| JP6897834 | Fluoropolyether group-containing compound |
| WO/1998/033854 | NEW COMPOSITION AND TREATING AGENT |
| JP3794507 | HIGH WATER REPELLENT AND OIL REPELLENT BN POWDER |
BREWER STUART ANSON (GB)
WILLIS COLIN ROBERT (GB)
BREWER STUART ANSON (GB)
| WO1992018332A1 | 1992-10-29 | |||
| WO1995024976A1 | 1995-09-21 |
| GB2291439A | 1996-01-24 | |||
| US4507324A | 1985-03-26 | |||
| US4032495A | 1977-06-28 | |||
| EP0221046A2 | 1987-05-06 |
| 1. | A polymer for the treatment of materials, characterised by a plurality of side groups of general formula AAz, where: A = (CH2)n, wherein non adjacent CH2 groups may be replaced by O, C02, OCO. OC02, or phenylene and n may have any integral value from 0 to 16; and Az is selected from: (CH2)n S°. |
| 2. | 6H5 •YCHBrCH2Br YC=CH2 and YCH=CH, Br where X,, X2 etc are independently selected from halogen, NHR. SO2CH3, Alkyl, Aryl, O Alkyl or OAryl and at least one of X,, X2 etc per group Az is halogen; Y = NH, NR (R=Alkyl), NHCO, O, or S and Z = SO2NH or SO2 2 The polymer of claim 1 and further containing fluorine bearing side groups. |
| 3. | The polymer of claim 2, containing side groups bearing Rf where:. |
| 4. | The polymer of claim 3. containing the side group CO2Rf. |
| 5. | The polymer of claim 4 having the repeat unit:. |
| 6. | A material characterised by treatment with a polymer as described in claim 1. |
| 7. | A method of treating a material characterised by the use of an aqueous formulation ofthe polymer described in claim 1. |
The present invention relates to a group of polymers suitable for binding to cellulose or woollen based material and is useful for the treatment of cloth, linen fabric and the like.
The durability of certain functional treatments (e.g. water or oil repellency) on cellulose based fabrics can by improved by the addition of cross-linkable resins to their formulations. Depending on the type of resin employed, fixation to the cloth may occur under acidic conditions (eg with dimethyloldihydroxyethylene urea) or under neutral conditions (eg with a blocked polyisocyanate).
The use of certain groups, for example triazines. to bind molecules to cellulose based, and other, materials is known from the chemistry of reactive dyes. For example, the 2,4- dichloro-6-aminotriazyl group is used to bind a family of dyes, known commercially as Procion dyes, to cellulose materials (see for example, The Chemistry of Synthetic Dyes, Vol. IV - Reactive Dyes. K Venkataraman Ed.. Academic Press.).
The use of fluoroalkyl compounds to improve the oil and water repellency of articles is described, for example, in GB 1,102.903. These compounds are non-polymeric and the invention described therein requires the use of organic solvents whereas the current invention may be carried out in aqueous solvents.
Whilst resin treatments can improve the durability of certain finishes and impart dimensional stability and durable press properties to fabrics, the acid catalysts required to bring about the cross-linking reactions can damage acid sensitive cloth such as cotton. Moreover, excessive cross-linking can also lead to a reduction in abrasion resistance (see for example Textile Chemist and Colorist. 1995. Vol. 27. page 17. R J Harper and Melliand Textilber.. 1986. Vol. 67. p.E61-5. J. Hearle). Problems also arise with resins that contain formaldehyde and this has prompted considerable research into the development of cross linking agents that do not contain this compound (see for example Textile Res. J.. 1994. Vol.64. page247. N. R. Bertoniere et al).
According to this invention, a polymer for the treatment of materials is characterised by a plurality of side groups of general formula -A-Az, where:
A = (CH 2 )n, wherein non adjacent CH 2 groups may be replaced bv O, C0 2 , OCO OC0 2 , or phenylene and n may have any integral value from.O to.fό, and Az is selected from:
-Y- (CH, ■ SO,C 6,H 5 -YCHBrCH.Br
■ Y-C=CH 2 and -Y-CH=CH 2
Br
where X,. X : etc are independently selected from halogen. -NHR. -SO 2 CH 3 , Alkyl. Aryl, - O- Alkyl or -O-Aryl and at least one of X,, X 2 etc per group Az is halogen: Y - -NH-, -NR- (R=Alkyl), -NHCO-. -0-. or -S- and Z = -S0 2 NH- or -SO : -
In a preferred embodiment, the polymer also contains fluorine bearing side groups.
In a further preferred embodiment, the polymer also contains side groups bearing R f where:
In a further preferred embodiment, the polymer contains the side group -CO 2 R f .
In a further preferred embodiment the polymer has the repeat unit:
According to a second aspect ofthe invention. a material is provided with improved physical properties by virtue of treatment of said material with the polymer of the first aspect ofthe invention.
According to a third aspect of the invention, a method is provided of treating a material with the polymer ofthe first aspect ofthe invention. Preferrably the material is treated in an aqueous solution.
Durability of the polymers may be further improved by the addition of polyhydric alcohols.
The invention will now be described, by way of non-limiting example, with reference to figures 1 which shows the reaction scheme during the production of a polymer used in a particular embodiment ofthe invention. Although the following example relates to the treatment of fabrics to improve their oil and water repellent properties, this should not be seen as limiting. The invention may be used inother situations where treatment of material with a polymer may improve physical properties eg. abrasion resistance or fire retardance.
EXPE TlvTFNTAI-
Referring to figure 1, a solution of 1250 parts surfactant FC 126 (available from Fluorochem Ltd.) in 60000 parts distilled water was added to a stirred solution containing 1050 parts 2,4- dichloro-6-(N-(2-acrylyl)ethylamino)-s-triazine 1, 22500 parts 2-(N- ethylperfluorooctylsulphonamicle)ethyl acrylate 2. and 125 parts octanethiol (C 8 H [7 SH) in acetone. The mixture was deaerated with argon and then warmed to 55°C before addition of 125 parts potassium persulphate. The temperature was increased to 65 °C and stirring maintained under a blanket of argon for 20 hours. The resulting dispersion of polymer 3 was allowed to cool, filtered and stored (total solids content = 20%).
Treatment of Cotton Fabrics using Formulation of Polymer 3.
Sample A: The formulation of polymer 3 obtained from the above experimental procedure was diluted to 30g/litre with a 7.5% w/v sodium carbonate solution. The cotton fabric was immersed in this solution, pad mangled to a 150% wet pick-up. and cured at 150°C for 10 minutes.
Sample B: Cotton fabric was treated in an identical manner to that described for sample A, except that the polymer formulation was diluted with distilled water rather than sodium carbonate solution.
Prior to repellency tests and laundering, the cloth samples were washed with detergent (Tepol, TM) and rinsed with water. Repellency rating are in accordance with AATCC Test Method 118 - 1978, (see AATCC Technical Manual 55, p242 (1979)). Tables 1 and 2 show the results of oil (O) and water (W) repellancy tests carried out on samples A and B.
Table 1.
Sample A Sample B
Initial 05 W5 05 W5
5hr Soxhlet with 05 W5 02 W4 trichloroethylene
3hr Soxhlet with 04 W-4 O3 W3 benzotri fluoride
Sample A Sample B
Initial 05 W5 O5 5
1 Omin boil 05 W5 02 W3
1 Omin boil 05 W5 W
20min boil 04 W4 W
45min boil 04 W4
Tables 1 and 2 show that a more durable oil and water repellent finish results when base is included in the formulation. This is consistent with reaction between cellulosate anions in the cotton (formed by reaction of hydroxyl groups with the base) and the fibre reactive groupings on the polymer.