Title:
FLUORINATED PENTACENE DERIVATIVES AND PROCESSES FOR PRODUCING THESE
Document Type and Number:
WIPO Patent Application WO2005042445
Kind Code:
A3
Abstract:
Fluorinated pentacene derivatives, e.g., tetradecafluoropentacene, 5,6,7,12,13,14-hexafluoropentacene, 5,7,12,14-tetrafluoropentacene, and 6,13-difluoropentacene, which are novel compounds, and intermediates therefor. Also provided are processes for producing fluorinated pentacene derivatives and intermediates therefor. Such a pentacene derivative in which the pentacene skeleton has been fluorinated in desired positions is obtained by introducing oxo, hydroxy, or alkoxy groups into a pentacene skeleton, fluorinating the resultant compound with sulfur tetrafluoride, and then partially defluorinating it with a reducing agent.
Inventors:
KOBAYASHI MASAFUMI (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
Application Number:
PCT/JP2004/016248
Publication Date:
July 14, 2005
Filing Date:
November 02, 2004
Export Citation:
Assignee:
KANTO DENKA KOGYO KK (JP)
KOBAYASHI MASAFUMI (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
KOBAYASHI MASAFUMI (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
International Classes:
C07C17/18; C07C17/23; C07C23/18; C07C25/22; C07C45/63; C07C46/00; C07C49/697; C07C50/36; C07B61/00; C07C; (IPC1-7): C07C25/22; C07C17/18; C07C17/23; C07C23/18; C07C45/63; C07C46/00; C07C49/697; C07C50/36
Domestic Patent References:
WO2003016599A1 | 2003-02-27 | |||
WO2002019022A1 | 2002-03-07 | |||
WO2003027050A2 | 2003-04-03 |
Foreign References:
JPH08254822A | 1996-10-01 | |||
JP2000026339A | 2000-01-25 |
Other References:
MARSCHALK C.: "Linear pentacene series. I. Synthese of pentacene derivatives and their transformation. II. Demonstration of the presence of the pentacene skeleton,", BULL.SOC.CHIM.5, vol. 4, 1937, pages 1535 - 1546, XP002987741
BURDOU J. ET AL: "Nucleophilic Replacement in Decafluoroanthracene.", J. CHEM. SOC. CHEM.COMMUN., 1982, pages 534 - 535, XP002987742
BURDOU J. ET AL: "Nucleophilic Replacement in Decafluoroanthracene.", J. CHEM. SOC. CHEM.COMMUN., 1982, pages 534 - 535, XP002987742
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