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Title:
FLUORINATED PENTACENE DERIVATIVES AND PROCESSES FOR PRODUCING THESE
Document Type and Number:
WIPO Patent Application WO2005042445
Kind Code:
A3
Abstract:
Fluorinated pentacene derivatives, e.g., tetradecafluoropentacene, 5,6,7,12,13,14-hexafluoropentacene, 5,7,12,14-tetrafluoropentacene, and 6,13-difluoropentacene, which are novel compounds, and intermediates therefor. Also provided are processes for producing fluorinated pentacene derivatives and intermediates therefor. Such a pentacene derivative in which the pentacene skeleton has been fluorinated in desired positions is obtained by introducing oxo, hydroxy, or alkoxy groups into a pentacene skeleton, fluorinating the resultant compound with sulfur tetrafluoride, and then partially defluorinating it with a reducing agent.

Inventors:
KOBAYASHI MASAFUMI (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
Application Number:
PCT/JP2004/016248
Publication Date:
July 14, 2005
Filing Date:
November 02, 2004
Export Citation:
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Assignee:
KANTO DENKA KOGYO KK (JP)
KOBAYASHI MASAFUMI (JP)
OMAE OSAMU (JP)
OHKUBO KIMITAKA (JP)
GAO YUAN (JP)
International Classes:
C07C17/18; C07C17/23; C07C23/18; C07C25/22; C07C45/63; C07C46/00; C07C49/697; C07C50/36; C07B61/00; C07C; (IPC1-7): C07C25/22; C07C17/18; C07C17/23; C07C23/18; C07C45/63; C07C46/00; C07C49/697; C07C50/36
Domestic Patent References:
WO2003016599A12003-02-27
WO2002019022A12002-03-07
WO2003027050A22003-04-03
Foreign References:
JPH08254822A1996-10-01
JP2000026339A2000-01-25
Other References:
MARSCHALK C.: "Linear pentacene series. I. Synthese of pentacene derivatives and their transformation. II. Demonstration of the presence of the pentacene skeleton,", BULL.SOC.CHIM.5, vol. 4, 1937, pages 1535 - 1546, XP002987741
BURDOU J. ET AL: "Nucleophilic Replacement in Decafluoroanthracene.", J. CHEM. SOC. CHEM.COMMUN., 1982, pages 534 - 535, XP002987742
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