode 104 absorbs radiation in the visible spectral region and at least a portion of the NIR spectral region. In an example, application of a first voltage having a negative bias may cause the electrochromic device to operate in the dark mode, blocking

transmittance of visible and NIR radiation at wavelengths of around 780-2500 nm. In another example, application of a second voltage having a positive bias may cause the electrochromic device to operate in the bright mode, allowing transmittance of radiation in both the visible and NIR spectral regions. In various embodiments, the applied voltage may be between -2V and 2V. For example, the first voltage may be -2V, and the second voltage may be 2V.

[0030] In various embodiments, the solid state electrolyte 106 may include at least a polymer material and a plasticizer material, such that electrolyte may permeate into crevices between the transition metal oxide bronze nanoparticles 112 (and/or nanoparticles 113 if present). The term "solid state," as used herein with respect to the electrolyte 106, refers to a polymer-gel and/or any other non-liquid material. In some embodiments, the solid state electrolyte 106 may further include a salt containing, for example, an ion species selected from the group of lanthanides (e.g., cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, and lutetium), alkali metals (e.g., lithium, sodium, potassium, rubidium, and cesium), and alkali earth metals (e.g., beryllium, magnesium, calcium, strontium, and barium). In an example embodiment, such salt in the solid state electrolyte 106 may contain a lithium and/or sodium ions. In some embodiments, the solid state electrolyte 106 may initially contain a solvent, such as butanol, which may be evaporated off once the electrochromic device is assembled. In some embodiments, the solid state electrolyte 106 may be around 40-60 wt% plasticizer material, preferably around 50-55 wt% plasticizer material. In an embodiment, the plasticizer material may include at least one of tetraglyme and an alkyl hydroperoxide. In an embodiment, the polymer material of the solid state electrolyte 106 may be polyvinylbutyral (PVB), and the salt may be lithium bis(trifluoromethane). In other embodiments, the solid state electrolyte 106 may include at least one of lithium phosphorus oxynitride (LiPON) and tantalum pentoxide (Ta ₂ O ₅ ).

[0031] In some embodiments, the electrolyte 106 may include a sacrificial redox agent (SRA). Suitable classes of SRAs may include, but are not limited to, alcohols, nitrogen heterocycles, alkenes, and functionalized hydrobenzenes. Specific examples of suitable SRAs may include benzyl alcohol, 4-methylbenzyl alcohol, 4- methoxybenzyl alcohol, dimethylbenzyl alcohol (3,5-dimethylbenzyl alcohol, 2,4- dimethylbenzyl alcohol etc.), other substituted benzyl alcohols, indoline, 1,2,3,4- tetrahydrocarbazole, Ν,Ν-dimethylaniline, 2,5-dihydroanisole, etc. In various embodiments, the SRA molecules may create an air stable layer that does not require an inert environment to maintain charge.

[0032] Polymers that may be part of the electrolyte 106 may include, but are not limited to, poly(methyl methacrylate) (PMMA), poly( vinyl butyral-co-vinyl alcohol- co- vinyl acetate) (PVB), poly (ethylene oxide) (PEO), fluorinated co-polymers such as poly(vinylidene fluoride-co-hexafluoropropylene), poly(acrylonitrile) (PAN), poly (vinyl alcohol) (PVA), etc. Plasticizers that may be part of the polymer electrolyte formulation include, but are not limited to, glymes (tetraglyme, triglyme, diglyme etc.), propylene carbonate, ethylene carbonate, ionic liquids (l-ethyl-3- methylimidazolium tetrafluoroborate, l-butyl-3-methylimidazolium

hexafluorophosphate, l-butyl-3-methylimidazolium bis(trifluoromethane sulfonyl) imide, 1 -butyl- 1 -methyl-pyrrolidinium bis(trifluoromethane sulfonyl)imide, etc.), Ν,Ν-dimethylacetamide, and mixtures thereof.

[0033] In some embodiments, the electrolyte 106 may include, by weight, 10-30% polymer, 40-80% plasticizer, 5-25% lithium salt, and 0.5-10% SRA.

[0034] The counter electrode 108 of the various embodiments should be capable of storing enough charge to sufficiently balance the charge needed to cause visible tinting to the nanostructured transition metal oxide bronze in the working electrode 104. In various embodiments, the counter electrode 108 may be formed as a conventional, single component film, a nanostructured film, or a nanocomposite layer. [0035] In some embodiments, the counter electrode 108 may be formed from at least one passive material that is optically transparent to both visible and NIR radiation during the applied biases. Examples of such passive counter electrode materials may include CeO ₂ , CeVO ₂ , TiO ₂ , indium tin oxide, indium oxide, tin oxide, manganese or antimony doped tin oxide, aluminum doped zinc oxide, zinc oxide, gallium zinc oxide, indium gallium zinc oxide, molybdenum doped indium oxide, Fe ₂ O3, and/or V ₂ Os In other embodiments the counter electrode 108 may be formed from at least one complementary material, which may be transparent to NIR radiation but which may be oxidized in response to application of a bias, thereby causing absorption of visible light radiation. Examples of such complementary counter electrode materials may include Cr ₂ O3, MnO ₂ , FeO ₂ , CoO ₂ , NiO ₂ , RhO ₂ , or IrO ₂ . The counter electrode materials may include a mixture of one or more passive materials and/or one or more complementary materials described above.

[0036] Without being bound to any particular theory, it is believed that the

application of a first voltage in the various embodiments may cause the interstitial dopant species (e.g., cesium) in the crystal structure of the transition metal oxide bronze to have a greater amount of free carrier electrons and/or to cause the interstitial dopant species (e.g., lithium ions from the electrolyte) to perform non-faradaic capacitive or pseudo-capacitive charge transfer on the surface of the nano structures 112, which may cause the surface plasmon resonance effect to increase the absorption of NIR radiation. In this manner, the absorption properties of the transition metal oxide bronze characteristics may change (i.e., increased absorption of NIR radiation) upon application of the first voltage. Further, application of a second voltage having a higher absolute value than the first voltage in the various embodiments may cause faradaic intercalation of an intercalation dopant species (e.g., lithium ions) from the electrolyte into the transition metal oxide nano structures. It is believed that the interaction of this dopant species provides interstitial dopant atoms in the lattice which creates a polaron effect. In this manner, the lattice structure of transition metal oxide nanoparticles may experience a polaron-type shift, thereby altering its absorption characteristics (i.e., shift to visible radiation) to block both visible and near infrared radiation.

[0037] In some embodiments, in response to radiation of certain spectral regions, such as UV (e.g., at wavelengths of around 10-400 nm) may cause excitons to be generated in the polymer material of the solid state electrolyte 106. The UV radiation may also excite electrons in the doped transition metal oxide bronze to move into the conduction band, leaving holes in the valence band. The generated excitons in the polymer material may dissociate to free carriers, the electrons of which may be attracted to the holes in the valence band in the doped transition metal oxide bronze (e.g., cesium-doped tungsten trioxide (Cs _x WO ₃ )) of nanoparticles 112. Since electrochemical reduction of various transition metal oxide bronzes by such free electron charge carriers may degrade their performance (i.e., from unwanted coloration of the transition metal oxide bronze), embodiment devices may include one or more layer of a protective material to prevent UV radiation from reaching the solid state electrolyte 106, in addition to or instead of nanostructures 113 mixed into the working electrode.

[0038] FIG. IB illustrates an embodiment electrochromic device 150 that addresses degradation of the doped transition metal oxide bronze nanostructures 112. Similar to device 100 shown in FIG. 1A, device 150 may include a first transparent conductor layer 102a, a working electrode 104, a solid state electrolyte 106, a counter electrode 108, a second transparent conductor layer 102b, and first and/or second light transmissive substrates 110a, 110b. In addition, device 150 may include one or more protective layers 116a, 116b made of a material that absorbs UV radiation. In an example embodiment, the device 150 may include a first protective layer 116a disposed between the first substrate 110a and the first transparent conductor layer 102a. The device may optionally include a second protective layer 116b disposed between the second substrate 110b and the second transparent conductor layer 102b. Alternatively, the UV protective layer 116a may be disposed on the outer surface of the first substrate 110a, or may be disposed between the first transparent conductor 102a and the working electrode 104. In other words, the first and/or second UV protective layers 116a, 116b may be disposed between any of the layers of the electrochromic device 150, such that UV radiation is substantially prevented from reaching the working electrode 104.

[0039] The UV radiation absorbing material of the protective layers 116a, 116b of the various embodiments may be any of a number of barrier films. For example, the first protective layer 116a may be a thin film of at least one TCO material, which may include a same as or different from TCO compositions in the nanostructures 113. In an example embodiment, the first protective layer 116a of the device 150 may be an ITO thin film, and therefore capable of absorbing UV radiation by band-to-band absorption (i.e., absorption of a UV photon providing enough energy to excite an electron from the valence band to the conduction band). In another example embodiment, the device may include the TCO nanostructures 113 made of ITO, as well as the first protective layer 116a composed of an ITO thin film. Alternatively, the TCO nanostructures 113 may be in the form of the separate second protective layer 116b disposed between the transition metal oxide bronze nanoparticles 112 and the transparent conductor 102a. In some embodiments, the UV radiation absorbing materials of protective layers 116a, 116b may include organic or inorganic laminates.

[0040] In another embodiment, at least one UV protective layer, such as protective layer 116a in FIG. IB, may be a UV radiation reflector made of a high index transparent metal oxide. Since birds can see radiation in the UV range, a UV reflector may be implemented in embodiments positioned as outside windows in order to prevent birds from hitting the windows. In some other embodiments, UV radiation absorbing organic molecules and/or inorganic UV radiation absorbing nanoparticles (e.g., zinc oxide, indium oxide, ITO, etc.) may be incorporated within the electrolyte 106 material.

[0041] FIG. 1C illustrates another embodiment electrochromic device 170 that addresses degradation of the doped transition metal oxide bronze nanostructures 112 by controlling the effects of the electron charge carriers generated in the electrolyte from exposure to UV radiation. Similar to devices 100 and 150 discussed above with respect to FIGS. 1 A and IB respectively, device 170 may include a first transparent conductor layer 102a, a working electrode 104, a solid state electrolyte 106, a counter electrode 108, a second transparent conductor layer 102b, and first and/or second light transmissive substrates 110a, 110b. In addition, device 170 may include a protective layer 118 positioned between the working electrode 104 and the electrolyte 106. The protective layer 118 may be composed of one or more ionically conductive and electrically insulating material.

[0042] As discussed above, without being bound to any particular theory, it is believed that the migration of intercalation ions between the electrolyte 106 and the working electrode 104 is responsible for at least some of the device's capability to modulate spectral absorption. Therefore, in order to maintain operability of the device, the electrically insulating material used to form the protective layer 118 should also be ionically conductive. That is, the material of the protective layer 118 may prevent or reduce free electrons in the solid state electrolyte 106 from reducing the transition oxide bronze of nanoparticles 112, while allowing the diffusion of ions of an intercalation dopant species (e.g., Na, Li, etc.) between the electrolyte 106 and working electrode 104. In an example embodiment, the electrically insulating material that makes up the protective layer 118 may be tantalum oxide, such as tantalum pentoxide (Ta ₂ O ₅ ), which blocks migration of electrons from the electrolyte 106 while allowing diffusion of the intercalation dopant species ions (e.g., lithium ions) from the electrolyte 106. In this manner, degradation of the transition metal oxide bronze is reduced or prevented by controlling the effect of the absorbed UV radiation in addition to or instead of instead of blocking its absorption. Other example materials that may be used to form the protective layer 118 in addition to or instead of tantalum pentoxide may include, without limitation, strontium titanate (SrTiO ₃ ), zirconium dioxide (ZrO ₂ ), indium oxide, zinc oxide, tantalum carbide, niobium oxide, and various other dielectric ceramics having similar electrical and/or crystalline properties to tantalum pentoxide.

[0043] In an alternative embodiment, instead of or in addition to the protective layer 118, the nanostructures 112 may each be encapsulated in a shell containing an electrically insulating and ionically conductive material, which may be the same as or different from the material of the protective layer 118 (e.g., tantalum oxide, strontium titanate, zinc oxide, indium oxide, zirconium oxide, tantalum carbide, or niobium oxide).

[0044] In an example embodiment, each nanostructure 112 may have a core of cubic or hexagonal unit cell lattice structure tungsten bronze, surrounded by a shell of tantalum pentoxide.

[0045] In some embodiments, the electrolyte 106 may include a polymer that reduces damage to the device due to UV radiation. The polymer may be any of a number of polymers that are stable upon absorption of UV radiation (e.g., no creation of proton/electron pairs). Examples of such polymers may include, but are not limited to, fluorinated polymers without hydroxyl (-OH) groups (e.g., polyvinylidene difluoride (PVDF)).

[0046] In another embodiment, a positive bias may be applied to the counter electrode 108 to draw UV radiation generated electrons from the electrolyte 106 to the counter electrode 108 in order to reduce or prevent electrons from the electrolyte 106 from moving to the working electrode 104 to avoid the free electron-caused coloration of the doped transition metal oxide bronze in the working electrode 104.

[0047] In another embodiment, a device may include more than one of, such as any two of, any three of, or all four of: (i) a protective layer of electrically insulating material (e.g., protective layer 118 or protective material shells around the bronze nanoparticles), (ii) one or more protective layer of UV radiation absorbing material (e.g., protective layer(s) 116a and/or 116b in FIG. IB and/or UV radiation absorbing organic molecules and/or inorganic UV radiation absorbing nanoparticles incorporated within the electrolyte 106 material), (iii) electrolyte polymer that is stable upon absorption of UV radiation, and/or (iv) application of positive bias to the counter electrode 108. In various embodiments, the nano structures 113 may be included in or omitted from electrochromic devices 150, 170. [0048] In another embodiment, the protective layer(s) 116a and/or 116b may comprise a stack of metal oxide layers. Alternatively, the stack may comprise a separate component that is provided instead of or in addition to the layer(s) 116a and/or 116b. The stack may provide improvement in the reflected color of the electrochromic device. Prior art devices generally have a reddish/purplish color when viewed in reflection. The stack may comprise index-matched layers between the glass and transparent conductive oxide layer to avoid the reddish/purplish reflected color. As noted above, the index-matched layer can serve as the UV absorber or be used in addition to another UV absorber. The stack may comprise a zinc oxide based layer (e.g., ZnO or AZO) beneath an indium oxide based layer (e.g., indium oxide or ITO).

[0049] Compared to nanocomposite electrochromic films, the various embodiments may involve similar production by utilizing a single nano structured material in the working electrode to achieve the desired spectral absorption control in both NIR and visible regions, and another nano structured material to enhance and expand such control in the NIR region. Further, the various embodiments may provide one or more additional layer(s) of a protective material to minimize degradation of the single nano structured material.

[0050] In some embodiments, the working electrode and/or the counter electrode may additionally include at least one material, such as an amorphous nano structured material, that enhances spectral absorption in the lower wavelength range of the visible region. In some embodiments, the at least one amorphous nanostructured material may be at least one nanostructured amorphous transition metal oxide.

[0051] In particular, the amorphous nanostructured materials may provide color balancing to the visible light absorption that may occur due to the polaron-type shift in the spectral absorption of the doped-transition metal oxide bronze. As discussed above, upon application of the second voltage having a higher absolute value, the transition metal oxide bronze may block (i.e., absorb) radiation in the visible range. In various embodiments, the absorbed visible radiation may have wavelengths in the upper visible wavelength range (e.g., 500-700 nm), which may cause the darkened layer to appear blue/violet corresponding to the un-absorbed lower visible wavelength range (e.g., around 400-500 nm). In various embodiments, upon application of the second voltage, the at least one nano structured amorphous transition metal oxide may absorb complementary visible radiation in the lower visible wavelength range (e.g., 400-500 nm), thereby providing a more even and complete darkening across the visible spectrum with application of the second voltage. That is, use of the amorphous nano structured material may cause the darkened layer to appear black.

[0052] In some embodiments, at least one nano structured amorphous transition metal oxide may be included in the working electrode 104 in addition to the doped- transition metal oxide bronze nanostructures 112 and the optional TCO nanostructures 113. An example of such material in the working electrode 104 may be, but is not limited to, nano structured amorphous niobium oxide, such as niobium(II) monoxide (NbO) or other niobium oxide materials (e.g., NbO _x ). In some embodiments, the counter electrode 108 may include, as a complementary material, at least one nano structured amorphous transition metal oxide. That is, in addition to optically passive materials, the counter electrode 108 may include at least one material for color balancing (i.e., complementing) the visible radiation absorbed in the working electrode (i.e., by the transition metal oxide bronze. An example of such material in the counter electrode 108 may be, but is not limited to, nano structured amorphous nickel oxide, such as nickel(II) oxide (NiO) or other nickel oxide materials (e.g., NiO _x ).

[0053] In the various embodiments, nanostructures that form the working and/or counter electrode, including the at least one amorphous nano structured material, may be mixed together in a single layer. An example of a mixed layer is shown in FIG. 1 A with respect to transition metal oxide bronze nanostructures 112 and TCO

nanostructures 113. Alternatively, nanostructures that form the working and/or counter electrode, including the at least one amorphous nano structured material, may be separately layered according to composition. For example, a working electrode may include a layer of amorphous NbO _x nanostructures, a layer of transition metal oxide bronze nanostructures, and a layer of ITO nanostructures, in any of a number of orders. [0054] The nano structured transition metal oxide bronzes that may be part of the working electrode 104 in various embodiment devices can be formed using any of a number of low cost solution process methodologies. For example, solutions of Nb:TiO ₂ and Cs _x WO ₃ may be synthesized using colloidal techniques. Compared to other synthetic methodologies, colloidal synthesis may offer a large amount of control over the nanostructure size, shape, and composition of the nano structured transition metal oxide bronze. After deposition, a nano structured transition metal oxide bronze material in the working electrode 104 may be subjected to a thermal post treatment in air to remove and cap ligands on the surface of the nanostructures.

[0055] In various embodiments, nano structured amorphous transition metal oxide materials may be formed at room temperature from an emulsion and an ethoxide precursor. For example, procedures used to synthesize tantalum oxide nanoparticles that are described in "Large-scale synthesis of bioinert tantalum oxide nanoparticles for X-ray computed tomography imaging and bimodal image-guided sentinel lymph node mapping" by MH Oh et al. (J Am Chem Soc. 2011 Apr 13;133(14):5508-15), incorporated by reference herein, may be similarly used to synthesize amorphous transition metal oxide nanoparticles. For example, an overall synthetic process of creating the nanoparticle, as described in Oh et al., may adopted from the

microemulsion synthesis of silica nanoparticles. In such process, a mixture of cyclohexane, ethanol, surfactant, and a catalysis for the sol-gel reaction may be emulsified. The ethoxide precursor may be added to the emulsion, and uniform nanoparticles may be formed by a controlled- sol gel reaction in the reverse micelles at room temperature within around 5 minutes. The sol-gel reaction may be catalyzed, for example, by NaOH.

[0056] In some embodiments, the nano structured amorphous transition metal oxide may be sintered at a temperature of at least 400°C for at least 30 minutes, such as 400 to 600°C for 30 to 120 minutes to form a porous web. In an example embodiment, the porous web may be included in a working electrode 104, with the tungsten bronze nanoparticles and ITO nanoparticles incorporated in/on the web. Alternatively, the sintering step may be omitted and the nano structured amorphous transition metal oxide may remain in the device in the form of nanoparticles having amorphous structure. In this embodiment, the device containing the nano structured amorphous transition metal oxide may include or may omit the protective layer(s) 116a, 116b, and/or 118, the UV stable electrolyte polymer, and the application of positive bias to the counter electrode.

[0057] Electrochromic responses of prepared nano structured transition metal oxide bronze materials (e.g., Cs _x WO ₃ , Nb:TiO ₂ , etc.) may be demonstrated by spectro- electrochemical measurements.

[0058] In various embodiments, the shape, size, and doping levels of nano structured transition metal oxide bronzes may be tuned to further contribute to the spectral response by the device. For instance, the use of rod versus spherical nanostructures 112 may provide a wider level of porosity, which may enhance the switching kinetics. Further, a different range of dynamic plasmonic control may occur for nanostructures with multiple facets, such as at least 20 facets.

[0059] Various embodiments may also involve alternation of the nanostructures 112 that form the working electrode 104. For example, the nanostructures may be nanoparticles of various shapes, sizes and/or other characteristics that may influence the absorption of NIR and/or visible light radiation. In some embodiments, the nanostructures 112 may be isohedrons that have multiple facets, preferably at least 20 facets.

[0060] In some embodiments, the transition metal oxide bronze nanostructures 112 may be a combination of nanoparticles having a cubic unit cell crystal lattice ("cubic nanoparticles") and nanoparticles having a hexagonal unit cell crystal lattice

("hexagonal nanoparticles"). Each unit cell type nanoparticle contributes to the performance of the working electrode 104. For example, the working electrode 104 may include both cubic and hexagonal cesium doped tungsten oxide bronze

nanoparticles. In alternative embodiments, the working electrode 104 may include either cubic or hexagonal cesium doped tungsten oxide nanoparticles. For example, the working electrode 104 may include cubic cesium-doped tungsten oxide (e.g. Cs W _{2 6} -x) nanoparticles and amorphous niobium oxide nanoparticles or hexagonal cesium-doped tungsten oxide (e.g. nanoparticles without niobium oxide. In alternative embodiments, the working electrode 104 may include undoped tungsten oxide (e.g. WO ₃ _ _x ) nanoparticles where 0 < X < 0.1.

[0061] For example, upon application of the first (i.e., lower absolute value) voltage described above, the hexagonal bronze nanostructures 112 may block NIR radiation having wavelengths in the range of around 800-1700 nm, with the peak absorption at the mid- NIR wavelength of around 1100 nm. The cubic bronze nanostructures 112 may block NIR radiation having wavelengths in the close-NIR range with the peak absorption of around 890 nm. The indium oxide based (including ITO) and/or zinc oxide based (including AZO) nanostructures 113 may be included in the working electrode 104 to block the higher wavelength IR radiation upon application of the first voltage. Thus, the cubic bronze and hexagonal bronze nanostructures may block respective close and mid-NIR radiation (e.g., using the Plasmon effect), while the nanostructures 113 may block the higher wavelength IR radiation.

[0062] Upon application of the second (i.e., higher absolute value) voltage described above, the cubic bronze nanostructures 112 may block visible and NIR radiation having wavelengths in the range of around 500-1500 nm, with the peak absorption at the close-NIR wavelength of around 890 nm (e.g., using the polaron effect).

Optionally, the amorphous niobium oxide may also be added to the working electrode 104 to block the short wavelength visible radiation (e.g., 400 to 500 nm wavelength).

[0063] The cubic bronze nanostructures block visible radiation via the polaron effect at a lower applied voltage than the hexagonal bronze nanostructures. Thus, the second voltage may have an absolute value which is below the value at which the hexagonal bronze nanostructures block visible radiation via the polaron effect such that these nanostructures do not contribute to blocking of visible radiation. Alternatively, the second voltage may have an absolute value which is above the value at which the hexagonal bronze nanostructures block visible radiation via the polaron effect such that these nanostructures also contribute to blocking of visible radiation. [0064] Embodiment nanoparticles that form the working electrode 104 may be around 4-6 nm in diameter, and may include 40 to 70 wt%, such as around 50 wt% cubic tungsten bronze nanostructures, 15 to 35 wt%, such as around 25 wt%

hexagonal tungsten bronze nanostructures, and optionally 15 to 35 wt%, such as around 25 wt% ITO nanostructures. In some embodiments, in order to achieve color balancing as described above, the nanoparticles that form the working electrode 104 may optionally include around 5-10 wt% amorphous NbO _x nanostructures in place of cubic tungsten bronze nanostructures. In this embodiment, the device containing two types of bronze nanoparticles may include or may omit the protective layer(s) 116a, 116b, and 118, the UV stable electrolyte polymer, the application of positive bias to the counter electrode, and the amorphous niobium oxide.

[0065] In summary, the working electrode 104 may include one or more of the following components:

[0066] (a) metal oxide bronze nanostructures 112 having (i) a cubic, (ii) hexagonal, or (iii) a combination of cubic and hexagonal unit cell lattice structure;

[0067] (b) protective (i) indium oxide based (including ITO) and/or zinc oxide based (including AZO) nanostructures 113;

[0068] (c) amorphous niobium oxide nanoparticles and/or web; and/or

[0069] (d) additional nanostructures selected from undoped tungsten oxide, molybdenum oxide, titanium oxide, and/or vanadium oxide.

[0070] The counter electrode 108 may include one or more of the following components:

[0071] (a) passive electrode material selected from cerium(IV) oxide (CeO ₂ ), titanium dioxide (TiO ₂ ), cerium(III) vanadate (CeVO ₂ ), indium(III) oxide (In ₂ O ₃ ), tin- doped indium oxide, tin(II) oxide (SnO ₂ ), manganese-doped tin oxide, antimony- doped tin oxide, zinc oxide (ZnO), aluminum- doped zinc oxide (AZO), iron(III) oxide (Fe ₂ O ₃ ), and vanadium(V) oxide (V ₂ O ₅ ); [0072] (b) an active electrode material selected from chromium(III) oxide (Cr ₂ O ₃ ), manganese dioxide (MnO ₂ ), iron(II) oxide (FeO), cobalt oxide (CoO), nickel(II) oxide (NiO), rhodium(IV) oxide (Rh0 ₂ ), and iridium(IV) oxide (IrO ₂ );

[0073] (c) amorphous nickel oxide nanoparticles and/or web; and/or

[0074] (d) conductivity enhancer nanoparticles selected from indium oxide, ITO, and zinc oxide.

[0075] While the various embodiments are described with respect to electrochromic windows, the embodiment methods, systems, and devices may also be used in materials for other types of smart windows. Such smart windows may include, but are not limited to, polymer-dispersed liquid crystals (PLDD), liquid crystal displays (LCDs), thermochromics, etc.

[0076] FIG. 2A illustrates a schematic view of an electrochromic device 200A, according to various embodiments of the present disclosure. The electrochromic device 200 is similar to the electrochromic device 100 of FIG. 1 A, so only the differences therebetween will be discussed in detail.

[0077] Referring to FIG. 2A, in contrast to the electrochromic device 100, the electrochromic device 200A includes a distributed Bragg reflector 111 ("Bragg reflector" hereinafter) disposed between a light transmissive first substrate 110a (e.g., a glass substrate), and the transparent conductor 102a. The Bragg reflector 111 is configured to selectively reflect UV radiation (e.g., radiation having a wavelength of less than about 400 nm, such as a wavelength ranging from about 100 to about 400 nm) from light transmitted through the first substrate 110a, away from the working electrode 104. The Bragg reflector 111 is also configured to transmit visible light there through. In this embodiment, the first substrate 110a may be configured in a window to receive outdoor light such as sunlight. For example, the first substrate 110a may be an outer window pane (e.g., a glass window pane facing outside of a vehicle or a structure, such as a building, in which the electrochromic device 200A is installed), and a light transmissive second substrate 110b may be an inner middle window pane (e.g., a glass window pane facing inside of the vehicle or structure in which the electrochromic device 200 A is installed). Accordingly, the electrochromic device 200 A may be configured as a dual pane or multi-pane electrochromic window.

[0078] FIG. 2B illustrates a schematic view of an electrochromic device 200B, according to various embodiments of the present disclosure. The electrochromic device 200B is similar to the electrochromic device 200A of FIG. 1 A, so only the differences therebetween will be discussed in detail.

[0079] Referring to FIG 2B, in contrast to the electrochromic device 200 A, the electrochromic device 200B is configured to receive outdoor light (e.g., sunlight) through a light transmissive second substrate 110b (e.g., a glass substrate).

Accordingly, the electrochromic device 200B includes a distributed Bragg reflector 111 that is disposed between the second substrate 110b and the transparent conductor 102b (e.g., the second substratel 10b may be an outer pane of a multi-pane

electrochromic window, with the first substrate 110a being a middle pane thereof).

[0080] Utilizing a single Bragg reflector 111 provides benefits in terms of reduced costs. In general, the Bragg reflector 111 is preferably located between one of the substrates (e.g., an outer window pane) and the rest of the electrochromic device (e.g., the nearest electrode to the outer window pane). As compared to the electrochromic device 200A, the configuration of the electrochromic device 200B provides a longer path length for UV radiation to travel to the working electrode 104.

[0081] FIG. 2C illustrates a schematic view of an electrochromic device 200C, according to various embodiments of the present disclosure. The electrochromic device 200C is similar to the electrochromic device 200A of FIG. 1 A, so only the differences therebetween will be discussed in detail.

[0082] Referring to FIG. 2C, the electrochromic device 200C may include a first Bragg reflector 111a disposed on the first substrate 110a and a second Bragg reflector 111b disposed on the second substrate 110b. The use of the two Bragg reflectors 111a, 111b operates to improve blocking of reflected UV radiation. [0083] FIG. 2D is a top schematic view of an electrochromic window 250, according to various embodiments of the present disclosure. Referring to FIG. 2D, the window 250 includes one of the electrochromic devices 200A, 200B, 200C an inner pane 260, and a frame 270. The frame 270 maintains a gap 280 between the electrochromic device 200A/200B and the inner pane 260. The gap 280 may be maintained at below atmospheric pressure, may be filled with air, or may be filled with argon. The inner pane 260 may be disposed inside of a structure in which the window 250 is mounted, and the electrochromic device 200A/200B may be disposed on the outside of the structure. The inner pane 260 may be formed of glass or plastic and may be coated with a low-emissivity coating.

[0084] FIG. 3 is a side view of the Bragg reflector 111 of FIGS. 2A, 2B or 2C.

Referring to FIG. 3, the Bragg reflector 111 includes an alternating stack of first layers 115 and second layers 117. The Bragg reflector 111 may include any suitable number of the first and second layers 115, 117. For example, the Bragg reflector 111 may include from, for example, 10 to 21 total layers, depending on the materials included in the layers 115, 117.

[0085] The first and second layers 115, 117 may be formed of materials that have different refractive indexes. For example, the first and second layers 115, 117 may be formed of different ones of TiO ₂ , SiO ₂ , ZnO _x , ZnAlO _x , and ZnSnO _x layers.

According to some embodiments, the first and second layers 115, 117 may be formed of different ones of TiO ₂ and SiO ₂ layers, respectively. The optical thickness of the first and second layers 115, 117 may be approximately four times the wavelength of UV radiation, in order to produce constructive interference and reflection of the UV radiation.

[0086] When operating the electrochromic device in a bright mode, the

electrochromic device transmits at least 50% of received visible light, and when operating the electrochromic device in a dark mode, the electrochromic device transmits 5% or less of received visible light. In both bright and dark modes, the Bragg reflector 111 selectively reflects a majority (e.g., at least 50%) of UV radiation incident thereto and transmits a majority (e.g., at least 50%) of received visible light incident thereto. The Bragg reflector 111 may transmit from about 75 to about 99% of visible light incident thereto, such as about 85 to about 95% of visible light incident thereto. The Bragg reflector may reflect from about 75 to about 99% of UV radiation incident thereto, such as from about 85 to about 95% of received UV radiation incident thereto.

[0087] The foregoing description of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and modifications and variations are possible in light of the above teachings or may be acquired from practice of the invention. The

description was chosen in order to explain the principles of the invention and its practical application. It is intended that the scope of the invention be defined by the claims appended hereto, and their equivalents.