Title:
GUEST-COMPOUND-ENVELOPING POLYMER-METAL-COMPLEX CRYSTAL, METHOD FOR PRODUCING SAME, METHOD FOR PREPARING CRYSTAL STRUCTURE ANALYSIS SAMPLE, AND METHOD FOR DETERMINING MOLECULAR STRUCTURE OF ORGANIC COMPOUND
Document Type and Number:
WIPO Patent Application WO/2014/038220
Kind Code:
A1
Abstract:
The present invention is: a guest-compound-enveloping polymer-metal-complex crystal characterized by at least one selected from an aliphatic hydrocarbon, an alicyclic hydrocarbon, an ether, an ester, an aromatic hydrocarbon, a halogenated hydrocarbon, and a nitrile being enveloped as a guest compound (A) in the minute pores or the like of a polymer-metal complex that contains a metal ion as a central metal and a ligand having at least two ligating sites, has a 3D network structure formed by the ligand being ligated to the metal ion, and has the minute pores or the like regularly arranged three-dimensionally within the 3D network structure, the amount of the guest compound (A) present within the minute pores or the like being at least 60 mol% of all the guest compounds enveloped in the minute pores or the like; a method for producing the guest-compound-enveloping polymer-metal-complex crystal; a method for preparing a crystal structure analysis sample using the crystal; and a method for determining the molecular structure of an organic compound using the sample obtained by said method.
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Inventors:
FUJITA MAKOTO (JP)
INOKUMA YASUHIDE (JP)
YOSHIOKA SHOTA (JP)
ARIYOSHI JUNKO (JP)
INOKUMA YASUHIDE (JP)
YOSHIOKA SHOTA (JP)
ARIYOSHI JUNKO (JP)
Application Number:
PCT/JP2013/056370
Publication Date:
March 13, 2014
Filing Date:
March 07, 2013
Export Citation:
Assignee:
JAPAN SCIENCE & TECH AGENCY (JP)
International Classes:
C07C13/52; C30B29/54; C07D307/92; C07D311/30; C07D401/14; C30B7/06
Domestic Patent References:
| WO2011062260A1 | 2011-05-26 | |||
| WO2011062260A1 | 2011-05-26 |
Foreign References:
| JP2006188560A | 2006-07-20 | |||
| JP2008247884A | 2008-10-16 | |||
| JP2006232738A | 2006-09-07 | |||
| JP2010090141A | 2010-04-22 | |||
| JP2008214584A | 2008-09-18 | |||
| JP2008214318A | 2008-09-18 | |||
| JP2006188560A | 2006-07-20 |
Other References:
M. KAWANO ET AL.: "Direct observation of crystalline-state guest exchange in coordination networks", COORDINATION CHEMISTRY REVIEWS, vol. 251, 2007, pages 2592 - 2605, XP022297456
J. AM. CHEM. SOC., vol. 126, 2004, pages 16292 - 16293
See also references of EP 2894242A4
J. AM. CHEM. SOC., vol. 126, 2004, pages 16292 - 16293
See also references of EP 2894242A4
Attorney, Agent or Firm:
OHISHI HARUHITO (JP)
Haruhito Oishi (JP)
Haruhito Oishi (JP)
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