^' TIT E ^"

Flame resistant yarns and fabrics, and furnishings incorporating such abrics

DESCRIPTION

5 Technical Eield

The invention relates to novel yarns having intrinsic flame-resistant properties, to weft-knitted fabrics made from such yarns, and to a novel use of such fabrics in furnishings to impart a good flame

10 resistance thereto. Background Art

A variety of flamer-resistant yarns is known, having inherent flame-resistant properties which vary from yarn to yarn. Some such yarns will burn if the

15 temperature is sufficiently high, some owe their flame-resistance to surface treatment which can wear or wash away, and some are made from fibres which are themselves inherently incapable of supporting combustion. The most satisfactory lame-resistant

20 yarns fall within the latter category. Glass-fibre

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yarn, which has this desirable property of inherent incombustibility^ is however basically unsuitable for making up into furnishing fabrics because on the one hand it is brittle and cannot satis ctorily be knitted on a weft knitting machine, and on the other hand it does not handle well and tends to shed short broken filaments or fibrils which are a skin irritant. The above two disadvantages have ^' con ined the use of glass fibre fabrics to a ield well removed from upholstery and-upholstery furnishing fabrics.

The most acute need for a reliable and economical flame-resistant fabric is in upholstered furniture when the fabric is used to cover foamed polyurethane.

The polyurethane is very in lammable, and is all the more dangerous .because while burning it emits large quantities of highly toxic smoke. Many fires start with cigarette ends being dropped on the furniture, melting the outer fabric and igniting the foamed polyurethane. Thus it is not sufficient, as a fire retardant measure, even to cover the foamed polyurethane with a flame-resistant fabric. If that fabric is low-melting, then it will simply melt on the application of heat to expose the inflammable polyurethane foam below.

With glass fibre fabrics being unsuitable for

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upholstery and furnishings for the reasons stated above, furniture manu acturers have turned to other fibres for their furnishing fabrics, but have failed to find an ideal fabric which is inexpensive and which has all of the desirable wear properties of the vast range of fabrics currently available and used. Accordingly furniture is still made and sold which is a very real fire hazard, and legislation to prevent its sale ^' s held back pending discovery of a satisfactory fibre and fabric for covering the foamed polyurethane to render it flameproof while retaining all of the appearance of the finished furniture which consumers have come to expect. Disclosure of the Invention

This invention provides a novel yarn which can be knitted on a weft knitting machine to a novel abric having the fire barrier and flame retardant properties needed in upholstered furniture. The invention also proposes .a novel way of incorporating such a fabric into upholstered furniture without affecting the appearance, feel or finish of the furniture.

The novel yarn of the invention is a covered yarn comprising a ultifilament glass fibre core covered with a staple fibre adhered to a polymer coating around the core.

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The technology is available for making a coated yarn according to the invention, using a Bobtex ICS (integrated composite spun) machine ("Bobtex" is a Trade Mark). The glass fibre core yarn is passed continuously through a solution of the polymer or through the molten polymer, to provide the core with its adhesive surface coating. Subsequent passage of the coated core yarn between opening rollers which rotate to open a sliver of staple yarn enables fibrils of the staple fibre to be adhered to the coating, and the yarn is then advantageously passed through a false twisting device, so as more firmly to anchor to the polymer of .the composite yarn.

Although the above integrated composite spinning technology is not new, it is a novel proposal to apply this technology to a glass fibre core yarn. The result is, most surprisingly, a composite yarn that handles well and which can be bent or kinked to an extent never before considered possible with glass fibre yarns. Indeed the yarn can be easily knitted into fabrics on a weft knitting machine such as a high speed circular knitting machine, which was not previously possible with any glass fibre-based yarn.

Also, tests have shown that the tensile strength of the glass fibre core yarn is increased by at

least 10% during its formation into the integrated composite spun yarn of the invention.

Moreover the knitted fabric, and the yarn itself, can be handled without the same irritant effect on the skin due to broken ends of glass fibres. This lack of irritation is probably due to the action of the polymer coating in retaining any broken ends of glass fibres within the yarn.

Because the glass fibre core of the yarn of the invention is inherently lame-resistant and high melting, these same properties are passed to the covered yarn. Advantangeously however, the polymer coating aήd/or the staple fibre covering also have lame-resistant properties, to improve even further the flame-resistance of the covered yarn. Examples of suitable polymer coatings include. polypropylene/ethylene-vinyϊ acetate mixtures, and PVDC or SARAN (Trade Mark) of which the latter two are flame-resistant. Examples of suitable staple fibres include natural fibres (particularly wool, which is naturally lame-resistant), polyester fibres, SEF acrylic (SEF is a Trade Mark), carbon fibre and NOMEX (Trade Mark) of which the latter three are flame-resistant or self-extinguishing.

Best Mode of Carrying Out The Invention

A fibre and fabric according to the invention were prepared as follows using a commercially available continuous glass filament yarn, namely Owens Corning EC968 (1/0) Z20 679 fibre glass (Trade Mark), which is a 68 tex, Z direction twist, 20 filament yarn.

The glass fibre yarn. as tensioned and passed through a fine tube into an area of molten polymer at a speed of approximately 600 metres per minute. In the example quoted the polymer was a compound of 60% ethy1ene-vinyl* acetate, being Imperial Chemical Industries* Evatane (Trade Mark) 28.20 (28% vinyl acetate content;'20 melt flow- index) and 40% Polypropylene, Shell • Chemicals' SY6100, at a temperature of 230°C.

Molten polymer was presented to the point of contact with the filament glass by means of an extruder .at a constant rate of 16 grams per minute. As the glass filaments pass through the molten polymer the polymer forms a cone around the running glass and is drawn down to form a very fine coating around the glass filament. ^" Whilst the polymer was still in a molten state staple fibres were presented to the molten polymer coating by means of a fibre opening system so that the individual fibres partially penetrated

or adhered to the polymer. The combination of glass/polymer/fibre was then passed through a false twist process which further acted to impress the individual fibres into the polymer coating to form a composite yarn. The yarn was allowed to cool and solidify prior to winding on a conventional textile package.

A subsequent rewinding process was used to lubricate the yarn with a paraffin or silthane wax in the conventional manner before winding onto a conventional textile cone suitable for presentation to a knitting machine.

The resultant yarn was then knitted without fracture on a conventional knitting machine, for , example a conventional single Jersey weft knitting 12 gauge machine. t commercial speeds, to produce a single jersey fabric without filamentation of the glass.

In the example outlined.the particular fabric described was manufactured as a reinforcing fabric for a vinyl coating for upholstery, so that should the vinyl be melted by, for example, a cigarette end the fibres and polymer will similarly melt but the glass knitted structure will remain intact to prevent the passage of the lighted cigarette end

into the upholstery foam beneath, thereby creating a physical barrier that will not be destroyed below the melting point of the glass. Further fabrics of glass composite yarn have been manufactured using different, and inherently flame proof, polymers and fibres that themselves will not ignite or support combustion. Industrial exploitation

The invention also provides a fabric knitted from the above coated yarn on a weft knitting machine. The fabric may be plain knit, and may be on any gauge of machine suitable for the tex of the yarn produced. The resulting fabric has the appearance of stockinette fabric, with good flexibility and stretch characteristics. One particularly important feature is the good abrasion resistance, which is many times greater than that of conventional woven glass fibre fabrics and which opens up a wide range of uses for the fabrics of the invention. The invention proposes a number of novel and useful applications for such a fabric. ,A first use is as a flame barrier layer in soft furnishings. A second is as a base fabric for vinyl and simulated leather upholstery materials. A third use is as a cladding to wrap around electrical installations

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or as a heat insulation bandage for pipework.

A fourth use is as a reinforcement for tbermoset resin mouldings.

When using the fabric of the invention in soft upholstery furnishings as a flame barrier layer, the article to be upholstered such as a foamed polyurethane cushion is first encased in a fabric according to the invention. Preferably the polyurethane is stiched completely into a cover of the fabric of the invention. An outer- cover

of conventional upholstery material is then provided. The outer cover may be .either a lame-resistant f bric or one that burns; the provision of a sublayer of the fabric of the invention provides a flame ^" barrier that effectively isolates the foamed polyurethane -w ϊch is the most dangerous part of the furniture from the point of view of fire hazard.

Tests have shown that burning cigarettes do not ignite -upholstered furniture covered as described above. If the outer cover- is a low-melting fabric then the ci _. garette end will melt a hole through to the sublayer of the fabric according to the invention, where it will char, melt or otherwise destroy the stapl

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fibre covej-ing of ^" the yarn forming the fabric of the invention. The glass fibre core of the covered yarn is not destroyed, however, and continues to present a lame-resistant barrier between the cigarette end and the polyurethane.

More extreme tests with naked flames have had equally favourable results.

Because of the inherent stretch properties of a lnitted fabric according "to the invention, it can be incorporated as a sublayer beneath the outer cover, of upholstered furniture without any- adverse effects, on the feel of the finished furniture. Moreover as a fi.re retardant measure it is very economical; much more go than the incorporation of fire retardant chemicals into the polyurethane foam. The fin l choice of surface fabric i.s not dictated by fire retardant considerations, which gives much more choice to the furniture ^* designers- Applications of this use of fabric according to the invention include cushion ^' covers, -upholstered chairs, settees, mattresses, beds, car seats and the seats of public service vehicles such as trains, omnibuses and aircraft-

TChen using the fabric of the invention as a base layer for vinyl or simulated leather sheeting, the plain

knit fabric of the invention is simply substituted for the stockinette base fabric conventionally used. The result is a vinyl sheet with inherent ire-resistant properties. Although the vinyl covering itself might melt or burn away in a fire, the knitted base fabric of the invention will not burn and will maintain its integrity up to the melting point of the glass.

When using the fabric of the invention as a reinforcement for sheets or mouldings, of theremoset resin, conventional moulding techniques should be followed. However the fabric is .much easier to handle than conventional glass fibre matting because on the one hand it does not have the same skin irritant effect and on the other hand its inherent stretch characteristics, resulting from the knitted structure, enable it to be formed into more complex shapes without creasing.

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