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Title:
FUNCTIONAL ACRYLIC EMULSION AND PREPARATION METHOD THEREFOR, WEAR-RESISTANT ACRYLIC COATED FILM, AND ACRYLIC COATED BOPP FILM
Document Type and Number:
WIPO Patent Application WO/2023/000420
Kind Code:
A1
Abstract:
The present invention provides a functional acrylic emulsion, which comprises: 5-20 parts by weight of a styrene-acrylic resin emulsion; 66.5-73.5 parts by weight of water; 5-10 parts by weight of a hard monomer; 5-10 parts by weight of a soft monomer; 1-2 parts by weight of a functional monomer; 0.5-1.5 parts by weight of acrylic acid; 0.5-1 parts by weight of diacetone acrylamide; 0.25-0.5 parts by weight of adipic dihydrazide; 0.5-2 parts by weight of an emulsifier; 0.5-2 parts by weight of an initiator; and 0.1-0.2 parts by weight of a defoaming agent. Compared with the prior art, the design principle of a hard core and a soft shell is used in the present invention. The styrene-acrylic resin emulsion is used as a seed emulsion and is subjected to core-shell polymerization with the hard monomer, the soft monomer, the functional monomer, and acrylic acid to obtain a self-crosslinking functional acrylic emulsion with a good wear resistance. In addition, diacetone acrylamide and adipic dihydrazide are introduced during the polymerization process for crosslinking, such that the wear resistance and after-tack resistance of the acrylic emulsion are further improved.

Inventors:
WANG ENFEI (CN)
ZHU QINGMEI (CN)
YIN RUHONG (CN)
LIU HAIYING (CN)
YUAN YEXING (CN)
Application Number:
PCT/CN2021/113227
Publication Date:
January 26, 2023
Filing Date:
August 18, 2021
Export Citation:
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Assignee:
HAINAN SHINER IND CO LTD HAIKOU CN (CN)
International Classes:
C08F257/02; C08F220/06; C08F220/14; C08F220/18; C08F220/20; C08F220/56; C08F220/58; C08J7/04; C08J7/046; C08L23/12
Foreign References:
CN113105581A2021-07-13
CN110591006A2019-12-20
CN111285958A2020-06-16
CN105294897A2016-02-03
CN105237675A2016-01-13
Attorney, Agent or Firm:
UNITALEN ATTORNEYS AT LAW (CN)
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