BACKGROUND OF THE INVENTION

1. FIELD OF THE INVENTION The present invention refers to a heat exchange system with a heat exchange chamber, a method for manufacturing the heat exchange system and a method for exchanging heat by using the heat exchange system. 2. DESCRIPTION OF THE RELATED ART

Despite the integration of renewable energy into the public electric energy system (power grid) a large share of elec ^¬ tricity is nowadays still generated by fossil energy sources. But the global climate change requires the further develop ^¬ ment of renewable energies.

The energy output of renewable energy sources like wind and solar is not constant throughout a day or throughout a year. Consequently, electricity which is generated by utilizing en ^¬ ergy from renewable energy sources fluctuates.

In order to manage this fluctuating electricity, heat (ther ^¬ mal energy) storage systems (heat exchange systems) are de- veloped for storing and releasing thermal energy. Such a heat exchange system comprises a heat exchange chamber with heat exchange chamber boundaries which surround a heat exchange chamber interior. The heat exchange chamber interior is filled with heat storage material like stones. The heat ex- change chamber boundaries comprise a first opening for guid ^¬ ing an inflow of a heat transfer fluid, e.g. air, into the heat exchange chamber interior and a second opening for guid- ing out an outflow of the heat transfer fluid out of the heat exchange chamber interior.

For a charging mode, the heat exchange system additionally comprises a charging unit for heating the heat transfer fluid with the aid of excess electricity. The resulting hot heat transfer fluid is infused into the heat exchange chamber in ^¬ terior via one of the openings (e.g. first opening) of the heat exchange chamber boundaries. This opening defines a "hot" terminal of the heat exchange chamber. The hot heat transfer fluid is guided through the heat exchange chamber interior. By the guiding of the hot heat transfer fluid through the heat exchange chamber interior a heat transfer from the heat transfer fluid to the heat storage material is caused. Heat is stored by the heat storage material.

Via the other opening (second opening) of the heat exchange chamber the resulting "cold" heat transfer fluid is guided out of the heat exchange chamber interior. Thereby, this opening of the heat exchange chamber boundaries defines a "cold" terminal (end) of the heat exchange chamber. The charging mode is stopped when the temperature at the cold terminal of the heat exchange chamber begins to rise above a predetermined temperature.

In a discharging mode of the heat exchange chamber this stored heat can be recovered: "cold" heat transfer fluid is infused into the heat exchange chamber interior via one of openings of the heat exchange chamber boundaries. In this case, this opening defines a "cold" terminal. The cold heat transfer fluid is guided through the hot heat exchange cham ^¬ ber interior. By the guiding of the cold heat transfer fluid through the heat exchange chamber interior a heat transfer from the heat storage material to the heat transfer fluid is caused. Heat is released from the heat storage material.

Via the second opening of the heat exchange chamber bounda ^¬ ries the resulting "hot" heat transfer fluid is guided out of the heat exchange chamber interior. Thereby, the second open ^¬ ing of the heat exchange chamber defines a "hot" terminal of the heat exchange chamber. The resulting hot heat transfer fluid can be used for generating steam with which a steam turbine is driven. Result of the described discharging mode: Heat is transformed back to electricity . The discharging mode is stopped when the temperature at the cold terminal of the heat exchange storage begins to drop be ^¬ low a certain temperature.

For a high round trip efficiency of the heat exchange system it is important that thermal losses to the environment are reduced .

SUMMARY OF THE INVENTION It is an objective of the invention to provide a heat ex ^¬ change system with little thermal losses.

This objective is achieved by the invention specified in the claims .

A heat exchange system with at least one heat exchange cham ^¬ ber is provided. The heat exchange chamber comprises heat ex ^¬ change chamber boundaries which surround at least one heat exchange chamber interior of the heat exchange chamber. The heat exchange chamber boundaries comprise at least one first opening for guiding in an inflow of at least one heat transfer fluid into the heat exchange chamber interior and at least one second opening for guiding out an outflow of the heat transfer fluid out of the heat exchange chamber interi- or. At least one heat storage material is arranged in the heat exchange chamber interior such that a heat exchange flow of the heat transfer fluid through the heat exchange chamber interior causes a heat exchange between the heat storage ma- terial and the heat transfer fluid. At least one thermal in ^¬ sulation layer is at least partly arranged in the heat ex ^¬ change chamber interior between the heat exchange chamber boundaries and the heat storage material. In a preferred em- bodiment the thermal insulation layer comprises at least one thermal insulation material which is selected from the group consisting of ceramics, sinter, bricks, foamed clay, mineral wool, mineral foam, mineral fibers, foam glass, vermiculite, perlite, chamotte, porous concrete, formed vacuum components, calciumsilicat and microporous insulation material.

Preferably, the thermal insulation layer comprises at least one support element for supporting the thermal insulation layer. Thereby, the supporting element comprises at least one supporting material which is selected from the group consist ^¬ ing of metal, ceramic, porous concrete and bricks.

In addition to the heat exchange system, a method for manu ^¬ facturing a heat exchange system with following manufacturing steps is provide: a) providing of a at least one component of the heat exchange chamber; and b) attaching of the thermal insulation layer to the component of the heat exchange cham ^¬ ber . Preferably, for the attaching of the thermal insulation layer at least one arranging method is used which is selected from the group consisting of gluing, spraying, casting and foaming thermal insulation material and/or at least one precursor of the thermal insulation material. The filling with solid heat storage material later on supports the thermal insulation layer. So, additional fixing devices are not necessary.

Alternatively or in combination, the thermal insulation layer can be directly attached, for instance with the aid of pins.

Moreover, a method for exchanging heat by using the heat exchange system is provided. In an operating mode of the heat exchange system the heat exchange flow of the heat transfer fluid is guided through the heat exchange chamber interior, wherein a heat exchange between the heat storage material and the heat transfer fluid is caused. The heat exchange chamber is a space, cavity or a housing in which the heat storage material is located. Inside of the heat exchange chamber the heat exchange takes place. In order to provide an efficient heat exchange, the heat exchange chamber is preferably thermally insulated against the sur- roundings . The loss of heat is reduced by the thermal insula ^¬ tion .

The heat transfer fluid is guided (led) into the heat ex ^¬ change chamber interior via the first opening and is guided out of the heat exchange chamber interior via the second opening. The first opening of the heat exchange chamber boundaries is an inlet opening. The second opening of the heat exchange chamber boundaries is an outlet opening. Thus, there are different areas of the heat exchange chamber bound- aries, namely an inlet area of the heat exchange chamber boundaries with the first opening and an outlet area of the heat exchange chamber boundaries with the second opening.

The operating mode of the heat exchange system is selected from the group consisting of charging mode with a heat trans ^¬ fer from the heat transfer fluid to the heat storage material and discharging mode with a heat transfer from the heat storage material to the heat transfer fluid. Depending on the operating mode, a specific opening can have the function of an inlet opening or the function of an outlet opening. The flow direction of the heat exchange flow depends on the operating mode. Preferably, during the charging mode the heat exchange flow is directed in a charging mode direc- tion, during the discharging mode the heat exchange flow is directed in a discharging mode direction and the charging mode direction and the discharging mode direction are opposed to each other (countercurrent operation) . But, a change of the directions of the heat exchange flow is not necessary. Charging mode direction and discharging mode direction comprise the same direction (co-current operation) . In countercurrent operation, switching from the charging mode to the discharging mode the direction of the heat exchange flow through the heat exchange chamber interior is reversed and consequently, the function of the openings (inlet open ^¬ ing, outlet opening) as well as a relative temperature (cold or hot) at the respective opening is reversed, too. With such a solution it is especially advantageous to use the same heat transfer fluid for the charging mode and for the discharging mode. But of course, different heat transfer fluids for the charging mode and the discharging mode can be used, too.

For the charging mode, the heat exchange system is equipped with at least one charging unit for heating the heat transfer fluid. In the charging mode with activated charging unit, the charging unit can be located upstream of the heat exchange chamber. In contrast to that, in the discharging mode with a deactivated charging unit, the charging unit can be located downstream of the heat exchange chamber.

Preferably, the charging unit comprises at least one electri- cal heating device which is selected from the group consist ^¬ ing of resistance heater, inductive heater, emitter of elec ^¬ tromagnetic radiation and heat pump. The electromagnetic ra ^¬ diation is preferably infrared radiation. A combination of different electrical heating devices is possible. With the aid of the electrical heating devices electricity is trans ^¬ formed into heat. This heat is absorbed by the heat transfer fluid and transported to the heat storage material in the heat exchange chamber interior. For instance, the electrical heating device comprises a re ^¬ sistance heater. This heater is located in the heat exchange inflow upstream of the heat exchange chamber (charging mode) . The heat transfer fluid is heated up before its entering into the heat exchange chamber interior. The resistance heater comprises a large heat exchange area for an efficient heat exchange from the resistance heater to the heat transfer flu ^¬ id. For instance, the large heat exchange area is formed by a grid of the resistance heater. A meander shaped resistance heater is possible, too. With such a measure, the heat trans ^¬ fer to the heat transfer fluid is enhanced. In addition, the possibility of the (not desired) occurrence of hot spots within the resistance heater is reduced.

The heat exchange system is preferably equipped with at least one discharging unit for discharging the heat transfer fluid of the outflow from heat for production of electricity. Heat is removed from the heat transfer fluid. The removed heat is transformed into electricity. In a preferred embodiment, the transformation of heat into electricity is carried by a wa ^¬ ter/steam cycle for driving a turbine of a steam power plant.

The discharging mode can be realized when electricity prices and demand are high or when the production of renewable ener ^¬ gies is low. For that and in order to limit the costs which are connected to the invention, it is advantageous to use ex ^¬ isting power plants. So, the heat exchange system is a kind of retrofit system. For instance, well suited are CCPP (com- bined cycle power plant) since their heat recovery steam gen ^¬ erator (HRSG) is similar to the application proposed here. Nevertheless, hard coal, oil, gas, waste incineration, wood or lignite fired power plants can be used since the charging unit can be designed for high temperatures to match the tem- peratures used in the steam generator. In a hybrid mode the fuel can be used to increase the temperature from the temper ^¬ ature level of the heat exchange system to the operating tem ^¬ perature of the original furnace or boiler design. In a preferred embodiment, the heat exchange system is equipped with a at least one flow adjusting element for ad ^¬ justing exchange flow through the heat exchange chamber inte ^¬ rior, for adjusting the inflow into the heat exchange chamber interior and/or for adjusting the outflow out of the heat exchange chamber. The flow adjusting element comprises at least one active fluid motion device which is selected from the group consisting of blower, fan and pump and/or the flow ad- justing element comprises at least one passive fluid control device which is selected from the group consisting of

activatable bypass pipe, nozzle, flap, damper and valve. A multitude of these devices are possible as well as a combina ^¬ tion of these devices. In addition, flow adjusting elements can be arranged serially or in parallel. For instance, two flaps are arranged at two openings in order to adjust the in ^¬ flows of the heat transfer fluid into the heat exchange cham ^¬ ber interior and consequently in order to adjust the tempera ^¬ ture distribution in the heat exchange chamber interior.

The advantage of passive control devices is that they are cheap. In addition, passive control devices are very relia ^¬ ble. But preferably, active motion devices are used. By that, it is advantageous that driving units of the active fluid mo- tion devices like electrical motors and electrical equipment are located outside of the heat exchange flow with the (pos ^¬ sibly very hot) heat transfer fluid.

Just to be noted: There are different locations for the flow adjusting element possible. The flow adjusting element can be directly arranged in the heat exchange chamber interior, downstream of the heat exchange chamber interior and/or upstream of the heat exchange chamber interior. The location depends - inter alia - on the kind of flow adjusting element (active fluid motion device or passive fluid control device) .

The heat storage material can be liquid and/or solid. For in ^¬ stance, a core of the heat storage material is solid and a coating of this solid core is liquid. Such a liquid coating can comprise ionic liquid.

The solid material comprises preferably bulk material. Mix ^¬ tures of different liquid materials and different solid mate- rials are possible as well as mixtures of liquid and solid materials .

It is possible that the heat storage material is a thermo- chemical energy storage material: Thermal energy can be stored via an endothermic reaction whereas thermal energy can be released via an exothermic reaction. Such a thermo chemi ^¬ cal storage material is for instance the calcium ox ^¬ ide/calcium hydroxide system.

The heat storage materials can be arranged in one or more specific containers made of non-reactive container material. Non-reactive means that no chemical reaction between the heat storage material and the container material takes place dur- ing the heat exchange process.

In a preferred embodiment, the heat storage material compris ^¬ es at least one chemically and/or physically stable material. In the range of the operational temperature of the heat ex- change system the heat storage material does not change its physical and/or chemical properties. A physically stable ma ^¬ terial does not change its physical properties during the heat exchange. For instance, the heat storage material re ^¬ mains in a solid state in the operating temperature range. A chemically stable material does not change its chemical com ^¬ position during the heat exchange. For instance, such a chem ^¬ ically stable material is a phase change material (PCM) .

Moreover, a complex heat exchange system with different heat exchange chambers with different heat storage materials and/or different heat transfer fluids is possible, too. For Instance, a heat exchange chamber with stones as heat storage material and a heat exchange chamber with a phase change ma ^¬ terial as a heat storage material are combined together (in parallel or in series) .

In a preferred embodiment, the heat storage material compris ^¬ es sand and/or stones. The stones can be natural stones or artificial stones. Mixtures thereof are possible, too. Arti ^¬ ficial stones can consist of containers which are filled with heat storage material. This heat storage material is for in ^¬ stance a phase change material or a thermo-chemical storage material (see above) .

Preferably, the stones comprise gravel (pebbles) , rubbles and/or grit (splits). The artificial material comprises pref ^¬ erably clinkers or ceramics. Again, mixtures of the mentioned materials are possible, too.

In order to provide a cheap energy storage material it is ad ^¬ vantageous to use waste material. Therefore, in a preferred embodiment, the artificial material comprises at least one by-product of an industrial process. For instance, the by ^¬ product is iron silicate. Iron silicate origins from a slag of copper production.

In a preferred embodiment, heat exchange channels are embed- ded in the heat storage material for guiding of the heat ex ^¬ change flow through the heat exchange chamber interior. The heat storage material forms a heat exchange bed. The heat ex ^¬ change bed comprises the heat exchange channels. The heat ex ^¬ change channels are embedded into the heat storage bed such that the heat exchange flow of the heat transfer fluid through the heat exchange channels causes the heat exchange between the heat storage material and the heat transfer flu ^¬ id. The heat exchange channels can be formed by interspaces (gaps) of the heat storage material. For instance, the heat storage material comprises stones. The stones form the heat exchange bed with the heat exchange channels. In addition or alternatively, the heat storage material is porous. Open pores of the heat storage material form the heat exchange channels .

The heat transfer fluid is selected from the group consisting of a liquid and a gas. The gas is selected from the group consisting of inorganic gas and/or organic gas. The inorganic gas is preferably air. Mixtures of different liquids are pos ^¬ sible as well as mixtures of different gases.

Preferably, the heat transfer fluid comprises a gas at ambi- ent gas pressure. Preferably, the gas at the ambient gas pressure is air. The ambient pressure (900 hPa to 1.100 hPa) varies such that the heat exchange flow through the heat ex ^¬ change chamber interior is caused. For the guiding of the heat transfer fluid into the heat ex ^¬ change chamber interior and for the guiding of the heat transfer fluid out of the heat exchange chamber interior a pipe system (or channel system, ducting system) is used. This pipe system can be closed (with a closed loop) or can be open (with an open loop) .

For instance the heat transfer fluid is ambient air of the environment. The loop is an open loop. Air from the environ ^¬ ment is introduced into the heat exchange system and air of the heat exchange system is released to the surroundings.

There is an air exchange during the operation of the heat ex ^¬ change system.

In contrast to that, there is no air exchange or a selective- ly adjustable air exchange during the operation in a closed loop. Air of the environment is not added or just added on a small scale to the air which is used as heat transfer fluid. This has following specific advantage: In a situation with almost completely charged heat storage material, heat trans- fer fluid with remaining heat would be released to the envi ^¬ ronment in an open loop. The remaining heat is lost. In con ^¬ trast to that, in a closed loop this heat transfer fluid with remaining heat stays in heat exchange system. The remaining heat is not lost. Therefore, in a preferred embodiment, a closed loop is implemented and wherein the inflow comprises the outflow. The outflow is guided back into the heat ex ^¬ change chamber interior. The heat exchange chamber is a vertical heat exchange chamber and/or a horizontal heat exchange chamber.

The term "horizontal heat exchange chamber" implies a hori- zontal main (average) flow of the heat transfer fluid through the heat exchange chamber interior. The flow direction of the horizontal main flow is essentially parallel to the average surface of the earth. The horizontal direction is essentially a perpendicular direction to the direction of the gravity force which affects the heat transfer fluid. Perpendicular means in this context that deviations from the perpendicular ^¬ ity of up to 20° and preferably deviations of up to 10° are possible . A horizontally oriented direction of the heat exchange flow can be achieved by lateral first openings and/or lateral se ^¬ cond openings. The horizontal heat exchange chamber comprises these openings in its side heat exchange chamber boundaries. In addition, with the aid of an active fluid motion device like a blower or a pump the heat exchange flow in the heat exchange chamber interior is caused. The heat transfer fluid is blown or pumped into the heat exchange chamber interior or is pumped or sucked out of the heat exchange chamber interi ^¬ or .

In contrast to the term "horizontal heat exchange chamber", the term "vertical heat exchange chamber" implies a vertical main flow of the heat transfer fluid through the heat ex ^¬ change chamber interior. For instance, the operating mode is the charging mode. In a vertical heat exchange chamber the heat exchange flow is preferably directed downwards (top down) during the charging mode. The vertical main flow (essentially parallel but in the opposite direction to the di ^¬ rection of gravity force) can be caused by an active fluid motion device (blower or pump) . The first opening is located at a top of the heat exchange chamber and the second opening is located at a bottom of the heat exchange chamber. Based on natural convection, in a vertical heat exchange chamber the temperature of the heat storage material along a cross section perpendicular to the flow direction of the heat transfer fluid is approximately the same (horizontal isother- mal lines) .

In contrast to that, in a horizontal heat exchange chamber due to natural convection the temperature of the heat storage material along the cross section perpendicular to the flow direction of the heat transfer fluid (see below) can differ (inclined isothermal lines) .

It has to be noted that the terms "horizontal" and "vertical" are independent from the dimensions of the heat exchange chamber and its orientation. Decisive is the direction of the flow of the heat transfer fluid through the heat exchange chamber interior. For instance, a "horizontal heat exchange chamber" can have a chamber length which is less than the chamber height of the heat exchange chamber.

Besides pure vertical and horizontal heat exchange chambers, a mixture of "vertical heat exchange chamber" and "horizontal heat exchange chamber" is possible, too. In such a heat ex ^¬ change chamber, the main flow of the heat transfer fluid is the result of horizontal and vertical movement of the heat transfer fluid through the heat exchange chamber interior.

In a preferred embodiment, at least two first openings are arranged vertically to each other and/or at least two second openings are arranged vertically to each other. Openings are arranged above each other. By this measure it is possible to influence a vertical distribution of heat exchange flows in order to improve a temperature distribution (temperature front) in the heat storage material and heat exchange chamber interior respectively. Isothermal lines perpendicular to the flow direction are influenced. The temperature front is defined by neighboring cold and hot areas of the heat storage material in the heat exchange cham ^¬ ber interior caused by the flow of the heat transfer fluid through the heat exchange chamber interior. The temperature front is aligned perpendicular to the respective flow direc ^¬ tion of the heat exchange flow through the heat exchange chamber. During the charging mode the heat exchange flow is directed in a charging mode direction wherein the temperature front moves along this charging mode direction. In contrast to that, during the discharging mode the heat exchange flow is directed in the discharging mode direction (opposite to the charging mode direction) wherein the temperature front moves along the discharging mode direction. In both cases, the temperature front of the heat exchange chamber is migrat- ing through the heat exchange chamber to the respective hot/cold ends of the heat exchange chamber. It is to be noted that in case of countercurrent operation, the hot (hot open ^¬ ing) end remains the hot end (hot opening) , independently from the mode (charging mode or discharging mode) .

The temperature front is a zone of strong temperature gradi ^¬ ent in the heat storage material, i.e. high temperature dif ^¬ ference between hot and cold areas. In this application it separates the hot (charged with heat) and the cold (not charged) zone in the heat exchange chamber with the heat storage material. The temperature front develops due to the transfer of heat from the heat transfer fluid to the heat storage material during the charging mode and due to the transfer of heat from the heat storage material to the heat transfer fluid during the discharging mode. Isothermal zones/lines develop ideally (e.g. without the influence of gravitation) perpendicular to the main flow direction, i.e. zones/lines of constant temperature. In order to optimize the efficiency of the heat exchange sys ^¬ tem it is advantageous to ensure a uniform temperature front. There are just small variations concerning the temperature gradients perpendicular to the flow direction. In a vertical heat exchange chamber with a flow direction top down, the temperature front is nearly uniform due to natural convec ^¬ tion. So, in this case additional measures are not necessary. In contrast to that, natural convection leads to a non- uniform temperature front in a horizontal heat exchange cham ^¬ ber. So, in this case additional measures could be meaningful (like usage of more openings or usage of more flow adjusting elements) . Preferably, the chamber boundary with one of the openings comprises a transition area with a tapering profile such that an opening diameter of the opening aligns to a first tapering profile diameter of the tapering profile and a chamber diame ^¬ ter of the heat exchange chamber aligns to a second tapering profile diameter of the tapering profile. The transition area comprises an increasing cross section from the respective opening towards the heat exchange chamber. This is especially advantageous for the first opening for guiding the heat transfer fluid into the heat exchange chamber. The diameter of the transition area expands from the opening diameter of the first opening to the diameter of the heat exchange cham ^¬ ber. With the aid of the tapering profile the inflow of the heat transfer fluid is guided into the heat exchange chamber interior. The guided inflow is distributed to a wide area with the heat storage material. By this measure a capacity of the heat exchange unit (heat storage material which is locat ^¬ ed in the heat exchange chamber) can be highly exploited. In addition, the efficiency of the heat exchange can be improved by adapting the heat exchange flow. Remark: For additionally adapting the heat exchange flow, a diffuser can be located at the first opening, especially in the transition area. By means of the diffuser an incident flow of the heat transfer fluid into the heat exchange chamber interior can be adjust ^¬ ed. For instance, such a diffuser is formed by stones which are located in the transition area with the tapering profile.

For the case that the heat exchange chamber comprises a num ^¬ ber of first openings it is very advantageous to arrange a described transition area at that number of first openings. Thereby, the first openings can comprise a joint transition area or individual transition areas. The transition area with the second opening for guiding the heat transfer fluid out of the heat exchange chamber interior can be tapered, too. By this measure the guiding of heat flow out of the heat exchange chamber interior of the heat ex ^¬ change chamber is simplified.

In this context, the use of a short transition area is very advantageous. For instance, the short transition area com ^¬ prises a dimension which is less than 50% of a length of the heat exchange chamber. For instance, the dimension is about 20% of the length of the heat exchange chamber. The length is the dimension of the heat exchange chamber that is parallel to the main flow direction of the heat transfer fluid through the heat exchange chamber interior. But of course, the dimen ^¬ sion of the transition area is dependent on a number of fea- tures of the complete heat exchange system, e.g. temperature of the heat transfer fluid, mass flow of the heat exchange flow, speed of the heat exchange flow at the relevant opening temperatures, etc. In order to save space and in order to reduce the surface- volume ratio for a reduced heat loss, it is advantageous to implement a transition area as short as possible. The result is a short transition channel for guiding the inflow into the heat exchange chamber interior. Besides an efficient usage of the capacity of the heat exchange chamber a low space re ^¬ quirement is connected to this solution.

Preferably, the heat exchange chamber comprises a cylindri- cally shaped chamber boundary. For instance, the chamber boundary which comprises the first opening is formed as a circular cylinder and/or the chamber boundary with the second opening is formed as a circular cylinder. Such shapes lead to best surface-volume ratios. The dimensions of the heat exchange chamber can be different. But, the invention is especially advantageous for heat ex ^¬ change systems with large heat exchange chambers. Therefore, in a preferred embodiment, the horizontal heat exchange cham ^¬ ber comprises a heat exchange chamber length which is at least twice of a heat exchange chamber width of the heat ex ^¬ change chamber and/ or which is at least twice of a heat ex ^¬ change chamber height of the heat exchange chamber. Prefera- bly, the heat exchange chamber length is selected from the range between 20 m and 300 m. In addition, the heat exchange chamber width and/or the heat exchange chamber height are se ^¬ lected from the range of 1 m to 100 m. The heat exchange system is especially adapted for operation at high temperatures of more than 300 °C. Therefore, in a preferred embodiment, an operating temperature of the operat ^¬ ing mode is selected from the range between 300 °C and 1000 °C, preferably selected from the range between 500 °C and 1000 °C, more preferably selected from the range between 600 °C and 1000 °C, 650 °C to 1000 °C and most preferably between 700 °C and 1000 °C. A deviation of the temperature ranges is possible. In this context, very advantageous is an upper lim ^¬ it of the temperature range of 900 °C and most preferably an upper limit of the temperature range of 800 °C. The heat ex ^¬ change system is a high temperature heat exchange system.

The proposed invention can be applied for renewable energy production as well as for conventional energy production. For instance, in order to increase the flexibility the steam cy ^¬ cle of fossil fired power plants (or nuclear power plants, etc.) it can be combined with the heat exchange system pro ^¬ posed here. In this case, the boiler of the steam cycle of the power plant can be operated with fuel when fuel costs are lower than electricity costs and the heat exchange system is charged in periods when electricity prices are low. Alterna ^¬ tively, the charging can take place during a period of excess production of energy. With the invention the effectiveness of the thermal insula ^¬ tion of the heat exchange chamber is guaranteed. The improve ^¬ ment lies in the fact that the heat exchange chamber support structure material as well as an airtight sealing of the heat exchange chamber does not have to resist high temperatures and temperature changes. This means that the structure of the heat exchange chamber does not expand due to thermal expan ^¬ sion and expansion joints are not necessary. This reduces the overall system cost and contributes to achieve a cost- effective design. As a consequence the heat exchange bounda ^¬ ries (walls) of the heat exchange chamber are made of cheap materials, since they are not exposed to pressure or high temperature .

Following additional aspects of the invention:

- Overlapping layers of thermal insulation material. By this an uncontrolled flow of the heat transfer fluid out of the heat exchange chamber can be avoided.

- Combination of different layer with different thermal insu ^¬ lation materials. By this, "inner" layers which are close to the heat storage material comprise thermal insulation materi- al with high resistance to heat. Layers which are averted to the heat storage material can comprise thermal insulation ma ^¬ terial with low resistance to heat and which is cheaper in comparison the thermal insulation material of the "inner" layer .

- An inner layer of the thermal insulation layer can comprise material which is resistant to abrasion. This is advantageous if the thermal insulation layer is in direct contact with solid heat storage material or if a local velocity of the heat transfer fluid is high, e.g. 10 m/s . For instance, the thermal insulation layer comprises thermal insulation material that flow at high temperatures. - The thermal insulation layer can comprise an additional function as flow resistance layer. By this, heat transfer fluid does not leave the heat storage chamber interior uncon ^¬ trolled . - The thermal insulation layers can compensate thermal in ^¬ duced tensions of solid heat storage material.

Additionally, following aspects should be noted: The novelty in this invention lies in the insulation of a heat exchange chamber with interior thermal insulation materials.

These thermal insulation materials are installed between the heat storage material and a supporting structure of the heat exchange chamber. For instance, the supporting structure is a ceiling of the heat exchange chamber or other boundaries of the heat exchange chamber (e.g. side walls and the bottom of the heat exchange chamber) .

Furthermore the inlet opening and the outlet opening of the heat exchange chamber have to be coated internally with insu ^¬ lation material. The thermal insulation extends to the open ^¬ ings of the heat exchange chamber.

The interior insulation of the heat exchange chamber can be built with high temperature resistance material which can be made of heat insulating stones, heat-insulating tamping-clay, heat insulating sprayed or foamed material or heat-insulating casting mass. Furthermore it is possible to use heat- insulating fiber materials e.g. heat-insulating rock or min- eral wool or boards. These constructions are used for heat exchange chambers which are accessible for installation from the inside. It is also possible to thermal insulation layer to use dif ^¬ ferent thermal insulation materials and to arrange them for the specific purpose. The thermal insulation layer comprises a multilayer structure. Furthermore the insulation at the bottom relates to a defined geometry of the heat exchange chamber. This part of the insu ^¬ lation needs to have a high pressure resistance due to the impact of the weight of the heat storage material. In order to improve the stability a support element (1186) can be pro- vided.

The inner layer, e.g. a metal foil, is used to separate the main mass flow from the insulation, e.g. to protect the mineral wool from abrasion by the working fluid.

Another purpose of the protection of the insulation from the main mass flow is to reduce the thermal load of the interior of the insulation. This improves the insulation performance and reduces the temperature of the supporting wall or ceiling of the heat exchange chamber. This effect can also be

achieved by an inner insulation layer that is leakage tight instead of an inner liner.

BRIEF DESCRIPTION OF THE DRAWINGS

Further features and advantages of the invention are produced from the description of exemplary embodiments with reference to the drawings. The drawings are schematic. Figures 1 shows a heat exchange chamber of the heat exchange system.

Figure 2 shows a temperature distribution of the heat ex- change chamber of figure 1 in a charging mode.

Figure 3 shows the heat exchange system in a charging mode.

Figure 4 shows the heat exchanges system in a discharging mode.

Figure 5 shows the heat exchange chamber of figure 1 in a cross longitudinal cross section. Figure 6 shows the heat exchange chamber of figure 1 in a further cross section perpendicular to the longitudinal cross section .

DESCRIPTION OF PREFERRED EMBODIMENTS

Core of this invention is a heat exchange system 1 with a heat exchange chamber 11 on a high temperature level. At least one thermal insulation layer 1182 is at least partly arranged in the heat exchange chamber interior between the heat exchange chamber boundaries and the heat storage materi ^¬ al .

With the aid of the proposed heat exchange system 1, thermal energy can be stored on a high temperature level during the charging mode. This stored thermal energy can be used during the discharging mode for the production of steam in a water steam cycle for reconversion into electrical energy.

The heat exchange chamber 11 is at least partly arranged in at least one soil excavation 160 of a soil 161. In a not shown embodiment, the heat storage chamber 11 is not buried. The heat storage chamber is free standing. The heat storage boundaries are made of concrete. Heat storage material 121 (e.g. stones or sand) which is lo ^¬ cated in the heat exchange chamber interior 112 of the heat exchange chamber 11 can be charged and discharged with heat via the heat transfer fluid 13. Heat is stored by the heat storage material 121 and can be release from the storage ma- terial.

The temperature level of the stored heat is significantly higher compared to methods applied so far to increase the ef ^¬ ficiency. The temperature level lies between 300 °C and 1000 °C, preferably between 500 °C and 1000 °C, more preferably between 650 °C and 1000 °C and most preferably between 700 °C and 1000 °C. The thermal capacity of the heat exchange system 1 lies in the range between 0.3 GWh and 100 GWh which causes a thermal power of 50 MW.

The heat exchange system 1 comprises at least one heat ex ^¬ change chamber 11 with heat exchange chamber boundaries 111 which surround at least one heat exchange chamber interior 112 of the heat exchange chamber 11. The heat exchange cham- ber 11 is a horizontal heat exchange chamber 113.

The heat exchange chamber boundaries 111 comprise at least one first opening 1111 for guiding in an inflow 132 of at least one heat transfer fluid 131 into the heat exchange chamber interior 112 and at least one second opening 1112 for guiding an outflow 133 of the heat transfer fluid 131 out of the heat exchange chamber interior 112. At least one heat storage material 121 is arranged in the heat exchange chamber interior 112 such that a heat exchange flow 13 of the heat transfer fluid 131 through the heat exchange chamber interior 112 causes a heat exchange between the heat storage material 121 and the heat transfer fluid 131.

Exemplarily, the heat exchange chamber length of the horizon- tal heat exchange chamber 11 is about 200 m, the heat ex ^¬ change chamber height of the heat exchange chamber 11 is about 10 m and the heat exchange chamber width of the heat exchange chamber is about 50 m. For the manufacturing of the heat exchange chamber of the heat exchange system following manufacturing steps are carried out a) providing of the soil excavation of a soil (re ^¬ moving soil) and b) attaching of the thermal insulation layer to the component of the heat exchange chamber.

One or more heat exchange chambers 11 are filled with solid heat storage material 121. The solid heat storage material comprises stones. Alternatively, sand is used. There is a transition area 116 of the heat exchange chamber 11 with a tapering profile 1161. Thereby an opening diameter 1113 of the opening 1111 or 1112 aligns to a first tapering profile diameter 1162 of the tapering profile 1161 and a chamber diameter 117 of the heat exchange chamber 11 aligns to a second tapering profile diameter 1163 of the tapering profile 1161. The thermal insulation layer extends to the transition area.

The inflow 132 of the heat transfer fluid 13 is guided into the heat exchange chamber interior 112. The guided inflow 132 is distributed to a wide area of heat storage material 121. By this measure a capacity of the heat exchange unit (heat storage material 121 which is located in the heat exchange chamber interior 112) can be utilized in an advantageous man- ner.

The transition area 116 is short. The short transition area 116 projects into the heat exchange chamber 11. The result is a short transition channel for the guiding of the inflow 132 into the heat exchange chamber interior 112 of the heat ex ^¬ change chamber 11. The heat exchange system 1 is additionally equipped with at least one flow adjusting element 134 for adjusting a mass flow of the heat exchange flow 13 of the heat transfer fluid 131 through the heat exchange chamber interior 11. The flow adjusting element 134 is an active fluid motion device 1341 like a blower or a pump. Such a device enables a transporta ^¬ tion of the heat transfer fluid 131 through the heat exchange chamber interior 112 of the heat exchange chamber 11. The blower or the pump can be installed upstream or downstream of to the heat exchange chamber 11.

In the charging mode, the heat transfer fluid 131 enters the heat exchange chamber 11 through a diffuser 1164. The diffus- er 1164 comprises stones 1165 and is arranged at the transi ^¬ tion area 116 of the heat exchange chamber 11.

The heat exchange flow 13 of the heat transfer fluid 131 is directed in the charging mode direction 135. The flow adjust ^¬ ing element 134, 1341 is advantageous installed upstream of the charging unit 200, 201 (figure 3) : Relatively cold heat transfer fluid passes the flow adjusting element 134, 1341 before absorbing heat from the charging unit.

For the charging mode, the heat transfer fluid 131 is heated up from ambient conditions by the electrical heating device 201 (charging unit 200) . This charged (heated) heat transfer fluid is guided into the heat exchange chamber interior 112 of the heat exchange chamber 11 for charging of the heat storage material. Thereby the heat exchange between the heat transfer fluid and the heat storage material takes place. With reference 2000 the temperature front at a certain time of this charging process is shown (figure 2) . In addition, the temperature gradient 2001 which results in the tempera ^¬ ture front is depicted. For the discharging mode the heat exchange system 1 comprises one or several heat exchange chambers 11 mentioned above, an active fluid motion device 1341 to circulate the heat trans- fer fluid 131 and a thermal machine for re-electrification, which can be a water/steam cycle 1003. The working fluid of this cycle is water and steam. The water/steam cycle 1003 has the function of a discharging unit 400. Essential components of the steam turbine cycle 1003 are a steam turbine 1006 and a generator 1004.

In the discharging mode, the heat exchange flow of the heat transfer fluid is directed into the charging mode direction 136.

With the aid of the heat exchange system (heat exchanger) 1002 heat of the heat transfer fluid is transferred to the working fluid of the steam cycle 1003. The heat exchange system 1 comprises a closed loop 1005. Heat exchange fluid which has passed the heat exchange chamber in ^¬ terior 112 is guided back into the heat exchange chamber in ^¬ terior 112.