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Title:
FLUOROALKYL DERIVATIVE AND PRODUCTION THEREOF
Document Type and Number:
WIPO Patent Application WO/1990/009972
Kind Code:
A1
Abstract:
The fluoroalkyl derivative of the invention is a new compound represented by general formula (I) or (II), wherein R1 represents (a) (wherein X represents hydrogen, chlorine, bromine, fluorine, iodine, methyl, ethyl, methoxy, ethoxy or nitro), aroyloxy, C1 to C20 alkyl, or alkoxycarbonyl; R2 represents hydrogen or methyl; and n is an integer of 1 to 20. The method of producing the same comprises reacting an olefinic compound with a fluoroalkanesulfonyl chloride in the presence of a metallic catalyst, optionally followed by alkaline treatment.

Inventors:
KAMIGATA NOBUMASA (JP)
YOSHIDA MASATO (JP)
SAWADA HIDEO (JP)
NAKAYAMA MASAHARU (JP)
Application Number:
PCT/JP1990/000242
Publication Date:
September 07, 1990
Filing Date:
February 27, 1990
Export Citation:
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Assignee:
NIPPON OILS & FATS CO LTD (JP)
International Classes:
C07C19/10; C07C21/18; C07C22/08; C07C25/13; C07C25/24; C07C43/225; C07C205/11; (IPC1-7): B01J27/053; B01J27/122; B01J31/24; C07C17/26; C07C19/08; C07C21/18; C07C22/08; C07C25/13; C07C25/24; C07C41/22; C07C43/225; C07C67/317; C07C67/347; C07C69/63; C07C69/653; C07C69/76; C07C201/12; C07C205/11
Foreign References:
JPS5857324A1983-04-05
JPS63222694A1988-09-16
JPS6479126A1989-03-24
JPS63146840A1988-06-18
JPS61134329A1986-06-21
JPS5892627A1983-06-02
JPS5754124A1982-03-31
JPS52145382A1977-12-03
DE2742685A11979-04-05
FR2612184A11988-09-16
GB2062620A1981-05-28
JPS61167645A1986-07-29
US3818074A1974-06-18
JPS5610121A1981-02-02
DE2439281A11976-02-26
JPS61176546A1986-08-08
JPS6176456A1986-04-18
JPS5659742A1981-05-23
Other References:
CHEMICAL ABSTRACTS, Vol. 55, No. 17, 21 August 1961 (21. 08. 61), (Columbus, Ohio, U.S.A.) Minnesota Mining and Manufg. Co., "Fluorocarbon Radical-Containing compounds" Abstract No. 16452C, Brit. 849,061, 21 September 1960 (21. 09. 60)
Tetrahedron. Vol. 42, No. 2, (1986), A. CHAUVIN, J. GRIENER, R. PASTOR, A. CAMBON (Synthesis and Reactions of Ethyl 3-(Alkyl Lthio)-3-(Perfluoroalkyl) Propenoates. Thiophenes and Perfluoroalkyl Thioxo Esters) p. 663-668
Journal of the American Chemical Society, Vol. 107, No. 18 (1985), TOMOYA KITAZUME, NOBOU ISHIKAWA (Ultrasound-Promoted Selective Perfluoroalkylation on the Desired Position of Organic Molecules) p. 5186-5191
Tetrahedron Letters, Vol. 25, No. 3, (1984), TAKAMASA FUCHIKAMI, IWAO OJIMA (Transition-Metal Complex Catalyzed Polyfluoroalkylation. I. Facile Addition of Polyfluoroalkyl Halides to Carbon-Carbon Multiple Bonds) p. 303-306
Tetrahedron Letters, Vol. 23, No. 35, (1982), TERUO UMEMOTO, YURIKO KURIU, OSAMU MIYANO (Perfluoroalkylation of Alkynes with RfI(ph)oSO2CF3) p. 3579-3582
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