This invention relates to a process for manufacturing a fire protection element having a layer structure, which element comprises at least two mineral wool layers in the form of slabs between which is arranged at least one inorganic material layer, which liberates water or carbon dioxide under the influence of heat, or which in some other way has a fire retarding effect.

This invention also relates to a fire protection element having a layer structure, which element comprises at least two mineral wool layers in the form of slabs and at least one intermediate layer of inorganic material.

This invention further relates to a fire protection element manufactured according to the process according to the invention.

The present invention also relates to use of an inorganic fire retardant such as gypsum, which dries up by itself, as an essential binder between mineral wool slabs in fire protection elements essentially consisting of mineral wool slabs, as well as use of a fire protection element according to any of the claims 11-16 or a fire protection element manufactured according to any of the claims 1-10 for buildings or equipment in buildings of all kinds.

It is previously known to use mineral wool in fire protection slabs. The reason for this are the good fire protection properties of the mineral wool itself. It is also known to e.g. between two layers of mineral wool such as stone wool arrange an inorganic material layer, consisting of a dehydrating hydroxide as a fire retardant in combination with a binder, which is to bind the mineral wool slabs together. Such solutions are described for example in prior art in publications EP 1239093 A2, EP 0741003 Bl, EP 0485867 Bl and EP 0353540 B2.

In EP 1239093 A2 is presented a fire protection element, essentially consisting of two mineral wool layers preferably stone wool layers as well as at least one intermediate layer consisting of a gypsum plate, which by way of glue is fixed between the mineral wool layers.

In EP 0741003 Bl is described on the other hand the use of one or several intermediate layers comprising an inorganic material in the form of a semi-finished product which may be manufactured by applying the inorganic material in viscous form on a glass fabric, or between two glass fabrics, in order to then be processed into a plate before it is arranged between the mineral wool layers. The inorganic layer may consist of a mixture of a water liberating hydroxide, such as aluminium hydroxide, and a binder comprising water glass, silica sol or magnesium.

In EP 0353540 B2 is presented a mainly inorganic layer between mineral wool slabs which comprises a water liberating hydroxide other than kaoline and a binder such that the hydroxide is added in at least two fractions having different grain size. As a binder is mentioned silica sol or dissolved water glass. In EP 0485867 Bl is on the other hand described the use of an exothermically curing magnesium binder and a dehydrating hydroxide such as aluminium hydroxide in the inorganic layer between the mineral wool slabs.

These known solutions are as such working, but common for them all is that the manufacturing process comprises unnecessarily many and costly non automatic steps such as manufacturing and gluing of plates of inorganic fire retardant be- tween the mineral wool slabs or the need of supplied drying energy for the purpose of forming a solid inorganic fire retarding layer between the mineral wool slabs.

Another problem is that there for applications where fire protection elements made of thin mineral wool slabs would be needed not really does exist any proper fire protection elements having a low water liberation temperature, i.e. having a fire protection which does not allow the temperature to rise too high before the fire protection element's fire retarding effect is initiated.

However, the inventors of this invention have now found a seemingly astonishingly simple solution to the problems mentioned above. The fact that nobody despite a not totally neglisable amount of patents/patent applications within this field has come up with this solution is however a proof for that the solution has not been obvious to the person skilled in the art.

The purpose of this invention is thereby to accomplish a fire protection element and a process for manufacturing thereof, whereby the above stated problems in the prior art can be avoided.

For accomplishing this, the process according to the invention is characterised by the following steps: a) at least one of two mineral wool slabs which are to be attached to each other is coated on one side with an inorganic fire retardant in the form of an aqueous suspension or paste, whereafter b) the mineral wool slabs are pressed against each other, so that a layer of the in- organic fire retardant is formed between them, whereby the mineral wool slabs are glued together by the inorganic fire retardant upon its drying.

The fire retardant according to the invention is preferably gypsum, which is applied in the form of an aqueous paste, having suitable binding and fire protection proper- ties. As fire retardant may also be used water glass according to the above. Also other fire retardants such as aluminium, or magnesium hydroxide, calcium or magnesium carbonate with a small addition e.g. 0-5 % of an organic binder may be used.

The mineral wool slabs are of the same thickness if the manufacturing is performed continuously in the line production, but the same principle may also be used after the line production and then they may also be of different thickness.

In an especially preferable embodiment the process according to the invention in continuous line production is characterised by first coating the cured mineral wool mat with a paste of gypsum, or alternatively with a paste of water glass, and then dividing the mineral wool mat in equally sized parts, which thereafter are piled on top of each other in such a manner that the uppermost part is simultaneously turned 180° so that the gypsum layer is positioned between the mineral wool. This gypsum layer will therefore become twice as thick as the coating. The number of gypsum layers in the final product will be one less than the number of parts which the mineral wool mat is divided into. The uppermost layer which is twice as thick as the others if several layers are made is therefore a more effective fire protection. The slab is installed in constructions so that this layer is placed so that it will be closest to that side which is intended to be protected against high temperatures at

the occasion of a fire (as far as possible from the fire). Then the effect of this layer will be used to its maximum, without the gypsum being on the outside.

Preferably the gypsum-coated mineral wool mat is divided into at least two, still more preferably into three equally sized parts with respect to the length and/or width, preferably the length and the width. Since the gypsum as such works as a binder (is applied in paste form) it may dry by itself at room temperature without any supplied drying energy and without any addition of any additional binders. This may take place for instance in a warehouse and/or in the packaging. This means that the production process becomes faster as well as cheaper in expenses, since the product does not need to be dried in a separate drying step. A small amount of binder (0 - 5 %, preferably < 2 %) may of course be added if higher requirements on tensile strength are needed. The mineral wool which is used in this invention is preferably stone wool but also other types of mineral wool such as slag wool or glass wool can be used.

Since in this invention gypsum is used as fire retardant, this means that using this invention one obtains an improved fire protection at lower temperatures than with other generally used fire retardants such as aluminium, or magnesium hydroxide, calcium or magnesium carbonate and the like. With gypsum the water liberation occurs already at just above 100 ⁰ C. Manufacturing a fire protection slab containing gypsum requires that the gypsum is added after the curing of the mineral wool mat, since the curing temperature normally is about 200 ⁰ C. Gypsum has therefore according to prior art been added in after-treatment, and one problem has been to get the gypsum integrated into the mineral wool. With the present invention even this problem may now be avoided.

The gypsum used for carrying out the invention may for example be untreated waste gypsum, possibly containing a small addition of glue (0 - 5 %, preferably 2 %) if so desired, which means less stress on the environment and lower raw material costs.

With the purpose of avoiding the problems in prior art, which have been presented above, the fire protection element according to the invention is characterised by

that the fire protection element essentially consists of mineral wool slabs glued together by means of intermediate layers of an inorganic fire retardant.

By using the present invention a simpler, cheaper and shorter manufacturing proc- ess for producing fire protection elements of mineral wool is therefore obtained, but first and foremost the process according to the invention enables production of thinner fire protection elements with an unchanged fire classification e.g. for HPAC- installations.

The benefit of having the fire protection material in two layers and the mineral wool in three layers is shown in the subsequent diagrams 1 and 2 where one test without, three with one layer in different positions, and one with two layers are compared. The position of the layer also has a significance.

The preferable embodiments of the fire protection element according to the invention is characterised by that which is said in the dependent product claims hereinafter.

In the following the invention is described in more detail by means of the following drawings and examples which by no manner of means should be interpreted in such a way that they could limit the scope defined by the claims.

List of drawings:

Figure Ia is a perspective of a mineral wool slab coated with an inorganic layer prior to dividing into several equally sized parts for gluing together of the parts,

Figure Ib is a perspective of a fire element according to the invention consisting of two mineral wool slabs glued together by means of one inorganic layer,

Figure 2 is a perspective of a fire element according to the invention consisting of three mineral wool slabs glued together by means of two inorganic layers,

Figure 3 is a schematic picture of the dividing of the mineral wool mat into parts according to the process of the invention

Figure 4 is a graph where the fire protection's length in minutes for an intermediate layer being made of different materials are compared with each other

Figure 5 is a graph where the fire protection's length in minutes for one or two intermediate layers of gypsum and different positions of the layers are compared.

Example 1. Automated manufacturing of a fire protection element 1 having a mineral wool/gypsum/mineral wool structure is performed on an automatic production line according to the following:

a) one side of an already cured mineral wool slab or mat 2 e.g. having width and length dimensions of 600x2400 mm and a thickness of about 20 mm, which mat's 2 edges have been cut off, is coated with an about 0.5 mm thick layer 3 of a water based suspension or paste of gypsum, which possibly contains a. small amount (0 - 5 %) of glue (e.g. any organic glue typical for the person skilled in the art), preferably < 2 %, b) the coated mineral wool mat 2 is cut on the production line in lengthwise direction so that two equally sized slabs are formed, whereafter c) the mineral wool slabs 2a and 2b are pressed against each other, so that a "double" gypsum layer 3 is formed between them, whereby the mineral wool slabs 2a and 2b are glued together by the gypsum when it dries. When the gypsum has dried is in other words obtained a fire protection element having the dimensions 600x1200 mm and a thickness of about 41 mm. Steps a, b, and c are preferably performed directly on the line directly after the curing oven and the cooling. The cooling which normally is needed is adjusted so that mineral wool has an appropriate temperature for drying of the "double" layer 3 of gypsum paste without deterioration of the gluing effect. The cutting of the mineral wool slab 2 and the turning of the slabs 2a and 2b is performed automatically.

In figure 4 is shown the results from tests which simulate fire, which follows the fire curve in EN 1363-1, in a ventilation channel where the mineral wool is on the outside of a channel made of sheet metal and the fire occurs inside the channel. In figure 4 the time dependent temperature rise, in other words the fire retarding ef- feet, of a fire protection element 1 manufactured according to example 1 is compared with an element having the same dimensions on the mineral wool slabs but lacking intermediate inorganic layers and an element having the same dimensions but where the inorganic layer consists of water glass. Figure 1 shows that the most fire retarding element of these three is the element having gypsum according to example 1.

The time which the fire sheet protects is prolonged significantly if the fire protection slabs has a layer comprising gypsum in the middle. The time until the allowable temperature rise of 140 ⁰ C is reached is prolonged from 25 minutes to 40 minutes in the presence of a layer of gypsum and to 33 minutes in the presence of a layer of water glass.

Example 2. Automatised manufacturing of a fire protection element 1' having a mineral wool/gypsum/mineral wool/gypsum/mineral wool structure is performed on a automatic production line according to the following:

a) one side of an already cured mineral wool slab or mat 2 e.g. having width and length dimensions of 1800x2700 mm and a thickness of about 20 mm, which mat's 2 edges have been cut off, is coated with an about 1 mm thick layer of a water based suspension or paste of gypsum, which preferably contains a small amount (0 - 5 %) of glue (e.g. some organic glue typically used by the person skilled in the art), preferably < 2 %, b) the mineral wool slab 2 is cut on the production line in lengthwise and crosswise direction so that three equally sized adjacent (in other words parallel sidewards with respect of the line, see figure 3) slabs 2a', 2b' and 2c' (and 2a", 2b" and 2c" as well as 2a'", 2b'" and 2c'") having the width and length dimensions of 600x900 mm, whereafter c) the mineral wool slabs 2a', 2b' and 2c' are pressed against each other so that two gypsum layers 4 and 5 are formed between them, whereby the mineral wool slabs are glued together when the gypsum dries up. Hence, according to example 2 one

obtains three fire protection elements V having the width and length dimensions of 600x900 mm and a thickness of about 63 mm.

Thus, here the automatised placement and gluing together of the slabs 2a', 2b' and 2c' (and 2a", 2b" and 2c" as well as 2a'", 2b'" and 2c'") against each other in parallel direction, in other words in crosswise direction with respect to the line direction L itself so that each slab is lifted and pressed against the gypsum layer of the underly ^¬ ing and previous slab, with the exception of the last slab 2a' (or 2a" or 2a'") which is lifted and turned 180° and pressed with its gypsum layer 3 against the gypsum layer 3 of the underlying previous slab 2b' (or 2b" or 2b'").

Alternatively, the slabs in step c) in example 2 (also in example 1) may be placed on top of each other in series i.e. so that a slab, which in the line direction successively follows the previous slab in the line direction is placed on top of and pressed against it. This alternative, as well as the placement in step c) is illustrated in figure 3, where the mineral wool mat is sawed (dashed lines) in three equally sized parts both with respect of the width and length of the mat i.e. so that the mat is divided into nine equally sized parts i.e. the slabs 2a', 2b', 2c', 2a", 2b", 2c", 2a'", 2b'" and 2c'". If parallel slabs (e.g. 2a', 2b', 2c' or 2a", 2b", 2c") are placed on top of each other sidewise, slab 2b' is first lifted up according to arrow I' in order to then be pressed against the underlying slab 2c' (2b' and 2c' both have the gypsum layer pointing upwards) and then slab 2a' is lifted and turned 180° and placed according to arrow II' on top of slab 2b' so that the gypsum layer of slab 2a' becomes positioned against the gypsum layer of sheet 2b'.

If the gluing together of the slabs is performed in the line direction L, the placement of the slabs on top of each other occurs according to the arrows I and II. This means in other words that the slab 2c" is lifted and pressed against the gypsum layer of the underlying slab 2c' whereafter slab 2c'" is lifted and turned 180° and pressed with its gypsum layer against the gypsum layer of the underlying slab 2c". The gluing together of 2b' with 2b" and 2c'" as well as 2a' with 2a" and 2a'" is performed in the same way.

Steps a, b and c are preferably performed directly on the line directly after the cur- ing oven and the cooling. The cooling which normally is needed is adjusted so that

the mineral wool has an appropriate temperature for drying of the layers 4 and 5 of gypsum paste without deterioration of the gluing effect. Cutting and turning of the slabs is performed automatically. In this type of elements one gypsum layer 4 will be single and the other one 5 "double", i.e. approximately double in thickness as compared to the single layer.

In figure 5 is presented a simulated fire where the fire occurs outside the insulated channel and the temperature is measured inside the channel (on the metal surface). In figure 5 is shown the time dependent temperature rise, i.e. the fire retarding effect, of a fire protection element Y having two gypsum layers 4 and 5 as well as three mineral wool layers 2a', 2b' and 2c' (three Paroc FPS 14 slabs having a thickness of 20 mm each and between these two gypsum layers 4 and 5) gives the best fire retarding effect (it takes about 60 minutes before the temperature rises up to 140 ⁰ C) in comparison with the fire protection element 1 having only one gypsum layer 3.

The positioning of the gypsum layers and the number of them affects the time of protection. More than a doubling is achieved when using double gypsum layers.

NB. Figures 4 and 5 describe two different constructions and are therefore not di- rectly comparable with each other.

The thickness of the gypsum layer can be limited to that amount which is needed for gluing the slabs together preferably 1 - 5 kg/m ² which gives the double amount/thickness in the finish product there where one gypsum layer is positioned against another.