The present invention relates to phenyltriazolinones of the general formula (I) defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation.

US 5,084,085 describes structurally similar compounds, wherein the substituent corresponding to Z of the present invention is not attached via vicinal carbon atoms. However, the herbicidal properties of these known compounds with regard to the harmful plants are not always entirely satisfactory.

It is therefore an object of the present invention to provide phenyltriazolinones of formula (I) having improved herbicidal action. To be provided are in particular phenyltriazolinones of formula (I) which have high herbicidal activity, in particular even at low application rates, and which are sufficiently compatible with crop plants for commercial utilization.

These and further objects are achieved by the phenyltriazolinones of formula (I), defined below, and by their agriculturally suitable salts.

Accordingly, the present invention provides phenyltriazolinones of formula (I)

wherein the substituents have the following meanings:

R ¹ hydrogen, Ci-C6-alkyl or Ci-C6-haloalkyl;

R ² hydrogen, Ci-C6-alkyl or Ci-C6-haloalkyl;

R ³ H or halogen;

R ⁴ halogen, CN, N0 ₂ or NH ₂ ;

R ⁵ H, halogen, CN, d-C ₃ -alkyl, Ci-C ₃ -haloalkyl, Ci-C ₃ -alkoxy, Ci-C ₃ -haloalkoxy, Ci-C ₃ - alkylthio, (Ci-C ₃ -alkyl)amino, di(Ci-C ₃ -alkyl)amino, Ci-C ₃ -alkoxy-Ci-C ₃ -alkyl, Ci-C ₃ - alkoxycarbonyl;

R ⁶ H, halogen, Ci-C ₃ -alkyl, Ci-C ₃ -alkoxy;

R ⁷ OR ⁸ , SR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ OR ⁸ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °, wherein

R ⁸ is hydrogen, Ci-C6-alkyl, C ₃ -C6-alkenyl, C ₃ -C6-alkynyl, Ci-C6-haloalkyl, C ₃ -C6- haloalkenyl, C ₃ -C6-haloalkynyl, Ci-C6-cyanoalkyl, Ci-C6-alkoxy-Ci-C6-alkyl, Ci- C6-alkoxy-Ci-C6-alkoxy-Ci-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, Ci-C6-halo- alkoxy-Ci-C6-alkyl, C ₃ -C6-alkenyloxy-Ci-C6-alkyl, C ₃ -C6-haloalkenyloxy-Ci-C6- alkyl, C3-C6-alkenyloxy-Ci-C6-alkoxy-Ci-C6-alkyl, Ci-C6-alkylthio-Ci-C6-alkyl, Ci-C ₆ -alkylsulfinyl-Ci-C ₆ -alkyl, Ci-C ₆ -alkylsulfonyl-Ci-C ₆ -alkyl, Ci-C ₆ - alkylcarbonyl-Ci-C6-alkyl, Ci-C6-alkoxycarbonyl-Ci-C6-alkyl, C1-C6- haloalkoxycarbonyl-Ci-C6-alkyl, C3-C6-alkenyloxycarbonyl-Ci-C6-alkyl, C3-C6- alkynyloxycarbonyl-Ci-C6-alkyl, amino, (Ci-C6-alkyl)amino, di(Ci-C6- alkyl)amino, (Ci-C6-alkylcarbonyl)amino, amino-Ci-C6-alkyl, (C1-C6- alkyl)amino-Ci-C6-alkyl, di(Ci-C6-alkyl)amino-Ci-C6-alkyl, aminocarbonyl-Ci- C6-alkyl, (Ci-C6-alkyl)aminocarbonyl-Ci-C6-alkyl, di(Ci-C6-alkyl)aminocarbonyl- d-Ce-alkyl,

-N=CR ¹¹ R ¹² , wherein R ¹¹ and R ¹² independently of one another are H, C1-C4- alkyl or phenyl;

C3-C6-cycloalkyl, C3-C6-cycloalkyl-Ci-C6-alkyl, C3-C6-heterocyclyl, C3-C6- heterocyclyl-Ci-C6-alkyl, phenyl, phenyl-Ci-C4-alkyl or a 5- or 6 membered heteroaryl,

wherein each cycloalkyl, heterocyclyl, phenyl or heteroaryl ring can be substituted by one to four substituents selected from R ¹³ or a 3- to 7- membered carbocyclus,

which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of -N(R ¹¹ )-, -N=N-, -C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ;

wherein R ¹³ is halogen, NO2, CN, Ci-C4-alkyl, Ci-C4-halo- alkyl, Ci-C4-alkoxy or Ci-C4-alkoxycarbonyl; R ⁹ , R ¹⁰ independently of one another are R ⁸ , or together form a 3- to 7-membered carbocyclus,

which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of -N(R ¹¹ )-, -N=N-, - C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ;

n 1 to 3;

Q O, S, SO, S0 ₂ , NH or (Ci-C ₃ -alkyl)N;

W O or S;

X O or S;

Y O or S;

Z phenyl, pyridyl, pyridazinyl, pyrimidinyl or pyrazinyl,

each of which is attached to X and Q via vicinal carbon atoms, and each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN , Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy,

Ci-C6-haloalkoxy; including their agriculturally acceptable salts or derivatives, provided the compounds of formula (I) have a carboxyl group. The present invention also provides agrochemical compositions comprising at least one phenyltriazolinone of formula (I) and auxiliaries customary for formulating crop protection agents.

The present invention also provides herbicidal compositions comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C).

The present invention also provides the use of phenyltriazolinones of formula (I) as herbicides, i.e. for controlling harmful plants.

The present invention furthermore provides a method for controlling unwanted vegetation where a herbicidal effective amount of at least one phenyltriazolinones of the formula (I) is allowed to act on plants, their seeds and/or their habitat. Application can be done before, during and/or after, preferably during and/or after, the emergence of the undesirable plants.

Moreover, the invention relates to processes and intermediates for preparing

phenyltriazolinones of formula (I).

Further embodiments of the present invention are evident from the claims, the description and the examples. It is to be understood that the features mentioned above and still to be illustrated below of the subject matter of the invention can be applied not only in the combination given in each particular case but also in other combinations, without leaving the scope of the invention.

As used herein, the terms "controlling" and "combating" are synonyms.

As used herein, the terms "undesirable vegetation" and "harmful plants" are synonyms. If the phenyltriazolinones of formula (I), the herbicidal compounds B and/or the safeners C as described herein are capable of forming geometrical isomers, for example E/Z isomers, it is possible to use both, the pure isomers and mixtures thereof, in the compositions according to the invention. If the phenyltriazolinones of formula (I), the herbicidal compounds B and/or the safeners C as described herein have one or more centres of chirality and, as a consequence, are present as enantiomers or diastereomers, it is possible to use both, the pure enantiomers and diastere- omers and their mixtures, in the compositions according to the invention. If the phenyltriazolinones of formula (I), the herbicidal compounds B and/or the safeners C as described herein have ionizable functional groups, they can also be employed in the form of their agriculturally acceptable salts. Suitable are, in general, the salts of those cations and the acid addition salts of those acids whose cations and anions, respectively, have no adverse effect on the activity of the active compounds. Preferred cations are the ions of the alkali metals, preferably of lithium, sodium and potassium, of the alkaline earth metals, preferably of calcium and magnesium, and of the transition metals, preferably of manganese, copper, zinc and iron, further ammonium and substituted ammonium in which one to four hydrogen atoms are replaced by Ci-C4-alkyl, hydroxy-Ci-C4-alkyl, C1-C4- alkoxy-Ci-C4-alkyl, hydroxy-Ci-C4-alkoxy-Ci-C4-alkyl, phenyl or benzyl, preferably ammonium, methylammonium, isopropylammonium, dimethylammonium, diethylammonium, diisoprop- ylammonium, trimethylammonium, triethylammonium, tris(isopropyl)ammonium, heptylammoni- um, dodecylammonium, tetradecylammonium, tetramethylammonium, tetraethylammonium, tetrabutylammonium, 2-hydroxyethylammonium (olamine salt), 2-(2-hydroxyeth-1 -oxy)eth-1 - ylammonium (diglycolamine salt), di(2-hydroxyeth-1 -yl)ammonium (diolamine salt), tris(2- hydroxyethyl)ammonium (trolamine salt), tris(2-hydroxypropyl)ammonium, benzyltrime- thylammonium, benzyltriethylammonium, Ν,Ν,Ν-trimethylethanolammonium (choline salt), furthermore phosphonium ions, sulfonium ions, preferably tri(Ci-C4-alkyl)sulfonium, such as trime- thylsulfonium, and sulfoxonium ions, preferably tri(Ci-C4-alkyl)sulfoxonium, and finally the salts of polybasic amines such as N,N-bis-(3-aminopropyl)methylamine and diethylenetriamine.

Anions of useful acid addition salts are primarily chloride, bromide, fluoride, iodide, hydrogensul- fate, methylsulfate, sulfate, dihydrogenphosphate, hydrogenphosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate and also the anions of C1-C4- alkanoic acids, preferably formate, acetate, propionate and butyrate.

Phenyltriazolinones of formula (I), herbicidal compounds B and/or safeners C as described herein having a carboxyl group can be employed in the form of the acid, in the form of an agriculturally suitable salt as mentioned above or else in the form of an agriculturally acceptable derivative, for example as amides, such as mono- and di-Ci-C6-alkylamides or arylamides, as esters, for example as allyl esters, propargyl esters, Ci-Cio-alkyl esters, alkoxyalkyl esters, te- furyl ((tetrahydrofuran-2-yl)methyl) esters and also as thioesters, for example as Ci-Cio-alkylthio esters. Preferred mono- and di-Ci-C6-alkylamides are the methyl and the dimethylamides. Preferred arylamides are, for example, the anilides and the 2-chloroanilides. Preferred alkyl esters are, for example, the methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, mexyl

(1 -methylhexyl), meptyl (1 -methylheptyl), heptyl, octyl or isooctyl (2-ethylhexyl) esters. Preferred Ci-C4-alkoxy-Ci-C4-alkyl esters are the straight-chain or branched Ci-C4-alkoxy ethyl esters, for example the 2-methoxyethyl, 2-ethoxyethyl, 2-butoxyethyl (butotyl), 2-butoxypropyl or 3- butoxypropyl ester. An example of a straight-chain or branched Ci-Cio-alkylthio ester is the ethylthio ester.

The ring "Z" is attached to X and Q via vicinal, i.e. adjacent, carbon atoms.

Accordingly, for "Z" being phenyl, the attachment of the phenyl ring between X and Q is as follows: optionally substituted

by 1 to 4 substituents

as defined

Accordingly, for "Z" being unsubstituted pyridyl, the possibilities of the attachment of the pyridyl ring between X and Q are as follows:

The organic moieties mentioned in the definition of the variables R ¹ to R ¹³ and R ^a to R ^e , are - like the term halogen - collective terms for individual enumerations of the individual group mem- bers. The term halogen denotes in each case fluorine, chlorine, bromine or iodine. All hydrocarbon chains, e.g. all alkyl, alkenyl, alkynyl, alkoxy chains, can be straight-chain or branched, the prefix C _n -C _m denoting in each case the possible number of carbon atoms in the group.

Examples of such meanings are:

- Ci-C3-alkyl and also the Ci-C3-alkyl moieties of di(Ci-C3-alkyl)amino, Ci-C3-alkoxy-Ci-C3- alkyl: for example CH3, C2H5, n-propyl and CH(CH3)2;

Ci-C4-alkyl and also the Ci-C4-alkyl moieties of phenyl-Ci-C4-alkyl: for example CH3, C ₂ H ₅ , n-propyl, CH(CH ₃ ) ₂ , n-butyl, CH(CH ₃ )-C ₂ H ₅ , CH ₂ -CH(CH ₃ ) ₂ and C(CH ₃ ) ₃ ;

Ci-C6-alkyl and also the Ci-C6-alkyl moieties of Ci-C6-cyanoalkyl, Ci-C6-alkyoxy-Ci-C6- alkyl, Ci-Ce-alkoxy-Ci-Ce-alkoxy-Ci-Ce-alkyl, di(Ci-C ₆ -alkoxy)Ci-C ₆ -alkyl, Ci-Ce-haloalkoxy-Ci- C6-alkyl, C3-C6-alkenyloxy-Ci-C6-alkyl, C3-C6-haloalkenyloxy-Ci-C6-alkyl, C3-C6-alkenyloxy-Ci- C ₆ -alkoxy-Ci-C ₆ -alkyl, Ci-C ₆ -alkylthio-Ci-C ₆ -alkyl, Ci-C ₆ -alkylsulfinyl-Ci-C ₆ -alkyl, Ci-C ₆ - alkylsulfonyl-Ci-C6-alkyl, Ci-C6-alkylcarbonyl-Ci-C6-alkyl, Ci-C6-alkoxycarbonyl-Ci-C6-alkyl, Ci- C6-haloalkoxycarbonyl-Ci-C6-alkyl, C3-C6-alkenyloxycarbonyl-Ci-C6-alkyl, C3-C6- alkynyloxycarbonyl-Ci-C6-alkyl, (Ci-C6-alkylcarbonyl)amino, amino-Ci-C6-alkyl, (C1-C6- alkyl)amino-Ci-C6-alkyl, di(Ci-C6-alkyl)amino-Ci-C6-alkyl, aminocarbonyl-Ci-C6-alkyl, (C1-C6- alkyl)aminocarbonyl-Ci-C6-alkyl, di(Ci-C6-alkyl)aminocarbonyl-Ci-C6-alkyl, C3-C6-cycloalkyl-Ci- C6-alkyl, C3-C6-heterocyclyl-Ci-C6-alkyl: Ci-C4-alkyl as mentioned above, and also, for example, n-pentyl, 1 -methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1 -ethyl propyl, n-hexyl, 1 ,1 -dimethylpropyl, 1 ,2-dimethylpropyl, 1 -methylpentyl, 2-methylpentyl, 3-methylpentyl, 4- methylpentyl, 1 ,1 -dimethylbutyl, 1 ,2-dimethylbutyl, 1 ,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3- dimethylbutyl, 3,3-dimethylbutyl, 1 -ethylbutyl, 2-ethylbutyl, 1 ,1 ,2-trimethylpropyl, 1 ,2,2- trimethylpropyl, 1 -ethyl-1 -methylpropyl or 1 -ethyl-2-methylpropyl, preferably methyl, ethyl, n- propyl, 1-methylethyl, n-butyl, 1 ,1-dimethylethyl, n-pentyl or n-hexyl;

- Ci-C3-haloalkyl: Ci-C3-alkyl as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, for example, chloromethyl, dichloromethyl, trichlorome- thyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlo- rodifluoromethyl, bromomethyl, iodomethyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2- iodoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, 2-fluoropropyl, 3-fluoropropyl, 2,2-difluoropropyl, 2,3-difluoropropyl, 2-chloropropyl, 3-chloropropyl, 2,3-dichloropropyl, 2- bromopropyl, 3-bromopropyl, 3,3,3-trifluoropropyl, 3,3,3-trichloropropyl, 2,2,3,3,3- pentafluoropropyl, heptafluoropropyl, 1 -(fluoromethyl)-2-fluoroethyl, 1 -(chloromethyl)-2- chloroethyl, 1 -(bromomethyl)-2-bromoethyl;

Ci-C4-haloalkyl: Ci-C4-alkyl as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, for example, chloromethyl, dichloromethyl, trichlorome- thyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlo- rodifluoromethyl, bromomethyl, iodomethyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2- iodoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl, 2-fluoropropyl, 3-fluoropropyl, 2,2-difluoropropyl, 2,3-difluoropropyl, 2-chloropropyl, 3-chloropropyl, 2,3-dichloropropyl, 2- bromopropyl, 3-bromopropyl, 3,3,3-trifluoropropyl, 3,3,3-trichloropropyl, 2,2,3,3,3- pentafluoropropyl, heptafluoropropyl, 1 -(fluoromethyl)-2-fluoroethyl, 1 -(chloromethyl)-2- chloroethyl, 1 -(bromomethyl)-2-bromoethyl, 4-fluorobutyl, 4-chlorobutyl, 4-bromobutyl, no- nafluorobutyl, 1 ,1 ,2,2,-tetrafluoroethyl and 1 -trifluoromethyl-1 ,2,2,2-tetrafluoroethyl;

- Ci-C6-haloalkyl: Ci-C4-haloalkyl as mentioned above, and also, for example,

5- fluoropentyl, 5-chloropentyl, 5-bromopentyl, 5-iodopentyl, undecafluoropentyl, 6-fluorohexyl,

6- chlorohexyl, 6-bromohexyl, 6-iodohexyl and dodecafluorohexyl;

C3-C6-alkenyl and also the C3-C6-alkenyl moieties of C3-C6-alkenyloxy-Ci-C6-alkyl, C3-C6- alkenyloxy-Ci-C6-alkoxy-Ci-C6-alkyl, C3-C6-alkenyloxycarbonyl-Ci-C6-alkyl: for example 1 - propenyl, 2-propenyl, 1 -methylethenyl, 1 -butenyl, 2-butenyl, 3-butenyl, 1 -methyl-1 -propenyl, 2- methyl-1 -propenyl, 1 -methyl-2-propenyl, 2-methyl-2-propenyl, 1 -pentenyl, 2-pentenyl,

3-pentenyl, 4-pentenyl, 1 -methyl-1 -butenyl, 2-methyl-1 -butenyl, 3-methyl-1 -butenyl, 1 -methyl-2- butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3- methyl-3-butenyl, 1 ,1 -dimethyl-2-propenyl, 1 ,2-dimethyl-1 -propenyl, 1 ,2-dimethyl-2-propenyl, 1 - ethyl-1 -propenyl, 1 -ethyl-2-propenyl, 1 -hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1 - methyl-1 -pentenyl, 2-methyl-1 -pentenyl, 3-methyl-1 -pentenyl, 4-methyl-1 -pentenyl, 1 -methyl- 2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1 -methyl-3- pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1 -methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1 ,1 -dimethyl-2-butenyl, 1 ,1 - dimethyl-3-butenyl, 1 ,2-dimethyl-1 -butenyl, 1 ,2-dimethyl-2-butenyl, 1 ,2-dimethyl-3-butenyl, 1 ,3- dimethyl-1 -butenyl, 1 ,3-dimethyl-2-butenyl, 1 ,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3- dimethyl-1 -butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1 -butenyl, 3,3- dimethyl-2-butenyl, 1 -ethyl-1 -butenyl, 1 -ethyl-2-butenyl, 1 -ethyl-3-butenyl, 2-ethyl-1 -butenyl, 2- ethyl-2-butenyl, 2-ethyl-3-butenyl, 1 ,1 ,2-trimethyl-2-propenyl, 1 -ethyl-1 -methyl-2-propenyl, 1 - ethyl-2-methyl-1 -propenyl and 1 -ethyl-2-methyl-2-propenyl;

C3-C6-haloalkenyl and also the C3-C6-haloalkenyl moieties of C3-C6-haloalkenyloxy-Ci-C6- alkyl: a C3-C6-alkenyl radical as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, for example 2-chloroprop-2-en-1 -yl, 3-chloroprop-2-en-1 - yl, 2,3-dichloroprop-2-en-1 -yl, 3,3-dichloroprop-2-en-1 -yl, 2,3,3-trichloro-2-en-1 -yl, 2,3- dichlorobut-2-en-1 -yl, 2-bromoprop-2-en-1 -yl, 3-bromoprop-2-en-1 -yl, 2,3-dibromoprop-2-en-1 - yl, 3,3-dibromoprop-2-en-1 -yl, 2,3,3-tribromo-2-en-1 -yl or 2,3-dibromobut-2-en-1 -yl;

C3-C6-alkynyl and also the C3-C6-alkynyl moieties of C3-C6-alkynyloxycarbonyl-Ci-C6-alkyl: for example 1 -propynyl, 2-propynyl, 1 -butynyl, 2-butynyl, 3-butynyl, 1 -methyl-2-propynyl, 1 - pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1 -methyl-2-butynyl, 1 -methyl-3-butynyl, 2-methyl-3- butynyl, 3-methyl-1 -butynyl, 1 ,1 -dimethyl-2-propynyl, 1 -ethyl-2-propynyl, 1 -hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1 -methyl-2-pentynyl, 1 -methyl-3-pentynyl, 1 -methyl-4-pentynyl,

2- methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl-1 -pentynyl, 3-methyl-4-pentynyl, 4-methyl-1 - pentynyl, 4-methyl-2-pentynyl, 1 ,1 -dimethyl-2-butynyl, 1 ,1 -dimethyl-3-butynyl, 1 ,2-dimethyl-3- butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1 -butynyl, 1 -ethyl-2-butynyl, 1 -ethyl-3-butynyl, 2- ethyl-3-butynyl and 1 -ethyl-1 -methyl-2-propynyl;

C3-C6-haloalkynyl: a C3-C6-alkynyl radical as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, for example 1 ,1 -difluoroprop-2-yn-1 -yl,

3- chloroprop-2-yn-1 -yl, 3-bromoprop-2-yn-1 -yl, 3-iodoprop-2-yn-1 -yl, 4-fluorobut-2-yn-1 -yl, 4- chlorobut-2-yn-1 -yl, 1 ,1 -difluorobut-2-yn-1 -yl, 4-iodobut-3-yn-1 -yl, 5-fluoropent-3-yn-1 -yl,

5-iodopent-4-yn-1 -yl, 6-fluorohex-4-yn-1 -yl or 6-iodohex-5-yn-1 -yl;

Ci-C3-alkoxy and also the Ci-C3-alkoxy moieties of Ci-C3-alkoxy-Ci-C3-alkyl, C1-C3- alkoxycarbonyl: for example methoxy, ethoxy, propoxy;

Ci-C4-alkoxy and also the Ci-C4-alkoxy moieties of Ci-C4-alkoxycarbonyl: for example methoxy, ethoxy, propoxy, 1 -methylethoxy butoxy, 1 -methylpropoxy, 2-methylpropoxy and 1 ,1 - dimethylethoxy;

Ci-C6-alkoxy and also the Ci-C6-alkoxy moieties of Ci-C6-alkyoxy-Ci-C6-alkyl, C1-C6- alkoxy-Ci-C6-alkoxy-Ci-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, C3-C6-alkenyloxy-Ci-C6-alkoxy-Ci- C6-alkyl, Ci-C6-alkoxycarbonyl-Ci-C6-alkyl: Ci-C4-alkoxy as mentioned above, and also, for ex- ample, pentoxy, 1 -methylbutoxy, 2-methylbutoxy, 3-methoxylbutoxy, 1 ,1 -dimethylpropoxy, 1 ,2- dimethylpropoxy, 2,2-dimethylpropoxy, 1 -ethylpropoxy, hexoxy, 1 -methylpentoxy, 2- methylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1 ,1 -dimethylbutoxy, 1 ,2-dimethylbutoxy, 1 ,3- dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1 -ethylbutoxy, 2-ethylbutoxy, 1 ,1 ,2-trimethylpropoxy, 1 ,2,2-trimethylpropoxy, 1 -ethyl-1 -methylpropoxy and 1 - ethyl-2-methylpropoxy.

Ci-C3-haloalkoxy: a Ci-C3-alkoxy radical as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, i.e., for example, fluoromethoxy, difluo- romethoxy, trifluoromethoxy, chlorodifluoromethoxy, bromodifluoromethoxy, 2-fluoroethoxy, 2- chloroethoxy, 2-bromomethoxy, 2-iodoethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro- 2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, 2-fluoropropoxy, 3-fluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, 2- bromopropoxy, 3-bromopropoxy, 2,2-difluoropropoxy, 2,3-difluoropropoxy, 2,3-dichloropropoxy, 3,3,3-trifluoropropoxy, 3,3,3-trichloropropoxy, 2,2,3,3,3-pentafluoropropoxy, heptafluoropropoxy, 1 -(fluoromethyl)-2-fluoroethoxy, 1 -(chloromethyl)-2-chloroethoxy, 1 -(bromomethyl)-2- bromoethoxy;

Ci-C4-haloalkoxy: a Ci-C4-alkoxy radical as mentioned above which is partially or fully substituted by fluorine, chlorine, bromine and/or iodine, i.e., for example, fluoromethoxy, difluo- romethoxy, trifluoromethoxy, chlorodifluoromethoxy, bromodifluoromethoxy, 2-fluoroethoxy, 2- chloroethoxy, 2-bromomethoxy, 2-iodoethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro- 2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy, pentafluoroethoxy, 2-fluoropropoxy, 3-fluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, 2- bromopropoxy, 3-bromopropoxy, 2,2-difluoropropoxy, 2,3-difluoropropoxy, 2,3-dichloropropoxy, 3,3,3-trifluoropropoxy, 3,3,3-trichloropropoxy, 2,2,3,3,3-pentafluoropropoxy, heptafluoropropoxy, 1 -(fluoromethyl)-2-fluoroethoxy, 1 -(chloromethyl)-2-chloroethoxy, 1 -(bromomethyl)-2- bromoethoxy, 4-fluorobutoxy, 4-chlorobutoxy, 4-bromobutoxy and nonafluorobutoxy;

Ci-C6-haloalkoxy and also the Ci-C6-haloalkoxy moieties of Ci-C6-haloalkoxy-Ci-C6-alkyl, Ci-C6-haloalkoxycarbonyl-Ci-C6-alkyl: a Ci-C4-haloalkoxy as mentioned above, and also, for example, 5-fluoropentoxy, 5-chloropentoxy, 5-bromopentoxy, 5-iodopentoxy, undecafluoro- pentoxy, 6-fluorohexoxy, 6-chlorohexoxy, 6-bromohexoxy, 6-iodohexoxy and dodecafluoro- hexoxy;

Ci-C3-alkylthio: for example methylthio, ethylthio, propylthio, 1 -methylethylthio;

Ci-C4-alkylthio: for example methylthio, ethylthio, propylthio, 1 -methylethylthio, butylthio, 1 -methylpropylthio, 2-methylpropylthio and 1 ,1 -dimethylethylthio;

- Ci-C6-alkylthio and also the Ci-C6-alkylthio moieties of Ci-C6-alkylthio-Ci-C6-alkyl: C1-C4- alkylthio as mentioned above, and also, for example, pentylthio, 1 -methylbutylthio, 2-methyl- butylthio, 3-methylbutylthio, 2,2-dimethylpropylthio, 1 -ethylpropylthio, hexylthio, 1 ,1 -di- methylpropylthio, 1 ,2-dimethylpropylthio, 1 -methylpentylthio, 2-methylpentylthio, 3-methyl- pentylthio, 4-methylpentylthio, 1 ,1 -dimethylbutylthio, 1 ,2-dimethylbutylthio, 1 ,3-dimethylbutylthio, 2,2-dimethylbutylthio, 2,3-dimethylbutylthio, 3,3-dimethylbutylthio, 1 -ethylbutylthio, 2- ethylbutylthio, 1 ,1 ,2-trimethylpropylthio, 1 ,2,2-trimethylpropylthio, 1 -ethyl-1 -methylpropylthio and 1 - ethyl-2-methylpropylthio;

C 1 -C6-a I ky I s u If i ny I (Ci-C6-alkyl-S(=0)-) and also the Ci-C6-alkylsulfinyl moieties of C1-C6- alkylsulfinyl-Ci-C6-alkyl: for example methylsulfinyl, ethylsulfinyl, propylsulfinyl, 1 -me- thylethylsulfinyl, butylsulfinyl, 1 -methylpropylsulfinyl, 2-methylpropylsulfinyl, 1 ,1 -di- methylethylsulfinyl, pentylsulfinyl, 1 -methylbutylsulfinyl, 2-methylbutylsulfinyl, 3- methylbutylsulfinyl, 2,2-dimethylpropylsulfinyl, 1 -ethylpropylsulfinyl, 1 ,1 -dimethylpropylsulfinyl, 1 ,2-dimethylpropylsulfinyl, hexylsulfinyl, 1 -methylpentylsulfinyl, 2-methylpentylsulfinyl, 3- methylpentylsulfinyl, 4-methylpentyl-sulfinyl, 1 ,1 -dimethylbutylsulfinyl, 1 ,2-dimethylbutylsulfinyl, 1 ,3-dimethylbutyl-sulfinyl, 2,2-dimethylbutylsulfinyl, 2,3-dimethylbutylsulfinyl, 3,3-dimethylbutyl- sulfinyl, 1 -ethylbutylsulf inyl , 2-ethylbutylsulfinyl, 1 ,1 ,2-trimethylpropylsulfinyl, 1 ,2,2- trimethylpropylsulfinyl, 1 -ethyl-1 -methylpropylsulfinyl and 1 -ethyl-2-methylpropylsulfinyl;

Ci-C6-alkylsulfonyl (Ci-C6-alkyl-S(0)2-) and also the Ci-C6-alkylsulfonyl moieties of C1-C6- alkylsulfonyl-Ci-C6-alkyl: for example methylsulfonyl, ethylsulfonyl, propylsulfonyl, 1 - methylethylsulfonyl, butylsulfonyl, 1 -methylpropylsulfonyl, 2-methyl-propylsulfonyl, 1 ,1 - dimethylethylsulfonyl, pentylsulfonyl, 1 -methylbutylsulfonyl, 2-methylbutylsulfonyl, 3- methylbutylsulfonyl, 1 ,1 -dimethylpropylsulfonyl, 1 ,2-dimethylpropylsulfonyl, 2,2- dimethylpropylsulfonyl, 1 -ethylpropylsulfonyl, hexylsulfonyl, 1 -methylpentylsulfonyl, 2- methylpentylsulfonyl, 3-methylpentylsulfonyl, 4-methylpentylsulfonyl, 1 ,1 -dimethylbutylsulfonyl, 1 ,2-dimethylbutylsulfonyl, 1 ,3-dimethylbutylsulfonyl, 2,2-dimethylbutylsulfonyl, 2,3-dimethyl- butylsulfonyl, 3,3-dimethylbutylsulfonyl, 1 -ethylbutylsulfonyl, 2-ethylbutylsulfonyl, 1 ,1 ,2-trimethyl- propylsulfonyl, 1 ,2,2-trimethylpropylsulfonyl, 1 -ethyl-1 -methylpropylsulfonyl and 1 -ethyl-2- methylpropylsulfonyl;

(Ci-C3-alkyl)amino: for example methylamino, ethylamino, propylamino, 1 -methylethyl- amino;

(Ci-C4-alkyl)amino: for example methylamino, ethylamino, propylamino, 1 -methylethyl- amino, butylamino, 1 -methylpropylamino, 2-methylpropylamino or 1 ,1 -dimethylethylamino;

(Ci-C6-alkyl)amino: (Ci-C4-alkylamino) as mentioned above, and also, for example, pen- tylamino, 1 -methylbutylamino, 2-methylbutylamino, 3-methylbutylamino, 2,2- dimethylpropylamino, 1 -ethylpropylamino, hexylamino, 1 ,1 -dimethylpropylamino, 1 ,2- dimethylpropylamino, 1 -methylpentylamino, 2-methylpentylamino, 3-methylpentylamino, 4- methylpentylamino, 1 ,1 -dimethylbutylamino, 1 ,2-dimethylbutylamino, 1 ,3-dimethylbutylamino, 2,2-dimethylbutylamino, 2,3-dimethylbutyl-amino 3,3-dimethylbutylamino, 1 -ethylbutylamino, 2- ethylbutylamino, 1 ,1 ,2-trimethylpropylamino, 1 ,2,2-trimethyl-propylamino, 1 -ethyl-1 - methylpropylamino or 1 -ethyl-2-methylpropylamino;

di(Ci-C6-alkyl)amino: di(Ci-C4-alkyl)amino as mentioned above, and also, for example, N- methyl-N-pentylamino, N-methyl-N-(1 -methylbutyl)amino, N-methyl-N-(2-methylbutyl)amino, N- methyl-N-(3-methylbutyl)amino, N-methyl-N-(2,2-dimethylpropyl)amino, N-methyl-N-(1 - ethylpropyl)amino, N-methyl-N-hexylamino, N-methyl-N-(1 ,1 -dimethylpropyl)amino, N-methyl-N- (1 ,2-dimethylpropyl)amino, N-methyl-N-(1 -methylpentyl)amino, N-methyl-N-(2- methylpentyl)amino, N-methyl-N-(3-methylpentyl)amino, N-methyl-N-(4-methylpentyl)amino, N- methyl-N-(1 ,1 -dimethylbutyl)amino, N-methyl-N-(1 ,2-dimethylbutyl)amino, N-methyl-N-(1 ,3- dimethylbutyl)amino, N-methyl-N-(2,2-dimethylbutyl)amino, N-methyl-N-(2,3- dimethylbutyl)amino, N-methyl-N-(3,3-dimethylbutyl)amino, N-methyl-N- (l -ethylbutyl)amino, N- methyl-N-(2-ethylbutyl)amino, N-methyl-N-(1 ,1 ,2-trimethylpropyl)amino, N-methyl-N- (1 ,2,2- trimethylpropyl)amino, N-methyl-N-(1 -ethyl-1 -methylpropyl)amino, N-methyl-N- (1 -ethyl-2- methylpropyl)amino, N-ethyl-N-pentylamino, N-ethyl-N-(1 -methylbutyl)amino, N-ethyl-N-(2- methylbutyl)amino, N-ethyl-N-(3-methylbutyl)amino, N-ethyl-N-(2,2-dimethylpropyl)amino, N- ethyl-N-(1 -ethylpropyl)amino, N-ethyl-N-hexylamino, N-ethyl-N-(1 ,1 -dimethylpropyl)amino, N- ethyl-N-(1 ,2-dimethylpropyl)amino, N-ethyl-N-(1 -methylpentyl)amino, N-ethyl-N-(2-methyl- pentyl)amino, N-ethyl-N-(3-methylpentyl)amino, N-ethyl-N-(4-methylpentyl)amino, N-ethyl-N- (1 ,1 -dimethylbutyl)amino, N-ethyl-N-(1 ,2-dimethylbutyl)amino, N-ethyl-N-(1 ,3- dimethylbutyl)amino, N-ethyl-N-(2,2-dimethylbutyl)amino, N-ethyl-N-(2,3-dimethylbutyl)amino, N-ethyl-N-(3,3-dimethylbutyl)amino, N-ethyl-N-(1 -ethylbutyl)amino, N-ethyl-N-(2- ethylbutyl)amino, N-ethyl-N-(1 ,1 ,2-trimethylpropyl)amino, N-ethyl-N-(1 ,2,2- trimethylpropyl)amino, N-ethyl-N-(1 -ethyl-1 -methylpropyl)amino, N-ethyl-N-(1 -ethyl-2- methylpropyl)amino, N-propyl-N-pentylamino, N-butyl-N-pentylamino, Ν,Ν-dipentylamino, N- propyl-N-hexylamino, N-butyl-N-hexylamino, N-pentyl-N-hexylamino or N,N-dihexylamino; - C3-C6-cycloalkyl and also the cycloalkyl moieties of C3-C6-cycloalkyl-Ci-C6-alkyl: monocyclic saturated hydrocarbons having 3 to 6 ring members, such as cyclopropyl, cyclobutyl, cyclo- pentyl and cyclohexyl;

C3-C6-heterocyclyl and also the heterocyclyl moieties of C3-C6-heterocyclyl-Ci-C6-alkyl: aliphatic heterocycle having 3 to 6 ring members which, in addition to carbon atoms, containsl to 4 nitrogen atoms, or 1 to 3 nitrogen atoms and an oxygen or sulphur atom, or an oxygen or a sulphur atom, for example

three- or four-membered heterocycles like 2-oxetanyl, 3-oxetanyl, 2-thietanyl, 3-thietanyl, 1 - azetidinyl, 2-azetidinyl, 1 -azetinyl, 2-azetinyl; five-membered saturated heterocycles like 2- tetrahydrofuranyl, 3-tetrahydrofuranyl, 2-tetrahydrothienyl, 3-tetrahydrothienyl, 1 -pyrrolidinyl,2- pyrrolidinyl, 3-pyrrolidinyl, 3-isoxazolidinyl, 4-isoxazolidinyl, 5-isoxazolidinyl, 2-isothiazolidinyl, 3- isothiazolidinyl, 4-isothiazolidinyl, 5-isothiazolidinyl, 1 -pyrazolidinyl, 3-pyrazolidinyl, 4- pyrazolidinyl, 5-pyrazolidinyl, 2-oxazolidinyl, 4-oxazolidinyl, 5-oxazolidinyl, 2-thiazolidinyl, 4- thiazolidinyl, 5-thiazolidinyl, 1 -imidazolidinyl, 2-imidazolidinyl, 4-imidazolidinyl, 3-oxazolidinyl, 1 ,2,4-oxadiazolidin-3-yl, 1 ,2,4-oxadiazolidin-5-yl, 3-thiazolidinyl, 1 ,2,4-thiadiazolidin-3-yl, 1 ,2,4- thiadiazolidin-5-yl, 1 ,2,4-triazolidin-3-yl, 1 ,2,4-oxadiazolidin-2-yl, 1 ,2,4-oxadiazolidin-4-yl, 1 ,3,4- oxadiazolidin-2-yl, 1 ,2,4-thiadiazolidin-2-yl, 1 ,2,4-thiadiazolidin-4-yl, 1 ,3,4-thiadiazolidin-2-yl, 1 ,2,4-triazolidin-1 -yl, 1 ,3,4-triazolidin-2-yl; six-membered saturated heterocycles like 1 - piperidinyl, 2-piperidinyl, 3-piperidinyl, 4-piperidinyl, 1 ,3-dioxan-5-yl, 1 ,4-dioxanyl, 1 ,3-dithian-5- yl, 1 ,3-dithianyl, 1 ,3-oxathian-5-yl, 1 ,4-oxathianyl, 2-tetrahydropyranyl, 3-tetrahydopyranyl, 4- tetrahydropyranyl, 2-tetrahydrothiopyranyl, 3-tetrahydrothiopyranyl,4-tetrahydrothiopyranyl, 1 - hexahydropyridazinyl, 3-hexahydropyridazinyl, 4-hexahydropyridazinyl, 1 -hexahydropyrimidinyl,

2- hexahydropyrimidinyl, 4-hexahydropyrimidinyl, 5-hexahydropyrimidinyl, 1 -piperazinyl, 2- piperazinyl, 1 ,3,5-hexahydrotriazin-1 -yl, 1 ,3,5-hexahydrotriazin-2-yl, 1 ,2,4-hexahydrotriazin-1 -yl, 1 ,2,4-hexahydrotriazin-3-yl, tetrahydro-1 ,3-oxazin-1 -yl, tetrahydro-1 ,3-oxazin-2-yl, tetrahydro- 1 ,3-oxazin-6-yl, 1 -morpholinyl, 2-morpholinyl, 3-morpholinyl;

5- or 6 membered heteroaryl: aromatic heteroaryl having 5 or 6 ring members which, in addition to carbon atoms, contains 1 to 4 nitrogen atoms, or 1 to 3 nitrogen atoms and an oxygen or sulphur atom, or an oxygen or a sulphur atom, for example 5-membered aromatic rings like furyl (for example 2-furyl, 3-furyl), thienyl (for example 2-thienyl, 3-thienyl), pyrrolyl (for example pyrrol-2-yl, pyrrol-3-yl), pyrazolyl (for example pyrazol-3-yl, pyrazol-4-yl), isoxazolyl (for example isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl), isothiazolyl (for example isothiazol-3-yl, iso- thiazol-4-yl, isothiazol-5-yl), imidazolyl (for example imidazole-2-yl, imidazole-4-yl), oxazolyl (for example oxazol-2-yl, oxazol-4-yl, oxazol-5-yl), thiazolyl (for example thiazol-2-yl, thiazol-4-yl, thiazol-5-yl), oxadiazolyl (for example 1 ,2,3-oxadiazol-4-yl, 1 ,2,3-oxadiazol-5-yl, 1 ,2,4-oxadiazol-

3- yl, 1 ,2,4-oxadiazol-5-yl, 1 ,3,4-oxadiazol-2-yl), thiadiazolyl (for example 1 ,2,3-thiadiazol-4-yl, 1 ,2,3-thiadiazol-5-yl, 1 ,2,4-thiadiazol-3-yl, 1 ,2,4-thiadiazol-5-yl, 1 ,3,4-thiadiazolyl-2-yl), triazolyl (for example 1 ,2,3-triazol-4-yl, 1 ,2,4-triazol-3-yl); 1-tetrazolyl; 6-membered aromatic rings like pyridyl (for example pyridine-2-yl, pyridine-3-yl, pyridine-4-yl), pyrazinyl (for example pyridazin- 3-yl, pyridazin-4-yl), pyrimidinyl (for example pyrimidin-2-yl, pyrimidin-4-yl, pyrimidin-5-yl), pyra- zin-2-yl, triazinyl (for example 1 ,3,5-triazin-2-yl, 1 ,2,4— triazin-3-yl, 1 ,2,4-triazin-5-yl, 1 ,2,4-triazin- 6-yl);

3- to 7-membered carbocyclus: a three- to seven-membered monocyclic, saturated, partial unsaturated or aromatic cycle having three to seven ring members which comprises apart from carbon atoms optionally one or two ring members selected from the group consisting of -N(R ¹² )- , -N=N-, -C(=0)-, -O- and -S-.

The preferred embodiments of the invention mentioned herein below have to be understood being preferred either independently from each other or in combination with one another. According to a preferred embodiment of the invention preference is also given to those phenyl- triazolinones of formula (I), wherein the variables, either independently of one another or in combination with one another, have the following meanings:

Preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is hydrogen, Ci-C4-alkyl or Ci-C4-haloalkyl;

preferably is Ci-C4-alkyl or Ci-C4-haloalkyl;

more preferred is Ci-C4-haloalkyl;

particularly preferred is Ci-haloalkyl;

especially preferred is CHF2.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ² is hydrogen, Ci-C4-alkyl or Ci-C4-haloalkyl;

preferably is Ci-C4-alkyl or Ci-C4-haloalkyl;

more preferred is Ci-C4-alkyl;

particularly preferred is CH3.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ³ is H, F or CI;

particularly preferred is H or F;

especially preferred is H;

also particularly preferred is H or CI;

especially preferred is CI;

also particularly preferred is F or CI;

especially preferred is F.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁴ is halogen or CN;

preferably F, CI, Br or CN;

particularly preferred is F, CI or CN;

especially preferred is CI or CN;

more preferred is CI;

also more preferred is CN;

also especially preferred is F or CI;

more preferred is F.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁵ is H, d-Cs-alkyl, Ci-C ₃ -haloalkyl, Ci-C ₃ -alkoxy, Ci-C ₃ -haloalkoxy or Ci-C ₃ -alkylthio; particularly preferred is H, Ci-C ₃ -alkyl, Ci-C ₃ -haloalkyl or Ci-C ₃ -alkoxy;

especially preferred is H, Ci-C ₃ -alkyl or Ci-C ₃ -alkoxy;

more preferred is H, CH ₃ or OCH ₃ .

Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁶ is H, halogen or Ci-C ₃ -alkyl; particularly preferred is H, F or CH3;

especially preferred is H.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁷ is OR ⁸ , SR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °;

particularly preferred is OR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °;

especially preferred OR ⁸ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R ¹⁰ ;

especially preferred is OR ⁸ or NR ⁸ S(0) ₂ R ⁹ .

Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁸ is hydrogen, Ci-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, Ci-C6-haloalkyl, C3-C6-haloalkenyl, C3-C6-haloalkynyl, Ci-C6-cyanoalkyl, Ci-C6-alkoxy-Ci-C6-alkyl, Ci-C6-alkoxy-Ci-C6-alkoxy- Ci-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, Ci-C6-haloalkoxy-Ci-C6-alkyl, C3-C6-alkenyloxy- Ci-C6-alkyl, C3-C6-haloalkenyloxy-Ci-C6-alkyl, C3-C6-alkenyloxy-Ci-C6-alkoxy-Ci-C6-alkyl, Ci-C ₆ -alkylthio-Ci-C ₆ -alkyl, Ci-C ₆ -alkylsulfinyl-Ci-C ₆ -alkyl, Ci-C ₆ -alkylsulfonyl-Ci-C ₆ -alkyl, Ci-C6-alkylcarbonyl-Ci-C6-alkyl, Ci-C6-alkoxycarbonyl-Ci-C6-alkyl, Ci-C6-haloalkoxy- carbonyl-Ci-C6-alkyl, C3-C6-alkenyloxycarbonyl-Ci-C6-alkyl, C3-C6-alkynyloxycarbonyl-Ci- C6-alkyl, amino, (Ci-C6-alkyl)amino, di(Ci-C6-alkyl)amino, (Ci-C6-alkylcarbonyl)amino, amino-Ci-C6-alkyl, (Ci-C6-alkyl)amino-Ci-C6-alkyl, di(Ci-C6-alkyl)amino-Ci-C6-alkyl, ami- nocarbonyl-Ci-C6-alkyl, (Ci-C6-alkyl)aminocarbonyl-Ci-C6-alkyl, di(Ci-C6- alkyl)aminocarbonyl-Ci-C6-alkyl,

-N=CR ¹¹ R ¹² ,

wherein R ¹¹ and R ¹² independently of one another are H, Ci-C4-alkyl or phenyl; C3-C6-cycloalkyl, C3-C6-cycloalkyl-Ci-C6-alkyl, C3-C6-heterocyclyl, phenyl, phenyl-Ci-C ₄ - alkyl or a 5- or 6 membered heteroaryl,

wherein each cycloalkyl, heterocyclyl, phenyl or heteroaryl ring can be substituted by one to four substituents selected from R ¹³ or a 3- to 7-membered carbocyclus, which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of -N(R ¹¹ )-, -N=N-, -C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ,

wherein R ¹³ is halogen, N0 ₂ , CN, Ci-C ₄ -alkyl, Ci-C ₄ -haloalkyl, C1-C4- alkoxy or Ci-C ₄ -alkoxycarbonyl; preferably is hydrogen, Ci-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, Ci-C6-haloalkyl, C1-C6- alkoxy-Ci-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, Ci-C6-alkylcarbonyl-Ci-C6- alkyl, Ci-C6-alkoxycarbonyl-Ci-C6-alkyl or C3-C6-cycloalkyl-Ci-C6-alkyl; particularly preferred is hydrogen, Ci-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or C1-C6- haloalkyl;

especially preferred is hydrogen, Ci-C6-alkyl, or C3-C6-alkynyl;

more preferred is hydrogen, CH3, C ₂ H ₅ or CH ₂ C≡CH. Also preferred are the phenyltriazolinones of formula (I) wherein R ⁹ is H or d-Ce-alkyl;

more preferred is H;

also more preferred is Ci-C6-alkyl.

Also preferred are the phenyltriazolinones of formula (I) wherein R ¹⁰ is H, d-Ce-alkyl or Ci-C ₆ -alkoxycarbonyl-Ci-C ₆ -alkyl; particularly preferred is H or Ci-C6-alkyl;

more preferred is H;

also more preferred is Ci-C6-alkyl.

Also preferred are the phenyltriazolinones of formula (I) wherein R ¹¹ is phenyl or Ci-C4-alkyl;

particularly preferred is phenyl or CH3;

also particularly preferred is phenyl;

also particularly preferred is Ci-C4-alkyl.

Also preferred are the phenyltriazolinones of formula (I) wherein R ¹² is phenyl or Ci-C4-alkyl;

particularly preferred is phenyl or CH3;

also particularly preferred is phenyl;

also particularly preferred is Ci-C4-alkyl.

Also preferred are the phenyltriazolinones of formula (I) wherein R ¹³ is halogen or Ci-Ce-alkyl;

particularly preferred is F, CI or CH3;

also particularly preferred is halogen;

especially preferred is F or CI;

also particularly preferred is Ci-C6-alkyl;

especially preferred is CH3.

Also preferred are the phenyltriazolinones of formula (I) wherein n is 1 or 2;

particularly preferred is 2;

also particularly preferred is 1 .

Also preferred are the phenyltriazolinones of formula (I) wherein Q is O or S;

particularly preferred is O.

Also preferred are the phenyltriazolinones of formula (I) wherein W is O,

also preferably is S. Also preferred are the phenyltriazolinones of formula (I) wherein

X is O,

also preferably is S. Also preferred are the phenyltriazolinones of formula (I) wherein

Y is O,

also preferably is S.

Also preferred are the phenyltriazolinones of formula (I) wherein

Z is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and

each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and C1-C6- haloalkoxy;

preferably is phenyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and C1-C6- haloalkoxy;

also preferably is pyridyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and C1-C6- haloalkoxy.

Also preferred are the phenyltriazolinones of formula (I) wherein

Z is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and

each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and C1-C6- haloalkoxy;

preferably is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and

each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or C1-C6- haloalkoxy;

particularly preferred is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and

each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen or Ci-C6-alkyl; especially preferred is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and each of which is optionally substituted by 1 to 4 substituents selected from the group consisting of F, CI or CH3;

more preferred is phenyl or pyridyl,

each of which is attached to X and Q via vicinal carbon atoms, and

each of which is unsubstituted.

Also preferred are the phenyltriazolinones of formula (I) wherein

Z is phenyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and Ci-Ce- haloalkoxy;

preferably is phenyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or Ci-C6-haloalkoxy; particularly preferred is phenyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of halogen or Ci-C6-alkyl;

especially preferred is phenyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 4 substituents selected from the group consisting of F, CI or CH3;

more preferred is unsubstituted phenyl, which is attached to X and Q via vicinal carbon atoms.

Also preferred are the phenyltriazolinones of formula (I) wherein

Z is pyridyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 3 substituents selected from the group consisting of halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy and Ci-Ce- haloalkoxy;

preferably is pyridyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 3 substituents selected from the group consisting of halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or Ci-C6-haloalkoxy; particularly preferred is pyridyl,

which is attached to X and Q via vicinal carbon atoms, and

which is optionally substituted by 1 to 3 substituents selected from the group consisting of halogen or Ci-C6-alkyl;

especially preferred is pyridyl,

which is attached to X and Q via vicinal carbon atoms, and which is optionally substituted by 1 to 3 substituents selected from the group consisting of F, CI or CH3;

more preferred is unsubstituted pyridyl, which is attached to X and Q via vicinal carbon atoms.

Also preferred are the phenyltriazolinones of formula (I) wherein

Z is selected from the roup consistin of Z ¹ to Z ¹¹

Z-5 Z-6 Z-7 Z-8

wherein

* denotes the point of attachment of Z to X;

^** denotes the point of attachment of Z to Q; and

R ^a , R ^b , R ^c and R ^d independently of one another are

H, halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy, Ci-C6-haloalkoxy;

preferably H, halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or C1-C6- haloalkoxy;

particularly preferred H, halogen or Ci-C6-alkyl;

especially preferred H, F, CI, or CH3;

more preferred H. Also preferred are the phenyltriazolinones of formula (I) wherein

Z is selected from the group consisting of Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ¹⁰ as defined above; particularly preferred is selected from the group consisting of Z ¹ , Z ² , Z ³ , Z ⁴ and Z ⁵ as defined above;

especially preferred is selected from the group consisting of Z ¹ and Z ⁵ as defined above. Also preferred are the phenyltriazolinones of formula (I) wherein

Z is selected from the group consisting of Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ¹⁰ as defined above, wherein R ^a , R ^b , R ^c and R ^d independently of one another are

H, halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy, Ci-C6-haloalkoxy;

preferably H, halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or C1-C6- haloalkoxy;

particularly preferred H, halogen or Ci-C6-alkyl;

especially preferred H, F, CI, or CH3;

more preferred H; particularly preferred is selected from the group consisting of Z ¹ , Z ² , Z ³ , Z ⁴ and Z ⁵ as defined above, wherein

R ^a , R ^b , R ^c and R ^d independently of one another are

H, halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy, Ci-C6-haloalkoxy;

preferably H, halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or C1-C6- haloalkoxy;

particularly preferred H, halogen or Ci-C6-alkyl;

especially preferred H, F, CI, or CH3;

more preferred H; especially preferred is selected from the group consisting of Z ¹ and Z ⁵ as defined above, wherein

R ^a , R ^b , R ^c and R ^d independently of one another are

H, halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy, Ci-C6-haloalkoxy;

preferably H, halogen, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci-C6-alkoxy or Ci-Ce- haloalkoxy;

particularly preferred H, halogen or Ci-C6-alkyl;

especially preferred H, F, CI, or CH3;

more preferred H.

Also preferred are the phenyltriazolinones of formula (I) wherei

R ¹ is Ci-C ₄ -alkyl or Ci-C ₄ -haloalkyl,

R ² is Ci-C ₄ -alkyl or Ci-C ₄ -haloalkyl, and

Y is O.

Also preferred are the phenyltriazolinones of formula (I) wherei

R ³ is H, F or CI,

preferably H or F; and

R ⁴ is F, CI or CN. Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁵ is H, d-Cs-alkyl or Ci-C ₃ -alkoxy, and

R ⁶ is H. Also preferred are the phenyltriazolinones of formula (I) wherein

R ⁷ is OR ⁸ ' NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °, wherein

R ⁸ is hydrogen, Ci-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, Ci-C6-haloalkyl, d-di-alkoxy- d-Ce-alkyl, di(Ci-C ₆ -alkoxy)Ci-C ₆ -alkyl, Ci-C ₆ -alkylcarbonyl-Ci-C ₆ -alkyl, d-C ₆ - alkoxycarbonyl-Ci-C6-alkyl or C3-C6-cycloalkyl-Ci-C6-alkyl; and

R ⁹ , R ¹⁰ are d-Ce-alkyl.

Also preferred are the phenyltriazolinones of formula (I) wherein

n is 1. Also preferred are the phenyltriazolinones of formula (I) wherein

Q, W and X are O.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is Ci-C ₄ -alkyl or Ci-C ₄ -haloalkyl;

R ² is Ci-C ₄ -alkyl or Ci-C ₄ -haloalkyl;

R ³ is H or halogen;

R ⁴ is halogen or CN;

R ⁵ is H, d-Cs-alkyl, d-C ₃ -haloalkyl, d-C ₃ -alkoxy, d-d-haloalkoxy or d-d-alkylthio; R ⁶ is H;

R ⁷ is OR ⁸ , SR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °; wherein

R ⁸ is hydrogen, d-dralkyl, d-dralkenyl, d-di-alkynyl, Ci-C6-haloalkyl, d-C6- haloalkenyl, d-drhaloalkynyl, Ci-C6-cyanoalkyl, Ci-C6-alkoxy-Ci-C6-alkyl, d-dr alkoxy-d-C6-alkoxy-d-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, d-d-haloalkoxy-d- C6-alkyl, d-d-alkenyloxy-d-d-alkyl, d-d-haloalkenyloxy-d-d-alkyl, d-d- alkenyloxy-Ci-C6-alkoxy-Ci-C6-alkyl, Ci-C6-alkylthio-Ci-C6-alkyl, d-d-alkylsulfinyl- d-d-alkyl, Ci-C ₆ -alkylsulfonyl-Ci-C ₆ -alkyl, Ci-C ₆ -alkylcarbonyl-Ci-C ₆ -alkyl, d-d- alkoxycarbonyl-Ci-C6-alkyl, d-d-haloalkoxycarbonyl-d-d-alkyl, d-d- alkenyloxycarbonyl-Ci-C6-alkyl, amino, (Ci-C6-alkyl)amino, di(d-C6-alkyl)amino, (Ci-C6-alkylcarbonyl)amino, amino-Ci-C6-alkyl, (Ci-C6-alkyl)amino-Ci-C6-alkyl, di(Ci-C6-alkyl)amino-Ci-C6-alkyl, aminocarbonyl-d-C6-alkyl, (Ci-C6-alkyl)amino- carbonyl-Ci-C6-alkyl, di(Ci-C6-alkyl)aminocarbonyl-Ci-C6-alkyl,

-N=CR ¹¹ R ¹² ,

wherein R ¹¹ and R ¹² independently of one another are H, d-C ₄ -alkyl or phenyl;

d-C6-cycloalkyl, d-C6-cycloalkyl-Ci-C6-alkyl, d-C6-heterocyclyl, phenyl, phenyl-Ci d-alkyl or a 5- or 6 membered heteroaryl, wherein each cycloalkyl, heterocyclyl, phenyl or heteroaryl ring can be substituted by one to four substituents selected from R ¹³ or a 3- to 7-membered car- bocyclus,

which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of -N(R ¹¹ )-, -N=N-, -

C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ;

R ⁹ is Ci-Ce-alkyI;

R ¹⁰ is H or d-Ce-alkyl;

R ^{1 1} is phenyl or CH ₃ ;

R ¹² is phenyl or CH ₃ ;

R ¹³ is halogen or Ci-C6-alkyl;

n is 1 or 2;

Q is 0, S, SO, SC-2, N H or (Ci-C ₃ -alkyl)N ;

W is 0;

X is 0;

Y is 0;

z Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ¹⁰ as defined above, wherein

R ^a , R ^b , R ^c , R ^d and R ^e independently of one another are H, halogen, CN , Ci-Ce-alkyI, Ci-C6-haloalkyl, Ci-C6-alkoxy or Ci-C6-haloalkoxy;

particularly preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is Ci-C ₄ -haloalkyl;

R ² is Ci-C ₄ -alkyl;

R ³ is H or halogen;

R ⁴ is halogen or CN;

R ⁵ is H, d-Cs-alkyl, Ci-C ₃ -haloalkyl or Ci-C ₃ -alkoxy;

R ⁶ is H;

R ⁷ OR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °; wherein

R ⁸ is hydrogen, Ci-C6-alkyl, C ₃ -C6-alkenyl, C ₃ -C6-alkynyl, Ci-C6-haloalkyl, Ci-C6-alkoxy- d-Ce-alkyl, di(Ci-C ₆ -alkoxy)Ci-C ₆ -alkyl, Ci-Ce-alkylcarbonyl-Ci-Ce-alkyl, Ci-C ₆ - alkoxycarbonyl-Ci-C6-alkyl or C ₃ -C6-cycloalkyl-Ci-C6-alkyl;

R ⁹ is d-Ce-alkyl;

R ¹⁰ is H or Ci-Ce-alkyl;

n is 1 ;

Q is O, S, SO, S0 ₂ , NH or (Ci-C ₃ -alkyl)N;

W is O;

X is O;

Y is O;

Z is selected from the group consisting of Z ¹ , Z ² , Z ³ , Z ⁴ , Z ⁵ and Z ¹⁰ as defined above, wherein R ^a , R ^b , R ^c and R ^d independently of one another are H, halogen, CN, Ci-C6-alkyl, C1-C6- haloalkyl, Ci-C6-alkoxy or Ci-C6-haloalkoxy; especially preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is d-haloalkyl;

R ² is CH ₃ ;

R ³ is H, F or CI;

R ⁴ is F, Cl or CN;

R ⁵ is H, d-Cs-alkyl or Ci-C ₃ -alkoxy;

R ⁶ is H;

R ⁷ is OR ⁸ or NR ⁸ S(0) ₂ R ⁹ , wherein

R ⁸ is hydrogen, C-i-Ce-alkyl, C ₃ -Ce-alkenyl, C ₃ -Ce-alkynyl or C-i-Ce-haloalkyl, and

R ⁹ is Ci-Ce-alkyl;

n is 1 ;

Q is O or S;

W is O;

X is O;

Y is O;

Z is selected from the group consisting of Z Z ² , Z ³ , Z ⁴ and Z ⁵ as defined above, wherein R ^a , R ^b , R ^c and R ^d independently of one another are H, halogen, CN, Ci-Ce-alkyl, Ci-Ce- haloalkyl, Ci-C6-alkoxy or Ci-C6-haloalkoxy;

more preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is CHF ₂ ;

R ² is CH ₃ ;

R ³ is H, F or CI;

R ⁴ is F, Cl or CN;

R ⁵ is H, CH ₃ or OCH ₃ ;

R ⁶ is H;

R ⁷ is OR ⁸ or NR ⁸ S(0) ₂ R ⁹ ; wherein

R ⁸ is hydrogen, Ci-Ce-alkyl, or C ₃ -Ce-alkynyl, and

R ⁹ is Ci-Ce-alkyl;

n is 1 ;

Q is O;

W is O;

X is O;

Y is O;

Z is selected from the group consisting of Z ¹ and Z ⁵ as defined above, wherein R ^a , R ^b , R ^c and R ^d independently of one another are H, halogen, CN, Ci-Ce-alkyl, Ci-Ce-haloalkyl, Ci- C6-alkoxy or Ci-C6-haloalkoxy.

Also preferred are the phenyltriazolinones of formula (I) wherein

R ¹ is CHF ₂ ;

R2 is CH ₃ ; R ³ is H, F or CI;

R ⁴ is F, Cl or CN;

R ⁵ is H, CH ₃ or OCH ₃ ;

R ⁶ is H;

R ⁷ OR ⁸ , SR ⁸ , NR ⁹ R ¹⁰ , NR ⁸ OR ⁸ , NR ⁸ S(0) ₂ R ⁹ or NR ⁸ S(0) ₂ NR ⁹ R °, wherein

R ⁸ is hydrogen, Ci-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, Ci-C6-haloalkyl, C3-C6- haloalkenyl, C3-C6-haloalkynyl, Ci-C6-cyanoalkyl, Ci-C6-alkoxy-Ci-C6-alkyl, C1-C6- alkoxy-Ci-C6-alkoxy-Ci-C6-alkyl, di(Ci-C6-alkoxy)Ci-C6-alkyl, Ci-C6-haloalkoxy-Ci- C6-alkyl, C3-C6-alkenyloxy-Ci-C6-alkyl, C3-C6-haloalkenyloxy-Ci-C6-alkyl, C3-C6- alkenyloxy-Ci-C6-alkoxy-Ci-C6-alkyl, Ci-C6-alkylthio-Ci-C6-alkyl, Ci-C6-alkylsulfinyl- d-Ce-alkyl, Ci-C ₆ -alkylsulfonyl-Ci-C ₆ -alkyl, Ci-C ₆ -alkylcarbonyl-Ci-C ₆ -alkyl, Ci-C ₆ - alkoxycarbonyl-Ci-C6-alkyl, Ci-C6-haloalkoxycarbonyl-Ci-C6-alkyl, C3-C6- alkenyloxycarbonyl-Ci-C6-alkyl, C3-C6-alkynyloxycarbonyl-Ci-C6-alkyl, amino, (Ci- C6-alkyl)amino, di(Ci-C6-alkyl)amino, (Ci-C6-alkylcarbonyl)amino, amino-Ci-C6-alkyl, (Ci-C6-alkyl)amino-Ci-C6-alkyl, di(Ci-C6-alkyl)amino-Ci-C6-alkyl, aminocarbonyl-Ci-

C6-alkyl, (Ci-C6-alkyl)aminocarbonyl-Ci-C6-alkyl, di(Ci-C6-alkyl)aminocarbonyl-Ci- Ce-alkyl,

-N=CR ¹¹ R ¹² , wherein R ¹¹ and R ¹² independently of one another are H, Ci-C4-alkyl or phenyl;

C3-C6-cycloalkyl, C3-C6-cycloalkyl-Ci-C6-alkyl, C3-C6-heterocyclyl, C3-C6- heterocyclyl-Ci-C6-alkyl, phenyl, phenyl-Ci-C4-alkyl or a 5- or 6 membered het- eroaryl,

wherein each cycloalkyl, heterocyclyl, phenyl or heteroaryl ring can be substituted by one to four substituents selected from R ¹⁴ or a 3- to 7-membered car- bocyclus,

which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of

-N(R ¹¹ )-, -N=N-, -C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ;

wherein R ¹³ is halogen, N0 ₂ , CN, Ci-C ₄ -alkyl, Ci-C ₄ -haloalkyl, Ci- C ₄ -alkoxy or Ci-C ₄ -alkoxycarbonyl;

R ⁹ , R ¹⁰ independently of one another are R ⁹ , or together form a 3- to 7-membered carbocyclus,

which carbocyclus optionally has in addition to carbon atoms one or two ring members selected from the group consisting of -N(R ¹² )-, -N=N-, -C(=0)-, -O- and -S-, and

which carbocyclus is optionally substituted with one to four substituents selected from R ¹³ ;

n is 1 ;

Q is O;

W is O;

X is O;

Y is 0; Z is selected from the group consisting of Z ¹ and Z ⁵ as defined above, wherein R ^a , R ^b , R ^c and R ^d independently of one another are H, halogen, CN, Ci-C6-alkyl, Ci-C6-haloalkyl, Ci- C6-alkoxy or Ci-C6-haloalkoxy.

Particular preference is given to uracilpyrimidines of formula (I. a) (corresponds to formula (I) wherein R ¹ is CHF ₂ , R ² is CH ₃ , R ⁶ is H, n is 1 , Q, W, X and Y are O, and Z is Z-1 as defined, wherein R ^a , R ^b , R ^c and R ^d are H:

wherein the variables R ³ , R ⁴ , R ⁵ and R ⁷ have the meanings, in particular the preferred meanings, as defined above.

Special preference is given to the compounds of the formulae l.a.1 to I. a.504 of Table A, where the definitions of the variables R ³ , R ⁴ ,R ⁵ and R ⁷ are of particular importance for the compounds according to the invention not only in combination with one another but in each case also on their own:

Table A

Also preferred are the phenyltriazolinones of formula (l.b), particularly preferred the phenylt zolinones of formulae (l.b.1 ) to (l.b.504), which differ from the corresponding phenyltriazolinones of formulae (l.a.1 ) to (I. a.504) only in that Q is S:

Also preferred are the phenyltriazolinones of formula (l.c), particularly preferred the phenyltriazolinones of formulae (l.c.1 ) to (l.c.504), which differ from the corresponding phenyltriazolinones of formulae (l.a.1 ) to (l.a.504) only in that Z is Z-2, wherein R ^b , R ^c and R ^d are H:

Also preferred are the phenyltriazolinones of formula (l.d), particularly preferred the phenylt zolinones of formulae (l.d.1 ) to (l.d.504), which differ from the corresponding phenyltriazolinones of formulae (l ^a , R ^c and R ^d are H:

Also preferred are the phenyltriazolinones of formula (I.e), particularly preferred the phenylt zolinones of formulae (l.e.1 ) to (I.e.504), which differ from the corresponding phenyltriazolinones of formulae (l ^a , R ^b and R ^d are H:

Also preferred are the phenyltriazolinones of formula (l.f), particularly preferred the phenyltriazolinones of formulae (l.f.1 ) to (l.f.504), which differ from the corresponding phenyltriazolinones of formulae (l.a.1 ) to (l.a.504) only in that Z is Z-5, wherein R ^a , R ^b and R ^c are H:

Also preferred are the phenyltriazolinones of formula (l.g), particularly preferred the phenyltriazolinones of formulae (l.g.1 ) to (l.g.504), which differ from the corresponding phenyltriazoli- nones of formulae (l.a.1 ) to (I. a.504) only in that Z is Z-5, wherein R ^a , R ^b and R ^c are H, and Q is S:

Also preferred are the phenyltriazolinones of formula (l.h), particularly preferred the phenylt zolinones of formulae (l.h.1 ) to (l.h.504), which differ from the corresponding phenyltriazolinones of formulae (l. ^a and R ^c are H:

The phenyltriazolinones of formula (I) according to the invention can be prepared by standard processes of organic chemistry, for example by the following processes A to D:

Process A)

The phenyltriazolinones of formula (I) can be prepared by reaction of compounds of formula (II) with alkylating agents of formula (III) in the presence of a base in analogy to known processes (e.g. WO 1 1/137088):

Within the alkylating agents of formula (III), L ¹ is a leaving group such halogen, C1-C6- alkylsulfonate or arylsulfonate;

preferably CI, Br, I, Ci-C6-alkylsulfonate or arylsulfonate;

especially preferred CI, Br or I;

more preferred CI or Br.

The reaction of the compounds of formula (II) with the alkylating agents of formula (III) in presence of a base is usually carried out from 0°C to the boiling point of the reaction mixture, preferably from 20°C to 80°C.

The reaction may in principle be carried out in substance. However, preference is given to reacting the compounds of formula (II) with the alkylating agents of formula (III) in an organic solvent.

Suitable in principle are all solvents which are capable of dissolving the compounds of formula (II) and the alkylating agents of formula (III) at least partly and preferably fully under reaction conditions.

Examples of suitable solvents are aliphatic hydrocarbons such as pentane, hexane, cyclohex- ane, nitromethane and mixtures of Cs-Cs-alkanes, aromatic hydrocarbons such as benzene, chlorobenzene, tolene, cresols, 0-, m- and p-xylene, halogenated hydrocarbons such as di- chloromethane, 1 ,2-dichloroethane, chloroform, carbon tetrachloride and chlorobenzene, ethers such as diethyl ether, diisopropyl ether, tert. -butyl methylether (TBME), dioxane, anisole and tetrahydrofuran (THF), esters such as ethyl acetate and butyl acetate; nitriles such as acetoni- trile and propionitrile, ketones such as acetone, methyl ethyl ketone, diethyl ketone, tert-butyl methyl ketone, cyclohexanone; as well as dipolar aprotic solvents such as sulfolane, dimethyl- sulfoxide, N,N-dimethylformamide (DMF), Ν,Ν-dimethylacetamide (DMAC), 1 ,3-dimethyl-2- imidazolidinone (DMI), Ν,Ν'-dimethylpropylene urea (DMPU), dimethyl sulfoxide (DMSO) and 1 - methyl-2 pyrrolidinone (NMP).

Preferred solvents are ethers, nitriles, ketones and dipolar aprotic solvents as mentioned above. More preferred solvents are ethers and dipolar aprotic solvents as mentioned above.

It is also possible to use mixtures of the solvents mentioned.

Examples of suitable bases include metal-containing bases and nitrogen-containing bases. Examples of suitable metal-containing bases are inorganic compounds such as alkali metal and alkaline earth metal hydroxides, and other metal hydroxides, such as lithium hydroxide, sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide and aluminum hydroxide; alkali metal and alkaline earth metal oxide, and other metal oxides, such as lithium oxide, sodium oxide, potassium oxide, magnesium oxide, calcium oxide and magnesium oxide, iron oxide, silver oxide; alkali metal and alkaline earth metal hydrides such as lithium hydride, sodium hydride, potassium hydride and calcium hydride, alkali metal amides such as lithium amide, sodium amide and potassium amide, alkali metal and alkaline earth metal carbonates such as lithium carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, cesium carbonate and calcium carbonate, as well as alkali metal hydrogen carbonates (bicarbonates) such as lithium hydrogen carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate; alkali metal and alkaline earth metal phosphates such as potassium phosphate, calcium phosphate; metal organic compounds, preferably alkali metal alkyls such as methyl lithium, butyl lithium and phenyl lithium, alkyl magnesium halides such as methyl magnesium chlo- ride as well as alkali metal and alkaline earth metal alkoxides such as sodium methoxide, sodium ethoxide, potassium ethoxide, potassium tert-butoxide, potassium tert-pentoxide and di- methoxymagnesium; and furthermore organic bases, such as tertiary amines such as trimethyl- amine, triethylamine, diisopropylethylamine and N-methylpiperidine, pyridine, substituted pyridines such as collidine, lutidine, N-methylmorpholine and 4-dimethylaminopyridine and also bicyclic amines.

Examples of suitable nitrogen-containing bases are Ci-C6-alkylamines, preferably trialkyla- mines, for example triethylamine, trimethylamine, N-ethyldiisopropylamine;

ammonia, pyridine, lutidine, collidine, 4-(dimethylamino)pyridine (DMAP), imidazole, 1 ,8- diazabicyclo[5.4.0]undec-7-ene (DBU) or 1 ,5-diazabicyclo[4.3.0]non-5-ene (DBN).

Preferred bases are alkali metal and alkaline earth metal hydrides, alkali metal and alkaline earth metal carbonates, as well as alkali metal hydrogen carbonates (bicarbonates); alkali metal and alkaline earth metal phosphates; metal organic compounds, alkyl magnesium halides as well as alkali metal and alkaline earth metal alkoxides;

and furthermore organic bases, such as tertiary amines, pyridine, substituted pyridines and also bicyclic amines.

Especially preferred bases are alkali metal and alkaline earth metal carbonates, metal organic compounds, alkyl magnesium halides as well as alkali metal and alkaline earth metal alkoxides; and furthermore organic bases, such as tertiary amines, pyridine, substituted pyridines and also bicyclic amines.

The term base as used herein also includes mixtures of two or more, preferably two of the above compounds. Particular preference is given to the use of one base.

The bases are generally used in equimolar amounts or in excess, more preferably with from 1 to 20 mole equivalents based on the compounds of formula (II), and they may also be used as solvent.

The bases are used preferably from 1 to 5 mole equivalents, very preferably from 1 to 3 mole equivalents, more preferably 1 to 2 mole equivalents, based on the compounds of formula (II). It may be advantageous to add the base offset over a period of time.

The alkylating agents of formula (III) are commercially available or can be prepared by known methods (e.g. Lowell, Andrew N. et al, Tetrahedron, 6(30), 5573-5582, 2010; WO 1 1/137088).

The reactants are generally employed in equimolar amounts. It might be advantageous using one of the reactants in excess, for example with a view to complete a reaction of the other reactant.

For the reaction, the compounds of formula (II), the alkylating agent of formula (III) and the base can be brought into contact in any way per se.

The reaction can be carried out at atmospheric pressure, reduced pressure or under elevated pressure, if appropriate under an inert gas, continuously or batchwise.

The end of the reaction can easily be determined by the skilled worker by means of routine methods.

The reaction mixtures are worked up in a customary manner, for example by filtration, mixing with water, separation of the phases and, if appropriate, chromatographic purification of the crude product.

Some of the intermediates and end products are obtained in the form of viscous oils, which can be purified or freed from volatile components under reduced pressure and at moderately elevated temperature.

If the intermediates and the end products are obtained as solid, purification can also be carried out by recrystallisation or digestion.

Process B)

As an alternative, the phenyltriazolinones of formula (I), wherein R ⁴ is NO2 can also be prepared by reaction of triazolinones of formula (IV) with compounds of formula (V) in the presence of a base:

(IV)

(I )

wherein R ⁴ is NO, Within the triazolinones of formula (IV), L ² is a leaving group such halogen, Ci-C6-alkylsulfonate or arylsulfonate;

preferably F, CI, Ci-C6-alkylsulfonate or arylsulfonate;

especially preferred F, CI, mesylat or tosylat;

more preferred F or CI.

The reaction of the triazolinones of formula (IV) with compounds of formula (V) in presence of a base is usually carried out from 0°C to the boiling point of the reaction mixture, preferably from 20°C to 100°C.

The reaction may in principle be carried out in substance. However, preference is given to reacting the triazolinones of formula (IV) with the compounds of formula (V) in an organic solvent. Suitable in principle are all solvents which are capable of dissolving the triazolinones of formula (IV) and the compounds of formula (V) at least partly and preferably fully under reaction condi- tions.

Examples of suitable solvents are aliphatic hydrocarbons such as pentane, hexane, cyclohex- ane, nitromethane and mixtures of Cs-Cs-alkanes, aromatic hydrocarbons such as benzene, chlorobenzene, tolene, cresols, o-, m- and p-xylene, halogenated hydrocarbons such as di- chloromethane, 1 ,2-dichloroethane, chloroform, carbon tetrachloride and chlorobenzene, ethers such as diethyl ether, diisopropyl ether, tert. -butyl methylether (TBME), dioxane, anisole and tetrahydrofuran (THF), esters such as ethyl acetate and butyl acetate; nitriles such as acetoni- trile and propionitrile, ketones such as acetone, methyl ethyl ketone, diethyl ketone, tert-butyl methyl ketone, cyclohexanone; as well as dipolar aprotic solvents such as sulfolane, dimethyl- sulfoxide, N,N-dimethylformamide (DMF), Ν,Ν-dimethylacetamide (DMAC), 1 ,3-dimethyl-2- imidazolidinone (DMI), Ν,Ν'-dimethylpropylene urea (DMPU), dimethyl sulfoxide (DMSO) and 1 - methyl-2 pyrrolidinone (NMP).

Preferred solvents are ethers, nitriles, ketones and dipolar aprotic solvents as mentioned above. More preferred solvents are ethers and dipolar aprotic solvents as mentioned above.

It is also possible to use mixtures of the solvents mentioned.

Examples of suitable bases include metal-containing bases and nitrogen-containing bases. Examples of suitable metal-containing bases are inorganic compounds such as alkali metal and alkaline earth metal hydroxides, and other metal hydroxides, such as lithium hydroxide, sodium hydroxide, potassium hydroxide, magnesium hydroxide, calcium hydroxide and aluminum hydroxide; alkali metal and alkaline earth metal oxide, and other metal oxides, such as lithium oxide, sodium oxide, potassium oxide, magnesium oxide, calcium oxide and magnesium oxide, iron oxide, silver oxide; alkali metal and alkaline earth metal hydrides such as lithium hydride, sodium hydride, potassium hydride and calcium hydride, alkali metal amides such as lithium amide, sodium amide and potassium amide, alkali metal and alkaline earth metal carbonates such as lithium carbonate, sodium carbonate, potassium carbonate, magnesium carbonate, cesium carbonate and calcium carbonate, as well as alkali metal hydrogen carbonates (bicarbonates) such as lithium hydrogen carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate; alkali metal and alkaline earth metal phosphates such as potassium phosphate, cal- cium phosphate; metal organic compounds, preferably alkali metal alkyls such as methyl lithium, butyl lithium and phenyl lithium, alkyl magnesium halides such as methyl magnesium chloride as well as alkali metal and alkaline earth metal alkoxides such as sodium methoxide, sodium ethoxide, potassium ethoxide, potassium tert-butoxide, potassium tert-pentoxide and di- methoxymagnesium; and furthermore organic bases, such as tertiary amines such as trimethyl- amine, triethylamine, diisopropylethylamine and N-methylpiperidine, pyridine, substituted pyridines such as collidinge, lutidine, N-methylmorpholine and 4-dimethylaminopyridine and also bicyclic amines.

Examples of suitable nitrogen-containing bases are Ci-C6-alkylamines, preferably trialkyla- mines, for example triethylamine, trimethylamine, N-ethyldiisopropylamine; ammonia, pyridine, lutidine, collidine, 4-(dimethylamino)pyridine (DMAP), imidazole, 1 ,8-diazabicyclo[5.4.0]undec-7- ene (DBU) or 1 ,5-diazabicyclo[4.3.0]non-5-ene (DBN).

Preferred bases are alkali metal and alkaline earth metal hydrides, alkali metal and alkaline earth metal carbonates, as well as alkali metal hydrogen carbonates (bicarbonates); alkali metal and alkaline earth metal phosphates; metal organic compounds, alkyl magnesium halides as well as alkali metal and alkaline earth metal alkoxides; and furthermore organic bases, such as tertiary amines, pyridine, substituted pyridines and also bicyclic amines. Especially preferred bases are alkali metal and alkaline earth metal carbonates, metal organic compounds, alkyl magnesium halides as well as alkali metal and alkaline earth metal alkoxides; and furthermore organic bases, such as tertiary amines, pyridine, substituted pyridines and also bicyclic amines. The term base as used herein also includes mixtures of two or more, preferably two of the above compounds. Particular preference is given to the use of one base.

The bases are can be employed in equimolar amounts or in excess; however, they can also be employed as solvent, or, if appropriate, in catalytic amounts.

The bases are preferably used in excess, more preferably with from 1 to 20 mole equivalents based on the compound of formula (V), and they may also be used as the solvent.

Preferably, the bases are used at from 1 to 5 mole equivalents, very preferably at from 1 to 3 mole equivalents, more preferably at 1 to 2 mole equivalents, based on the compound of formula (V). It may be advantageous to add the base offset over a period of time.

The reactants are generally employed in equimolar amounts. It might be advantageous using one of the reactants in excess, for example with a view to complete a reaction of the other reactant.

For the reaction the triazolinones of formula (IV), the compounds of formula (V) and the base can be brought into contact in any way per se.

The reaction can be carried out at atmospheric pressure, reduced pressure or under elevated pressure, if appropriate under an inert gas, continuously or batchwise.

The end of the reaction can easily be determined by the skilled worker by means of routine methods.

The reaction mixtures are worked up in a customary manner, for example by filtration, mixing with water, separation of the phases and, if appropriate, chromatographic purification of the crude product.

Some of the intermediates and end products are obtained in the form of viscous oils, which can be purified or freed from volatile components under reduced pressure and at moderately elevated temperature.

If the intermediates and the end products are obtained as solid, purification can also be carried out by recrystallisation or digestion.

Process C)

As an alternative, the phenyltriazolinones of formula (I), wherein R ⁴ is Nhb, can also be prepared by reduction of phenyltriazolinones of formula (I), wherein R ⁴ is NO2:

(I), (I),

wherein R ⁴ is NO, wherein R ⁴ is NH, The reduction of the nitro group on can be achieved by treatment with iron powder in acetic acid at a temperature ranging from 0 °C to 100 °C. Alternatively, the reduction can be carried out by catalytic hydrogenation in hydrogen gas at a pressure of 70 to 700 kPa, preferably 270 to 350 kPa, in the presence of a metal catalyst such as palladium supported on an inert carrier such as activated carbon, in a weight ratio of 5 to 20% of metal to carrier, suspended in a solvent such as ethanol at ambient temperature (see e.g. WO 201 1/137088) The reaction of phenyltriazolinones of formula (I), wherein R ⁴ is NO2, whith the reducing agent is usually carried out from 0°C to the boiling point of the reaction mixture, preferably from 20°C to the boiling point of the reaction mixture, in an inert solvent. The reaction may in principle be carried out in substance. However, preference is given to reacting the phenyltriazolinones of formula (I), wherein R ⁴ is NO2, with the reducing agent in an organic solvent. Suitable in principle are all solvents, which are capable of dissolving the phenyltriazolinones of formula (I), wherein R ⁴ is NO2, at least partly, and preferably fully under reaction conditions.

Examples of suitable solvents are aliphatic hydrocarbons such as pentane, hexane,

cyclohexane, and mixtures of Cs-Cs-alkanes; aromatic hydrocarbons such as benzene, tolene, cresols, 0-, m- and p-xylene; ethers such as diethyl ether, diisopropyl ether, tert. -butyl methylether (TBME), dioxane, anisole and tetrahydrofuran (THF); esters such as ethyl acetate and butyl acetate; dipolar aprotic solvents such as sulfolane, dimethylsulfoxide, N,N- dimethylformamide (DMF), Ν,Ν-dimethylacetamide (DMAC), 1 ,3-dimethyl-2-imidazolidinone (DMI), Ν,Ν'-dimethylpropylene urea (DMPU), dimethyl sulfoxide (DMSO) and 1 -methyl-2 pyrrolidinone (NMP) and polar protic solvents as methanol, ethanol and water.

Preferred solvents are esters as mentioned above.

It is also possible to use mixtures of the solvents mentioned.

The reducing agents are generally used in excess, more preferably with from 1 to 6 equivalents based on the nitro compounds (VI). For the reaction, the phenyltriazolinones of formula (I), wherein R ⁴ is NO2, and the reducing agent can be brought into contact in any way per se.

The reaction can be carried out at atmospheric pressure, reduced pressure or under elevated pressure, if appropriate under an inert gas, continuously or batchwise.

The end of the reaction can easily be determined by the skilled worker by means of routine methods.

The reaction mixtures are worked up in a customary manner, for example by filtration, mixing with water, separation of the phases and, if appropriate, chromatographic purification of the crude product.

Some of the intermediates and end products are obtained in the form of viscous oils, which can be purified or freed from volatile components under reduced pressure and at moderately elevated temperature.

If the intermediates and the end products are obtained as solid, purification can also be carried out by recrystallisation or digestion.

The reducing agents are commercially available. Process D)

As an alternative, the phenyltriazolinones of formula (I), wherein R ⁴ is halogen or CN can also be prepared by reacting phenyltriazolinones of formula (I), wherein R ⁴ is NH2, with a diazotizing agent optionally in the presence of copper salts:

(I), (I),

w ^{herei n R4 is NH} 2 wherein R« is halogen or CN

The halogenation of the phenyltriazolinones of formula (I), wherein R ⁴ is NH2, is facilitated by diazotization with an alkyl nitrite (e.g. isoamyl nitrite, tert-Butyl nitrite or NaN02) followed by treatment with a copper (I) and/or copper (II) halide (e.g. CuCI, CuC , CuBr, CuBr2 or CuCN) in a solvent such as acetonitrile at a temperature ranging from 0 °C to the reflux temperature of the solvent to give the corresponding phenyltriazolinones of formula (I) wherein R ⁴ is a halogen such as chloride or bromide (WO 201 1/137088). This reaction is known as "Sandmeyer" reaction (see for example L. Kurti, B. Czako Strategic Applications of Named Reactions in Organic Synthesis, Elsevier: San Diego, 2005, p. 394-395).

To obtain phenyltriazolinones of formula (I), wherein R ⁴ is iodine, no copper salts are required. The below mentioned reaction conditions can be used, adding instead of a copper salt an iodine salt such as potassium iodide after diazotization. To obtain phenyltriazolinones of formula (I), wherein R ⁴ is fluorine, tetrafluoroborate salts of the diazonium compound can be used. These are obtained by adding hydrogene tetrafluoroborate during the diazotization. Subsequent thermal or photolytical decomposition delivers the corresponding fluoro compounds (Langlois, B. In Introduction of Fluorine via Diazonium

Compounds (Fluorodediazoniation); Baasner, B., Hagemann, H., Tatlow, J. C, Eds.; Houben- Weyl, Methods of Organic Chemistry; Thieme: Stuttgart, 1999; Vol. E10a, Organo-Fluorine Compounds, pp 686-740).

The reaction of phenyltriazolinones of formula (I), wherein R ⁴ is NH2, with a diazotization agent and optionally copper salts is usually carried out from 0°C to the boiling point of the reaction mixture, preferably from 0°C to 100°C, particularly preferably from 0°C to 40°C, in an inert solvent.

The reaction may in principle be carried out in substance. However, preference is given to reacting the phenyltriazolinones of formula (I), wherein R ⁴ is NH2, with the copper salts and the diazotization agent in an organic solvent. Suitable in principle are all solvents, which are capable of dissolving the phenyltriazolinones of formula (I), wherein R ⁴ is NH2, the copper salts and the diazotization agent at least partly, and preferably fully under reaction conditions. Examples of suitable solvents are aliphatic hydrocarbons such as pentane, hexane,

cyclohexane, nitromethane and mixtures of Cs-Cs-alkanes; aromatic hydrocarbons such as benzene, chlorobenzene, tolene, cresols, o-, m- and p-xylene; halogenated hydrocarbons such as dichloromethane, 1 ,2-dichloroethane, chloroform, carbon tetrachloride and chlorobenzene; ethers such as diethyl ether, diisopropyl ether, tert. -butyl methylether (TBME), dioxane, anisole and tetrahydrofuran (THF); esters such as ethyl acetate and butyl acetate; nitriles such as acetonitrile and propionitrile; ketones such as acetone, methyl ethyl ketone, diethyl ketone, tert- butyl methyl ketone, cyclohexanone; dipolar aprotic solvents such as sulfolane, dimethyl- sulfoxide, N,N-dimethylformamide (DMF), Ν,Ν-dimethylacetamide (DMAC), 1 ,3-dimethyl-2- imidazolidinone (DMI), Ν,Ν'-dimethylpropylene urea (DMPU), dimethyl sulfoxide (DMSO) and 1 - methyl-2 pyrrolidinone (NMP) and polar protic solvents as water.

Preferred solvents are nitriles or polar protic solvents as mentioned above.

It is also possible to use mixtures of the solvents mentioned.

The copper salts are generally used in excess, more preferably with from 1 to 3 equivalents based on the phenyltriazolinones of formula (I), wherein R ⁴ is Nhb. The diazotization agent (II) is generally used in excess, more preferably with from 1 to 3 equivalents based on the phenyltriazolinones of formula (I), wherein R ⁴ is Nhb.

For the reaction, the phenyltriazolinones of formula (I), wherein R ⁴ is Nhb, the copper salts and the diazotization agent can be brought into contact in any way per se.

The reaction can be carried out at atmospheric pressure, reduced pressure or under elevated pressure, if appropriate under an inert gas, continuously or batchwise.

The copper salts and the diazotization agents are commercially available.

The intermediates necessary for preparation of the phenyltriazolinones of formula (I) according to the invention, and mentioned in processes A and B above, are commercially available or can be prepared by standard processes of organic chemistry, for example by the following processes:

Compounds of formula (II) necessary for process A mentioned above can be prepared by deprotection of the respective compounds of formula (VI):

Within the compounds of formula (VI) "PG" is a protecting group selected from the group consisting of Ci-C6-alkyl, Ci-C6-cyanoalkyl, Ci-C6-haloalkyl, Ci-C6-alkylthio-Ci-C4-alkyl, C1-C6- alkoxy-Ci-C4-alkyl, Ci-C6-alkoxy-Ci-C4-alkoxy-Ci-C4-alkyl, (tri-Ci-C6-alkyl)silyl-Ci-C4-alkyl, (tri- Ci-C6-alkyl)silyl-Ci-C4-alkyoxy-Ci-C4-alkyl, C2-C6-alkenyl, C3-C6-alkynyl, C3-C6-cycloalkyl, C3-C6- cylcloalkyl-Ci-C4-alkyl, Cs-Ce-cycloalkenyl, tetrahydropyranyl, (tri-Ci-C6-alkyl)silyl, [(diphe- nyl)(Ci-C4-alkyl)]silyl, formyl, Ci-C6-alkyl-carbonyl, Ci-C6-alkyl-0-carbonyl, C2-C6-alkenyl-0- carbonyl, [(diphenyl)(Ci-C4-alkyl)]silyl-Ci-C4-alkyl, phenyl-Ci-C4-alkyl, phenylthio-Ci-C6-alkyl, phenylcarbonyl,

wherein each phenyl ring can be substituted by one to three substituents selected from the group consisting of halogen, CN, NO2, Ci-C4-alkyl and Ci-C4-alkoxy.

Preferably PG is Ci-C ₆ -alkyl, Ci-C ₆ -alkoxy-Ci-C ₄ -alkyl, (tri-Ci-C ₆ -alkyl)silyl-Ci-C ₄ -alkyl, C ₂ -C ₆ - alkenyl, tetrahydropyranyl, (tri-Ci-C6-alkyl)silyl, [(diphenyl)(Ci-C4-alkyl)]silyl or phenyl-Ci-C4- alkyl.

For example, the compounds of formula (II) can be prepared by treating the compounds of formula (VI), wherein "PG" is methyl, with boron tribromide in a solvent such as dichloromethane, acetonitrile or 1 ,4-dioxane, or without a solvent at temperatures ranging from 0 °C to 150 °C.

Alternatively, compounds of formula (II) can be prepared by deprotecting compounds of formula (VI), wherein "PG" is a benzyl group, by catalytic hydrogenation in a hydrogen gas atmosphere at a pressure of 70 to 700 kPa, preferably 270 to 350 kPa, in the presence of a metal catalyst such as palladium supported on an inert carrier such as activated carbon, in a weight ratio of 5 to 20% of metal to carrier, suspended in a solvent such as ethanol at ambient temperature.

The process, use and choice of the protecting groups will be apparent to one skilled in chemical synthesis (see, for example, Greene, T. W.; Wuts, P. G. M. Protective Groups in Organic Syn- thesis, 4th ed.; Wiley: New York, 2007).

Alkylating agents of formula (III) necessary for process A mentioned above are commercially available.

Triazolinones of formula (IV) necessary for process B mentioned above can be prepared by nitration reaction of the respective compounds of formula (VIII) following the known literature procedures (Langlois, B. In Introduction of Nitrogen group by exchange of hydrogen for the nitro group; Baasner, B., Hagemann, H., Tatlow, J. C, Eds.; Houben-Weyl, Methods of Organic Chemistry; Thieme: Stuttgart, 1974; 4 ^th Edition, Vol. 11, R-NH ₂ Compounds, pp 479-870.):

(VIII) (IV)

Suitable Nitration agents are e.g. H2SO4/HNO3, acetic acid/HN03 or acetic acid anhy- dride/HNOs.

The reaction of compounds (VIII) with the nitration agent is usually carried out from -40°C to 100°C, preferably from -20°C to 50°C, more preferably from -10°C to 20°C, in an inert solvent. The reaction may in principle be carried out in substance. However, preference is given to reacting the nitro compouds (VI) with the reducing agent in an organic solvent. Suitable in principle are all solvents, which are capable of dissolving the nitro compounds (VI) at least partly, and preferably fully under reaction conditions.

Examples of suitable solvents are aliphatic hydrocarbons such as pentane, hexane, cyclohexane, and mixtures of Cs-Cs-alkanes; ethers such as diethyl ether, diisopropyl ether, tert. -butyl methylether (TBME), dioxane, tetrahydrofuran (THF), organic acids and water;

Preferrebly the reaction is carried out with the nitration agents as solvent. The nitration agents are generally used in excess, more preferably with from 1 to 6 equivalents based on compounds (VIII).

For the reaction, the compounds (VIII), and the nitration agent can be brought into contact in any way per se.

The reaction can be carried out at atmospheric pressure, reduced pressure or under elevated pressure, if appropriate under an inert gas, continuously or batchwise.

The end of the reaction can easily be determined by the skilled worker by means of routine methods.

The reaction mixtures are worked up in a customary manner, for example by filtration, mixing with water, separation of the phases and, if appropriate, chromatographic purification of the crude product.

Some of the intermediates and end products are obtained in the form of viscous oils, which can be purified or freed from volatile components under reduced pressure and at moderately elevated temperature.

If the intermediates and the end products are obtained as solid, purification can also be carried out by recrystallisation or digestion. The nitration agents are commercially available.

Compounds of formula (V) necessary fpr process B mentioned above are commercially availa- ble or can be prepared by known methods (e.g. WO 02/098227 or WO 07/083090).

The compounds of formula (VI), wherein R ⁴ is NO2 required for the preparation of the compounds of formula (II), wherein R ⁴ is NO2, can be prepared by reaction of triazolinones of formu- la (IV) with compounds of formula (VII) in the presence of a base in analogy to the process B mentioned above:

Within the compounds of formula (IV), L ² is a leaving group such halogen, Ci-C6-alkylsulfonate or arylsulfonate; preferably F, CI, Ci-C6-alkylsulfonate or arylsulfonate; especially preferred F, CI, mesylat or tosylat; more preferred F or CI.

The compounds of formula (VI), wherein R ⁴ is NH2 required for the preparation of the com pounds of formula (II), wherein R ⁴ is NH2, can be prepared by reduction of respective com pounds of formula (VI), wherein R ² is NO2 in analogy to the process C mentioned above:

Within the compounds of formula (VI) the group "PG" is a protecting group as defined above.

The compounds of formula (VI), wherein R ⁴ is halogen or CN required for the preparation of the compounds of formula (II), wherein R ⁴ is halogen or CN, can be prepared by diazotation of respective compounds of formula (VI), wherein R ² is NH2 in analogy to the process D mentioned above:

Within the compounds of formula (VI) the group "PG" is a protecting group as defined above.

Compounds of formula (VII) are commercially available.

Compounds of formula (VIII) wherein R ¹ is H can be prepared as described in the literature (e.g. US 6,333,296).

Compounds of formula (VIII) wherein R ¹ is Ci-C6-alkyl or Ci-C6-haloalkyl can be prepared by (halo)alkylation of the respective NH-compounds (i.e. compounds of formula (VIII) wherein R ¹ is H) in analogy to WO 90/02120 or US 6,333,296.

For haloalkylation, agents like e.g. ethyl bromo(difluoro)acetat or chlorodifluoromethane can be used.

To widen the spectrum of action and to achieve synergistic effects, the phenyltriazolinones of formula (I) may be mixed with a large number of representatives of other herbicidal or growth- regulating active ingredient groups and then applied concomitantly. Suitable components for mixtures are, for example,

herbicides from the classes of the acetamides, amides, aryloxyphenoxypropionat.es,

benzamides, benzofuran, benzoic acids, benzothiadiazinones, bipyridylium, carbamates, chloroacetamides, chlorocarboxylic acids, cyclohexanediones, dinitroanilines, dinitrophenol, diphenyl ether, glycines, imidazolinones, isoxazoles, isoxazolidinones, nitriles, N- phenylphthalimides, oxadiazoles, oxazolidinediones, oxyacetamides, phenoxycarboxylic acids, phenylcarbamates, phenylpyrazoles, phenylpyrazolines, phenylpyridazines, phosphinic acids, phosphoroamidates, phosphorodithioates, phthalamates, pyrazoles, pyridazinones, pyridines, pyridinecarboxylic acids, pyridinecarboxamides, pyrimidinediones, pyrimidinyl(thio)benzoates, quinolinecarboxylic acids, semicarbazones, sulfonylaminocarbonyltriazolinones, sulfonylureas, tetrazolinones, thiadiazoles, thiocarbamates, triazines, triazinones, triazoles, triazolinones, triazolocarboxamides, triazolopyrimidines, triketones, uracils, ureas. It may furthermore be beneficial to apply the phenyltriazolinones of formula (I) alone or in combination with other herbicides, or else in the form of a mixture with other crop protection agents, for example together with agents for controlling pests or phytopathogenic fungi or bacteria. Also of interest is the miscibility with mineral salt solutions, which are employed for treating nutritional and trace element deficiencies. Other additives such as non-phytotoxic oils and oil concentrates may also be added.

In one embodiment of the present invention the compositions according to the present invention comprise at least one phenyltriazolinone of formula (I) (compound A) and at least one further active compound selected from herbicides B, preferably herbicides B of class b1 ) to b15), and safeners C (compound C).

In another embodiment of the present invention the compositions according to the present in- vention comprise at least one phenyltriazolinone of formula (I) and at least one further active compound B (herbicide B).

The further herbicidal compound B (component B) is preferably selected from the herbicides of class b1 ) to b15):

b1 ) lipid biosynthesis inhibitors;

b2) acetolactate synthase inhibitors (ALS inhibitors);

b3) photosynthesis inhibitors;

b4) protoporphyrinogen-IX oxidase inhibitors,

b5) bleacher herbicides;

b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors);

b7) glutamine synthetase inhibitors;

b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors);

b9) mitosis inhibitors;

b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors);

b1 1 ) cellulose biosynthesis inhibitors;

b12) decoupler herbicides;

b13) auxinic herbicides;

b14) auxin transport inhibitors; and

b15) other herbicides selected from the group consisting of bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, dalapon, dazomet, difenzoquat, dif- enzoquat-metilsulfate, dimethipin, DSMA, dymron, endothal and its salts, etoben- zanid, flamprop, flamprop-isopropyl, flamprop-methyl, flamprop-M-isopropyl, flam- prop-M-methyl, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine- ammonium, indanofan, indaziflam, maleic hydrazide, mefluidide, metam, methi- ozolin (CAS 403640-27-7), methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoc- lamine, triaziflam, tridiphane and 6-chloro-3-(2-cyclopropyl-6-methylphenoxy)-4- pyridazinol (CAS 499223-49-3) and its salts and esters; including their agriculturally acceptable salts or derivatives.

Preference is given to those compositions according to the present invention comprising at least one herbicide B selected from herbicides of class b2, b3, b4, b5, b6, b7, b9, b10 and b13. Specific preference is given to those compositions according to the present invention which comprise at least one herbicide B selected from the herbicides of class b4, b6, b7, b9, b10 and b13. Particular preference is given to those compositions according to the present invention which comprise at least one herbicide B selected from the herbicides of class b4, b6, b10 and b13.

Examples of herbicides B which can be used in combination with the phenyltriazolinones of formula (I) according to the present invention are: b1 ) from the group of the lipid biosynthesis inhibitors:

ACC-herbicides such as alloxydim, alloxydim-sodium, butroxydim, clethodim, clodinafop, clodinafop-propargyl, cycloxydim, cyhalofop, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxa- prop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-tefuryl, quizalo- fop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, sethoxydim, tepraloxydim, tralkoxydim, 4-(4'- Chloro-4-cyclopropyl-2'-fluoro[1 ,1 '-biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran- 3(6H)-one (CAS 1312337-72-6); 4-(2',4'-Dichloro-4-cyclopropyl[1 ,1 '-biphenyl]-3-yl)-5-hydroxy- 2,2,6,6-tetramethyl-2H-pyran-3(6H)-one (CAS 1312337-45-3); 4-(4'-Chloro-4-ethyl-2'-fluoro[1 ,1 '- biphenyl]-3-yl)-5-hydroxy-2,2,6,6-tetramethyl-2H-pyran-3(6H) -one (CAS 1033757-93-5); 4-(2',4'- Dichloro-4-ethyl[1 ,1 '-biphenyl]-3-yl)-2,2,6,6-tetramethyl-2H-pyran-3,5(4H,6H)-di one (CAS 1312340-84-3); 5-(Acetyloxy)-4-(4'-chloro-4-cyclopropyl-2'-fluoro[1 ,1 '-biphenyl]-3-yl)-3,6- dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one (CAS 1312337-48-6); 5-(Acetyloxy)-4-(2 ^' ,4'- dichloro-4-cyclopropyl- [1 ,1 '-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H-pyran-3 -one; 5- (Acetyloxy)-4-(4'-chloro-4-ethyl-2'-fluoro[1 ,1 '-biphenyl]-3-yl)-3,6-dihydro-2,2,6,6-tetramethyl-2H- pyran-3-one (CAS 1312340-82-1 ); 5-(Acetyloxy)-4-(2',4'-dichloro-4-ethyl[1 ,1 '-biphenyl]-3-yl)-3,6- dihydro-2,2,6,6-tetramethyl-2H-pyran-3-one (CAS 1033760-55-2); 4-(4'-Chloro-4-cyclopropyl-2'- fluoro[1 ,1 '-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6-tetramethyl-5-oxo-2H-p yran-3-yl carbonic acid methyl ester (CAS 1312337-51 -1 ); 4-(2 ^' ,4'-Dichloro -4-cyclopropyl- [1 ,1 '-biphenyl]-3-yl)-5,6- dihydro-2,2,6,6-tetramethyl-5-oxo-2H-pyran-3-yl carbonic acid methyl ester; 4-(4'-Chloro-4- ethyl-2'-fluoro[1 ,1 '-biphenyl]-3-yl)-5,6-dihydro-2,2,6,6-tetramethyl-5-oxo-2H-p yran-3-yl carbonic acid methyl ester (CAS 1312340-83-2); 4-(2',4'-Dichloro-4-ethyl[1 ,1 '-biphenyl]-3-yl)-5,6-dihydro- 2,2,6,6-tetramethyl-5-oxo-2H-pyran-3-yl carbonic acid methyl ester (CAS 1033760-58-5); and non ACC herbicides such as benfuresate, butylate, cycloate, dalapon, dimepiperate, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, pebulate, prosulfocarb, TCA, thio- bencarb, tiocarbazil, triallate and vernolate; b2) from the group of the ALS inhibitors:

sulfonylureas such as amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlo- rimuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethametsulfuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, flupyrsul- furon-methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazosulfuron, iodosul- furon, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, mesosulfuron, met- azosulfuron, metsulfuron, metsulfuron-methyl, nicosulfuron, orthosulfamuron, oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, prosulfuron, pyrazosulfuron, pyrazosulfu- ron-ethyl, rimsulfuron, sulfometuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron, thifen- sulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, trifloxysulfuron, triflusulfuron, tri- flusulfuron-methyl and tritosulfuron,

imidazolinones such as imazamethabenz, imazamethabenz-methyl, imazamox, imazapic, ima- zapyr, imazaquin and imazethapyr, triazolopyrimidine herbicides and sulfonanilides such as cloransulam, cloransulam-methyl, diclosulam, flumetsulam, florasulam, metosulam, penoxsu- lam, pyrimisulfan and pyroxsulam,

pyrimidinylbenzoates such as bispyribac, bispyribac-sodium, pyribenzoxim, pyriftalid, pyrimino- bac, pyriminobac-methyl, pyrithiobac, pyrithiobac-sodium, 4-[[[2-[(4,6-dimethoxy-2- pyrimidinyl)oxy]phenyl]methyl]amino]-benzoic acid-1 -methylethyl ester (CAS 420138-41 -6), 4- [[[2-[(4,6-dimethoxy-2-pyrimidinyl)oxy]phenyl]methyl]amino]- benzoic acid propyl ester (CAS 420138-40-5), N-(4-bromophenyl)-2-[(4,6-dimethoxy-2-pyrimidinyl)oxy]benzen emethanamine (CAS 420138-01 -8),

sulfonylaminocarbonyl-triazolinone herbicides such as flucarbazone, flucarbazone-sodium, propoxycarbazone, propoxycarbazone-sodium, thiencarbazone and thiencarbazone-methyl; and triafamone;

among these, a preferred embodiment of the invention relates to those compositions comprising at least one imidazolinone herbicide; b3) from the group of the photosynthesis inhibitors:

amicarbazone, inhibitors of the photosystem II, e.g. 1 -(6-tert-butylpyrimidin-4-yl)-2-hydroxy-4- methoxy-3-methyl-2H-pyrrol-5-one (CAS 1654744-66-7), 1 -(5-tert-butylisoxazol-3-yl)-2-hydroxy- 4-methoxy-3-methyl-2H-pyrrol-5-one (CAS 1637455-12-9), 1 -(5-tert-butylisoxazol-3-yl)-4-chloro- 2-hydroxy-3-methyl-2H-pyrrol-5-one (CAS 1637453-94-1 ), 1 -(5-tert-butyl-1 -methyl-pyrazol-3-yl)- 4-chloro-2-hydroxy-3-methyl-2H-pyrrol-5-one (CAS 1654057-29-0), 1 -(5-tert-butyl-1 -methyl- pyrazol-3-yl)-3-chloro-2-hydroxy-4-methyl-2H-pyrrol-5-one (CAS 1654747-80-4), 4-hydroxy-1 - methoxy-5-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolid in-2-one; (CAS 2023785-78-4), 4- hydroxy-1 ,5-dimethyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2- one (CAS 2023785-79-5), 5- ethoxy-4-hydroxy-1 -methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one (CAS 1701416-69- 4), 4-hydroxy-1 -methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one (CAS 1708087-22-2), 4-hydroxy-1 ,5-dimethyl-3-[1 -methyl-5-(trifluoromethyl)pyrazol-3-yl]imidazolidin-2-one (CAS 2023785-80-8), 1 -(5-tert-butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imi dazolidin-2-one (CAS 1844836-64-1 ), triazine herbicides, including of chlorotriazine, triazinones, triazindiones, methylthiotriazines and pyridazinones such as ametryn, atrazine, chloridazone, cyanazine, desmetryn, dimethametryn,hexazinone, metribuzin, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazin, terbutryn and trietazin, aryl urea such as chlorobromuron, chlorotoluron, chloroxuron, dimefuron, diuron, fluometuron, isoproturon, isouron, linuron, met- amitron, methabenzthiazuron, metobenzuron, metoxuron, monolinuron, neburon, siduron, tebuthiuron and thiadiazuron, phenyl carbamates such as desmedipham, karbutilat, phen- medipham, phenmedipham-ethyl, nitrile herbicides such as bromofenoxim, bromoxynil and its salts and esters, ioxynil and its salts and esters, uraciles such as bromacil, lenacil and terbacil, and bentazon and bentazon-sodium, pyridate, pyridafol, pentanochlor and propanil and inhibitors of the photosystem I such as diquat, diquat-dibromide, paraquat, paraquat-dichloride and paraquat-dimetilsulfate. Among these, a preferred embodiment of the invention relates to those compositions comprising at least one aryl urea herbicide. Among these, likewise a preferred embodiment of the invention relates to those compositions comprising at least one triazine herb- icide. Among these, likewise a preferred embodiment of the invention relates to those compositions comprising at least one nitrile herbicide; b4) from the group of the protoporphyrinogen-IX oxidase inhibitors:

acifluorfen, acifluorfen-sodium, azafenidin, bencarbazone, benzfendizone, bifenox, butafenacil, carfentrazone, carfentrazone-ethyl, chlomethoxyfen, chlorphthalim, cinidon-ethyl, fluazolate, flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, flumioxazin, fluoroglycofen, fluorogly- cofen-ethyl, fluthiacet, fluthiacet-methyl, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen, pyraflufen-ethyl, saflufenacil, sulfen- trazone, thidiazimin, tiafenacil, trifludimoxazin, ethyl [3-[2-chloro-4-fluoro-5-(1 -methyl-6- trifluoromethyl-2,4-dioxo-1 ,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetat e (CAS 353292-31 -6; S-3100), N-ethyl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1 H-pyrazole- 1 -carboxamide (CAS 452098-92-9), N-tetrahydrofurfuryl-3-(2,6-dichloro-4- trifluoromethylphenoxy)-5-methyl-1 /-/-pyrazole-1 -carboxamide (CAS 915396-43-9), N-ethyl-3-(2- chloro-6-fluoro-4-trifluoromethylphenoxy)-5-methyl-1 H-pyrazole-1 -carboxamide (CAS 452099- 05-7), N-tetrahydrofurfuryl-3-(2-chloro-6-fluoro-4-trifluoromethylp henoxy)-5-methyl-1 H-pyrazole- 1 -carboxamide (CAS 452100-03-7), 3-[7-fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H- benzo[1 ,4]oxazin-6-yl]-1 ,5-dimethyl-6-thioxo-[1 ,3,5]triazinan-2,4-dione (CAS 451484-50-7), 2- (2,2,7-trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1 ,4]oxazin-6-yl)-4,5,6,7-tetrahydro- isoindole-1 ,3-dione (CAS 13001 18-96-0), 1 -methyl-6-trifluoromethyl-3-(2,2,7-trifluoro-3-oxo-4- prop-2-ynyl-3,4-dihydro-2H-benzo[1 ,4]oxazin-6-yl)-1 H-pyrimidine-2,4-dione (CAS 13041 13-05- 0), methyl (E)-4-[2-chloro-5-[4-chloro-5-(difluoromethoxy)-1 H-methyl-pyrazol-3-yl]-4-fluoro- phenoxy]-3-methoxy-but-2-enoate (CAS 948893-00-3), and 3-[7-chloro-5-fluoro-2- (trifluoromethyl)-l H-benzimidazol-4-yl]-1 -methyl-6-(trifluoromethyl)-1 H-pyrimidine-2,4-dione (CAS 212754-02-4); b5) from the group of the bleacher herbicides:

PDS inhibitors: beflubutamid, diflufenican, fluridone, flurochloridone, flurtamone, norflurazon, picolinafen, and 4-(3-trifluoromethylphenoxy)-2-(4-trifluoromethylphenyl)pyri midine (CAS 180608-33-7), HPPD inhibitors: benzobicyclon, benzofenap, bicyclopyrone, clomazone, fenquinotrione, isoxaflutole, mesotrione, oxotrione (CAS 1486617-21 -3), pyrasulfotole, pyrazol- ynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, tolpyralate, topramezone , bleacher, unknown target: aclonifen, amitrole, flumeturon, 2-chloro-3-methylsulfanyl-N-(1 -methyltetrazol- 5-yl)-4-(trifluoromethyl)benzamide (CAS 1361 139-71 -0), 2-(2,4-dichlorophenyl)methyl-4,4- dimethyl-3-isoxazolidone (CAS 81777-95-9) and 2-(2,5-dichlorophenyl)methyl-4,4-dimethyl-3- isoxazolidinone (CAS 81778-66-7); b6) from the group of the EPSP synthase inhibitors:

glyphosate, glyphosate-isopropylammonium, glyposate-potassium and glyphosate-trimesium

(sulfosate); b7) from the group of the glutamine synthase inhibitors:

bilanaphos (bialaphos), bilanaphos-sodium, glufosinate, glufosinate-P and glufosinate- ammonium; b8) from the group of the DHP synthase inhibitors:

asulam; b9) from the group of the mitosis inhibitors:

compounds of group K1 : dinitroanilines such as benfluralin, butralin, dinitramine, ethalfluralin, fluchloralin, oryzalin, pendimethalin, prodiamine and trifluralin, phosphoramidates such as ami- prophos, amiprophos-methyl, and butamiphos, benzoic acid herbicides such as chlorthal, chlor- thal-dimethyl, pyridines such as dithiopyr and thiazopyr, benzamides such as propyzamide and tebutam; compounds of group K2: carbetamide, chlorpropham, flamprop, flamprop-isopropyl, flamprop-methyl, flamprop-M-isopropyl, flamprop-M-methyl and propham ; among these, compounds of group K1 , in particular dinitroanilines are preferred; b10) from the group of the VLCFA inhibitors:

chloroacetamides such as acetochlor, alachlor, amidochlor, butachlor, dimethachlor, dimethe- namid, dimethenamid-P, metazachlor, metolachlor, metolachlor-S, pethoxamid, pretilachlor, propachlor, propisochlor and thenylchlor, oxyacetanilides such as flufenacet and mefenacet, acetanilides such as diphenamid, naproanilide, napropamide and napropamide-M, tetrazoli- nones such fentrazamide, and other herbicides such as anilofos, cafenstrole, fenoxasulfone, ipfencarbazone, piperophos, pyroxasulfone and isoxazoline compounds of the formulae 11.1 , II.2, 11.3 , II.4, II.5, II.6, II.7, II.8 and II.9

11.1

II.2

the isoxazoline compounds of the formula (1)1 are known in the art, e.g. from WO

2006/024820, WO 2006/037945, WO 2007/071900 and WO 2007/096576; among the VLCFA inhibitors, preference is given to chloroacetamides and oxyacetamides; b1 1 ) from the group of the cellulose biosynthesis inhibitors:

chlorthiamid, dichlobenil, flupoxam, indaziflam, isoxaben, triaziflam and 1 -cyclohexyl-5- pentafluorphenyloxy-1 ⁴ -[1 -2,4,6]thiatriazin-3-ylamine (CAS 175899-01 -1 ); b12) from the group of the decoupler herbicides:

dinoseb, dinoterb and DNOC and its salts; b13) from the group of the auxinic herbicides:

2,4-D and its salts and esters such as clacyfos, 2,4-DB and its salts and esters, aminocyclopy- rachlor and its salts and esters, aminopyralid and its salts such as aminopyralid- dimethylammonium, aminopyralid-tris(2-hydroxypropyl)ammonium and its esters, benazolin, benazolin-ethyl, chloramben and its salts and esters, clomeprop, clopyralid and its salts and esters, dicamba and its salts and esters, dichlorprop and its salts and esters, dichlorprop-P and its salts and esters, flopyrauxifen, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, halauxifen and its salts and esters (CAS 943832-60-8); MCPA and its salts and esters, MCPA-thioethyl, MCPB and its salts and esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, quinclorac, quinmerac, TBA (2,3,6) and its salts and esters, triclopyr and its salts and esters, florpyrauxifen, florpyrauxifen-benzyl (CAS 1390661 -72- 9) and 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1 H-indol-6-yl)picolinic acid (CAS 1629965-65-6); b14) from the group of the auxin transport inhibitors: diflufenzopyr, diflufenzopyr-sodium, nap- talam and naptalam-sodium; b15) from the group of the other herbicides: bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, cyclopyrimorate (CAS 499223-49-3) and its salts and esters, dalapon, dazomet, difenzoquat, difenzoquat-metilsulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, inda- nofan, maleic hydrazide, mefluidide, metam, methiozolin (CAS 403640-27-7), methyl azide, me- thyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine and tridiphane.

Active compounds B and C having a carboxyl group can be employed in the form of the acid, in the form of an agriculturally suitable salt as mentioned above or else in the form of an agriculturally acceptable derivative in the compositions according to the invention.

In the case of dicamba, suitable salts include those, where the counterion is an agriculturally acceptable cation. For example, suitable salts of dicamba are dicamba-sodium, dicamba- potassium, dicamba-methylammonium, dicamba-dimethylammonium, dicamba- isopropylammonium, dicamba-diglycolamine, dicamba-olamine, dicamba-diolamine, dicamba- trolamine, dicamba-N,N-bis-(3-aminopropyl)methylamine and dicamba-diethylenetriamine. Examples of a suitable ester are dicamba-methyl and dicamba-butotyl.

Suitable salts of 2,4-D are 2,4-D-ammonium, 2,4-D-dimethylammonium, 2,4-D- diethylammonium, 2,4-D-diethanolammonium (2,4-D-diolamine), 2,4-D-triethanolammonium, 2,4-D-isopropylammonium, 2,4-D-triisopropanolammonium, 2,4-D-heptylammonium, 2,4-D- dodecylammonium, 2,4-D-tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2- hydroxypropyl)ammonium, 2,4-D-tris(isopropyl)ammonium, 2,4-D-trolamine, 2,4-D-lithium, 2,4- D-sodium. Examples of suitable esters of 2,4-D are 2,4-D-butotyl, 2,4-D-2-butoxypropyl, 2,4-D- 3-butoxypropyl, 2,4-D-butyl, 2,4-D-ethyl, 2,4-D-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D- isopropyl, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-propyl, 2,4-D-tefuryl and clacyfos.

Suitable salts of 2,4-DB are for example 2,4-DB-sodium, 2,4-DB-potassium and 2,4-DB- dimethylammonium. Suitable esters of 2,4-DB are for example 2,4-DB-butyl and 2,4-DB-isoctyl. Suitable salts of dichlorprop are for example dichlorprop-sodium, dichlorprop-potassium and dichlorprop-dimethylammonium. Examples of suitable esters of dichlorprop are dichlorprop- butotyl and dichlorprop-isoctyl.

Suitable salts and esters of MCPA include MCPA-butotyl, MCPA-butyl, MCPA-dimethyl- ammonium, MCPA-diolamine, MCPA-ethyl, MCPA-thioethyl, MCPA-2-ethylhexyl, MCPA- isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-isopropylammonium, MCPA-methyl, MCPA- olamine, MCPA-potassium, MCPA-sodium and MCPA-trolamine.

A suitable salt of MCPB is MCPB sodium. A suitable ester of MCPB is MCPB-ethyl. Suitable salts of clopyralid are clopyralid-potassium, clopyralid-olamine and clopyralid-tris-(2- hydroxypropyl)ammonium. Example of suitable esters of clopyralid is clopyralid-methyl.

Examples of a suitable ester of fluroxypyr are fluroxypyr-meptyl and fluroxypyr-2-butoxy-1 - methylethyl, wherein fluroxypyr-meptyl is preferred.

Suitable salts of picloram are picloram-dimethylammonium, picloram-potassium, picloram- triisopropanolammonium, picloram-triisopropylammonium and picloram-trolamine. A suitable ester of picloram is picloram-isoctyl.

A suitable salt of triclopyr is triclopyr-triethylammonium. Suitable esters of triclopyr are for example triclopyr-ethyl and triclopyr-butotyl.

Suitable salts and esters of chloramben include chloramben-ammonium, chloramben-diolamine, chloramben-methyl, chloramben-methylammonium and chloramben-sodium. Suitable salts and esters of 2,3,6-TBA include 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA- potassium and 2,3,6-TBA-sodium.

Suitable salts and esters of aminopyralid include aminopyralid-potassium, aminopyralid- dimethylammonium, and aminopyralid-tris(2-hydroxypropyl)ammonium.

Suitable salts of glyphosate are for example glyphosate-ammonium, glyphosate-diammonium, glyphoste-dimethylammonium, glyphosate-isopropylammonium, glyphosate-potassium, glypho- sate-sodium, glyphosate-trimesium as well as the ethanolamine and diethanolamine salts, preferably glyphosate-diammonium, glyphosate-isopropylammonium and glyphosate-trimesium (sulfosate).

A suitable salt of glufosinate is for example glufosinate-ammonium.

A suitable salt of glufosinate-P is for example glufosinate-P-ammonium.

Suitable salts and esters of bromoxynil are for example bromoxynil-butyrate, bromoxynil- heptanoate, bromoxynil-octanoate, bromoxynil-potassium and bromoxynil-sodium.

Suitable salts and esters of ioxonil are for example ioxonil-octanoate, ioxonil-potassium and ioxonil-sodium.

Suitable salts and esters of mecoprop include mecoprop-butotyl, mecoprop-dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-2-ethylhexyl, mecoprop-isoctyl, mecoprop- methyl, mecoprop-potassium, mecoprop-sodium and mecoprop-trolamine.

Suitable salts of mecoprop-P are for example mecoprop-P-butotyl, mecoprop-P- dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop-P-isobutyl, mecoprop-P-potassium and mecoprop-P-sodium.

A suitable salt of diflufenzopyr is for example diflufenzopyr-sodium.

A suitable salt of naptalam is for example naptalam-sodium.

Suitable salts and esters of aminocyclopyrachlor are for example aminocyclopyrachlor- dimethylammonium, aminocyclopyrachlor-methyl, aminocyclopyrachlor- triisopropanolammonium, aminocyclopyrachlor-sodium and aminocyclopyrachlor-potassium.

A suitable salt of quinclorac is for example quinclorac-dimethylammonium.

A suitable salt of quinmerac is for example quinmerac-dimethylammonium.

A suitable salt of imazamox is for example imazamox-ammonium.

Suitable salts of imazapic are for example imazapic-ammonium and imazapic- isopropylammonium. Suitable salts of imazapyr are for example imazapyr-ammonium and imazapyr- isopropylammonium.

A suitable salt of imazaquin is for example imazaquin-ammonium.

Suitable salts of imazethapyr are for example imazethapyr-ammonium and imazethapyr- isopropylammonium.

A suitable salt of topramezone is for example topramezone-sodium.

Particularly preferred herbicides B are the herbicides B as defined above; in particular the herbicides B.1 - B.202, preferably the herbicides B.1 - B.201 , listed below in table B:

Table B:

Herbicide B Herbicide B

B.1 clethodim B.27 flumetsulam

B.2 clodinafop-propargyl B.28 flupyrsulfuron-methyl-

B.3 cycloxydim sodium

B.4 cyhalofop-butyl B.29 foramsulfuron

B.5 fenoxaprop-ethyl B.30 imazamox

B.6 fenoxaprop-P-ethyl B.31 imazamox-ammonium

B.7 metamifop B.32 imazapic

B.8 pinoxaden B.33 imazapic-ammonium

B.9 profoxydim B.34 imazapic-

B.10 sethoxydim isopropylammonium

B.1 1 tepraloxydim B.35 imazapyr

B.12 tralkoxydim B.36 imazapyr-ammonium

B.13 esprocarb B.37 imazapyr-

B.14 ethofumesate isopropylammonium

B.15 molinate B.38 imazaquin

B.16 prosulfocarb B.39 imazaquin-ammonium

B.17 thiobencarb B.40 imazethapyr

B.18 triallate B.41 imazethapyr-ammonium

B.19 bensulfuron-methyl B.42 imazethapyr-

B.20 bispyribac-sodium isopropylammonium

B.21 cloransulam-methyl B.43 imazosulfuron

B.22 chlorsulfuron B.44 iodosulfuron-methyl-

B.23 clorimuron sodium

B.24 cyclosulfamuron B.45 iofensulfuron

B.25 diclosulam B.46 iofensulfuron-sodium

B.26 florasulam B.47 mesosulfuron-methyl Herbicide B Herbicide B

B.48 metazosulfuron B.85 acifluorfen

B.49 metsulfuron-methyl B.86 butafenacil

B.50 metosulam B.87 carfentrazone-ethyl

B.51 nicosulfuron B.88 flumioxazin

B.52 penoxsulam B.89 fomesafen

B.53 propoxycarbazon-sodium B.90 oxadiargyl

B.54 pyrazosulfuron-ethyl B.91 oxyfluorfen

B.55 pyribenzoxim B.92 pyraflufen

B.56 pyriftalid B.93 pyraflufen-ethyl

B.57 pyroxsulam B.94 saflufenacil

B.58 propyrisulfuron B.95 sulfentrazone

B.59 rimsulfuron B.96 trifludimoxazin

B.60 sulfosulfuron B.97 ethyl [3-[2-chloro-4-fluoro-

B.61 thiencarbazone-methyl 5-(1 -methyl-6-

B.62 thifensulfuron-methyl trifluoromethyl-2,4-dioxo-

B.63 tribenuron-methyl 1 ,2,3,4-tetrahydropyri-

B.64 tritosulfuron midin-3-yl)phenoxy]-2-

B.65 triafamone pyridyloxy]acetate (CAS

B.66 ametryne 353292-31 -6)

B.67 atrazine B.98 benzobicyclon

B.68 bentazon B.99 bicyclopyrone

B.69 bromoxynil B.100 clomazone

B.70 bromoxynil-octanoate B.101 diflufenican

B.71 bromoxynil-heptanoate B.102 flurochloridone

B.72 bromoxynil-potassium B.103 isoxaflutole

B.73 diuron B.104 mesotrione

B.74 fluometuron B.105 norflurazone

B.75 hexazinone B.106 picolinafen

B.76 isoproturon B.107 sulcotrione

B.77 linuron B.108 tefuryltrione

B.78 metamitron B.109 tembotrione

B.79 metribuzin B.1 10 tolpyralate

B.80 propanil B.11 1 topramezone

B.81 simazin B.1 12 topramezone-sodium

B.82 terbuthylazine B.1 13 amitrole

B.83 terbutryn B.1 14 fluometuron

B.84 paraquat-dichloride B.1 15 fenquinotrione Herbicide B Herbicide B

B.1 16 glyphosate B.149 aminopyralid

B.1 17 glyphosate-ammonium B.150 aminopyralid-methyl

B.1 18 glyphosate- B.151 aminopyralid-dimethyl- dimethylammonium ammonium

B.1 19 glyphosate- B.152 aminopyralid-tris(2- isopropylammonium hydroxypropyl)ammonium

B.120 glyphosate-trimesium (sul- B.153 clopyralid

fosate) B.154 clopyralid-methyl

B.121 glyphosate-potassium B.155 clopyralid-olamine

B.122 glufosinate B.156 dicamba

B.123 glufosinate-ammonium B.157 dicamba-butotyl

B.124 glufosinate-P B.158 dicamba-diglycolamine

B.125 glufosinate-P-ammonium B.159 dicamba-

B.126 pendimethalin dimethylammonium

B.127 trifluralin B.160 dicamba-diolamine

B.128 acetochlor B.161 dicamba-

B.129 butachlor isopropylammonium

B.130 cafenstrole B.162 dicamba-potassium

B.131 dimethenamid-P B.163 dicamba-sodium

B.132 fentrazamide B.164 dicamba-trolamine

B.133 flufenacet B.165 dicamba-N,N-bis-(3-

B.134 mefenacet aminopropyl)methylamine

B.135 metazachlor B.166 dicamba-

B.136 metolachlor diethylenetriamine

B.137 S-metolachlor B.167 fluroxypyr

B.138 pretilachlor B.168 fluroxypyr-meptyl

B.139 fenoxasulfone B.169 halauxifen

B.140 indaziflam B.170 halauxifen-methyl

B.141 isoxaben B.171 MCPA

B.142 triaziflam B.172 MCPA-2-ethylhexyl

B.143 ipfencarbazone B.173 MCPA-dimethylammonium

B.144 pyroxasulfone B.174 quinclorac

B.145 2,4-D B.175 quinclorac-

B.146 2,4-D-isobutyl dimethylammonium

B.147 2,4-D-dimethylammonium B.176 quinmerac

B.148 2,4-D-N,N,N- B.177 quinmerac- trimethylethanolammonium dimethylammonium Herbicide B Herbicide B

B.178 florpyrauxifen B.195 II.8

B.179 florpyrauxifen-benzyl (CAS B.196 II.9

1390661 -72-9) B.197 4-amino-3-chloro-5-fluoro-

B.180 aminocyclopyrachlor 6-(7-fluoro-1 H-indol-6-

B.181 aminocyclopyrachlor- yl)picolinic acid (CAS

potassium 1629965-65-6)

B.182 aminocyclopyrachlor- B.198 flopyrauxifen

methyl B.199 oxotrione (CAS 1486617-

B.183 diflufenzopyr 21 -3)

B.184 diflufenzopyr-sodium B.200 cinmethylin

B.185 dymron B.201 2-chloro-3-methylsulfanyl-

B.186 indanofan N-(1 -methyltetrazol-5-yl)-4-

B.187 oxaziclomefone (trifluoromethyl)benzamide

B.188 11.1 (CAS 1361 139-71 -0)

B.189 II.2 B.202 2-(2,4-dichlorophenyl)-

B.190 11.3 methyl-4,4-dimethyl-3-

B.191 II.4 isoxazolidone (CAS

B.192 II.5 81777-95-9)

B.193 II.6

B.194 II.7

Moreover, it may be useful to apply the phenyltriazolinones of formula (I) in

combination with safeners. Safeners are chemical compounds which prevent or reduce damage on useful plants without having a major impact on the herbicidal action of the phenyltriazolinones of the formula (I) towards unwanted plants. They can be applied either before sowings (e.g. on seed treatments, shoots or seedlings) or in the pre- emergence application or post-emergence application of the useful plant. The safeners and the phenyltriazolinones of formula (I) and optionally the herbicides B can be applied simultaneously or in succession.

In another embodiment of the present invention the compositions according to the present invention comprise at least one phenyltriazolinone of formula (I) and at least one safener C (component C).

Suitable safeners are e.g. (quinolin-8-oxy)acetic acids, 1 -phenyl-5-haloalkyl-1 H-1 ,2,4- triazol-3-carboxylic acids, 1 -phenyl-4,5-dihydro-5-alkyl-1 H-pyrazol-3,5-dicarboxylic acids, 4,5-dihydro-5,5-diaryl-3-isoxazol carboxylic acids, dichloroacetamides, alpha- oximinophenylacetonitriles, acetophenonoximes, 4,6-dihalo-2-phenylpyrimidines, N-[[4- (aminocarbonyl)phenyl]sulfonyl]-2-benzoic amides, 1 ,8-naphthalic anhydride, 2-halo-4- (haloalkyl)-5-thiazol carboxylic acids, phosphorthiolates and N-alkyl-O-phenyl- carbamates and their agriculturally acceptable salts and their agriculturally acceptable derivatives such amides, esters, and thioesters, provided they have an acid group.

Examples of preferred safeners C are benoxacor, cloquintocet, cyometrinil, cyprosul- famide, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxofen- im, furilazole, isoxadifen, mefenpyr, mephenate, naphthalic anhydride, oxabetrinil, 4-(dichloroacetyl)-1 -oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3), 2,2,5- trimethyl-3-(dichloroacetyl)-1 ,3-oxazolidine (R-29148, CAS 52836-31 -4), metcamifen and BPCMS.

Particularly preferred safeners C, which, as component C, are constituent of the composition according to the invention are the safeners C as defined above; in particular the safeners C.1 - C.17 listed below in table C:

Table C

Safener C

C.1 benoxacor

C.2 cloquintocet

C.3 cloquintocet-mexyl

C.4 cyprosulfamide

C.5 dichlormid

C.6 fenchlorazole

C.7 fenchlorazole-ethyl

C.8 fenclorim

C.9 furilazole

C.10 isoxadifen

C.1 1 isoxadifen-ethyl

C.12 mefenpyr

C.13 mefenpyr-diethyl

C.14 naphtalic acid anhydride

C.15 4-(dichloroacetyl)-1 -oxa-4-azaspiro[4.5]decane (MON4660, CAS 71526-07-3)

C.16 2,2,5-trimethyl-3-(dichloroacetyl)-1 ,3-oxazolidine (R-29148, CAS 52836-31 -4)

C.17 metcamifen The active compounds B of groups b1 ) to b15) and the active compounds C are known herbicides and safeners, see, for example, The Compendium of Pesticide Common Names (http://www.alanwood.net/pesticides/); Farm Chemicals Handbook 2000 volume 86, Meister Publishing Company, 2000; B. Hock, C. Fedtke, R. R. Schmidt, Herbi- zide [Herbicides], Georg Thieme Verlag, Stuttgart 1995; W. H. Ahrens, Herbicide Handbook, 7th edition, Weed Science Society of America, 1994; and K. K. Hatzios, Herbicide Handbook, Supplement for the 7th edition, Weed Science Society of America, 1998. 2,2,5-Trimethyl-3-(dichloroacetyl)-1 ,3-oxazolidine [CAS No. 52836-31 -4] is also referred to as R-29148. 4-(Dichloroacetyl)-1 -oxa-4-azaspiro[4.5]decane [CAS No. 71526-07-3] is also referred to as AD-67 and MON 4660.

The assignment of the active compounds to the respective mechanisms of action is based on current knowledge. If several mechanisms of action apply to one active compound, this substance was only assigned to one mechanism of action.

According to a preferred embodiment of the invention, the composition comprises as herbicidal active compound B or component B at least one, preferably exactly one herbicide B.

According to another preferred embodiment of the invention, the composition comprises as herbicidal active compounds B or component B at least two, preferably exactly two herbicides B different from each other. According to another preferred embodiment of the invention, the composition comprises as herbicidal active compounds B or component B at least three, preferably exactly three herbicides B different from each other.

According to another preferred embodiment of the invention, the composition compris- es as herbicidal active compounds B or component B at least four, preferably exactly four herbicides B different from each other.

According to another preferred embodiment of the invention, the composition comprises as safening component C or component C at least one, preferably exactly one saf- ener C.

According to another preferred embodiment of the invention, the composition comprises as component B at least one, preferably exactly one herbicide B, and as component C at least one, preferably exactly one, safener C. According to another preferred embodiment of the invention, the composition comprises at least two, preferably exactly two, herbicides B different from each other, and as component C at least one, preferably exactly one, safener C.

According to another preferred embodiment of the invention, the composition comprises at least three, preferably exactly three, herbicides B different from each other, and as component C at least one, preferably exactly one, safener C.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), and as component B at least one, preferably exactly one, herbicide B.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), and at least two, preferably exactly two, herbicides B different from each other.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), and at least three, preferably exactly three, herbicides B different from each other.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), and at least four, preferably exactly four, herbicides B different from each other.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), and as component C at least one, preferably exactly one, safener C.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), as component B at least one, preferably exactly one, herbicide B, and as component C at least one, preferably exactly one safener C. According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), at least two, preferably exactly two herbicides B different from each other, and as component C at least one, preferably exactly one, safener C.

According to another preferred embodiment of the invention, the composition comprises as component A at least one, preferably exactly one compound of formula (I), preferably of formula (I. a) or (l.f), at least three, preferably exactly three herbicides B differ- ent from each other, and as component C at least one, preferably exactly one, safener C.

According to another preferred embodiment of the invention, the composition comprises, in addition to an phenyltriazolinone of formula (I), especially an active compound from the group consisting of (l.a.85), (l.a.86), (l.a.87), (l.a.109), (l.a.1 13), (l.a.1 14), (l.a.1 15), (l.a.137), (l.f.85), (l.f.86), (l.f.87), (l.f.109), (l.f.1 13), (l.f.1 14), (l.f.1 15) and (l.f.137), at least one and especially exactly one herbicidally active compound from group b4), in particular selected from the group consisting of acifluorfen, butafencil, carfenetrazone-ethyl, flumioxazin, fomesafen, oxadiargyl, oxyfluorfen, pyraflufen, pyra- flufen-ethyl, saflufenacil, sulfentrazone, trifludimoxazin, ethyl [3-[2-chloro-4-fluoro-5-(1 - methyl-6-trifluoromethyl-2,4-dioxo-1 ,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2- pyridyloxy]acetate (CAS 353292-31 -6; S-3100).

According to another preferred embodiment of the invention, the composition comprises, in addition to an phenyltriazolinone of formula (I), especially an active compound from the group consisting of (l.a.85), (l.a.86), (l.a.87), (l.a.109), (l.a.1 13), (l.a.1 14), (l.a.1 15), (l.a.137), (l.f.85), (l.f.86), (l.f.87), (l.f.109), (l.f.1 13), (l.f.1 14), (l.f.1 15) and (l.f.137), at least one and especially exactly one herbicidally active compound from group b6), in particular selected from the group consisting of glyphosate, glyphosate- ammonium, glyphosate-dimethylammonium , glyphosate-isopropylammonium and glyphosate-trimesium (sulfosate) and glyphosate-potassium.

According to another preferred embodiment of the invention, the composition comprises, in addition to an phenyltriazolinone of formula (I), especially an active compound from the group consisting of (l.a.85), (l.a.86), (l.a.87), (l.a.109), (l.a.1 13), (l.a.1 14), (l.a.1 15), (l.a.137), (l.f.85), (l.f.86), (l.f.87), (l.f.109), (l.f.1 13), (l.f.1 14), (l.f.1 15) and (l.f.137), at least one and especially exactly one herbicidally active compound from group b10), in particular selected from the group consisting of acetochlor, butachlor, cafenstrole, dimethenamid-P, fentrazamide, flufenacet, mefenacet, metazachlor, metolachlor, S-metolachlor, fenoxasulfone, ipfencarbazone and pyroxasulfone. Likewise, preference is given to compositions comprising in addition to an phenyltriazoli- none of formula (I), especially an active compound from the group consisting of (l.a.85), (l.a.86), (l.a.87), (l.a.109), (l.a.1 13), (l.a.1 14), (l.a.1 15), (l.a.137), (l.f.85), (l.f.86), (l.f.87), (l.f.109), (l.f.1 13), (l.f.1 14), (l.f.1 15) and (l.f.137), at least one and especially exactly one herbicidally active compound from group b10), in particular selected from the group consisting of isoxazoline compounds of the formulae 11.1 , II.2, II.3, II.4, II.5, II.6, II.7, II.8 and II.9, as defined above. According to another preferred embodiment of the invention, the composition comprises, in addition to an phenyltriazolinone of formula (I), especially an active compound from the group consisting of (l.a.85), (l.a.86), (l.a.87), (l.a.109), (l.a.1 13), (l.a.1 14), (l.a.1 15), (l.a.137), (l.f.85), (l.f.86), (l.f.87), (l.f.109), (l.f.1 13), (l.f.1 14), (l.f.1 15) and (l.f.137), at least one and especially exactly one herbicidally active compound from group b13), in particular selected from the group consisting of 2,4-D, 2,4-D-isobutyl, 2,4-D-dimethylammonium, 2,4-D-N,N,N-trimethylethanolammonium, aminocyclopyra- chlor, aminocyclopyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid, ami- nopyralid-methyl, aminopyralid-dimethylammonium, aminopyralid-tris(2- hydroxypropyl)ammonium, clopyralid, clopyralid-methyl, clopyralid-olamine, dicamba, dicamba-butotyl, dicamba-diglycolamine, dicamba-dimethylammonium, dicamba- diolamine, dicamba-isopropylammonium, dicamba-potassium, dicamba-sodium, dicamba-trolamine, dicamba-N,N-bis-(3-aminopropyl)methylamine, dicamba- diethylenetriamine, flopyrauxifen, fluroxypyr, fluroxypyr-meptyl, halauxifen, halauxifen- methyl, MCPA, MCPA-2-ethylhexyl, MCPA-dimethylammonium, quinclorac, quinclorac- dimethylammonium, quinmerac, quinmerac-dimethylammonium, florpyrauxifen, florpyrauxifen-benzyl (CAS 1390661 -72-9), and 4-amino-3-chloro-5-fluoro-6-(7-fluoro- 1 H-indol-6-yl)picolinic acid.

Here and below, the term "binary compositions" includes compositions comprising one or more, for example 1 , 2 or 3, active compounds of the formula (I) and either one or more, for example 1 , 2 or 3, herbicides B or one or more safeners C.

Correspondingly, the term "ternary compositions" includes compositions comprising one or more, for example 1 , 2 or 3, active compounds of the formula (I), one or more, for example 1 , 2 or 3, herbicides B and one or more, for example 1 , 2 or 3, safeners C.

In binary compositions comprising at least one compound of the formula (I) as component A and at least one herbicide B, the weight ratio of the active compounds A:B is generally in the range of from 1 :1000 to 1000:1 , preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :125 to 125:1 . In binary compositions comprising at least one compound of the formula (I) as component A and at least one safener C, the weight ratio of the active compounds A:C is generally in the range of from 1 :1000 to 1000:1 , preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :75 to 75: 1.

In ternary compositions comprising at least one phenyltriazolinone of formula (I) as component A, at least one herbicide B and at least one safener C, the relative proportions by weight of the components A:B are generally in the range of from 1 :1000 to 1000:1 , preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :125 to 125:1 , the weight ratio of the components A:C is generally in the range of from 1 :1000 to 1000:1 , preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :75 to 75:1 , and the weight ratio of the components B:C is generally in the range of from 1 :1000 to 1000:1 , preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :75 to 75:1 . The weight ratio of components A + B to component C is preferably in the range of from 1 :500 to 500:1 , in particular in the range of from 1 :250 to 250:1 and particularly preferably in the range of from 1 :75 to 75:1 .

The weight ratios of the individual components in the preferred mixtures mentioned below are within the limits given herein, in particular within the preferred limits.

Particularly preferred are the compositions mentioned below comprising the phenyltria- zolinones of formula (I) as defined and the substance(s) as defined in the respective row of table 1 ;

especially preferred comprising as only herbicidal active compounds the phenyltriazoli- nones of formula (I) as defined and the substance(s) as defined in the respective row of table 1 ;

most preferably comprising as only active compounds the phenyltriazolinones of formula (I) as defined and the substance(s) as defined in the respective row of table 1 . Particularly preferred are compositions 1.1 to 1.3653, especially compositions 1.1 to 1.3635, comprising the phenyltriazolinone (I. a.87) and the substance(s) as defined in the respective row of table 1 : Table 1 (compositions 1.1 to 1.3653):

comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C

1.1 B.1 — 1.32 B.32 — 1.63 B.63 —

1.2 B.2 — 1.33 B.33 — 1.64 B.64 —

1.3 B.3 — 1.34 B.34 — 1.65 B.65 —

1.4 B.4 — 1.35 B.35 — 1.66 B.66 —

1.5 B.5 — 1.36 B.36 — 1.67 B.67 —

1.6 B.6 — 1.37 B.37 — 1.68 B.68 —

1.7 B.7 — 1.38 B.38 — 1.69 B.69 —

1.8 B.8 — 1.39 B.39 — 1.70 B.70 —

1.9 B.9 — 1.40 B.40 — 1.71 B.71 —

1.10 B.10 — 1.41 B.41 — 1.72 B.72 —

1.11 B.11 — 1.42 B.42 — 1.73 B.73 —

1.12 B.12 — 1.43 B.43 — 1.74 B.74 —

1.13 B.13 — 1.44 B.44 — 1.75 B.75 —

1.14 B.14 — 1.45 B.45 — 1.76 B.76 —

1.15 B.15 — 1.46 B.46 — 1.77 B.77 —

1.16 B.16 — 1.47 B.47 — 1.78 B.78 —

1.17 B.17 — 1.48 B.48 — 1.79 B.79 —

1.18 B.18 — 1.49 B.49 — 1.80 B.80 —

1.19 B.19 — 1.50 B.50 — 1.81 B.81 —

1.20 B.20 — 1.51 B.51 — 1.82 B.82 —

1.21 B.21 — 1.52 B.52 — 1.83 B.83 —

1.22 B.22 — 1.53 B.53 — 1.84 B.84 —

1.23 B.23 — 1.54 B.54 — 1.85 B.85 —

1.24 B.24 — 1.55 B.55 — 1.86 B.86 —

1.25 B.25 — 1.56 B.56 — 1.87 B.87 —

1.26 B.26 — 1.57 B.57 — 1.88 B.88 —

1.27 B.27 — 1.58 B.58. — 1.89 B.89 —

1.28 B.28 — 1.59 B.59 — 1.90 B.90 —

1.29 B.29 — 1.60 B.60 — 1.91 B.91 —

1.30 B.30 — 1.61 B.61 — 1.92 B.92 —

1.31 B.31 — 1.62 B.62 — 1.93 B.93 — comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.94 B.94 — 1.130 B.130 — 1.166 B.166 —.95 B.95 — 1.131 B.131 — 1.167 B.167 —.96 B.96 — 1.132 B.132 — 1.168 B.168 —.97 B.97 — 1.133 B.133 — 1.169 B.169 —.98 B.98 — 1.134 B.134 — 1.170 B.170 —.99 B.99 — 1.135 B.135 — 1.171 B.171 —.100 B.100 — 1.136 B.136 — 1.172 B.172 —.101 B.101 — 1.137 B.137 — 1.173 B.173 —.102 B.102 — 1.138 B.138 — 1.174 B.174 —.103 B.103 — 1.139 B.139 — 1.175 B.175 —.104 B.104 — 1.140 B.140 — 1.176 B.176 —.105 B.105 — 1.141 B.141 — 1.177 B.177 —.106 B.106 — 1.142 B.142 — 1.178 B.178 —.107 B.107 — 1.143 B.143 — 1.179 B.179 —.108 B.108 — 1.144 B.144 — 1.180 B.180 —.109 B.109 — 1.145 B.145 — 1.181 B.181 —.110 B.110 — 1.146 B.146 — 1.182 B.182 —.111 B.111 — 1.147 B.147 — 1.183 B.183 —.112 B.112 — 1.148 B.148 — 1.184 B.184 —.113 B.113 — 1.149 B.149 — 1.185 B.185 —.114 B.114 — 1.150 B.150 — 1.186 B.186 —.115 B.115 — 1.151 B.151 — 1.187 B.187 —.116 B.116 — 1.152 B.152 — 1.188 B.188 —.117 B.117 — 1.153 B.153 — 1.189 B.189 —.118 B.118 — 1.154 B.154 — 1.190 B.190 —.119 B.119 — 1.155 B.155 — 1.191 B.191 —.120 B.120 — 1.156 B.156 — 1.192 B.192 —.121 B.121 — 1.157 B.157 — 1.193 B.193 —.122 B.122 — 1.158 B.158 — 1.194 B.194 —.123 B.123 — 1.159 B.159 — 1.195 B.195 —.124 B.124 — 1.160 B.160 — 1.196 B.196 —.125 B.125 — 1.161 B.161 — 1.197 B.197 —.126 B.126 — 1.162 B.162 — 1.198 B.198 —.127 B.127 — 1.163 B.163 — 1.199 B.199 —.128 B.128 — 1.164 B.164 — 1.200 B.200 —.129 B.129 1.165 B.165 1.201 B.201 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.202 B.1 C.1 1.238 B.37 C.1 1.274 B.73 C.1.203 B.2 C.1 1.239 B.38 C.1 1.275 B.74 C.1.204 B.3 C.1 1.240 B.39 C.1 1.276 B.75 C.1.205 B.4 C.1 1.241 B.40 C.1 1.277 B.76 C.1.206 B.5 C.1 1.242 B.41 C.1 1.278 B.77 C.1.207 B.6 C.1 1.243 B.42 C.1 1.279 B.78 C.1.208 B.7 C.1 1.244 B.43 C.1 1.280 B.79 C.1.209 B.8 C.1 1.245 B.44 C.1 1.281 B.80 C.1.210 B.9 C.1 1.246 B.45 C.1 1.282 B.81 C.1.211 B.10 C.1 1.247 B.46 C.1 1.283 B.82 C.1.212 B.11 C.1 1.248 B.47 C.1 1.284 B.83 C.1.213 B.12 C.1 1.249 B.48 C.1 1.285 B.84 C.1.214 B.13 C.1 1.250 B.49 C.1 1.286 B.85 C.1.215 B.14 C.1 1.251 B.50 C.1 1.287 B.86 C.1.216 B.15 C.1 1.252 B.51 C.1 1.288 B.87 C.1.217 B.16 C.1 1.253 B.52 C.1 1.289 B.88 C.1.218 B.17 C.1 1.254 B.53 C.1 1.290 B.89 C.1.219 B.18 C.1 1.255 B.54 C.1 1.291 B.90 C.1.220 B.19 C.1 1.256 B.55 C.1 1.292 B.91 C.1.221 B.20 C.1 1.257 B.56 C.1 1.293 B.92 C.1.222 B.21 C.1 1.258 B.57 C.1 1.294 B.93 C.1.223 B.22 C.1 1.259 B.58. C.1 1.295 B.94 C.1.224 B.23 C.1 1.260 B.59 C.1 1.296 B.95 C.1.225 B.24 C.1 1.261 B.60 C.1 1.297 B.96 C.1.226 B.25 C.1 1.262 B.61 C.1 1.298 B.97 C.1.227 B.26 C.1 1.263 B.62 C.1 1.299 B.98 C.1.228 B.27 C.1 1.264 B.63 C.1 1.300 B.99 C.1.229 B.28 C.1 1.265 B.64 C.1 1.301 B.100 C.1.230 B.29 C.1 1.266 B.65 C.1 1.302 B.101 C.1.231 B.30 C.1 1.267 B.66 C.1 1.303 B.102 C.1.232 B.31 C.1 1.268 B.67 C.1 1.304 B.103 C.1.233 B.32 C.1 1.269 B.68 C.1 1.305 B.104 C.1.234 B.33 C.1 1.270 B.69 C.1 1.306 B.105 C.1.235 B.34 C.1 1.271 B.70 C.1 1.307 B.106 C.1.236 B.35 C.1 1.272 B.71 C.1 1.308 B.107 C.1.237 B.36 C.1 1.273 B.72 C.1 1.309 B.108 C.1 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.310 B.109 C.1 1.346 B.145 C.1 1.382 B.181 C.1.311 B.110 C.1 1.347 B.146 C.1 1.383 B.182 C.1.312 B.111 C.1 1.348 B.147 C.1 1.384 B.183 C.1.313 B.112 C.1 1.349 B.148 C.1 1.385 B.184 C.1.314 B.113 C.1 1.350 B.149 C.1 1.386 B.185 C.1.315 B.114 C.1 1.351 B.150 C.1 1.387 B.186 C.1.316 B.115 C.1 1.352 B.151 C.1 1.388 B.187 C.1.317 B.116 C.1 1.353 B.152 C.1 1.389 B.188 C.1.318 B.117 C.1 1.354 B.153 C.1 1.390 B.189 C.1.319 B.118 C.1 1.355 B.154 C.1 1.391 B.190 C.1.320 B.119 C.1 1.356 B.155 C.1 1.392 B.191 C.1.321 B.120 C.1 1.357 B.156 C.1 1.393 B.192 C.1.322 B.121 C.1 1.358 B.157 C.1 1.394 B.193 C.1.323 B.122 C.1 1.359 B.158 C.1 1.395 B.194 C.1.324 B.123 C.1 1.360 B.159 C.1 1.396 B.195 C.1.325 B.124 C.1 1.361 B.160 C.1 1.397 B.196 C.1.326 B.125 C.1 1.362 B.161 C.1 1.398 B.197 C.1.327 B.126 C.1 1.363 B.162 C.1 1.399 B.198 C.1.328 B.127 C.1 1.364 B.163 C.1 1.400 B.199 C.1.329 B.128 C.1 1.365 B.164 C.1 1.401 B.200 C.1.330 B.129 C.1 1.366 B.165 C.1 1.402 B.201 C.1.331 B.130 C.1 1.367 B.166 C.1 1.403 B.1 C.2.332 B.131 C.1 1.368 B.167 C.1 1.404 B.2 C.2.333 B.132 C.1 1.369 B.168 C.1 1.405 B.3 C.2.334 B.133 C.1 1.370 B.169 C.1 1.406 B.4 C.2.335 B.134 C.1 1.371 B.170 C.1 1.407 B.5 C.2.336 B.135 C.1 1.372 B.171 C.1 1.408 B.6 C.2.337 B.136 C.1 1.373 B.172 C.1 1.409 B.7 C.2.338 B.137 C.1 1.374 B.173 C.1 1.410 B.8 C.2.339 B.138 C.1 1.375 B.174 C.1 1.411 B.9 C.2.340 B.139 C.1 1.376 B.175 C.1 1.412 B.10 C.2.341 B.140 C.1 1.377 B.176 C.1 1.413 B.11 C.2.342 B.141 C.1 1.378 B.177 C.1 1.414 B.12 C.2.343 B.142 C.1 1.379 B.178 C.1 1.415 B.13 C.2.344 B.143 C.1 1.380 B.179 C.1 1.416 B.14 C.2.345 B.144 C.1 1.381 B.180 C.1 1.417 B.15 C.2 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.418 B.16 C.2 1.454 B.52 C.2 1.490 B.88 C.2.419 B.17 C.2 1.455 B.53 C.2 1.491 B.89 C.2.420 B.18 C.2 1.456 B.54 C.2 1.492 B.90 C.2.421 B.19 C.2 1.457 B.55 C.2 1.493 B.91 C.2.422 B.20 C.2 1.458 B.56 C.2 1.494 B.92 C.2.423 B.21 C.2 1.459 B.57 C.2 1.495 B.93 C.2.424 B.22 C.2 1.460 B.58. C.2 1.496 B.94 C.2.425 B.23 C.2 1.461 B.59 C.2 1.497 B.95 C.2.426 B.24 C.2 1.462 B.60 C.2 1.498 B.96 C.2.427 B.25 C.2 1.463 B.61 C.2 1.499 B.97 C.2.428 B.26 C.2 1.464 B.62 C.2 1.500 B.98 C.2.429 B.27 C.2 1.465 B.63 C.2 1.501 B.99 C.2.430 B.28 C.2 1.466 B.64 C.2 1.502 B.100 C.2.431 B.29 C.2 1.467 B.65 C.2 1.503 B.101 C.2.432 B.30 C.2 1.468 B.66 C.2 1.504 B.102 C.2.433 B.31 C.2 1.469 B.67 C.2 1.505 B.103 C.2.434 B.32 C.2 1.470 B.68 C.2 1.506 B.104 C.2.435 B.33 C.2 1.471 B.69 C.2 1.507 B.105 C.2.436 B.34 C.2 1.472 B.70 C.2 1.508 B.106 C.2.437 B.35 C.2 1.473 B.71 C.2 1.509 B.107 C.2.438 B.36 C.2 1.474 B.72 C.2 1.510 B.108 C.2.439 B.37 C.2 1.475 B.73 C.2 1.511 B.109 C.2.440 B.38 C.2 1.476 B.74 C.2 1.512 B.110 C.2.441 B.39 C.2 1.477 B.75 C.2 1.513 B.111 C.2.442 B.40 C.2 1.478 B.76 C.2 1.514 B.112 C.2.443 B.41 C.2 1.479 B.77 C.2 1.515 B.113 C.2.444 B.42 C.2 1.480 B.78 C.2 1.516 B.114 C.2.445 B.43 C.2 1.481 B.79 C.2 1.517 B.115 C.2.446 B.44 C.2 1.482 B.80 C.2 1.518 B.116 C.2.447 B.45 C.2 1.483 B.81 C.2 1.519 B.117 C.2.448 B.46 C.2 1.484 B.82 C.2 1.520 B.118 C.2.449 B.47 C.2 1.485 B.83 C.2 1.521 B.119 C.2.450 B.48 C.2 1.486 B.84 C.2 1.522 B.120 C.2.451 B.49 C.2 1.487 B.85 C.2 1.523 B.121 C.2.452 B.50 C.2 1.488 B.86 C.2 1.524 B.122 C.2.453 B.51 C.2 1.489 B.87 C.2 1.525 B.123 C.2 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.526 B.124 C.2 1.562 B.160 C.2 1.598 B.196 C.2.527 B.125 C.2 1.563 B.161 C.2 1.599 B.197 C.2.528 B.126 C.2 1.564 B.162 C.2 1.600 B.198 C.2.529 B.127 C.2 1.565 B.163 C.2 1.601 B.199 C.2.530 B.128 C.2 1.566 B.164 C.2 1.602 B.200 C.2.531 B.129 C.2 1.567 B.165 C.2 1.603 B.201 C.2.532 B.130 C.2 1.568 B.166 C.2 1.604 B.1 C.3.533 B.131 C.2 1.569 B.167 C.2 1.605 B.2 C.3.534 B.132 C.2 1.570 B.168 C.2 1.606 B.3 C.3.535 B.133 C.2 1.571 B.169 C.2 1.607 B.4 C.3.536 B.134 C.2 1.572 B.170 C.2 1.608 B.5 C.3.537 B.135 C.2 1.573 B.171 C.2 1.609 B.6 C.3.538 B.136 C.2 1.574 B.172 C.2 1.610 B.7 C.3.539 B.137 C.2 1.575 B.173 C.2 1.611 B.8 C.3.540 B.138 C.2 1.576 B.174 C.2 1.612 B.9 C.3.541 B.139 C.2 1.577 B.175 C.2 1.613 B.10 C.3.542 B.140 C.2 1.578 B.176 C.2 1.614 B.11 C.3.543 B.141 C.2 1.579 B.177 C.2 1.615 B.12 C.3.544 B.142 C.2 1.580 B.178 C.2 1.616 B.13 C.3.545 B.143 C.2 1.581 B.179 C.2 1.617 B.14 C.3.546 B.144 C.2 1.582 B.180 C.2 1.618 B.15 C.3.547 B.145 C.2 1.583 B.181 C.2 1.619 B.16 C.3.548 B.146 C.2 1.584 B.182 C.2 1.620 B.17 C.3.549 B.147 C.2 1.585 B.183 C.2 1.621 B.18 C.3.550 B.148 C.2 1.586 B.184 C.2 1.622 B.19 C.3.551 B.149 C.2 1.587 B.185 C.2 1.623 B.20 C.3.552 B.150 C.2 1.588 B.186 C.2 1.624 B.21 C.3.553 B.151 C.2 1.589 B.187 C.2 1.625 B.22 C.3.554 B.152 C.2 1.590 B.188 C.2 1.626 B.23 C.3.555 B.153 C.2 1.591 B.189 C.2 1.627 B.24 C.3.556 B.154 C.2 1.592 B.190 C.2 1.628 B.25 C.3.557 B.155 C.2 1.593 B.191 C.2 1.629 B.26 C.3.558 B.156 C.2 1.594 B.192 C.2 1.630 B.27 C.3.559 B.157 C.2 1.595 B.193 C.2 1.631 B.28 C.3.560 B.158 C.2 1.596 B.194 C.2 1.632 B.29 C.3.561 B.159 C.2 1.597 B.195 C.2 1.633 B.30 C.3 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.634 B.31 C.3 1.670 B.67 C.3 1.706 B.103 C.3.635 B.32 C.3 1.671 B.68 C.3 1.707 B.104 C.3.636 B.33 C.3 1.672 B.69 C.3 1.708 B.105 C.3.637 B.34 C.3 1.673 B.70 C.3 1.709 B.106 C.3.638 B.35 C.3 1.674 B.71 C.3 1.710 B.107 C.3.639 B.36 C.3 1.675 B.72 C.3 1.711 B.108 C.3.640 B.37 C.3 1.676 B.73 C.3 1.712 B.109 C.3.641 B.38 C.3 1.677 B.74 C.3 1.713 B.110 C.3.642 B.39 C.3 1.678 B.75 C.3 1.714 B.111 C.3.643 B.40 C.3 1.679 B.76 C.3 1.715 B.112 C.3.644 B.41 C.3 1.680 B.77 C.3 1.716 B.113 C.3.645 B.42 C.3 1.681 B.78 C.3 1.717 B.114 C.3.646 B.43 C.3 1.682 B.79 C.3 1.718 B.115 C.3.647 B.44 C.3 1.683 B.80 C.3 1.719 B.116 C.3.648 B.45 C.3 1.684 B.81 C.3 1.720 B.117 C.3.649 B.46 C.3 1.685 B.82 C.3 1.721 B.118 C.3.650 B.47 C.3 1.686 B.83 C.3 1.722 B.119 C.3.651 B.48 C.3 1.687 B.84 C.3 1.723 B.120 C.3.652 B.49 C.3 1.688 B.85 C.3 1.724 B.121 C.3.653 B.50 C.3 1.689 B.86 C.3 1.725 B.122 C.3.654 B.51 C.3 1.690 B.87 C.3 1.726 B.123 C.3.655 B.52 C.3 1.691 B.88 C.3 1.727 B.124 C.3.656 B.53 C.3 1.692 B.89 C.3 1.728 B.125 C.3.657 B.54 C.3 1.693 B.90 C.3 1.729 B.126 C.3.658 B.55 C.3 1.694 B.91 C.3 1.730 B.127 C.3.659 B.56 C.3 1.695 B.92 C.3 1.731 B.128 C.3.660 B.57 C.3 1.696 B.93 C.3 1.732 B.129 C.3.661 B.58. C.3 1.697 B.94 C.3 1.733 B.130 C.3.662 B.59 C.3 1.698 B.95 C.3 1.734 B.131 C.3.663 B.60 C.3 1.699 B.96 C.3 1.735 B.132 C.3.664 B.61 C.3 1.700 B.97 C.3 1.736 B.133 C.3.665 B.62 C.3 1.701 B.98 C.3 1.737 B.134 C.3.666 B.63 C.3 1.702 B.99 C.3 1.738 B.135 C.3.667 B.64 C.3 1.703 B.100 C.3 1.739 B.136 C.3.668 B.65 C.3 1.704 B.101 C.3 1.740 B.137 C.3.669 B.66 C.3 1.705 B.102 C.3 1.741 B.138 C.3 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.742 B.139 C.3 1.778 B.175 C.3 1.814 B.10 C.4.743 B.140 C.3 1.779 B.176 C.3 1.815 B.11 C.4.744 B.141 C.3 1.780 B.177 C.3 1.816 B.12 C.4.745 B.142 C.3 1.781 B.178 C.3 1.817 B.13 C.4.746 B.143 C.3 1.782 B.179 C.3 1.818 B.14 C.4.747 B.144 C.3 1.783 B.180 C.3 1.819 B.15 C.4.748 B.145 C.3 1.784 B.181 C.3 1.820 B.16 C.4.749 B.146 C.3 1.785 B.182 C.3 1.821 B.17 C.4.750 B.147 C.3 1.786 B.183 C.3 1.822 B.18 C.4.751 B.148 C.3 1.787 B.184 C.3 1.823 B.19 C.4.752 B.149 C.3 1.788 B.185 C.3 1.824 B.20 C.4.753 B.150 C.3 1.789 B.186 C.3 1.825 B.21 C.4.754 B.151 C.3 1.790 B.187 C.3 1.826 B.22 C.4.755 B.152 C.3 1.791 B.188 C.3 1.827 B.23 C.4.756 B.153 C.3 1.792 B.189 C.3 1.828 B.24 C.4.757 B.154 C.3 1.793 B.190 C.3 1.829 B.25 C.4.758 B.155 C.3 1.794 B.191 C.3 1.830 B.26 C.4.759 B.156 C.3 1.795 B.192 C.3 1.831 B.27 C.4.760 B.157 C.3 1.796 B.193 C.3 1.832 B.28 C.4.761 B.158 C.3 1.797 B.194 C.3 1.833 B.29 C.4.762 B.159 C.3 1.798 B.195 C.3 1.834 B.30 C.4.763 B.160 C.3 1.799 B.196 C.3 1.835 B.31 C.4.764 B.161 C.3 1.800 B.197 C.3 1.836 B.32 C.4.765 B.162 C.3 1.801 B.198 C.3 1.837 B.33 C.4.766 B.163 C.3 1.802 B.199 C.3 1.838 B.34 C.4.767 B.164 C.3 1.803 B.200 C.3 1.839 B.35 C.4.768 B.165 C.3 1.804 B.201 C.3 1.840 B.36 C.4.769 B.166 C.3 1.805 B.1 C.4 1.841 B.37 C.4.770 B.167 C.3 1.806 B.2 C.4 1.842 B.38 C.4.771 B.168 C.3 1.807 B.3 C.4 1.843 B.39 C.4.772 B.169 C.3 1.808 B.4 C.4 1.844 B.40 C.4.773 B.170 C.3 1.809 B.5 C.4 1.845 B.41 C.4.774 B.171 C.3 1.810 B.6 C.4 1.846 B.42 C.4.775 B.172 C.3 1.811 B.7 C.4 1.847 B.43 C.4.776 B.173 C.3 1.812 B.8 C.4 1.848 B.44 C.4.777 B.174 C.3 1.813 B.9 C.4 1.849 B.45 C.4 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.850 B.46 C.4 1.886 B.82 C.4 1.922 B.118 C.4.851 B.47 C.4 1.887 B.83 C.4 1.923 B.119 C.4.852 B.48 C.4 1.888 B.84 C.4 1.924 B.120 C.4.853 B.49 C.4 1.889 B.85 C.4 1.925 B.121 C.4.854 B.50 C.4 1.890 B.86 C.4 1.926 B.122 C.4.855 B.51 C.4 1.891 B.87 C.4 1.927 B.123 C.4.856 B.52 C.4 1.892 B.88 C.4 1.928 B.124 C.4.857 B.53 C.4 1.893 B.89 C.4 1.929 B.125 C.4.858 B.54 C.4 1.894 B.90 C.4 1.930 B.126 C.4.859 B.55 C.4 1.895 B.91 C.4 1.931 B.127 C.4.860 B.56 C.4 1.896 B.92 C.4 1.932 B.128 C.4.861 B.57 C.4 1.897 B.93 C.4 1.933 B.129 C.4.862 B.58. C.4 1.898 B.94 C.4 1.934 B.130 C.4.863 B.59 C.4 1.899 B.95 C.4 1.935 B.131 C.4.864 B.60 C.4 1.900 B.96 C.4 1.936 B.132 C.4.865 B.61 C.4 1.901 B.97 C.4 1.937 B.133 C.4.866 B.62 C.4 1.902 B.98 C.4 1.938 B.134 C.4.867 B.63 C.4 1.903 B.99 C.4 1.939 B.135 C.4.868 B.64 C.4 1.904 B.100 C.4 1.940 B.136 C.4.869 B.65 C.4 1.905 B.101 C.4 1.941 B.137 C.4.870 B.66 C.4 1.906 B.102 C.4 1.942 B.138 C.4.871 B.67 C.4 1.907 B.103 C.4 1.943 B.139 C.4.872 B.68 C.4 1.908 B.104 C.4 1.944 B.140 C.4.873 B.69 C.4 1.909 B.105 C.4 1.945 B.141 C.4.874 B.70 C.4 1.910 B.106 C.4 1.946 B.142 C.4.875 B.71 C.4 1.911 B.107 C.4 1.947 B.143 C.4.876 B.72 C.4 1.912 B.108 C.4 1.948 B.144 C.4.877 B.73 C.4 1.913 B.109 C.4 1.949 B.145 C.4.878 B.74 C.4 1.914 B.110 C.4 1.950 B.146 C.4.879 B.75 C.4 1.915 B.111 C.4 1.951 B.147 C.4.880 B.76 C.4 1.916 B.112 C.4 1.952 B.148 C.4.881 B.77 C.4 1.917 B.113 C.4 1.953 B.149 C.4.882 B.78 C.4 1.918 B.114 C.4 1.954 B.150 C.4.883 B.79 C.4 1.919 B.115 C.4 1.955 B.151 C.4.884 B.80 C.4 1.920 B.116 C.4 1.956 B.152 C.4.885 B.81 C.4 1.921 B.117 C.4 1.957 B.153 C.4 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.958 B.154 C.4 1.994 B.190 C.4 1.1030 B.25 C.5.959 B.155 C.4 1.995 B.191 C.4 1.1031 B.26 C.5.960 B.156 C.4 1.996 B.192 C.4 1.1032 B.27 C.5.961 B.157 C.4 1.997 B.193 C.4 1.1033 B.28 C.5.962 B.158 C.4 1.998 B.194 C.4 1.1034 B.29 C.5.963 B.159 C.4 1.999 B.195 C.4 1.1035 B.30 C.5.964 B.160 C.4 1.1000 B.196 C.4 1.1036 B.31 C.5.965 B.161 C.4 1.1001 B.197 C.4 1.1037 B.32 C.5.966 B.162 C.4 1.1002 B.198 C.4 1.1038 B.33 C.5.967 B.163 C.4 1.1003 B.199 C.4 1.1039 B.34 C.5.968 B.164 C.4 1.1004 B.200 C.4 1.1040 B.35 C.5.969 B.165 C.4 1.1005 B.201 C.4 1.1041 B.36 C.5.970 B.166 C.4 1.1006 B.1 C.5 1.1042 B.37 C.5.971 B.167 C.4 1.1007 B.2 C.5 1.1043 B.38 C.5.972 B.168 C.4 1.1008 B.3 C.5 1.1044 B.39 C.5.973 B.169 C.4 1.1009 B.4 C.5 1.1045 B.40 C.5.974 B.170 C.4 1.1010 B.5 C.5 1.1046 B.41 C.5.975 B.171 C.4 1.1011 B.6 C.5 1.1047 B.42 C.5.976 B.172 C.4 1.1012 B.7 C.5 1.1048 B.43 C.5.977 B.173 C.4 1.1013 B.8 C.5 1.1049 B.44 C.5.978 B.174 C.4 1.1014 B.9 C.5 1.1050 B.45 C.5.979 B.175 C.4 1.1015 B.10 C.5 1.1051 B.46 C.5.980 B.176 C.4 1.1016 B.11 C.5 1.1052 B.47 C.5.981 B.177 C.4 1.1017 B.12 C.5 1.1053 B.48 C.5.982 B.178 C.4 1.1018 B.13 C.5 1.1054 B.49 C.5.983 B.179 C.4 1.1019 B.14 C.5 1.1055 B.50 C.5.984 B.180 C.4 1.1020 B.15 C.5 1.1056 B.51 C.5.985 B.181 C.4 1.1021 B.16 C.5 1.1057 B.52 C.5.986 B.182 C.4 1.1022 B.17 C.5 1.1058 B.53 C.5.987 B.183 C.4 1.1023 B.18 C.5 1.1059 B.54 C.5.988 B.184 C.4 1.1024 B.19 C.5 1.1060 B.55 C.5.989 B.185 C.4 1.1025 B.20 C.5 1.1061 B.56 C.5.990 B.186 C.4 1.1026 B.21 C.5 1.1062 B.57 C.5.991 B.187 C.4 1.1027 B.22 C.5 1.1063 B.58. C.5.992 B.188 C.4 1.1028 B.23 C.5 1.1064 B.59 C.5.993 B.189 C.4 1.1029 B.24 C.5 1.1065 B.60 C.5 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1066 B.61 C.5 1.1102 B.97 C.5 1.1138 B.133 C.5.1067 B.62 C.5 1.1103 B.98 C.5 1.1139 B.134 C.5.1068 B.63 C.5 1.1104 B.99 C.5 1.1140 B.135 C.5.1069 B.64 C.5 1.1105 B.100 C.5 1.1141 B.136 C.5.1070 B.65 C.5 1.1106 B.101 C.5 1.1142 B.137 C.5.1071 B.66 C.5 1.1107 B.102 C.5 1.1143 B.138 C.5.1072 B.67 C.5 1.1108 B.103 C.5 1.1144 B.139 C.5.1073 B.68 C.5 1.1109 B.104 C.5 1.1145 B.140 C.5.1074 B.69 C.5 1.1110 B.105 C.5 1.1146 B.141 C.5.1075 B.70 C.5 1.1111 B.106 C.5 1.1147 B.142 C.5.1076 B.71 C.5 1.1112 B.107 C.5 1.1148 B.143 C.5.1077 B.72 C.5 1.1113 B.108 C.5 1.1149 B.144 C.5.1078 B.73 C.5 1.1114 B.109 C.5 1.1150 B.145 C.5.1079 B.74 C.5 1.1115 B.110 C.5 1.1151 B.146 C.5.1080 B.75 C.5 1.1116 B.111 C.5 1.1152 B.147 C.5.1081 B.76 C.5 1.1117 B.112 C.5 1.1153 B.148 C.5.1082 B.77 C.5 1.1118 B.113 C.5 1.1154 B.149 C.5.1083 B.78 C.5 1.1119 B.114 C.5 1.1155 B.150 C.5.1084 B.79 C.5 1.1120 B.115 C.5 1.1156 B.151 C.5.1085 B.80 C.5 1.1121 B.116 C.5 1.1157 B.152 C.5.1086 B.81 C.5 1.1122 B.117 C.5 1.1158 B.153 C.5.1087 B.82 C.5 1.1123 B.118 C.5 1.1159 B.154 C.5.1088 B.83 C.5 1.1124 B.119 C.5 1.1160 B.155 C.5.1089 B.84 C.5 1.1125 B.120 C.5 1.1161 B.156 C.5.1090 B.85 C.5 1.1126 B.121 C.5 1.1162 B.157 C.5.1091 B.86 C.5 1.1127 B.122 C.5 1.1163 B.158 C.5.1092 B.87 C.5 1.1128 B.123 C.5 1.1164 B.159 C.5.1093 B.88 C.5 1.1129 B.124 C.5 1.1165 B.160 C.5.1094 B.89 C.5 1.1130 B.125 C.5 1.1166 B.161 C.5.1095 B.90 C.5 1.1131 B.126 C.5 1.1167 B.162 C.5.1096 B.91 C.5 1.1132 B.127 C.5 1.1168 B.163 C.5.1097 B.92 C.5 1.1133 B.128 C.5 1.1169 B.164 C.5.1098 B.93 C.5 1.1134 B.129 C.5 1.1170 B.165 C.5.1099 B.94 C.5 1.1135 B.130 C.5 1.1171 B.166 C.5.1100 B.95 C.5 1.1136 B.131 C.5 1.1172 B.167 C.5.1101 B.96 C.5 1.1137 B.132 C.5 1.1173 B.168 C.5 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1174 B.169 C.5 1.1210 B.4 C.6 1.1246 B.40 C.6.1175 B.170 C.5 1.1211 B.5 C.6 1.1247 B.41 C.6.1176 B.171 C.5 1.1212 B.6 C.6 1.1248 B.42 C.6.1177 B.172 C.5 1.1213 B.7 C.6 1.1249 B.43 C.6.1178 B.173 C.5 1.1214 B.8 C.6 1.1250 B.44 C.6.1179 B.174 C.5 1.1215 B.9 C.6 1.1251 B.45 C.6.1180 B.175 C.5 1.1216 B.10 C.6 1.1252 B.46 C.6.1181 B.176 C.5 1.1217 B.11 C.6 1.1253 B.47 C.6.1182 B.177 C.5 1.1218 B.12 C.6 1.1254 B.48 C.6.1183 B.178 C.5 1.1219 B.13 C.6 1.1255 B.49 C.6.1184 B.179 C.5 1.1220 B.14 C.6 1.1256 B.50 C.6.1185 B.180 C.5 1.1221 B.15 C.6 1.1257 B.51 C.6.1186 B.181 C.5 1.1222 B.16 C.6 1.1258 B.52 C.6.1187 B.182 C.5 1.1223 B.17 C.6 1.1259 B.53 C.6.1188 B.183 C.5 1.1224 B.18 C.6 1.1260 B.54 C.6.1189 B.184 C.5 1.1225 B.19 C.6 1.1261 B.55 C.6.1190 B.185 C.5 1.1226 B.20 C.6 1.1262 B.56 C.6.1191 B.186 C.5 1.1227 B.21 C.6 1.1263 B.57 C.6.1192 B.187 C.5 1.1228 B.22 C.6 1.1264 B.58. C.6.1193 B.188 C.5 1.1229 B.23 C.6 1.1265 B.59 C.6.1194 B.189 C.5 1.1230 B.24 C.6 1.1266 B.60 C.6.1195 B.190 C.5 1.1231 B.25 C.6 1.1267 B.61 C.6.1196 B.191 C.5 1.1232 B.26 C.6 1.1268 B.62 C.6.1197 B.192 C.5 1.1233 B.27 C.6 1.1269 B.63 C.6.1198 B.193 C.5 1.1234 B.28 C.6 1.1270 B.64 C.6.1199 B.194 C.5 1.1235 B.29 C.6 1.1271 B.65 C.6.1200 B.195 C.5 1.1236 B.30 C.6 1.1272 B.66 C.6.1201 B.196 C.5 1.1237 B.31 C.6 1.1273 B.67 C.6.1202 B.197 C.5 1.1238 B.32 C.6 1.1274 B.68 C.6.1203 B.198 C.5 1.1239 B.33 C.6 1.1275 B.69 C.6.1204 B.199 C.5 1.1240 B.34 C.6 1.1276 B.70 C.6.1205 B.200 C.5 1.1241 B.35 C.6 1.1277 B.71 C.6.1206 B.201 C.5 1.1242 B.36 C.6 1.1278 B.72 C.6.1207 B.1 C.6 1.1243 B.37 C.6 1.1279 B.73 C.6.1208 B.2 C.6 1.1244 B.38 C.6 1.1280 B.74 C.6.1209 B.3 C.6 1.1245 B.39 C.6 1.1281 B.75 C.6 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1282 B.76 C.6 1.1318 B.112 C.6 1.1354 B.148 C.6.1283 B.77 C.6 1.1319 B.113 C.6 1.1355 B.149 C.6.1284 B.78 C.6 1.1320 B.114 C.6 1.1356 B.150 C.6.1285 B.79 C.6 1.1321 B.115 C.6 1.1357 B.151 C.6.1286 B.80 C.6 1.1322 B.116 C.6 1.1358 B.152 C.6.1287 B.81 C.6 1.1323 B.117 C.6 1.1359 B.153 C.6.1288 B.82 C.6 1.1324 B.118 C.6 1.1360 B.154 C.6.1289 B.83 C.6 1.1325 B.119 C.6 1.1361 B.155 C.6.1290 B.84 C.6 1.1326 B.120 C.6 1.1362 B.156 C.6.1291 B.85 C.6 1.1327 B.121 C.6 1.1363 B.157 C.6.1292 B.86 C.6 1.1328 B.122 C.6 1.1364 B.158 C.6.1293 B.87 C.6 1.1329 B.123 C.6 1.1365 B.159 C.6.1294 B.88 C.6 1.1330 B.124 C.6 1.1366 B.160 C.6.1295 B.89 C.6 1.1331 B.125 C.6 1.1367 B.161 C.6.1296 B.90 C.6 1.1332 B.126 C.6 1.1368 B.162 C.6.1297 B.91 C.6 1.1333 B.127 C.6 1.1369 B.163 C.6.1298 B.92 C.6 1.1334 B.128 C.6 1.1370 B.164 C.6.1299 B.93 C.6 1.1335 B.129 C.6 1.1371 B.165 C.6.1300 B.94 C.6 1.1336 B.130 C.6 1.1372 B.166 C.6.1301 B.95 C.6 1.1337 B.131 C.6 1.1373 B.167 C.6.1302 B.96 C.6 1.1338 B.132 C.6 1.1374 B.168 C.6.1303 B.97 C.6 1.1339 B.133 C.6 1.1375 B.169 C.6.1304 B.98 C.6 1.1340 B.134 C.6 1.1376 B.170 C.6.1305 B.99 C.6 1.1341 B.135 C.6 1.1377 B.171 C.6.1306 B.100 C.6 1.1342 B.136 C.6 1.1378 B.172 C.6.1307 B.101 C.6 1.1343 B.137 C.6 1.1379 B.173 C.6.1308 B.102 C.6 1.1344 B.138 C.6 1.1380 B.174 C.6.1309 B.103 C.6 1.1345 B.139 C.6 1.1381 B.175 C.6.1310 B.104 C.6 1.1346 B.140 C.6 1.1382 B.176 C.6.1311 B.105 C.6 1.1347 B.141 C.6 1.1383 B.177 C.6.1312 B.106 C.6 1.1348 B.142 C.6 1.1384 B.178 C.6.1313 B.107 C.6 1.1349 B.143 C.6 1.1385 B.179 C.6.1314 B.108 C.6 1.1350 B.144 C.6 1.1386 B.180 C.6.1315 B.109 C.6 1.1351 B.145 C.6 1.1387 B.181 C.6.1316 B.110 C.6 1.1352 B.146 C.6 1.1388 B.182 C.6.1317 B.111 C.6 1.1353 B.147 C.6 1.1389 B.183 C.6 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1390 B.184 C.6 1.1426 B.19 C.7 1.1462 B.55 C.7.1391 B.185 C.6 1.1427 B.20 C.7 1.1463 B.56 C.7.1392 B.186 C.6 1.1428 B.21 C.7 1.1464 B.57 C.7.1393 B.187 C.6 1.1429 B.22 C.7 1.1465 B.58. C.7.1394 B.188 C.6 1.1430 B.23 C.7 1.1466 B.59 C.7.1395 B.189 C.6 1.1431 B.24 C.7 1.1467 B.60 C.7.1396 B.190 C.6 1.1432 B.25 C.7 1.1468 B.61 C.7.1397 B.191 C.6 1.1433 B.26 C.7 1.1469 B.62 C.7.1398 B.192 C.6 1.1434 B.27 C.7 1.1470 B.63 C.7.1399 B.193 C.6 1.1435 B.28 C.7 1.1471 B.64 C.7.1400 B.194 C.6 1.1436 B.29 C.7 1.1472 B.65 C.7.1401 B.195 C.6 1.1437 B.30 C.7 1.1473 B.66 C.7.1402 B.196 C.6 1.1438 B.31 C.7 1.1474 B.67 C.7.1403 B.197 C.6 1.1439 B.32 C.7 1.1475 B.68 C.7.1404 B.198 C.6 1.1440 B.33 C.7 1.1476 B.69 C.7.1405 B.199 C.6 1.1441 B.34 C.7 1.1477 B.70 C.7.1406 B.200 C.6 1.1442 B.35 C.7 1.1478 B.71 C.7.1407 B.201 C.6 1.1443 B.36 C.7 1.1479 B.72 C.7.1408 B.1 C.7 1.1444 B.37 C.7 1.1480 B.73 C.7.1409 B.2 C.7 1.1445 B.38 C.7 1.1481 B.74 C.7.1410 B.3 C.7 1.1446 B.39 C.7 1.1482 B.75 C.7.1411 B.4 C.7 1.1447 B.40 C.7 1.1483 B.76 C.7.1412 B.5 C.7 1.1448 B.41 C.7 1.1484 B.77 C.7.1413 B.6 C.7 1.1449 B.42 C.7 1.1485 B.78 C.7.1414 B.7 C.7 1.1450 B.43 C.7 1.1486 B.79 C.7.1415 B.8 C.7 1.1451 B.44 C.7 1.1487 B.80 C.7.1416 B.9 C.7 1.1452 B.45 C.7 1.1488 B.81 C.7.1417 B.10 C.7 1.1453 B.46 C.7 1.1489 B.82 C.7.1418 B.11 C.7 1.1454 B.47 C.7 1.1490 B.83 C.7.1419 B.12 C.7 1.1455 B.48 C.7 1.1491 B.84 C.7.1420 B.13 C.7 1.1456 B.49 C.7 1.1492 B.85 C.7.1421 B.14 C.7 1.1457 B.50 C.7 1.1493 B.86 C.7.1422 B.15 C.7 1.1458 B.51 C.7 1.1494 B.87 C.7.1423 B.16 C.7 1.1459 B.52 C.7 1.1495 B.88 C.7.1424 B.17 C.7 1.1460 B.53 C.7 1.1496 B.89 C.7.1425 B.18 C.7 1.1461 B.54 C.7 1.1497 B.90 C.7 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1498 B.91 C.7 1.1534 B.127 C.7 1.1570 B.163 C.7.1499 B.92 C.7 1.1535 B.128 C.7 1.1571 B.164 C.7.1500 B.93 C.7 1.1536 B.129 C.7 1.1572 B.165 C.7.1501 B.94 C.7 1.1537 B.130 C.7 1.1573 B.166 C.7.1502 B.95 C.7 1.1538 B.131 C.7 1.1574 B.167 C.7.1503 B.96 C.7 1.1539 B.132 C.7 1.1575 B.168 C.7.1504 B.97 C.7 1.1540 B.133 C.7 1.1576 B.169 C.7.1505 B.98 C.7 1.1541 B.134 C.7 1.1577 B.170 C.7.1506 B.99 C.7 1.1542 B.135 C.7 1.1578 B.171 C.7.1507 B.100 C.7 1.1543 B.136 C.7 1.1579 B.172 C.7.1508 B.101 C.7 1.1544 B.137 C.7 1.1580 B.173 C.7.1509 B.102 C.7 1.1545 B.138 C.7 1.1581 B.174 C.7.1510 B.103 C.7 1.1546 B.139 C.7 1.1582 B.175 C.7.1511 B.104 C.7 1.1547 B.140 C.7 1.1583 B.176 C.7.1512 B.105 C.7 1.1548 B.141 C.7 1.1584 B.177 C.7.1513 B.106 C.7 1.1549 B.142 C.7 1.1585 B.178 C.7.1514 B.107 C.7 1.1550 B.143 C.7 1.1586 B.179 C.7.1515 B.108 C.7 1.1551 B.144 C.7 1.1587 B.180 C.7.1516 B.109 C.7 1.1552 B.145 C.7 1.1588 B.181 C.7.1517 B.110 C.7 1.1553 B.146 C.7 1.1589 B.182 C.7.1518 B.111 C.7 1.1554 B.147 C.7 1.1590 B.183 C.7.1519 B.112 C.7 1.1555 B.148 C.7 1.1591 B.184 C.7.1520 B.113 C.7 1.1556 B.149 C.7 1.1592 B.185 C.7.1521 B.114 C.7 1.1557 B.150 C.7 1.1593 B.186 C.7.1522 B.115 C.7 1.1558 B.151 C.7 1.1594 B.187 C.7.1523 B.116 C.7 1.1559 B.152 C.7 1.1595 B.188 C.7.1524 B.117 C.7 1.1560 B.153 C.7 1.1596 B.189 C.7.1525 B.118 C.7 1.1561 B.154 C.7 1.1597 B.190 C.7.1526 B.119 C.7 1.1562 B.155 C.7 1.1598 B.191 C.7.1527 B.120 C.7 1.1563 B.156 C.7 1.1599 B.192 C.7.1528 B.121 C.7 1.1564 B.157 C.7 1.1600 B.193 C.7.1529 B.122 C.7 1.1565 B.158 C.7 1.1601 B.194 C.7.1530 B.123 C.7 1.1566 B.159 C.7 1.1602 B.195 C.7.1531 B.124 C.7 1.1567 B.160 C.7 1.1603 B.196 C.7.1532 B.125 C.7 1.1568 B.161 C.7 1.1604 B.197 C.7.1533 B.126 C.7 1.1569 B.162 C.7 1.1605 B.198 C.7 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1606 B.199 C.7 1.1642 B.34 C.8 1.1678 B.70 C.8.1607 B.200 C.7 1.1643 B.35 C.8 1.1679 B.71 C.8.1608 B.201 C.7 1.1644 B.36 C.8 1.1680 B.72 C.8.1609 B.1 C.8 1.1645 B.37 C.8 1.1681 B.73 C.8.1610 B.2 C.8 1.1646 B.38 C.8 1.1682 B.74 C.8.1611 B.3 C.8 1.1647 B.39 C.8 1.1683 B.75 C.8.1612 B.4 C.8 1.1648 B.40 C.8 1.1684 B.76 C.8.1613 B.5 C.8 1.1649 B.41 C.8 1.1685 B.77 C.8.1614 B.6 C.8 1.1650 B.42 C.8 1.1686 B.78 C.8.1615 B.7 C.8 1.1651 B.43 C.8 1.1687 B.79 C.8.1616 B.8 C.8 1.1652 B.44 C.8 1.1688 B.80 C.8.1617 B.9 C.8 1.1653 B.45 C.8 1.1689 B.81 C.8.1618 B.10 C.8 1.1654 B.46 C.8 1.1690 B.82 C.8.1619 B.11 C.8 1.1655 B.47 C.8 1.1691 B.83 C.8.1620 B.12 C.8 1.1656 B.48 C.8 1.1692 B.84 C.8.1621 B.13 C.8 1.1657 B.49 C.8 1.1693 B.85 C.8.1622 B.14 C.8 1.1658 B.50 C.8 1.1694 B.86 C.8.1623 B.15 C.8 1.1659 B.51 C.8 1.1695 B.87 C.8.1624 B.16 C.8 1.1660 B.52 C.8 1.1696 B.88 C.8.1625 B.17 C.8 1.1661 B.53 C.8 1.1697 B.89 C.8.1626 B.18 C.8 1.1662 B.54 C.8 1.1698 B.90 C.8.1627 B.19 C.8 1.1663 B.55 C.8 1.1699 B.91 C.8.1628 B.20 C.8 1.1664 B.56 C.8 1.1700 B.92 C.8.1629 B.21 C.8 1.1665 B.57 C.8 1.1701 B.93 C.8.1630 B.22 C.8 1.1666 B.58. C.8 1.1702 B.94 C.8.1631 B.23 C.8 1.1667 B.59 C.8 1.1703 B.95 C.8.1632 B.24 C.8 1.1668 B.60 C.8 1.1704 B.96 C.8.1633 B.25 C.8 1.1669 B.61 C.8 1.1705 B.97 C.8.1634 B.26 C.8 1.1670 B.62 C.8 1.1706 B.98 C.8.1635 B.27 C.8 1.1671 B.63 C.8 1.1707 B.99 C.8.1636 B.28 C.8 1.1672 B.64 C.8 1.1708 B.100 C.8.1637 B.29 C.8 1.1673 B.65 C.8 1.1709 B.101 C.8.1638 B.30 C.8 1.1674 B.66 C.8 1.1710 B.102 C.8.1639 B.31 C.8 1.1675 B.67 C.8 1.1711 B.103 C.8.1640 B.32 C.8 1.1676 B.68 C.8 1.1712 B.104 C.8.1641 B.33 C.8 1.1677 B.69 C.8 1.1713 B.105 C.8 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1714 B.106 C.8 1.1750 B.142 C.8 1.1786 B.178 C.8.1715 B.107 C.8 1.1751 B.143 C.8 1.1787 B.179 C.8.1716 B.108 C.8 1.1752 B.144 C.8 1.1788 B.180 C.8.1717 B.109 C.8 1.1753 B.145 C.8 1.1789 B.181 C.8.1718 B.110 C.8 1.1754 B.146 C.8 1.1790 B.182 C.8.1719 B.111 C.8 1.1755 B.147 C.8 1.1791 B.183 C.8.1720 B.112 C.8 1.1756 B.148 C.8 1.1792 B.184 C.8.1721 B.113 C.8 1.1757 B.149 C.8 1.1793 B.185 C.8.1722 B.114 C.8 1.1758 B.150 C.8 1.1794 B.186 C.8.1723 B.115 C.8 1.1759 B.151 C.8 1.1795 B.187 C.8.1724 B.116 C.8 1.1760 B.152 C.8 1.1796 B.188 C.8.1725 B.117 C.8 1.1761 B.153 C.8 1.1797 B.189 C.8.1726 B.118 C.8 1.1762 B.154 C.8 1.1798 B.190 C.8.1727 B.119 C.8 1.1763 B.155 C.8 1.1799 B.191 C.8.1728 B.120 C.8 1.1764 B.156 C.8 1.1800 B.192 C.8.1729 B.121 C.8 1.1765 B.157 C.8 1.1801 B.193 C.8.1730 B.122 C.8 1.1766 B.158 C.8 1.1802 B.194 C.8.1731 B.123 C.8 1.1767 B.159 C.8 1.1803 B.195 C.8.1732 B.124 C.8 1.1768 B.160 C.8 1.1804 B.196 C.8.1733 B.125 C.8 1.1769 B.161 C.8 1.1805 B.197 C.8.1734 B.126 C.8 1.1770 B.162 C.8 1.1806 B.198 C.8.1735 B.127 C.8 1.1771 B.163 C.8 1.1807 B.199 C.8.1736 B.128 C.8 1.1772 B.164 C.8 1.1808 B.200 C.8.1737 B.129 C.8 1.1773 B.165 C.8 1.1809 B.201 C.8.1738 B.130 C.8 1.1774 B.166 C.8 1.1810 B.1 C.9.1739 B.131 C.8 1.1775 B.167 C.8 1.1811 B.2 C.9.1740 B.132 C.8 1.1776 B.168 C.8 1.1812 B.3 C.9.1741 B.133 C.8 1.1777 B.169 C.8 1.1813 B.4 C.9.1742 B.134 C.8 1.1778 B.170 C.8 1.1814 B.5 C.9.1743 B.135 C.8 1.1779 B.171 C.8 1.1815 B.6 C.9.1744 B.136 C.8 1.1780 B.172 C.8 1.1816 B.7 C.9.1745 B.137 C.8 1.1781 B.173 C.8 1.1817 B.8 C.9.1746 B.138 C.8 1.1782 B.174 C.8 1.1818 B.9 C.9.1747 B.139 C.8 1.1783 B.175 C.8 1.1819 B.10 C.9.1748 B.140 C.8 1.1784 B.176 C.8 1.1820 B.11 C.9.1749 B.141 C.8 1.1785 B.177 C.8 1.1821 B.12 C.9 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1822 B.13 C.9 1.1858 B.49 C.9 1.1894 B.85 C.9.1823 B.14 C.9 1.1859 B.50 C.9 1.1895 B.86 C.9.1824 B.15 C.9 1.1860 B.51 C.9 1.1896 B.87 C.9.1825 B.16 C.9 1.1861 B.52 C.9 1.1897 B.88 C.9.1826 B.17 C.9 1.1862 B.53 C.9 1.1898 B.89 C.9.1827 B.18 C.9 1.1863 B.54 C.9 1.1899 B.90 C.9.1828 B.19 C.9 1.1864 B.55 C.9 1.1900 B.91 C.9.1829 B.20 C.9 1.1865 B.56 C.9 1.1901 B.92 C.9.1830 B.21 C.9 1.1866 B.57 C.9 1.1902 B.93 C.9.1831 B.22 C.9 1.1867 B.58. C.9 1.1903 B.94 C.9.1832 B.23 C.9 1.1868 B.59 C.9 1.1904 B.95 C.9.1833 B.24 C.9 1.1869 B.60 C.9 1.1905 B.96 C.9.1834 B.25 C.9 1.1870 B.61 C.9 1.1906 B.97 C.9.1835 B.26 C.9 1.1871 B.62 C.9 1.1907 B.98 C.9.1836 B.27 C.9 1.1872 B.63 C.9 1.1908 B.99 C.9.1837 B.28 C.9 1.1873 B.64 C.9 1.1909 B.100 C.9.1838 B.29 C.9 1.1874 B.65 C.9 1.1910 B.101 C.9.1839 B.30 C.9 1.1875 B.66 C.9 1.1911 B.102 C.9.1840 B.31 C.9 1.1876 B.67 C.9 1.1912 B.103 C.9.1841 B.32 C.9 1.1877 B.68 C.9 1.1913 B.104 C.9.1842 B.33 C.9 1.1878 B.69 C.9 1.1914 B.105 C.9.1843 B.34 C.9 1.1879 B.70 C.9 1.1915 B.106 C.9.1844 B.35 C.9 1.1880 B.71 C.9 1.1916 B.107 C.9.1845 B.36 C.9 1.1881 B.72 C.9 1.1917 B.108 C.9.1846 B.37 C.9 1.1882 B.73 C.9 1.1918 B.109 C.9.1847 B.38 C.9 1.1883 B.74 C.9 1.1919 B.110 C.9.1848 B.39 C.9 1.1884 B.75 C.9 1.1920 B.111 C.9.1849 B.40 C.9 1.1885 B.76 C.9 1.1921 B.112 C.9.1850 B.41 C.9 1.1886 B.77 C.9 1.1922 B.113 C.9.1851 B.42 C.9 1.1887 B.78 C.9 1.1923 B.114 C.9.1852 B.43 C.9 1.1888 B.79 C.9 1.1924 B.115 C.9.1853 B.44 C.9 1.1889 B.80 C.9 1.1925 B.116 C.9.1854 B.45 C.9 1.1890 B.81 C.9 1.1926 B.117 C.9.1855 B.46 C.9 1.1891 B.82 C.9 1.1927 B.118 C.9.1856 B.47 C.9 1.1892 B.83 C.9 1.1928 B.119 C.9.1857 B.48 C.9 1.1893 B.84 C.9 1.1929 B.120 C.9 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.1930 B.121 C.9 1.1966 B.157 C.9 1.2002 B.193 C.9.1931 B.122 C.9 1.1967 B.158 C.9 1.2003 B.194 C.9.1932 B.123 C.9 1.1968 B.159 C.9 1.2004 B.195 C.9.1933 B.124 C.9 1.1969 B.160 C.9 1.2005 B.196 C.9.1934 B.125 C.9 1.1970 B.161 C.9 1.2006 B.197 C.9.1935 B.126 C.9 1.1971 B.162 C.9 1.2007 B.198 C.9.1936 B.127 C.9 1.1972 B.163 C.9 1.2008 B.199 C.9.1937 B.128 C.9 1.1973 B.164 C.9 1.2009 B.200 C.9.1938 B.129 C.9 1.1974 B.165 C.9 1.2010 B.201 C.9.1939 B.130 C.9 1.1975 B.166 C.9 1.2011 B.1 C.10.1940 B.131 C.9 1.1976 B.167 C.9 1.2012 B.2 C.10.1941 B.132 C.9 1.1977 B.168 C.9 1.2013 B.3 C.10.1942 B.133 C.9 1.1978 B.169 C.9 1.2014 B.4 C.10.1943 B.134 C.9 1.1979 B.170 C.9 1.2015 B.5 C.10.1944 B.135 C.9 1.1980 B.171 C.9 1.2016 B.6 C.10.1945 B.136 C.9 1.1981 B.172 C.9 1.2017 B.7 C.10.1946 B.137 C.9 1.1982 B.173 C.9 1.2018 B.8 C.10.1947 B.138 C.9 1.1983 B.174 C.9 1.2019 B.9 C.10.1948 B.139 C.9 1.1984 B.175 C.9 1.2020 B.10 C.10.1949 B.140 C.9 1.1985 B.176 C.9 1.2021 B.11 C.10.1950 B.141 C.9 1.1986 B.177 C.9 1.2022 B.12 C.10.1951 B.142 C.9 1.1987 B.178 C.9 1.2023 B.13 C.10.1952 B.143 C.9 1.1988 B.179 C.9 1.2024 B.14 C.10.1953 B.144 C.9 1.1989 B.180 C.9 1.2025 B.15 C.10.1954 B.145 C.9 1.1990 B.181 C.9 1.2026 B.16 C.10.1955 B.146 C.9 1.1991 B.182 C.9 1.2027 B.17 C.10.1956 B.147 C.9 1.1992 B.183 C.9 1.2028 B.18 C.10.1957 B.148 C.9 1.1993 B.184 C.9 1.2029 B.19 C.10.1958 B.149 C.9 1.1994 B.185 C.9 1.2030 B.20 C.10.1959 B.150 C.9 1.1995 B.186 C.9 1.2031 B.21 C.10.1960 B.151 C.9 1.1996 B.187 C.9 1.2032 B.22 C.10.1961 B.152 C.9 1.1997 B.188 C.9 1.2033 B.23 C.10.1962 B.153 C.9 1.1998 B.189 C.9 1.2034 B.24 C.10.1963 B.154 C.9 1.1999 B.190 C.9 1.2035 B.25 C.10.1964 B.155 C.9 1.2000 B.191 C.9 1.2036 B.26 C.10.1965 B.156 C.9 1.2001 B.192 C.9 1.2037 B.27 C.10 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.2038 B.28 C.10 1.2074 B.64 C.10 1.2110 B.100 C.10.2039 B.29 C.10 1.2075 B.65 C.10 1.2111 B.101 C.10 .2040 B.30 C.10 1.2076 B.66 C.10 1.2112 B.102 C.10.2041 B.31 C.10 1.2077 B.67 C.10 1.2113 B.103 C.10 .2042 B.32 C.10 1.2078 B.68 C.10 1.2114 B.104 C.10 .2043 B.33 C.10 1.2079 B.69 C.10 1.2115 B.105 C.10 .2044 B.34 C.10 1.2080 B.70 C.10 1.2116 B.106 C.10 .2045 B.35 C.10 1.2081 B.71 C.10 1.2117 B.107 C.10 .2046 B.36 C.10 1.2082 B.72 C.10 1.2118 B.108 C.10 .2047 B.37 C.10 1.2083 B.73 C.10 1.2119 B.109 C.10 .2048 B.38 C.10 1.2084 B.74 C.10 1.2120 B.110 C.10 .2049 B.39 C.10 1.2085 B.75 C.10 1.2121 B.111 C.10 .2050 B.40 C.10 1.2086 B.76 C.10 1.2122 B.112 C.10.2051 B.41 C.10 1.2087 B.77 C.10 1.2123 B.113 C.10 .2052 B.42 C.10 1.2088 B.78 C.10 1.2124 B.114 C.10 .2053 B.43 C.10 1.2089 B.79 C.10 1.2125 B.115 C.10 .2054 B.44 C.10 1.2090 B.80 C.10 1.2126 B.116 C.10 .2055 B.45 C.10 1.2091 B.81 C.10 1.2127 B.117 C.10 .2056 B.46 C.10 1.2092 B.82 C.10 1.2128 B.118 C.10 .2057 B.47 C.10 1.2093 B.83 C.10 1.2129 B.119 C.10 .2058 B.48 C.10 1.2094 B.84 C.10 1.2130 B.120 C.10 .2059 B.49 C.10 1.2095 B.85 C.10 1.2131 B.121 C.10 .2060 B.50 C.10 1.2096 B.86 C.10 1.2132 B.122 C.10.2061 B.51 C.10 1.2097 B.87 C.10 1.2133 B.123 C.10 .2062 B.52 C.10 1.2098 B.88 C.10 1.2134 B.124 C.10 .2063 B.53 C.10 1.2099 B.89 C.10 1.2135 B.125 C.10 .2064 B.54 C.10 1.2100 B.90 C.10 1.2136 B.126 C.10 .2065 B.55 C.10 1.2101 B.91 C.10 1.2137 B.127 C.10 .2066 B.56 C.10 1.2102 B.92 C.10 1.2138 B.128 C.10 .2067 B.57 C.10 1.2103 B.93 C.10 1.2139 B.129 C.10 .2068 B.58. C.10 1.2104 B.94 C.10 1.2140 B.130 C.10 .2069 B.59 C.10 1.2105 B.95 C.10 1.2141 B.131 C.10 .2070 B.60 C.10 1.2106 B.96 C.10 1.2142 B.132 C.10.2071 B.61 C.10 1.2107 B.97 C.10 1.2143 B.133 C.10 .2072 B.62 C.10 1.2108 B.98 C.10 1.2144 B.134 C.10 .2073 B.63 C.10 1.2109 B.99 C.10 1.2145 B.135 C.10 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.2146 B.136 C.10 1.2182 B.172 C.10 1.2218 B.7 C.11.2147 B.137 C.10 1.2183 B.173 C.10 1.2219 B.8 C.11.2148 B.138 C.10 1.2184 B.174 C.10 1.2220 B.9 C.11.2149 B.139 C.10 1.2185 B.175 C.10 1.2221 B.10 C.11.2150 B.140 C.10 1.2186 B.176 C.10 1.2222 B.11 C.11.2151 B.141 C.10 1.2187 B.177 C.10 1.2223 B.12 C.11.2152 B.142 C.10 1.2188 B.178 C.10 1.2224 B.13 C.11.2153 B.143 C.10 1.2189 B.179 C.10 1.2225 B.14 C.11.2154 B.144 C.10 1.2190 B.180 C.10 1.2226 B.15 C.11.2155 B.145 C.10 1.2191 B.181 C.10 1.2227 B.16 C.11.2156 B.146 C.10 1.2192 B.182 C.10 1.2228 B.17 C.11.2157 B.147 C.10 1.2193 B.183 C.10 1.2229 B.18 C.11.2158 B.148 C.10 1.2194 B.184 C.10 1.2230 B.19 C.11.2159 B.149 C.10 1.2195 B.185 C.10 1.2231 B.20 C.11.2160 B.150 C.10 1.2196 B.186 C.10 1.2232 B.21 C.11.2161 B.151 C.10 1.2197 B.187 C.10 1.2233 B.22 C.11.2162 B.152 C.10 1.2198 B.188 C.10 1.2234 B.23 C.11.2163 B.153 C.10 1.2199 B.189 C.10 1.2235 B.24 C.11.2164 B.154 C.10 1.2200 B.190 C.10 1.2236 B.25 C.11.2165 B.155 C.10 1.2201 B.191 C.10 1.2237 B.26 C.11.2166 B.156 C.10 1.2202 B.192 C.10 1.2238 B.27 C.11.2167 B.157 C.10 1.2203 B.193 C.10 1.2239 B.28 C.11.2168 B.158 C.10 1.2204 B.194 C.10 1.2240 B.29 C.11.2169 B.159 C.10 1.2205 B.195 C.10 1.2241 B.30 C.11.2170 B.160 C.10 1.2206 B.196 C.10 1.2242 B.31 C.11.2171 B.161 C.10 1.2207 B.197 C.10 1.2243 B.32 C.11.2172 B.162 C.10 1.2208 B.198 C.10 1.2244 B.33 C.11.2173 B.163 C.10 1.2209 B.199 C.10 1.2245 B.34 C.11.2174 B.164 C.10 1.2210 B.200 C.10 1.2246 B.35 C.11.2175 B.165 C.10 1.2211 B.201 C.10 1.2247 B.36 C.11.2176 B.166 C.10 1.2212 B.1 C.11 1.2248 B.37 C.11.2177 B.167 C.10 1.2213 B.2 C.11 1.2249 B.38 C.11.2178 B.168 C.10 1.2214 B.3 C.11 1.2250 B.39 C.11.2179 B.169 C.10 1.2215 B.4 C.11 1.2251 B.40 C.11.2180 B.170 C.10 1.2216 B.5 C.11 1.2252 B.41 C.11.2181 B.171 C.10 1.2217 B.6 C.11 1.2253 B.42 C.11 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2254 B.43 C.11 1.2290 B.79 C.11 1.2326 B.115 C.11 .2255 B.44 C.11 1.2291 B.80 C.11 1.2327 B.116 C.11 .2256 B.45 C.11 1.2292 B.81 C.11 1.2328 B.117 C.11 .2257 B.46 C.11 1.2293 B.82 C.11 1.2329 B.118 C.11 .2258 B.47 C.11 1.2294 B.83 C.11 1.2330 B.119 C.11 .2259 B.48 C.11 1.2295 B.84 C.11 1.2331 B.120 C.11 .2260 B.49 C.11 1.2296 B.85 C.11 1.2332 B.121 C.11.2261 B.50 C.11 1.2297 B.86 C.11 1.2333 B.122 C.11 .2262 B.51 C.11 1.2298 B.87 C.11 1.2334 B.123 C.11 .2263 B.52 C.11 1.2299 B.88 C.11 1.2335 B.124 C.11 .2264 B.53 C.11 1.2300 B.89 C.11 1.2336 B.125 C.11 .2265 B.54 C.11 1.2301 B.90 C.11 1.2337 B.126 C.11 .2266 B.55 C.11 1.2302 B.91 C.11 1.2338 B.127 C.11 .2267 B.56 C.11 1.2303 B.92 C.11 1.2339 B.128 C.11 .2268 B.57 C.11 1.2304 B.93 C.11 1.2340 B.129 C.11 .2269 B.58. C.11 1.2305 B.94 C.11 1.2341 B.130 C.11 .2270 B.59 C.11 1.2306 B.95 C.11 1.2342 B.131 C.11.2271 B.60 C.11 1.2307 B.96 C.11 1.2343 B.132 C.11 .2272 B.61 C.11 1.2308 B.97 C.11 1.2344 B.133 C.11 .2273 B.62 C.11 1.2309 B.98 C.11 1.2345 B.134 C.11 .2274 B.63 C.11 1.2310 B.99 C.11 1.2346 B.135 C.11 .2275 B.64 C.11 1.2311 B.100 C.11 1.2347 B.136 C.11 .2276 B.65 C.11 1.2312 B.101 C.11 1.2348 B.137 C.11 .2277 B.66 C.11 1.2313 B.102 C.11 1.2349 B.138 C.11 .2278 B.67 C.11 1.2314 B.103 C.11 1.2350 B.139 C.11 .2279 B.68 C.11 1.2315 B.104 C.11 1.2351 B.140 C.11 .2280 B.69 C.11 1.2316 B.105 C.11 1.2352 B.141 C.11.2281 B.70 C.11 1.2317 B.106 C.11 1.2353 B.142 C.11 .2282 B.71 C.11 1.2318 B.107 C.11 1.2354 B.143 C.11 .2283 B.72 C.11 1.2319 B.108 C.11 1.2355 B.144 C.11 .2284 B.73 C.11 1.2320 B.109 C.11 1.2356 B.145 C.11 .2285 B.74 C.11 1.2321 B.110 C.11 1.2357 B.146 C.11 .2286 B.75 C.11 1.2322 B.111 C.11 1.2358 B.147 C.11 .2287 B.76 C.11 1.2323 B.112 C.11 1.2359 B.148 C.11 .2288 B.77 C.11 1.2324 B.113 C.11 1.2360 B.149 C.11 .2289 B.78 C.11 1.2325 B.114 C.11 1.2361 B.150 C.11 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2362 B.151 C.11 1.2398 B.187 C.11 1.2434 B.22 C.12 .2363 B.152 C.11 1.2399 B.188 C.11 1.2435 B.23 C.12 .2364 B.153 C.11 1.2400 B.189 C.11 1.2436 B.24 C.12 .2365 B.154 C.11 1.2401 B.190 C.11 1.2437 B.25 C.12 .2366 B.155 C.11 1.2402 B.191 C.11 1.2438 B.26 C.12 .2367 B.156 C.11 1.2403 B.192 C.11 1.2439 B.27 C.12 .2368 B.157 C.11 1.2404 B.193 C.11 1.2440 B.28 C.12 .2369 B.158 C.11 1.2405 B.194 C.11 1.2441 B.29 C.12 .2370 B.159 C.11 1.2406 B.195 C.11 1.2442 B.30 C.12.2371 B.160 C.11 1.2407 B.196 C.11 1.2443 B.31 C.12 .2372 B.161 C.11 1.2408 B.197 C.11 1.2444 B.32 C.12 .2373 B.162 C.11 1.2409 B.198 C.11 1.2445 B.33 C.12 .2374 B.163 C.11 1.2410 B.199 C.11 1.2446 B.34 C.12 .2375 B.164 C.11 1.2411 B.200 C.11 1.2447 B.35 C.12 .2376 B.165 C.11 1.2412 B.201 C.11 1.2448 B.36 C.12 .2377 B.166 C.11 1.2413 B.1 C.12 1.2449 B.37 C.12 .2378 B.167 C.11 1.2414 B.2 C.12 1.2450 B.38 C.12 .2379 B.168 C.11 1.2415 B.3 C.12 1.2451 B.39 C.12 .2380 B.169 C.11 1.2416 B.4 C.12 1.2452 B.40 C.12.2381 B.170 C.11 1.2417 B.5 C.12 1.2453 B.41 C.12 .2382 B.171 C.11 1.2418 B.6 C.12 1.2454 B.42 C.12 .2383 B.172 C.11 1.2419 B.7 C.12 1.2455 B.43 C.12 .2384 B.173 C.11 1.2420 B.8 C.12 1.2456 B.44 C.12 .2385 B.174 C.11 1.2421 B.9 C.12 1.2457 B.45 C.12 .2386 B.175 C.11 1.2422 B.10 C.12 1.2458 B.46 C.12 .2387 B.176 C.11 1.2423 B.11 C.12 1.2459 B.47 C.12 .2388 B.177 C.11 1.2424 B.12 C.12 1.2460 B.48 C.12 .2389 B.178 C.11 1.2425 B.13 C.12 1.2461 B.49 C.12.2390 B.179 C.11 1.2426 B.14 C.12 1.2462 B.50 C.12.2391 B.180 C.11 1.2427 B.15 C.12 1.2463 B.51 C.12 .2392 B.181 C.11 1.2428 B.16 C.12 1.2464 B.52 C.12.2393 B.182 C.11 1.2429 B.17 C.12 1.2465 B.53 C.12 .2394 B.183 C.11 1.2430 B.18 C.12 1.2466 B.54 C.12.2395 B.184 C.11 1.2431 B.19 C.12 1.2467 B.55 C.12.2396 B.185 C.11 1.2432 B.20 C.12 1.2468 B.56 C.12.2397 B.186 C.11 1.2433 B.21 C.12 1.2469 B.57 C.12 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2470 B.58. C.12 1 .2506 B.94 C.12 1 .2542 B.130 C.12.2471 B.59 C.12 1 .2507 B.95 C.12 1 .2543 B.131 C.12 .2472 B.60 C.12 1 .2508 B.96 C.12 1 .2544 B.132 C.12 .2473 B.61 C.12 1 .2509 B.97 C.12 1 .2545 B.133 C.12 .2474 B.62 C.12 1 .2510 B.98 C.12 1 .2546 B.134 C.12 .2475 B.63 C.12 1 .251 1 B.99 C.12 1 .2547 B.135 C.12 .2476 B.64 C.12 1 .2512 B.100 C.12 1 .2548 B.136 C.12 .2477 B.65 C.12 1 .2513 B.101 C.12 1 .2549 B.137 C.12 .2478 B.66 C.12 1 .2514 B.102 C.12 1 .2550 B.138 C.12 .2479 B.67 C.12 1 .2515 B.103 C.12 1 .2551 B.139 C.12 .2480 B.68 C.12 1 .2516 B.104 C.12 1 .2552 B.140 C.12.2481 B.69 C.12 1 .2517 B.105 C.12 1 .2553 B.141 C.12 .2482 B.70 C.12 1 .2518 B.106 C.12 1 .2554 B.142 C.12 .2483 B.71 C.12 1 .2519 B.107 C.12 1 .2555 B.143 C.12 .2484 B.72 C.12 1 .2520 B.108 C.12 1 .2556 B.144 C.12 .2485 B.73 C.12 1 .2521 B.109 C.12 1 .2557 B.145 C.12 .2486 B.74 C.12 1 .2522 B.1 10 C.12 1 .2558 B.146 C.12 .2487 B.75 C.12 1 .2523 B.1 1 1 C.12 1 .2559 B.147 C.12 .2488 B.76 C.12 1 .2524 B.1 12 C.12 1 .2560 B.148 C.12 .2489 B.77 C.12 1 .2525 B.1 13 C.12 1 .2561 B.149 C.12 .2490 B.78 C.12 1 .2526 B.1 14 C.12 1 .2562 B.150 C.12.2491 B.79 C.12 1 .2527 B.1 15 C.12 1 .2563 B.151 C.12 .2492 B.80 C.12 1 .2528 B.1 16 C.12 1 .2564 B.152 C.12 .2493 B.81 C.12 1 .2529 B.1 17 C.12 1 .2565 B.153 C.12 .2494 B.82 C.12 1 .2530 B.1 18 C.12 1 .2566 B.154 C.12 .2495 B.83 C.12 1 .2531 B.1 19 C.12 1 .2567 B.155 C.12 .2496 B.84 C.12 1 .2532 B.120 C.12 1 .2568 B.156 C.12 .2497 B.85 C.12 1 .2533 B.121 C.12 1 .2569 B.157 C.12 .2498 B.86 C.12 1 .2534 B.122 C.12 1 .2570 B.158 C.12 .2499 B.87 C.12 1 .2535 B.123 C.12 1 .2571 B.159 C.12 .2500 B.88 C.12 1 .2536 B.124 C.12 1 .2572 B.160 C.12.2501 B.89 C.12 1 .2537 B.125 C.12 1 .2573 B.161 C.12 .2502 B.90 C.12 1 .2538 B.126 C.12 1 .2574 B.162 C.12 .2503 B.91 C.12 1 .2539 B.127 C.12 1 .2575 B.163 C.12 .2504 B.92 C.12 1 .2540 B.128 C.12 1 .2576 B.164 C.12 .2505 B.93 C.12 1 .2541 B.129 C.12 1 .2577 B.165 C.12 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2578 B.166 C.12 1 .2614 B.1 C.13 1 .2650 B.37 C.13 .2579 B.167 C.12 1 .2615 B.2 C.13 1 .2651 B.38 C.13 .2580 B.168 C.12 1 .2616 B.3 C.13 1 .2652 B.39 C.13.2581 B.169 C.12 1 .2617 B.4 C.13 1 .2653 B.40 C.13 .2582 B.170 C.12 1 .2618 B.5 C.13 1 .2654 B.41 C.13 .2583 B.171 C.12 1 .2619 B.6 C.13 1 .2655 B.42 C.13 .2584 B.172 C.12 1 .2620 B.7 C.13 1 .2656 B.43 C.13 .2585 B.173 C.12 1 .2621 B.8 C.13 1 .2657 B.44 C.13 .2586 B.174 C.12 1 .2622 B.9 C.13 1 .2658 B.45 C.13 .2587 B.175 C.12 1 .2623 B.10 C.13 1 .2659 B.46 C.13 .2588 B.176 C.12 1 .2624 B.1 1 C.13 1 .2660 B.47 C.13 .2589 B.177 C.12 1 .2625 B.12 C.13 1 .2661 B.48 C.13 .2590 B.178 C.12 1 .2626 B.13 C.13 1 .2662 B.49 C.13.2591 B.179 C.12 1 .2627 B.14 C.13 1 .2663 B.50 C.13 .2592 B.180 C.12 1 .2628 B.15 C.13 1 .2664 B.51 C.13 .2593 B.181 C.12 1 .2629 B.16 C.13 1 .2665 B.52 C.13 .2594 B.182 C.12 1 .2630 B.17 C.13 1 .2666 B.53 C.13 .2595 B.183 C.12 1 .2631 B.18 C.13 1 .2667 B.54 C.13 .2596 B.184 C.12 1 .2632 B.19 C.13 1 .2668 B.55 C.13 .2597 B.185 C.12 1 .2633 B.20 C.13 1 .2669 B.56 C.13 .2598 B.186 C.12 1 .2634 B.21 C.13 1 .2670 B.57 C.13 .2599 B.187 C.12 1 .2635 B.22 C.13 1 .2671 B.58. C.13 .2600 B.188 C.12 1 .2636 B.23 C.13 1 .2672 B.59 C.13.2601 B.189 C.12 1 .2637 B.24 C.13 1 .2673 B.60 C.13 .2602 B.190 C.12 1 .2638 B.25 C.13 1 .2674 B.61 C.13 .2603 B.191 C.12 1 .2639 B.26 C.13 1 .2675 B.62 C.13 .2604 B.192 C.12 1 .2640 B.27 C.13 1 .2676 B.63 C.13 .2605 B.193 C.12 1 .2641 B.28 C.13 1 .2677 B.64 C.13 .2606 B.194 C.12 1 .2642 B.29 C.13 1 .2678 B.65 C.13 .2607 B.195 C.12 1 .2643 B.30 C.13 1 .2679 B.66 C.13 .2608 B.196 C.12 1 .2644 B.31 C.13 1 .2680 B.67 C.13 .2609 B.197 C.12 1 .2645 B.32 C.13 1 .2681 B.68 C.13.2610 B.198 C.12 1 .2646 B.33 C.13 1 .2682 B.69 C.13.261 1 B.199 C.12 1 .2647 B.34 C.13 1 .2683 B.70 C.13.2612 B.200 C.12 1 .2648 B.35 C.13 1 .2684 B.71 C.13.2613 B.201 C.12 1 .2649 B.36 C.13 1 .2685 B.72 C.13 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2686 B.73 C.13 1 .2722 B.109 C.13 1 .2758 B.145 C.13 .2687 B.74 C.13 1 .2723 B.1 10 C.13 1 .2759 B.146 C.13 .2688 B.75 C.13 1 .2724 B.1 1 1 C.13 1 .2760 B.147 C.13 .2689 B.76 C.13 1 .2725 B.1 12 C.13 1 .2761 B.148 C.13 .2690 B.77 C.13 1 .2726 B.1 13 C.13 1 .2762 B.149 C.13.2691 B.78 C.13 1 .2727 B.1 14 C.13 1 .2763 B.150 C.13 .2692 B.79 C.13 1 .2728 B.1 15 C.13 1 .2764 B.151 C.13 .2693 B.80 C.13 1 .2729 B.1 16 C.13 1 .2765 B.152 C.13 .2694 B.81 C.13 1 .2730 B.1 17 C.13 1 .2766 B.153 C.13 .2695 B.82 C.13 1 .2731 B.1 18 C.13 1 .2767 B.154 C.13 .2696 B.83 C.13 1 .2732 B.1 19 C.13 1 .2768 B.155 C.13 .2697 B.84 C.13 1 .2733 B.120 C.13 1 .2769 B.156 C.13 .2698 B.85 C.13 1 .2734 B.121 C.13 1 .2770 B.157 C.13 .2699 B.86 C.13 1 .2735 B.122 C.13 1 .2771 B.158 C.13 .2700 B.87 C.13 1 .2736 B.123 C.13 1 .2772 B.159 C.13.2701 B.88 C.13 1 .2737 B.124 C.13 1 .2773 B.160 C.13 .2702 B.89 C.13 1 .2738 B.125 C.13 1 .2774 B.161 C.13 .2703 B.90 C.13 1 .2739 B.126 C.13 1 .2775 B.162 C.13 .2704 B.91 C.13 1 .2740 B.127 C.13 1 .2776 B.163 C.13 .2705 B.92 C.13 1 .2741 B.128 C.13 1 .2777 B.164 C.13 .2706 B.93 C.13 1 .2742 B.129 C.13 1 .2778 B.165 C.13 .2707 B.94 C.13 1 .2743 B.130 C.13 1 .2779 B.166 C.13 .2708 B.95 C.13 1 .2744 B.131 C.13 1 .2780 B.167 C.13 .2709 B.96 C.13 1 .2745 B.132 C.13 1 .2781 B.168 C.13.2710 B.97 C.13 1 .2746 B.133 C.13 1 .2782 B.169 C.13.271 1 B.98 C.13 1 .2747 B.134 C.13 1 .2783 B.170 C.13.2712 B.99 C.13 1 .2748 B.135 C.13 1 .2784 B.171 C.13.2713 B.100 C.13 1 .2749 B.136 C.13 1 .2785 B.172 C.13.2714 B.101 C.13 1 .2750 B.137 C.13 1 .2786 B.173 C.13.2715 B.102 C.13 1 .2751 B.138 C.13 1 .2787 B.174 C.13.2716 B.103 C.13 1 .2752 B.139 C.13 1 .2788 B.175 C.13.2717 B.104 C.13 1 .2753 B.140 C.13 1 .2789 B.176 C.13.2718 B.105 C.13 1 .2754 B.141 C.13 1 .2790 B.177 C.13.2719 B.106 C.13 1 .2755 B.142 C.13 1 .2791 B.178 C.13 .2720 B.107 C.13 1 .2756 B.143 C.13 1 .2792 B.179 C.13.2721 B.108 C.13 1 .2757 B.144 C.13 1 .2793 B.180 C.13 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2794 B.181 C.13 1 .2830 B.16 C.14 1 .2866 B.52 C.14 .2795 B.182 C.13 1 .2831 B.17 C.14 1 .2867 B.53 C.14 .2796 B.183 C.13 1 .2832 B.18 C.14 1 .2868 B.54 C.14 .2797 B.184 C.13 1 .2833 B.19 C.14 1 .2869 B.55 C.14 .2798 B.185 C.13 1 .2834 B.20 C.14 1 .2870 B.56 C.14 .2799 B.186 C.13 1 .2835 B.21 C.14 1 .2871 B.57 C.14 .2800 B.187 C.13 1 .2836 B.22 C.14 1 .2872 B.58. C.14.2801 B.188 C.13 1 .2837 B.23 C.14 1 .2873 B.59 C.14 .2802 B.189 C.13 1 .2838 B.24 C.14 1 .2874 B.60 C.14 .2803 B.190 C.13 1 .2839 B.25 C.14 1 .2875 B.61 C.14 .2804 B.191 C.13 1 .2840 B.26 C.14 1 .2876 B.62 C.14 .2805 B.192 C.13 1 .2841 B.27 C.14 1 .2877 B.63 C.14 .2806 B.193 C.13 1 .2842 B.28 C.14 1 .2878 B.64 C.14 .2807 B.194 C.13 1 .2843 B.29 C.14 1 .2879 B.65 C.14 .2808 B.195 C.13 1 .2844 B.30 C.14 1 .2880 B.66 C.14 .2809 B.196 C.13 1 .2845 B.31 C.14 1 .2881 B.67 C.14.2810 B.197 C.13 1 .2846 B.32 C.14 1 .2882 B.68 C.14.281 1 B.198 C.13 1 .2847 B.33 C.14 1 .2883 B.69 C.14.2812 B.199 C.13 1 .2848 B.34 C.14 1 .2884 B.70 C.14.2813 B.200 C.13 1 .2849 B.35 C.14 1 .2885 B.71 C.14.2814 B.201 C.13 1 .2850 B.36 C.14 1 .2886 B.72 C.14.2815 B.1 C.14 1 .2851 B.37 C.14 1 .2887 B.73 C.14.2816 B.2 C.14 1 .2852 B.38 C.14 1 .2888 B.74 C.14.2817 B.3 C.14 1 .2853 B.39 C.14 1 .2889 B.75 C.14.2818 B.4 C.14 1 .2854 B.40 C.14 1 .2890 B.76 C.14.2819 B.5 C.14 1 .2855 B.41 C.14 1 .2891 B.77 C.14 .2820 B.6 C.14 1 .2856 B.42 C.14 1 .2892 B.78 C.14.2821 B.7 C.14 1 .2857 B.43 C.14 1 .2893 B.79 C.14 .2822 B.8 C.14 1 .2858 B.44 C.14 1 .2894 B.80 C.14 .2823 B.9 C.14 1 .2859 B.45 C.14 1 .2895 B.81 C.14 .2824 B.10 C.14 1 .2860 B.46 C.14 1 .2896 B.82 C.14 .2825 B.1 1 C.14 1 .2861 B.47 C.14 1 .2897 B.83 C.14 .2826 B.12 C.14 1 .2862 B.48 C.14 1 .2898 B.84 C.14 .2827 B.13 C.14 1 .2863 B.49 C.14 1 .2899 B.85 C.14 .2828 B.14 C.14 1 .2864 B.50 C.14 1 .2900 B.86 C.14 .2829 B.15 C.14 1 .2865 B.51 C.14 1 .2901 B.87 C.14 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .2902 B.88 C.14 1 .2938 B.124 C.14 1 .2974 B.160 C.14.2903 B.89 C.14 1 .2939 B.125 C.14 1 .2975 B.161 C.14 .2904 B.90 C.14 1 .2940 B.126 C.14 1 .2976 B.162 C.14.2905 B.91 C.14 1 .2941 B.127 C.14 1 .2977 B.163 C.14.2906 B.92 C.14 1 .2942 B.128 C.14 1 .2978 B.164 C.14.2907 B.93 C.14 1 .2943 B.129 C.14 1 .2979 B.165 C.14.2908 B.94 C.14 1 .2944 B.130 C.14 1 .2980 B.166 C.14.2909 B.95 C.14 1 .2945 B.131 C.14 1 .2981 B.167 C.14.2910 B.96 C.14 1 .2946 B.132 C.14 1 .2982 B.168 C.14.291 1 B.97 C.14 1 .2947 B.133 C.14 1 .2983 B.169 C.14.2912 B.98 C.14 1 .2948 B.134 C.14 1 .2984 B.170 C.14.2913 B.99 C.14 1 .2949 B.135 C.14 1 .2985 B.171 C.14.2914 B.100 C.14 1 .2950 B.136 C.14 1 .2986 B.172 C.14.2915 B.101 C.14 1 .2951 B.137 C.14 1 .2987 B.173 C.14.2916 B.102 C.14 1 .2952 B.138 C.14 1 .2988 B.174 C.14.2917 B.103 C.14 1 .2953 B.139 C.14 1 .2989 B.175 C.14.2918 B.104 C.14 1 .2954 B.140 C.14 1 .2990 B.176 C.14.2919 B.105 C.14 1 .2955 B.141 C.14 1 .2991 B.177 C.14 .2920 B.106 C.14 1 .2956 B.142 C.14 1 .2992 B.178 C.14.2921 B.107 C.14 1 .2957 B.143 C.14 1 .2993 B.179 C.14 .2922 B.108 C.14 1 .2958 B.144 C.14 1 .2994 B.180 C.14 .2923 B.109 C.14 1 .2959 B.145 C.14 1 .2995 B.181 C.14 .2924 B.1 10 C.14 1 .2960 B.146 C.14 1 .2996 B.182 C.14 .2925 B.1 1 1 C.14 1 .2961 B.147 C.14 1 .2997 B.183 C.14 .2926 B.1 12 C.14 1 .2962 B.148 C.14 1 .2998 B.184 C.14 .2927 B.1 13 C.14 1 .2963 B.149 C.14 1 .2999 B.185 C.14 .2928 B.1 14 C.14 1 .2964 B.150 C.14 1 .3000 B.186 C.14 .2929 B.1 15 C.14 1 .2965 B.151 C.14 1 .3001 B.187 C.14.2930 B.1 16 C.14 1 .2966 B.152 C.14 1 .3002 B.188 C.14.2931 B.1 17 C.14 1 .2967 B.153 C.14 1 .3003 B.189 C.14 .2932 B.1 18 C.14 1 .2968 B.154 C.14 1 .3004 B.190 C.14.2933 B.1 19 C.14 1 .2969 B.155 C.14 1 .3005 B.191 C.14 .2934 B.120 C.14 1 .2970 B.156 C.14 1 .3006 B.192 C.14.2935 B.121 C.14 1 .2971 B.157 C.14 1 .3007 B.193 C.14.2936 B.122 C.14 1 .2972 B.158 C.14 1 .3008 B.194 C.14.2937 B.123 C.14 1 .2973 B.159 C.14 1 .3009 B.195 C.14 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.3010 B.196 C.14 1.3046 B.31 C.15 1.3082 B.67 C.15.3011 B.197 C.14 1.3047 B.32 C.15 1.3083 B.68 C.15.3012 B.198 C.14 1.3048 B.33 C.15 1.3084 B.69 C.15.3013 B.199 C.14 1.3049 B.34 C.15 1.3085 B.70 C.15.3014 B.200 C.14 1.3050 B.35 C.15 1.3086 B.71 C.15.3015 B.201 C.14 1.3051 B.36 C.15 1.3087 B.72 C.15.3016 B.1 C.15 1.3052 B.37 C.15 1.3088 B.73 C.15.3017 B.2 C.15 1.3053 B.38 C.15 1.3089 B.74 C.15.3018 B.3 C.15 1.3054 B.39 C.15 1.3090 B.75 C.15.3019 B.4 C.15 1.3055 B.40 C.15 1.3091 B.76 C.15.3020 B.5 C.15 1.3056 B.41 C.15 1.3092 B.77 C.15.3021 B.6 C.15 1.3057 B.42 C.15 1.3093 B.78 C.15 .3022 B.7 C.15 1.3058 B.43 C.15 1.3094 B.79 C.15.3023 B.8 C.15 1.3059 B.44 C.15 1.3095 B.80 C.15 .3024 B.9 C.15 1.3060 B.45 C.15 1.3096 B.81 C.15.3025 B.10 C.15 1.3061 B.46 C.15 1.3097 B.82 C.15.3026 B.11 C.15 1.3062 B.47 C.15 1.3098 B.83 C.15.3027 B.12 C.15 1.3063 B.48 C.15 1.3099 B.84 C.15.3028 B.13 C.15 1.3064 B.49 C.15 1.3100 B.85 C.15.3029 B.14 C.15 1.3065 B.50 C.15 1.3101 B.86 C.15.3030 B.15 C.15 1.3066 B.51 C.15 1.3102 B.87 C.15.3031 B.16 C.15 1.3067 B.52 C.15 1.3103 B.88 C.15.3032 B.17 C.15 1.3068 B.53 C.15 1.3104 B.89 C.15.3033 B.18 C.15 1.3069 B.54 C.15 1.3105 B.90 C.15.3034 B.19 C.15 1.3070 B.55 C.15 1.3106 B.91 C.15.3035 B.20 C.15 1.3071 B.56 C.15 1.3107 B.92 C.15.3036 B.21 C.15 1.3072 B.57 C.15 1.3108 B.93 C.15.3037 B.22 C.15 1.3073 B.58. C.15 1.3109 B.94 C.15.3038 B.23 C.15 1.3074 B.59 C.15 1.3110 B.95 C.15.3039 B.24 C.15 1.3075 B.60 C.15 1.3111 B.96 C.15.3040 B.25 C.15 1.3076 B.61 C.15 1.3112 B.97 C.15.3041 B.26 C.15 1.3077 B.62 C.15 1.3113 B.98 C.15 .3042 B.27 C.15 1.3078 B.63 C.15 1.3114 B.99 C.15.3043 B.28 C.15 1.3079 B.64 C.15 1.3115 B.100 C.15 .3044 B.29 C.15 1.3080 B.65 C.15 1.3116 B.101 C.15.3045 B.30 C.15 1.3081 B.66 C.15 1.3117 B.102 C.15 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.3118 B.103 C.15 1.3154 B.139 C.15 1.3190 B.175 C.15.3119 B.104 C.15 1.3155 B.140 C.15 1.3191 B.176 C.15.3120 B.105 C.15 1.3156 B.141 C.15 1.3192 B.177 C.15.3121 B.106 C.15 1.3157 B.142 C.15 1.3193 B.178 C.15.3122 B.107 C.15 1.3158 B.143 C.15 1.3194 B.179 C.15.3123 B.108 C.15 1.3159 B.144 C.15 1.3195 B.180 C.15.3124 B.109 C.15 1.3160 B.145 C.15 1.3196 B.181 C.15.3125 B.110 C.15 1.3161 B.146 C.15 1.3197 B.182 C.15.3126 B.111 C.15 1.3162 B.147 C.15 1.3198 B.183 C.15.3127 B.112 C.15 1.3163 B.148 C.15 1.3199 B.184 C.15.3128 B.113 C.15 1.3164 B.149 C.15 1.3200 B.185 C.15.3129 B.114 C.15 1.3165 B.150 C.15 1.3201 B.186 C.15.3130 B.115 C.15 1.3166 B.151 C.15 1.3202 B.187 C.15.3131 B.116 C.15 1.3167 B.152 C.15 1.3203 B.188 C.15.3132 B.117 C.15 1.3168 B.153 C.15 1.3204 B.189 C.15.3133 B.118 C.15 1.3169 B.154 C.15 1.3205 B.190 C.15.3134 B.119 C.15 1.3170 B.155 C.15 1.3206 B.191 C.15.3135 B.120 C.15 1.3171 B.156 C.15 1.3207 B.192 C.15.3136 B.121 C.15 1.3172 B.157 C.15 1.3208 B.193 C.15.3137 B.122 C.15 1.3173 B.158 C.15 1.3209 B.194 C.15.3138 B.123 C.15 1.3174 B.159 C.15 1.3210 B.195 C.15.3139 B.124 C.15 1.3175 B.160 C.15 1.3211 B.196 C.15.3140 B.125 C.15 1.3176 B.161 C.15 1.3212 B.197 C.15.3141 B.126 C.15 1.3177 B.162 C.15 1.3213 B.198 C.15.3142 B.127 C.15 1.3178 B.163 C.15 1.3214 B.199 C.15.3143 B.128 C.15 1.3179 B.164 C.15 1.3215 B.200 C.15.3144 B.129 C.15 1.3180 B.165 C.15 1.3216 B.201 C.15.3145 B.130 C.15 1.3181 B.166 C.15 1.3217 B.1 C.16.3146 B.131 C.15 1.3182 B.167 C.15 1.3218 B.2 C.16.3147 B.132 C.15 1.3183 B.168 C.15 1.3219 B.3 C.16.3148 B.133 C.15 1.3184 B.169 C.15 1.3220 B.4 C.16.3149 B.134 C.15 1.3185 B.170 C.15 1.3221 B.5 C.16.3150 B.135 C.15 1.3186 B.171 C.15 1.3222 B.6 C.16.3151 B.136 C.15 1.3187 B.172 C.15 1.3223 B.7 C.16.3152 B.137 C.15 1.3188 B.173 C.15 1.3224 B.8 C.16.3153 B.138 C.15 1.3189 B.174 C.15 1.3225 B.9 C.16 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .3226 B.10 C.16 1.3262 B.46 C.16 1.3298 B.82 C.16 .3227 B.11 C.16 1.3263 B.47 C.16 1.3299 B.83 C.16 .3228 B.12 C.16 1.3264 B.48 C.16 1.3300 B.84 C.16 .3229 B.13 C.16 1.3265 B.49 C.16 1.3301 B.85 C.16.3230 B.14 C.16 1.3266 B.50 C.16 1.3302 B.86 C.16.3231 B.15 C.16 1.3267 B.51 C.16 1.3303 B.87 C.16 .3232 B.16 C.16 1.3268 B.52 C.16 1.3304 B.88 C.16.3233 B.17 C.16 1.3269 B.53 C.16 1.3305 B.89 C.16 .3234 B.18 C.16 1.3270 B.54 C.16 1.3306 B.90 C.16.3235 B.19 C.16 1.3271 B.55 C.16 1.3307 B.91 C.16.3236 B.20 C.16 1.3272 B.56 C.16 1.3308 B.92 C.16.3237 B.21 C.16 1.3273 B.57 C.16 1.3309 B.93 C.16.3238 B.22 C.16 1.3274 B.58. C.16 1.3310 B.94 C.16.3239 B.23 C.16 1.3275 B.59 C.16 1.3311 B.95 C.16 .3240 B.24 C.16 1.3276 B.60 C.16 1.3312 B.96 C.16.3241 B.25 C.16 1.3277 B.61 C.16 1.3313 B.97 C.16 .3242 B.26 C.16 1.3278 B.62 C.16 1.3314 B.98 C.16 .3243 B.27 C.16 1.3279 B.63 C.16 1.3315 B.99 C.16 .3244 B.28 C.16 1.3280 B.64 C.16 1.3316 B.100 C.16 .3245 B.29 C.16 1.3281 B.65 C.16 1.3317 B.101 C.16 .3246 B.30 C.16 1.3282 B.66 C.16 1.3318 B.102 C.16 .3247 B.31 C.16 1.3283 B.67 C.16 1.3319 B.103 C.16 .3248 B.32 C.16 1.3284 B.68 C.16 1.3320 B.104 C.16 .3249 B.33 C.16 1.3285 B.69 C.16 1.3321 B.105 C.16 .3250 B.34 C.16 1.3286 B.70 C.16 1.3322 B.106 C.16.3251 B.35 C.16 1.3287 B.71 C.16 1.3323 B.107 C.16 .3252 B.36 C.16 1.3288 B.72 C.16 1.3324 B.108 C.16 .3253 B.37 C.16 1.3289 B.73 C.16 1.3325 B.109 C.16 .3254 B.38 C.16 1.3290 B.74 C.16 1.3326 B.110 C.16 .3255 B.39 C.16 1.3291 B.75 C.16 1.3327 B.111 C.16 .3256 B.40 C.16 1.3292 B.76 C.16 1.3328 B.112 C.16 .3257 B.41 C.16 1.3293 B.77 C.16 1.3329 B.113 C.16 .3258 B.42 C.16 1.3294 B.78 C.16 1.3330 B.114 C.16 .3259 B.43 C.16 1.3295 B.79 C.16 1.3331 B.115 C.16 .3260 B.44 C.16 1.3296 B.80 C.16 1.3332 B.116 C.16.3261 B.45 C.16 1.3297 B.81 C.16 1.3333 B.117 C.16 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C.3334 B.118 C.16 1.3370 B.154 C.16 1.3406 B.190 C.16.3335 B.119 C.16 1.3371 B.155 C.16 1.3407 B.191 C.16.3336 B.120 C.16 1.3372 B.156 C.16 1.3408 B.192 C.16.3337 B.121 C.16 1.3373 B.157 C.16 1.3409 B.193 C.16.3338 B.122 C.16 1.3374 B.158 C.16 1.3410 B.194 C.16.3339 B.123 C.16 1.3375 B.159 C.16 1.3411 B.195 C.16.3340 B.124 C.16 1.3376 B.160 C.16 1.3412 B.196 C.16.3341 B.125 C.16 1.3377 B.161 C.16 1.3413 B.197 C.16 .3342 B.126 C.16 1.3378 B.162 C.16 1.3414 B.198 C.16.3343 B.127 C.16 1.3379 B.163 C.16 1.3415 B.199 C.16 .3344 B.128 C.16 1.3380 B.164 C.16 1.3416 B.200 C.16.3345 B.129 C.16 1.3381 B.165 C.16 1.3417 B.201 C.16.3346 B.130 C.16 1.3382 B.166 C.16 1.3418 B.1 C.17.3347 B.131 C.16 1.3383 B.167 C.16 1.3419 B.2 C.17.3348 B.132 C.16 1.3384 B.168 C.16 1.3420 B.3 C.17.3349 B.133 C.16 1.3385 B.169 C.16 1.3421 B.4 C.17.3350 B.134 C.16 1.3386 B.170 C.16 1.3422 B.5 C.17.3351 B.135 C.16 1.3387 B.171 C.16 1.3423 B.6 C.17 .3352 B.136 C.16 1.3388 B.172 C.16 1.3424 B.7 C.17.3353 B.137 C.16 1.3389 B.173 C.16 1.3425 B.8 C.17 .3354 B.138 C.16 1.3390 B.174 C.16 1.3426 B.9 C.17.3355 B.139 C.16 1.3391 B.175 C.16 1.3427 B.10 C.17.3356 B.140 C.16 1.3392 B.176 C.16 1.3428 B.11 C.17.3357 B.141 C.16 1.3393 B.177 C.16 1.3429 B.12 C.17.3358 B.142 C.16 1.3394 B.178 C.16 1.3430 B.13 C.17.3359 B.143 C.16 1.3395 B.179 C.16 1.3431 B.14 C.17.3360 B.144 C.16 1.3396 B.180 C.16 1.3432 B.15 C.17.3361 B.145 C.16 1.3397 B.181 C.16 1.3433 B.16 C.17 .3362 B.146 C.16 1.3398 B.182 C.16 1.3434 B.17 C.17.3363 B.147 C.16 1.3399 B.183 C.16 1.3435 B.18 C.17 .3364 B.148 C.16 1.3400 B.184 C.16 1.3436 B.19 C.17.3365 B.149 C.16 1.3401 B.185 C.16 1.3437 B.20 C.17.3366 B.150 C.16 1.3402 B.186 C.16 1.3438 B.21 C.17.3367 B.151 C.16 1.3403 B.187 C.16 1.3439 B.22 C.17.3368 B.152 C.16 1.3404 B.188 C.16 1.3440 B.23 C.17.3369 B.153 C.16 1.3405 B.189 C.16 1.3441 B.24 C.17 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .3442 B.25 C.17 1.3478 B.61 C.17 1.3514 B.97 C.17 .3443 B.26 C.17 1.3479 B.62 C.17 1.3515 B.98 C.17 .3444 B.27 C.17 1.3480 B.63 C.17 1.3516 B.99 C.17 .3445 B.28 C.17 1.3481 B.64 C.17 1.3517 B.100 C.17 .3446 B.29 C.17 1.3482 B.65 C.17 1.3518 B.101 C.17 .3447 B.30 C.17 1.3483 B.66 C.17 1.3519 B.102 C.17 .3448 B.31 C.17 1.3484 B.67 C.17 1.3520 B.103 C.17 .3449 B.32 C.17 1.3485 B.68 C.17 1.3521 B.104 C.17 .3450 B.33 C.17 1.3486 B.69 C.17 1.3522 B.105 C.17.3451 B.34 C.17 1.3487 B.70 C.17 1.3523 B.106 C.17 .3452 B.35 C.17 1.3488 B.71 C.17 1.3524 B.107 C.17 .3453 B.36 C.17 1.3489 B.72 C.17 1.3525 B.108 C.17 .3454 B.37 C.17 1.3490 B.73 C.17 1.3526 B.109 C.17 .3455 B.38 C.17 1.3491 B.74 C.17 1.3527 B.110 C.17 .3456 B.39 C.17 1.3492 B.75 C.17 1.3528 B.111 C.17 .3457 B.40 C.17 1.3493 B.76 C.17 1.3529 B.112 C.17 .3458 B.41 C.17 1.3494 B.77 C.17 1.3530 B.113 C.17 .3459 B.42 C.17 1.3495 B.78 C.17 1.3531 B.114 C.17 .3460 B.43 C.17 1.3496 B.79 C.17 1.3532 B.115 C.17.3461 B.44 C.17 1.3497 B.80 C.17 1.3533 B.116 C.17 .3462 B.45 C.17 1.3498 B.81 C.17 1.3534 B.117 C.17 .3463 B.46 C.17 1.3499 B.82 C.17 1.3535 B.118 C.17 .3464 B.47 C.17 1.3500 B.83 C.17 1.3536 B.119 C.17 .3465 B.48 C.17 1.3501 B.84 C.17 1.3537 B.120 C.17 .3466 B.49 C.17 1.3502 B.85 C.17 1.3538 B.121 C.17 .3467 B.50 C.17 1.3503 B.86 C.17 1.3539 B.122 C.17 .3468 B.51 C.17 1.3504 B.87 C.17 1.3540 B.123 C.17 .3469 B.52 C.17 1.3505 B.88 C.17 1.3541 B.124 C.17 .3470 B.53 C.17 1.3506 B.89 C.17 1.3542 B.125 C.17.3471 B.54 C.17 1.3507 B.90 C.17 1.3543 B.126 C.17 .3472 B.55 C.17 1.3508 B.91 C.17 1.3544 B.127 C.17 .3473 B.56 C.17 1.3509 B.92 C.17 1.3545 B.128 C.17 .3474 B.57 C.17 1.3510 B.93 C.17 1.3546 B.129 C.17 .3475 B.58. C.17 1.3511 B.94 C.17 1.3547 B.130 C.17 .3476 B.59 C.17 1.3512 B.95 C.17 1.3548 B.131 C.17 .3477 B.60 C.17 1.3513 B.96 C.17 1.3549 B.132 C.17 comp. herbisafe- comp. herbisafe- comp. herbisafe- no. cide B ner C no. cide B ner C no. cide B ner C .3550 B.133 C.17 1.3585 B.168 C.17 1.3620 — C.2.3551 B.134 C.17 1.3586 B.169 C.17 1.3621 — C.3 .3552 B.135 C.17 1.3587 B.170 C.17 1.3622 — C.4 .3553 B.136 C.17 1.3588 B.171 C.17 1.3623 — C.5 .3554 B.137 C.17 1.3589 B.172 C.17 1.3624 — C.6 .3555 B.138 C.17 1.3590 B.173 C.17 1.3625 — C.7 .3556 B.139 C.17 1.3591 B.174 C.17 1.3626 — C.8 .3557 B.140 C.17 1.3592 B.175 C.17 1.3627 — C.9 .3558 B.141 C.17 1.3593 B.176 C.17 1.3628 — C.10 .3559 B.142 C.17 1.3594 B.177 C.17 1.3629 — C.11 .3560 B.143 C.17 1.3595 B.178 C.17 1.3630 — C.12.3561 B.144 C.17 1.3596 B.179 C.17 1.3631 — C.13 .3562 B.145 C.17 1.3597 B.180 C.17 1.3632 — C.14 .3563 B.146 C.17 1.3598 B.181 C.17 1.3633 — C.15 .3564 B.147 C.17 1.3599 B.182 C.17 1.3634 — C.16 .3565 B.148 C.17 1.3600 B.183 C.17 1.3635 — C.17 .3566 B.149 C.17 1.3601 B.184 C.17 1.3636 B.202 — .3567 B.150 C.17 1.3602 B.185 C.17 1.3637 B.202 C.1 .3568 B.151 C.17 1.3603 B.186 C.17 1.3638 B.202 C.2 .3569 B.152 C.17 1.3604 B.187 C.17 1.3639 B.202 C.3 .3570 B.153 C.17 1.3605 B.188 C.17 1.3640 B.202 C.4.3571 B.154 C.17 1.3606 B.189 C.17 1.3641 B.202 C.5 .3572 B.155 C.17 1.3607 B.190 C.17 1.3642 B.202 C.6 .3573 B.156 C.17 1.3608 B.191 C.17 1.3643 B.202 C.7 .3574 B.157 C.17 1.3609 B.192 C.17 1.3644 B.202 C.8 .3575 B.158 C.17 1.3610 B.193 C.17 1.3645 B.202 C.9 .3576 B.159 C.17 1.3611 B.194 C.17 1.3646 B.202 C.10 .3577 B.160 C.17 1.3612 B.195 C.17 1.3647 B.202 C.11 .3578 B.161 C.17 1.3613 B.196 C.17 1.3648 B.202 C.12 .3579 B.162 C.17 1.3614 B.197 C.17 1.3649 B.202 C.13 .3580 B.163 C.17 1.3615 B.198 C.17 1.3650 B.202 C.14.3581 B.164 C.17 1.3616 B.199 C.17 1.3651 B.202 C.15 .3582 B.165 C.17 1.3617 B.200 C.17 1.3652 B.202 C.16 .3583 B.166 C.17 1.3618 B.201 C.17 1.3653 B.202 C.17 .3584 B.167 C.17 1.3619 — C.1 The specific number for each single composition is deductible as follows:

Composition 1.200 for example comprises the phenyltriazolinone I. a.87 and cinmethylin (B.200) (see table 1 , entry 1 .200; as well as table B, entry B.200).

Composition 2.200 for example comprises the phenyltriazolinone l.f.87 (see the definition for compositions 2.1 to 2.3653, preferably 2.1 to 2.3635, below) and cinmethylin (B.200) (see table 1 , entry 1.200; as well as table B, entry B.200).

Composition 7.200 for example comprises imazapyr (B.35) (see the definition for compositions 7.1 to 7.3653, preferably 7.1 to 7.3635, below), the phenyltriazolinone I. a.87 and cinmethylin (B.200) (see table 1 , entry 1 .200; as well as table B, entry B.200).

Also especially preferred are compositions 2.1 to 2.3653, more preferred 2.1 . to 2.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1.1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87).

Also especially preferred are compositions 3.1 to 3.3653, more preferred 3.1 . to 3.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635 only in that they additionally comprise B.2 as further herbicide B. Also especially preferred are compositions 4.1 to 4.3653, more preferred 4.1 . to 4.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.8 as further herbicide B.

Also especially preferred are compositions 5.1 to 5.3653, more preferred 5.1 . to 5.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.30 as further herbicide B.

Also especially preferred are compositions 6.1 to 6.3653, more preferred 6.1 . to 6.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.32 as further herbicide B.

Also especially preferred are compositions 7.1 to 7.3653, more preferred 7.1 . to 7.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.35 as further herbicide B.

Also especially preferred are compositions 8.1 to 8.3653, more preferred 8.1 . to 8.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.38 as further herbicide B.

Also especially preferred are compositions 9.1 to 9.3653, more preferred 9.1 . to 9.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.40 as further herbicide B.

Also especially preferred are compositions 10.1 to 10.3653, more preferred 10.1. to 10.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.51 as further herbicide B.

Also especially preferred are compositions 1 1.1 to 1 1 .3653, more preferred 1 1 .1. to 1 1 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.55 as further herbicide B. Also especially preferred are compositions 12.1 to 12.3653, more preferred 12.1. to 12.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.56 as further herbicide B.

Also especially preferred are compositions 13.1 to 13.3653, more preferred 13.1. to 13.363,5 which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.64 as further herbicide B.

Also especially preferred are compositions 14.1 to 14.3653, more preferred 14.1. to 14.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.66 as further herbicide B.

Also especially preferred are compositions 15.1 to 15.3653, more preferred 15.1. to 15.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.67 as further herbicide B.

Also especially preferred are compositions 16.1 to 16.3653, more preferred 16.1. to 16.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.68 as further herbicide B. Also especially preferred are compositions 17.1 to 17.3653, more preferred 17.1. to 17.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.69 as further herbicide B.

Also especially preferred are compositions 18.1 to 18.3653, more preferred 18.1. to 18.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.73 as further herbicide B. Also especially preferred are compositions 19.1 to 19.3653, more preferred 19.1. to 19.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.76 as further herbicide B. Also especially preferred are compositions 20.1 to 20.3653, more preferred 20.1. to 20.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.81 as further herbicide B.

Also especially preferred are compositions 21.1 to 21.3653, more preferred 21 .1. to 21 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.82 as further herbicide B.

Also especially preferred are compositions 22.1 to 22.3653, more preferred 22.1. to 22.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.85 as further herbicide B.

Also especially preferred are compositions 23.1 to 23.3653, more preferred 23.1. to 23.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.88 as further herbicide B.

Also especially preferred are compositions 24.1 to 24.3653, more preferred 24.1. to 24.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.89 as further herbicide B. Also especially preferred are compositions 25.1 to 25.3653, more preferred 25.1. to 25.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.94 as further herbicide B.

Also especially preferred are compositions 26.1 to 26.3653, more preferred 26.1. to 26.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.95 as further herbicide B.

Also especially preferred are compositions 27.1 to 27.3653, more preferred 27.1. to 27.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.98 as further herbicide B.

Also especially preferred are compositions 28.1 to 28.3653, more preferred 28.1. to 28.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.100 as further herbicide B.

Also especially preferred are compositions 29.1 to 29.3653, more preferred 29.1. to 29.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.103 as further herbicide B.

Also especially preferred are compositions 30.1 to 30.3653, more preferred 30.1. to 30.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.103 and B.67 as further herbicides B.

Also especially preferred are compositions 31.1 to 31 .3653, more preferred 31 .1. to 31 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.103 and B.76 as further herbicides B.

Also especially preferred are compositions 32.1 to 32.3653, more preferred 32.1. to 32.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.103 and B.82 as further herbicides B. Also especially preferred are compositions 33.1 to 33.3653, more preferred 33.1. to 33.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.104 as further herbicide B.

Also especially preferred are compositions 34.1 to 34.3653, more preferred 34.1. to 34.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.104 and B.67 as further herbicides B.

Also especially preferred are compositions 35.1 to 35.3653, more preferred 35.1. to 35.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.104 and B.76 as further herbicides B.

Also especially preferred are compositions 36.1 to 36.3653, more preferred 36.1. to 36.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.104 and B.82 as further herbicides B.

Also especially preferred are compositions 37.1 to 37.3653, more preferred 37.1. to 37.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.106 as further herbicide B. Also especially preferred are compositions 38.1 to 38.3653, more preferred 38.1. to 38.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.107 as further herbicide B.

Also especially preferred are compositions 39.1 to 39.3653, more preferred 39.1. to 39.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B. 107 and B.67 as further herbicides B. Also especially preferred are compositions 40.1 to 40.3653, more preferred 40.1. to 40.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B. 107 and B.76 as further herbicides B. Also especially preferred are compositions 41.1 to 41 .3653, more preferred 41 .1. to 41 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B. 107 and B.82 as further herbicides B.

Also especially preferred are compositions 42.1 to 42.3653, more preferred 42.1. to 42.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.109 as further herbicide B.

Also especially preferred are compositions 43.1 to 43.3653, more preferred 43.1. to 43.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 1 1 as further herbicide B.

Also especially preferred are compositions 44.1 to 44.3653, more preferred 44.1. to 44.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 1 1 and B.67 as further herbicides B.

Also especially preferred are compositions 45.1 to 45.3653, more preferred 45.1. to 45.3635, which differ from the corresponding compositions 1 .1 to 1.3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 1 1 and B.76 as further herbicides B. Also especially preferred are compositions 46.1 to 46.3653, more preferred 46.1. to 46.3635, which differ from the corresponding compositions 1 .1 to 1.3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 1 1 and B.82 as further herbicides B.

Also especially preferred are compositions 47.1 to 47.3653, more preferred 47.1. to 47.3635, which differ from the corresponding compositions 1 .1 to 1.3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B. 1 16 as further herbicide B.

Also especially preferred are compositions 48.1 to 48.3653, more preferred 48.1. to 48.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 16 and B.67 as further herbicides B.

Also especially preferred are compositions 49.1 to 49.3653, more preferred 49.1. to 49.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 16 and B.94 as further herbicides B.

Also especially preferred are compositions 50.1 to 50.3653, more preferred 50.1. to 50.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.1 16 and B.103 as further herbicides B.

Also especially preferred are compositions 51.1 to 51 .3653, more preferred 51 . to 51 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.1 16 and B.128 as further herbicides B.

Also especially preferred are compositions 52.1 to 52.3653, more preferred 52 . to 52.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.1 16 and B.104 as further herbicides B.

Also especially preferred are compositions 53.1 to 53.3653, more preferred 53 . to 53.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.1 16 and B.107 as further herbicides B.

Also especially preferred are compositions 54.1 to 54.3653, more preferred 54 . to 54.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.1 16 and B.1 1 1 as further herbicides B.

Also especially preferred are compositions 55.1 to 55.3653, more preferred 55 . to 55.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.122 as further herbicide B.

Also especially preferred are compositions 56.1 to 56.3653, more preferred 56 . to 56.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.126 as further herbicide B.

Also especially preferred are compositions 57.1 to 57.3653, more preferred 57 . to 57.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.128 as further herbicide B.

Also especially preferred are compositions 58.1 to 58.3653, more preferred 58 . to 58.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.131 as further herbicide B.

Also especially preferred are compositions 59.1 to 59.3653, more preferred 59 . to 59.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.132 as further herbicide B.

Also especially preferred are compositions 60.1 to 60.3653, more preferred 60 . to 60.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 . to 1.3635, only in that they additionally comprise B.133 as further herbicide B. Also especially preferred are compositions 61.1 to 61 .3653, more preferred 61 .1. to 61 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.135 as further herbicide B. Also especially preferred are compositions 62.1 to 62.3653, more preferred 62.1. to 62.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.137 as further herbicide B.

Also especially preferred are compositions 63.1 to 63.3653, more preferred 63.1. to 63.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred compositions 1 .1 to 1 .3635, even more preferred 1 1.1 to 1 .3635, only in that they additionally comprise B.138 as further herbicide B.

Also especially preferred are compositions 64.1 to 64.3653, more preferred 64.1. to 64.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.140 /as further herbicide B.

Also especially preferred are compositions 65.1 to 65.3653, more preferred 65.1. to 65.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.145 as further herbicide B.

Also especially preferred are compositions 66.1 to 66.3653, more preferred 66.1. to 66.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.153 as further herbicide B.

Also especially preferred are compositions 67.1 to 67.3653, more preferred 67.1. to 67.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.156 as further herbicide B. Also especially preferred are compositions 68.1 to 68.3653, more preferred 68.1. to 68.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.171 as further herbicide B.

Also especially preferred are compositions 69.1 to 69.3653, more preferred 69.1. to 69.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they additionally comprise B.174 as further herbicide B.

Also especially preferred are compositions 70.1 to 70.3653, more preferred 70.1. to 70.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.2 as further herbicide B. Also especially preferred are compositions 71.1 to 71 .3653, more preferred 71.1. to 71 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.8 as further herbicide B.

Also especially preferred are compositions 72.1 to 72.3653, more preferred 72.1. to 72.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.30 as further herbicide B.

Also especially preferred are compositions 73.1 to 73.3653, more preferred 73.1. to 73.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.32 as further herbicide B.

Also especially preferred are compositions 74.1 to 74.3653, more preferred 74.1. to 74.3635, which differ from the corresponding compositions 1 .1 to 1.3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.35 as further herbicide B.

Also especially preferred are compositions 75.1 to 75.3653, more preferred 75.1. to 75.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula ((l.f.87) and additionally comprise B.38 as further herbicide B.

Also especially preferred are compositions 76.1 to 76.3653, more preferred 76.1. to 76.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.40 as further herbicide B.

Also especially preferred are compositions 77.1 to 77.3653, more preferred 77.1. to 77.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.51 as further herbicide B.

Also especially preferred are compositions 78.1 to 78.3653, more preferred 78.1. to 78.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.55 as further herbicide B.

Also especially preferred are compositions 79.1 to 79.3653, more preferred 79.1. to 79.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.56 as further herbicide B.

Also especially preferred are compositions 80.1 to 80.3653, more preferred 80.1. to 80.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.64 as further herbicide B.

Also especially preferred are compositions 81.1 to 81 .3653, more preferred 81 .1. to 81 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.66 as further herbicide B.

Also especially preferred are compositions 82.1 to 82.3653, more preferred 82.1. to 82.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.67 as further herbicide B.

Also especially preferred are compositions 83.1 to 83.3653, more preferred 83.1. to 83.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.68 as further herbicide B.

Also especially preferred are compositions 84.1 to 84.3653, more preferred 84.1. to 84.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.69 as further herbicide B.

Also especially preferred are compositions 85.1 to 85.3653, more preferred 85.1. to 85.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.73 as further herbicide B.

Also especially preferred are compositions 86.1 to 86.3653, more preferred 86.1. to 86.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.76 as further herbicide B.

Also especially preferred are compositions 87.1 to 87.3653, more preferred 87.1. to 87.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.81 as further herbicide B. Also especially preferred are compositions 88.1 to 88.3653, more preferred 88.1. to 88.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.82 as further herbicide B.

Also especially preferred are compositions 89.1 to 89.3653, more preferred 89.1. to 89.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.85 as further herbicide B.

Also especially preferred are compositions 90.1 to 90.3653, more preferred 90.1. to 90.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.88 as further herbicide B.

Also especially preferred are compositions 91.1 to 91.3653, more preferred 91.1. to 91 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.89 as further herbicide B.

Also especially preferred are compositions 92.1 to 92.3653, more preferred 92.1. to 92.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.94 as further herbicide B.

Also especially preferred are compositions 93.1 to 93.3653, more preferred 93.1. to 93.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.95 as further herbicide B.

Also especially preferred are compositions 94.1 to 94.3653, more preferred 94.1. to 94.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.98 as further herbicide B.

Also especially preferred are compositions 95.1 to 95.3653, more preferred 95.1. to 95.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.100 as further herbicide B.

Also especially preferred are compositions 96.1 to 96.3653, more preferred 96.1. to 96.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.103 as further herbicide B. Also especially preferred are compositions 97.1 to 97.3653, more preferred 97.1. to 97.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.103 and B.67 as further herbicides B. Also especially preferred are compositions 98.1 to 98.3653, more preferred 98.1. to 98.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.103 and B.76 as further herbicides B. Also especially preferred are compositions 99.1 to 99.3653, more preferred 99.1. to 99.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1.3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.103 and B.82 as further herbicides B. Also especially preferred are compositions 100.1 to 100.3653, more preferred 100.1. to 100.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.104 as further herbicide B. Also especially preferred are compositions 101 .1 to 101.3653, more preferred 101 .1. to 101 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.104 and B.67 as further herbicides B. Also especially preferred are compositions 102.1 to 102.3653, more preferred 102.1. to 102.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.104 and B.76 as further herbicides B. Also especially preferred are compositions 103.1 to 103.3653, more preferred 103.1. to 103.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.104 and B.82 as further herbicides B. Also especially preferred are compositions 104.1 to 104.3653, more preferred 104.1. to 104.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formu- la (l.f.87) and additionally comprise B.106 as further herbicide B.

Also especially preferred are compositions 105.1 to 105.3653, more preferred 105.1. to 105.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.107 as further herbicide B.

Also especially preferred are compositions 106.1 to 106.3653, more preferred 106.1. to 106.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B. 107 and B.67 as further herbicides B.

Also especially preferred are compositions 107.1 to 107.3653, more preferred 107.1. to 107.3635, which differ from the corresponding compositions 1 .1 to 1.3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B. 107 and B.76 as further herbicides B.

Also especially preferred are compositions 108.1 to 108.3653, more preferred 108.1. to 108.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B. 107 and B.82 as further herbicides B.

Also especially preferred are compositions 109.1 to 109.3653, more preferred 109.1. to 109.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.109 as further herbicide B.

Also especially preferred are compositions 1 10.1 to 1 10.3653, more preferred 1 10.1. to 1 10.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 1 1 as further herbicide B.

Also especially preferred are compositions 1 1 1 .1 to 1 1 1 .3653, more preferred 1 1 1 .1. to 1 1 1 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 1 1 and B.67 as further herbicides B.

Also especially preferred are compositions 1 12.1 to 1 12.3653, more preferred 1 12.1. to 1 12.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 1 1 and B.76 as further herbicides B. Also especially preferred are compositions 1 13.1 to 1 13.3653, more preferred 1 13.1. to 1 13.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 1 1 and B.82 as further herbicides B.

Also especially preferred are compositions 1 14.1 to 1 14.3653, more preferred 1 14.1. to 1 14.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B. 1 16 as further herbicide B.

Also especially preferred are compositions 1 15.1 to 1 15.3653, more preferred 1 15.1. to 1 15.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.67 as further herbicides B.

Also especially preferred are compositions 1 16.1 to 1 16.3653, more preferred 1 16.1 . to 1 16.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.94 as further herbicides B.

Also especially preferred are compositions 1 17.1 to 1 17.3653, more preferred 1 17.1. to 1 17.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.103 as further herbicides B.

Also especially preferred are compositions 1 18.1 to 1 18.3653, more preferred 1 18.1. to 1 18.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.128 as further herbicides B.

Also especially preferred are compositions 1 19.1 to 1 19.3653, more preferred 1 19.1. to 1 19.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.104 as further herbicides B.

Also especially preferred are compositions 120.1 to 120.3653, more preferred 120.1. to 120.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.107 as further herbicides B.

Also especially preferred are compositions 121 .1 to 121.3653, more preferred 121 .1. to 121 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.1 16 and B.1 1 1 as further herbicides B.

Also especially preferred are compositions 122.1 to 122.3653, more preferred 122.1. to 122.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.122 as further herbicide B.

Also especially preferred are compositions 123.1 to 123.3653, more preferred 123.1. to 123.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.126 as further herbicide B.

Also especially preferred are compositions 124.1 to 124.3653, more preferred 124.1. to 124.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.128 as further herbicide B.

Also especially preferred are compositions 125.1 to 125.3653, more preferred 125.1. to 125.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.131 as further herbicide B.

Also especially preferred are compositions 126.1 to 126.3653, more preferred 126.1. to 126.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.132 as further herbicide B.

Also especially preferred are compositions 127.1 to 127.3653, more preferred 127.1. to 127.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.133 as further herbicide B.

Also especially preferred are compositions 128.1 to 128.3653, more preferred 128.1. to 128.3635 which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.135 as further herbicide B.

Also especially preferred are compositions 129.1 to 129.3653, more preferred 129.1. to 129.3635 which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.137 as further herbicide B. Also especially preferred are compositions 130.1 to 130.3653, more preferred 130.1 . to 130.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, even more preferred 1 1.1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.138 as further herbicide B.

Also especially preferred are compositions 131 .1 to 131.3653, more preferred 131 .1. to 131 .3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.140 as further herbicide B.

Also especially preferred are compositions 132.1 to 132.3653, more preferred 132.1. to 132.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.145 as further herbicide B.

Also especially preferred are compositions 133.1 to 133.3653, more preferred 133.1. to 133.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.153 as further herbicide B.

Also especially preferred are compositions 134.1 to 134.3653, more preferred 134.1. to 134.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.156 as further herbicide B.

Also especially preferred are compositions 135.1 to 135.3653, more preferred 135.1. to 135.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.171 as further herbicide B.

Also especially preferred are compositions 136.1 to 136.3653, more preferred 136.1. to 136.3635, which differ from the corresponding compositions 1 .1 to 1 .3653, more preferred 1 .1 to 1 .3635, only in that they comprise as the active compound A the phenyltriazolinone of formula (l.f.87) and additionally comprise B.174 as further herbicide B.

The invention also relates to agrochemical compositions comprising at least an auxiliary and at least one phenyltriazolinone of formula (I) according to the invention. An agrochemical composition comprises a pesticidally effective amount of an phenyltriazolinone of formula (I). The term "effective amount" denotes an amount of the composition or of the compounds I, which is sufficient for controlling unwanted plants, especially for controlling unwanted plants in crops (i.e. cultivated plants) and which does not result in a substantial damage to the treated plants. Such an amount can vary in a broad range and is dependent on various factors, such as the plants to be controlled, the treated crop or material, the climatic conditions and the specific phenyltriazolinone of formula (I) used.

The phenyltriazolinones of formula (I), their N-oxides, salts or derivatives can be converted into customary types of agrochemical compositions, e. g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof. Examples for agrochemical composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g. BR, TB, DT), granules (e.g. WG, SG, GR, FG, GG, MG), insecticidal articles (e.g. LN), as well as gel formulations for the treatment of plant propagation materials such as seeds (e.g. GF). These and further agrochemical compositions types are defined in the "Catalogue of pesticide formulation types and international coding system", Technical Monograph No. 2, 6 ^th Ed. May 2008, CropLife International. The agrochemical compositions are prepared in a known manner, such as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders. Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclohexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g. lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof. Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & De- tergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).

Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.

Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar- based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or al- kylpolyglucosides. Examples of polymeric surfactants are home- or copolymers of vinylpyrroli- done, vinylalcohols, or vinylacetate.

Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetains and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or pol- yethyleneamines.

Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the phenyltriazolinones of formula (I) on the target. Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F In- forma UK, 2006, chapter 5. Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates. Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin. Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.

Suitable colorants (e.g. in red, blue, or green) are pigments of low water solubility and water- soluble dyes. Examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer- rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).

Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols, pol- yacrylates, biological or synthetic waxes, and cellulose ethers.

Examples for agrochemical composition types and their preparation are:

i) Water-soluble concentrates (SL, LS)

10-60 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention and 5-15 wt% wetting agent (e.g. alcohol alkoxylates) are dissolved in water and/or in a water-soluble solvent (e.g. alcohols) ad 100 wt%. The active substance dissolves upon dilution with water.

ii) Dispersible concentrates (DC)

5-25 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention and 1 -10 wt% dispersant (e. g. polyvinylpyrrolidone) are dissolved in organic solvent (e.g. cyclohexanone) ad 100 wt%. Dilution with water gives a dispersion.

iii) Emulsifiable concentrates (EC)

15-70 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention and 5-10 wt% emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in water-insoluble organic solvent (e.g. aromatic hydrocarbon) ad 100 wt%. Dilution with water gives an emulsion.

iv) Emulsions (EW, EO, ES)

5-40 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention and 1 -10 wt% emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20-40 wt% water-insoluble organic solvent (e.g. aromatic hydrocarbon). This mixture is introduced into water ad 100 wt% by means of an emulsifying machine and made into a homogeneous emulsion. Dilution with water gives an emulsion.

v) Suspensions (SC, OD, FS)

In an agitated ball mill, 20-60 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C)according to the invention are comminuted with addition of 2-10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0,1 -2 wt% thickener (e.g. xanthan gum) and water ad 100 wt% to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance. For FS type composition up to 40 wt% binder (e.g. polyvinylalcohol) is added.

vi) Water-dispersible granules and water-soluble granules (WG, SG)

50-80 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C)according to the invention are ground finely with addition of dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) ad 100 wt% and prepared as water-dispersible or water- soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.

vii) Water-dispersible powders and water-soluble powders (WP, SP, WS)

50-80 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention are ground in a rotor-stator mill with addition of 1 -5 wt% dispersants (e.g. sodium lignosulfonate), 1 -3 wt% wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g. silica gel) ad 100 wt%. Dilution with water gives a stable dispersion or solution of the active substance. viii) Gel (GW, GF)

In an agitated ball mill, 5-25 wt% of an phenyltriazolinone of formula (I) or a herbicidal composi- tion comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention are comminuted with addition of 3-10 wt% dispersants (e.g. sodium lignosulfonate), 1 -5 wt% thickener (e.g. carboxymethylcellulose) and water ad 100 wt% to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance,

iv) Microemulsion (ME)

5-20 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate), and water ad 100 %. This mixture is stirred for 1 h to produce spontaneously a thermo- dynamically stable microemulsion.

iv) Microcapsules (CS) An oil phase comprising 5-50 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aro- matic hydrocarbon), 2-15 wt% acrylic monomers (e.g. methylmethacrylate, methacrylic acid and a di- or triacrylate) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules. Alternatively, an oil phase comprising 5-50 wt% of an phenyltriazolinone of formula (I) according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g. diphenylmethene-4,4'- diisocyanate) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). The addition of a polyamine (e.g. hexamethylenediamine) results in the formation of poly- urea microcapsules. The monomers amount to 1 -10 wt%. The wt% relate to the total CS composition.

ix) Dustable powders (DP, DS)

1 -10 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention are ground finely and mixed intimately with solid carrier (e.g. finely divided kaolin) ad 100 wt%.

x) Granules (GR, FG)

0.5-30 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) ac- cording to the invention is ground finely and associated with solid carrier (e.g. silicate) ad 100 wt%. Granulation is achieved by extrusion, spray-drying or the fluidized bed.

xi) Ultra-low volume liquids (UL)

1 -50 wt% of an phenyltriazolinone of formula (I) or a herbicidal composition comprising at least one phenyltriazolinone of formula (I) (component A) and at least one further compound selected from the herbicidal compounds B (component B) and safeners C (component C) according to the invention are dissolved in organic solvent (e.g. aromatic hydrocarbon) ad 100 wt%.

The agrochemical compositions types i) to xi) may optionally comprise further auxiliaries, such as 0,1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0,1 -1 wt% anti-foaming agents, and 0,1 -1 wt% colorants.

The agrochemical compositions and /or herbicidal compositions comprising generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of the phenyltriazolinones of formula (I). The phenyltriazolinones of formula (I) are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum). Solutions for seed treatment (LS), suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds. The agrochemi- cal compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.

Methods for applying phenyltriazolinones of formula (I), agrochemical compositions and /or her- bicidal compositions thereof, on to plant propagation material, especially seeds, include dress- ing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material. Preferably, phenyltriazolinones of formula (I), agrochemical compositions and /or her- bicidal compositions thereof thereof, respectively, are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.

Various types of oils, wetters, adjuvants, fertilizer, or micronutrients, and further pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, safeners) may be added to the phenyltriazolinones of formula (I), the agrochemical compositions and/or the herbicidal compositions comprising them as premix or, if appropriate not until immediately prior to use (tank mix). These agents can be admixed with the agrochemical compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.

The user applies the phenyltriazolinones of formula (I) according to the invention, the agrochemical compositions and/or the herbicidal compositions comprising them usually from a pre- dosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system. Usually, the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained. Usually, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.

According to one embodiment, either individual components of the agrochemical composition according to the invention or partially premixed components, e. g. components comprising phenyltriazolinones of formula (I) and optionally active substances from the groups B and/or C), may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate.

In a further embodiment, individual components of the agrochemical composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.

In a further embodiment, either individual components of the agrochemical composition ac- cording to the invention or partially premixed components, e. g components comprising phenyltriazolinones of formula (I) and optionally active substances from the groups B and/or C), can be applied jointly (e.g. after tank mix) or consecutively. The phenyltriazolinones of formula (I) are suitable as herbicides. They are suitable as such, as an appropriately formulated composition (agrochemical composition) or as an herbicidal composition in combination with at least one further compound selected from the herbicidal active compounds B (component B) and safeners C (component C).

The phenyltriazolinones of formula (I), or the agrochemical compositions and /or herbicidal compositions comprising the phenyltriazolinones of formula (I), control vegetation on non-crop areas very efficiently, especially at high rates of application. They act against broad-leaved weeds and grass weeds in crops such as wheat, rice, maize, soya and cotton without causing any significant damage to the crop plants. This effect is mainly observed at low rates of application.

The phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, are applied to the plants mainly by spraying the leaves. Here, the application can be carried out using, for example, water as carrier by customary spraying techniques using spray liquor amounts of from about 100 to 1000 l/ha (for example from 300 to 400 l/ha). The phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, may also be applied by the low-volume or the ultra- low-volume method, or in the form of microgranules.

Application of the phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, can be done before, during and/or after, preferably during and/or after, the emergence of the undesirable plants. The phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, can be applied pre-, post-emergence or pre-plant, or together with the seed of a crop plant. It is also possible to apply the phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, by applying seed, pretreated with the phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions comprising them, of a crop plant. If the active ingredients are less well tolerated by certain crop plants, application techniques may be used in which the herbicidal compositions are sprayed, with the aid of the spraying equipment, in such a way that as far as possible they do not come into contact with the leaves of the sensitive crop plants, while the active ingredients reach the leaves of undesirable plants growing underneath, or the bare soil surface (post-directed, lay-by).

In a further embodiment, the phenyltriazolinones of formula (I), or the agrochemical

compositions and/or the herbicidal compositions comprising them, can be applied by treating seed. The treatment of seeds comprises essentially all procedures familiar to the person skilled in the art (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multilayer coating, seed encrusting, seed dripping and seed pelleting) based on the

phenyltriazolinones of formula (I), or the agrochemical compositions and/or the herbicidal compositions prepared therefrom. Here, the herbicidal compositions can be applied diluted or undiluted. The term "seed" comprises seed of all types, such as, for example, corns, seeds, fruits, tubers, seedlings and similar forms. Here, preferably, the term seed describes corns and seeds. The seed used can be seed of the useful plants mentioned above, but also the seed of transgenic plants or plants obtained by customary breeding methods.

When employed in plant protection, the amounts of active substances applied, i.e. the phe- nyltriazolinones of formula (I), component B and, if appropriate, component C without formulation auxiliaries, are, depending on the kind of effect desired, from 0.001 to 2 kg per ha, prefera- bly from 0.005 to 2 kg per ha, more preferably from 0.05 to 1.5 kg per ha and in particular from 0.1 to 1 kg per ha.

In another embodiment of the invention, the application rate of the phenyltriazolinones of formula (I), component B and, if appropriate, component C, is from 0.001 to 3 kg/ha, preferably from 0.005 to 2.5 kg/ha and in particular from 0.01 to 2 kg/ha of active substance (a.s.).

In another preferred embodiment of the invention, the rates of application of the

phenyltriazolinones of formula (I) according to the present invention (total amount of

phenyltriazolinones of formula (I)) are from 0.1 g/ha to 3000 g/ha, preferably 1 g/ha to 1000 g/ha, depending on the control target, the season, the target plants and the growth stage.

In another preferred embodiment of the invention, the application rates of the phenyltriazolinones of formula (I) are in the range from 0.1 g/ha to 5000 g/ha and preferably in the range from 0.5 g/ha to 2500 g/ha or from 2.5 g/ha to 2000 g/ha.

In another preferred embodiment of the invention, the application rate of the phenyltriazolinones of formula (I) is 0.1 to 1000 g/ha, preferably 0.5 to 750 g/ha, more preferably 2.5 to 500 g/ha. The required application rates of herbicidal compounds B are generally in the range of from 0.0005 kg/ha to 2.5 kg/ha and preferably in the range of from 0.005 kg/ha to 2 kg/ha or

0.01 kg/ha to 1.5 kg/h of a.s.

The required application rates of safeners C are generally in the range of from 0.0005 kg/ha to 2.5 kg/ha and preferably in the range of from 0.005 kg/ha to 2 kg/ha or 0.01 kg/ha to 1.5 kg/h of a.s.

In treatment of plant propagation materials such as seeds, e. g. by dusting, coating or drenching seed, amounts of active substance of from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g and most preferably from 5 to 100 g, per 100 kilogram of plant propagation material (preferably seeds) are generally required. In another embodiment of the invention, to treat the seed, the amounts of active substances applied, i.e. the phenyltriazolinones of formula (I), component B and, if appropriate, component C are generally employed in amounts of from 0.001 to 10 kg per 100 kg of seed. When used in the protection of materials or stored products, the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.

In case of herbicidal compositions according to the present invention it is immaterial whether the phenyltriazolinones of formula (I), and the further component B and/or the component C are formulated and applied jointly or separately.

In the case of separate application it is of minor importance, in which order the application takes place. It is only necessary, that the phenyltriazolinones of formula (I), and the further component B and/or the component C are applied in a time frame that allows simultaneous action of the active ingredients on the plants, preferably within a time-frame of at most 14 days, in particular at most 7 days.

Depending on the application method in question, the phenyltriazolinones of formula (I), or the agrochemical compositions and /or herbicidal compositions comprising them, can additionally be employed in a further number of crop plants for eliminating undesirable plants. Examples of suitable crops are the following:

Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Avena sativa, Beta vulgaris spec, altissima, Beta vulgaris spec, rapa, Brassica napus var. napus, Brassica napus var. napobrassica, Brassica rapa var. silvestris, Brassica oleracea, Brassica nigra, Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus, Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum, (Gossypium arboreum,

Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus, Hevea brasiliensis, Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec, Manihot esculenta, Medicago sativa, Musa spec, Nicotiana tabacum (N.rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spec, Pistacia vera, Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Prunus armeniaca, Prunus cerasus, Prunus dulcis and Prunus domestica, Ribes sylvestre, Ricinus communis, Saccharum officinarum, Secale cereale, Sinapis alba, Solanum tuberosum, Sorghum bicolor (s. vulgare), Theobroma cacao, Trifolium pratense, Triticum aestivum, Triticale, Triticum durum, Vicia faba, Vitis vinifera and Zea mays.

Preferred crops are Arachis hypogaea, Beta vulgaris spec, altissima, Brassica napus var.

napus, Brassica oleracea, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cynodon dactylon, Glycine max, Gossypium hirsutum, (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus, Hordeum vulgare, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec, Medicago sativa, Nicotiana tabacum (N.rustica), Olea europaea, Oryza sativa , Phaseolus lunatus, Phaseolus vulgaris, Pistacia vera, Pisum sativum, Prunus dulcis, Saccharum officinarum, Secale cereale, Solanum tuberosum, Sorghum bicolor (s. vulgare), Triticale, Triticum aestivum, Triticum durum, Vicia faba, Vitis vinifera and Zea mays.

Especially preferred crops are crops of cereals, corn, soybeans, rice, oilseed rape, cotton, potatoes, peanuts or permanent crops.

The phenyltriazolinones of formula (I) according to the invention, or the agrochemical compositions and /or herbicidal compositions comprising them, can also be used in genetically modified plants. The term "genetically modified plants" is to be understood as plants whose genetic mate- rial has been modified by the use of recombinant DNA techniques to include an inserted sequence of DNA that is not native to that plant species' genome or to exhibit a deletion of DNA that was native to that species' genome, wherein the modification(s) cannot readily be obtained by cross breeding, mutagenesis or natural recombination alone. Often, a particular genetically modified plant will be one that has obtained its genetic modification(s) by inheritance through a natural breeding or propagation process from an ancestral plant whose genome was the one directly treated by use of a recombinant DNA technique. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. Such genetic modifications also include but are not limited to targeted post-translational modification of protein(s), oligo- or polypeptides, e. g., by inclusion therein of amino acid mutation(s) that permit, decrease, or promote glycosylation or polymer additions such as prenylation, acetylation farnesylation, or PEG moiety attachment.

Plants that have been modified by breeding, mutagenesis or genetic engineering, e.g. have been rendered tolerant to applications of specific classes of herbicides, such as auxin herbi- cides such as dicamba or 2,4-D; bleacher herbicides such as hydroxyphenylpyruvate dioxygen- ase (HPPD) inhibitors or phytoene desaturase (PDS) inhibitors; acetolactate synthase (ALS) inhibitors such as sulfonyl ureas or imidazolinones; enolpyruvyl shikimate 3-phosphate synthase (EPSP) inhibitors such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen-IX oxidase inhibitors; lipid biosynthesis inhibitors such as acetyl CoA car- boxylase (ACCase) inhibitors; or oxynil (i. e. bromoxynil or ioxynil) herbicides as a result of conventional methods of breeding or genetic engineering; furthermore, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or to both glyphosate and a herbicide from another class such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors. These herbicide resistance technologies are, for example, described in Pest Management Science 61 , 2005, 246; 61 , 2005, 258; 61 , 2005, 277; 61 , 2005, 269; 61 , 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108; Australian Journal of Agricultural Research 58, 2007, 708; Science 316, 2007, 1 185; and references quoted therein. Several cultivated plants have been rendered tolerant to herbicides by mutagenesis and conventional methods of breeding, e. g., Clearfield® summer rape (Canola, BASF SE, Germany) being tolerant to imidazolinones, e. g., imazamox, or ExpressSun® sunflowers (DuPont, USA) being tolerant to sulfonyl ureas, e. g., tribenuron. Genetic engineering methods have been used to render cultivated plants such as soybean, cotton, corn, beets and rape, tolerant to herbicides such as glyphosate, imidazoli- nones and glufosinate, some of which are under development or commercially available under the brands or trade names RoundupReady® (glyphosate tolerant, Monsanto, USA), Cul- tivance® (imidazolinone tolerant, BASF SE, Germany) and LibertyLink® (glufosinate tolerant, Bayer CropScience, Germany). Furthermore, plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as delta-endotoxins, e. g., CrylA(b), CrylA(c), CrylF, CrylF(a2), CryllA(b), CrylllA, CrylllB(bl ) or Cry9c; vegetative insecticidal proteins (VIP), e. g., VIP1 , VIP2, VIP3 or VIP3A; insecticidal proteins of bacteria colonizing nema- todes, e. g., Photorhabdus spp. or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cys- tatin or papain inhibitors; ribosome-inactivating proteins (RIP), such as ricin, maize-RIP, abrin, luffin, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxy-steroid oxidase, ec- dysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA- reductase; ion channel blockers, such as blockers of sodium or calcium channels; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilbene synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention these insecticidal proteins or toxins are to be understood expressly also as including pre-toxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a new combination of protein domains, (see, e. g., WO 02/015701 ). Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073. The methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e. g., in the publications mentioned above. These insecticidal proteins contained in the genetically modified plants impart to the plants producing these proteins tolerance to harmful pests from all taxonomic groups of arthropods, especially to beetles (Coeloptera), two-winged insects (Diptera), and moths (Lepidoptera) and to nematodes (Nematoda). Genetically modified plants capable to synthesize one or more insecticidal proteins are, e. g., described in the publications mentioned above, and some of which are commercially available such as YieldGard® (corn cultivars producing the CrylAb toxin), YieldGard® Plus (corn cultivars producing CrylAb and Cry3Bb1 toxins), Starlink® (corn cultivars producing the Cry9c toxin), Herculex® RW (corn cultivars producing Cry34Ab1 , Cry35Ab1 and the enzyme Phosphinothricin-N-Acetyltransferase [PAT]); NuCOTN® 33B (cotton cultivars producing the CrylAc toxin), Bollgard® I (cotton cultivars producing the CrylAc toxin), Bollgard® II (cotton cultivars producing CrylAc and Cry2Ab2 toxins); VIPCOT® (cotton cultivars producing a VI P- toxin); NewLeaf® (potato cultivars producing the Cry3A toxin); Bt-Xtra®, NatureGard®, Knockout®, BiteGard®, Protecta®, Bt1 1 (e. g., Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars producing the CrylAb toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (corn cultivars producing a modified version of the Cry3A toxin, c.f. WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe S.A., Belgium (cotton cultivars producing a modified version of the CrylAc toxin) and 1507 from Pioneer Overseas Corporation, Belgium (corn cultivars producing the Cry1 F toxin and PAT enzyme).

Furthermore, plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenesis- related proteins" (PR proteins, see, e.g., EP-A 392 225), plant disease resistance genes (e. g., potato culti-vars, which express resistance genes acting against Phytophthora infestans derived from the Mexican wild potato, Solanum bulbocastanum) or T4-lyso-zym (e.g., potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Er- winia amylovora). The methods for producing such genetically modi-fied plants are generally known to the person skilled in the art and are described, e.g., in the publications mentioned above.

Furthermore, plants are also covered that are by the use of recombinant DNA techniques capa- ble to synthesize one or more proteins to increase the productivity (e.g., bio-mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants. Furthermore, plants are also covered that contain by the use of recombinant DNA techniques a modified amount of ingredients or new ingredients, specifically to improve human or animal nutrition, e. g., oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g., Nexera® rape, Dow AgroSciences, Canada). Furthermore, plants are also covered that contain by the use of recombinant DNA techniques a modified amount of ingredients or new ingredients, specifically to improve raw material production, e.g., potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).

Furthermore, it has been found that the phenyltriazolinones of formula (I) according to the invention, or the agrochemical compositions and /or herbicidal compositions comprising them, are also suitable for the defoliation and/or desiccation of plant parts, for which crop plants such as cotton, potato, oilseed rape, sunflower, soybean or field beans, in particular cotton, are suitable. In this regard, agrochemical compositions and /or herbicidal compositions for the desiccation and/or defoliation of plants, processes for preparing these agrochemical compositions and /or herbicidal compositions and methods for desiccating and/or defoliating plants using the phenyltriazolinones of formula (I) have been found.

As desiccants, the phenyltriazolinones of formula (I) are particularly suitable for desiccating the above-ground parts of crop plants such as potato, oilseed rape, sunflower and soybean, but also cereals. This makes possible the fully mechanical harvesting of these important crop plants. Also of economic interest is to facilitate harvesting, which is made possible by concentrating within a certain period of time the dehiscence, or reduction of adhesion to the tree, in citrus fruit, olives and other species and varieties of pernicious fruit, stone fruit and nuts. The same mechanism, i.e. the promotion of the development of abscission tissue between fruit part or leaf part and shoot part of the plants is also essential for the controlled defoliation of useful plants, in particular cotton.

Moreover, a shortening of the time interval in which the individual cotton plants mature leads to an increased fiber quality after harvesting.

Moreover, it has been found, that the phenyltriazolinones of formula (I), or the agrochemical compositions and /or herbicidal compositions comprising the phenyltriazolinones of formula (I), very efficiently also control PPO resistant weeds. Accordingly, the present invention also provides a method for controlling the growth of PPO resistant weeds, which comprises contacting such weeds, parts of it, its propagation material or its habitat with phenyltriazolinones of formula (I), wherein the PPO resistant weeds are weeds, that are resistant to PPO-inhibiting herbicides except the phenyltriazolinones of formula (I). The invention particularly relates to a method for controlling PPO resistant weeds in crops which comprises applying phenyltriazolinones of formula (I) to crops, where said PPO herbicide resistant weeds occur or might occur.

As used herein, the terms "PPO inhibitor", "PPO inhibitor herbicide", "PPO-inhibiting herbicide", "protoporphyrinogen IX oxidase inhibitor herbicide", "protoporphyrinogen IX oxidase-inhibiting herbicide", "protoporphyrinogen oxidase inhibitor herbicide" and "protoporphyrinogen oxidase- inhibiting herbicide" are synonyms and refer to a herbicide that inhibits the enzyme protoporphyrinogen oxidase of a plant.

As used herein, the terms "PPO inhibitor herbicide resistant weed", "PPO-inhibiting herbicide resistant weed", "PPO inhibitor resistant weed", "PPO resistant weed", "protoporphyrinogen IX oxidase inhibitor herbicide resistant weed", "protoporphyrinogen IX oxidase inhibiting herbicide resistant weed", "protoporphyrinogen oxidase inhibitor herbicide resistant weed" , and "proto- porphyrinogen oxidase inhibiting herbicide resistant weed" are synonyms and refer to a plant that, in relation to a treatment with an appropriate or over-appropriate rate of PPO-inhibiting herbicide application, has inherited, developed or acquired an ability

(1 ) to survive that treatment, if it is one that is lethal to (i.e. eradicates) the wild type weed; or (2) to exhibit significant vegetative growth or thrive after that treatment, if it is one that suppresses groth of the wild-type weed.

Effective weed control is defined as at least 70% weed suppresison or eradication from the crop, or as at least 70% weed plant phototixicty, as determined 2 weeks after treatment.

Thus, PPO resistant weeds are weeds, which are not controlled by the application of PPO inhibitors except the phenyltriazolinones of formula (I), whereas the respective sensitive biotype is controlled at that use rate.

Here, "not controlled" means that in a visual rating the weed control (herbicidal effect) is < 70 % of weed suppression or eradication as determined 2 weeks after treatment; and "controlled" means that in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment.

Preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides except the phenyltriazolinones of formula (I).

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides selected from azafenidin.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides selected from azafenidin, fomesafen and lactofen.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides selected from fomesafen and lactofen. Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides selected from acifluorfen, azafenidin, carfentrazone, flumiclorac, flumioxazin, fomesafen, lactofen, oxadiazon, oxyfluorfen, pyraflufen and sulfentrazone.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application of PPO-inhibiting herbicides selected from acifluorfen, carfentrazone, flumiclorac, flumioxazin, fomesafen, lactofen, oxadiazon, oxyfluorfen, pyraflufen and sul- fentrazone.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application rate of

200 g/ha or lower,

particularly preferred 100 g/ha or lower,

especially preferred 50 to 200 g/ha,

more preferred 50 to 100 g/ha,

of PPO-inhibiting herbicides except the phenyltriazolinones of formula (I), whereas the respective sensitive biotype is controlled (i.e. in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment) at that use rate.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application rate of

200 g/ha or lower,

particularly preferred 100 g/ha or lower,

especially preferred 50 to 200 g/ha,

more preferred 50 to 100 g/ha,

of PPO-inhibiting herbicides selected from azafenidin, fomesafen and lactofen, whereas the respective sensitive biotype is controlled (i.e. in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment) at that use rate.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application rate of

200 g/ha or lower,

particularly preferred 100 g/ha or lower,

especially preferred 50 to 200 g/ha,

more preferred 50 to 100 g/ha,

of PPO-inhibiting herbicides selected from fomesafen and lactofen, whereas the respective sensitive biotype is controlled (i.e. in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment) at that use rate.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application rate of

200 g/ha or lower,

particularly preferred 100 g/ha or lower,

especially preferred 50 to 200 g/ha, more preferred 50 to 100 g/ha,

of PPO-inhibiting herbicides selected from acifluorfen, azafenidin, carfentrazone, flumiclorac, flumioxazin, fomesafen, lactofen, oxadiazon, oxyfluorfen, pyraflufen and sulfentrazone, whereas the respective sensitive biotype is controlled (i.e. in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment) at that use rate.

Also preferably, PPO resistant weeds are weeds, which are not controlled (i.e. in a visual rating the weed control is < 70 % of weed suppression or eradication as determined 2 weeks after treatment) by the application rate of

200 g/ha or lower,

particularly preferred 100 g/ha or lower,

especially preferred 50 to 200 g/ha,

more preferred 50 to 100 g/ha,

of PPO-inhibiting herbicides selected from acifluorfen, carfentrazone, flumiclorac, flumioxazin, fomesafen, lactofen, oxadiazon, oxyfluorfen, pyraflufen and sulfentrazone, whereas the respective sensitive biotype is controlled (i.e. in a visual rating the weed control is > 90 % of weed suppression or eradication as determined 2 weeks after treatment) at that use rate.

Also preferably PPO-resistant weeds are those classified as being "PPO resistant" and thus listed according to Anonymous: List of herbicide resistant weeds by herbicide mode of action - weeds resistant to PPO-inhibitors (URL: http://www.weedscience.org/summary/MOA.aspx ).

Particularly preferred the PPO resistant weeds are selected from the group consisting of Aca- lypha ssp., Amaranthus ssp., Ambrosia ssp., Avena ssp., Conyza ssp., Descurainia ssp., Euphorbia ssp. and Senecio ssp.;

especially preferred Amaranthus ssp., Ambrosia ssp. and Euphorbia ssp.;

more preferred Amaranthus ssp. and Ambrosia ssp.. Also particularly preferred the PPO resistant weeds are selected from the group consisting of Asian copperleaf (Acalypha australis), smooth pigweed (Amaranthus hybridus), Palmer amaranth (Amaranthus Palmeri), redroot pigweed (Amaranthus retroflexus), tall/common waterhemp (Amaranthus tuberculatus, Amaranthus rudis, or Amaranthus tamariscinus), common ragweed (Ambrosia artemisiifolia), wild oat (Avena fatua), fleabane (Conyza ambigua), marestail (Conyza Canadensis), flixweed (Descurainia Sophia), wild poinsettia (Euphorbia heterophylla) and eastern groundsel (Senecio vernalis);

especially preferred smooth pigweed (Amaranthus hybridus), Palmer amaranth (Amaranthus Palmeri), redroot pigweed (Amaranthus retroflexus), tall/common waterhemp (Amaranthus tuberculatus or Amaranthus rudis), common ragweed (Ambrosia artemisiifolia) and wild poinsettia (Euphorbia heterophylla);

more preferred tall/common waterhemp (Amaranthus tuberculatus, Amaranthus rudis or Amaranthus tamariscinus) and common ragweed (Ambrosia artemisiifolia). Most PPO resistant weeds, in particular the biotypes of Amaranthus tuberculatus, are resistant due to a codon deletion on the nuclear-encoded gene PPX2L that codes for the PPO enzyme which is dual-targeted to the mitochondria and the chloroplasts. This results in a loss of the glycine amino acid in position 210 (see e.g. B. G. Young et al, Characterization of PPO-lnhibitor-Resistant Wa- terhemp (Amaranthus tuberculatus) Response to Soil-Applied PPO-lnhibiting Herbicides, Weed Science 2015, 63, 51 1 -521 ). A second type of mutation, in particular in a resistant biotype of Ambrosia artemisiifolia, was identified as a mutation that expressed a R98L change of the PPX2 enzyme (S. L. Rousonelos, R. M. Lee, M. S. Moreira, M. J. VanGessel, P. J. Tranel, Characterization of a Common Ragweed (Ambrosia artemisiifolia) Population Resistant to ALS- and PPO-lnhibiting Herbicides, Weed Science 60, 2012, 335- 344.).

Accordingly, preferably PPO-resistant weeds are weeds whose Protox enzyme is resistant to the application of PPO inhibitors due to a mutation that is expressed as a ΔΘ210 or R98L change of said Protox enzyme or equivalents to the PPX2L or PPX2 respectively, in particular that is expressed as a ΔΘ210 or R98L change of said Protox enzyme.

The preparation of the phenyluracils of formula (I) is illuuracilstrated by examples; however, the subject matter of the present invention is not limited to the examples given.

A Preparation examples

Example 1 :

Ethyl 2-[2-[5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro-2-nitro- phenoxy]phenoxy]acetate

(2E/Z)-2-[(2,5-difluorophenyl)hydrazono]propanoic acid

To a solution of 25.0 g (173 mmol) of (2,5-difluorophenyl)hydrazine in 430 mL EtOH was added 15.28 g (173 mmol) pyruvic acid dropwise and the mixture was stirred at room temperature for 18 hours. The solvent was removed under reduced pressure and the crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 26.2 g (122 mmol, 71 %) of the desired example 1.1 .

[M+H] = 215.1 ; Rt = 0.917 min.

1 .2: 2-(2,5-difluorophenyl)-5-methyl-4H-1 ,2,4-triazol-3-one

To a solution of 1.6 g (7.24 mmol) of example 1 .1 in 24 ml toluene was added 0.73 g (7.24 mmol) triethylamine followed by dropwise addition of 1.99 g (7.24 mmol) diphenyl phosphoryl azide at room temperature. The mixture was refluxed for 3 hours, cooled to room temperature and stirred another 18 hours. Then the mixture was washed with sat. aqueous Na2C03, the aqueous layer was extracted again with EtOAc, the combined organic layer was dried over MgS04, filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 0.79 g (3.74 mmol, 52%) of the desired example 1 .2.

H-NMR (CDCIs, ppm): 1 1.47 (s, 1 H); 7.29 (ddd, J=8.71 Hz, J=5.78 Hz, J=3.15 Hz, 1 H); 7.20 (td, J=9.37 Hz, J=4.75 Hz, 1 H); 7.07 (ddt, J=9.19 Hz, J=7.00 Hz, J=3.36 Hz, 1 H); 2.30 (s, 3 H). [M+H] = 212.1 ; Rt = 0.708 min.

1 .3: 4-(difluoromethyl)-2-(2,5-difluorophenyl)-5-methyl-1 ,2,4-triazol-3-one

To a solution of 19.8 g (93.9 mmol) of example 1.2 in acetonitrile was added 14.3 g (103 mmol) K2CO3 followed by 28.6 g (141 mmol) ethyl bromodifluoroacetate at room temperature. The mixture was refluxed for 6 hours, cooled to room temperature and stirred at room temperature for additional 18 hours. The solvent was removed under reduced pressure, ethyl acetate was added and the mixture was washed with water. The combined organic layer was dried over MgSC , filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 9.83 g (37.7 mmol, 40%) of the desired example 1 .3.

[M+H] = 262.0; Rt = 1 .064 min.

1 .4: 4-(difluoromethyl)-2-(2,5-difluoro-4-nitro-phenyl)-5-methyl- 1 ,2,4-triazol-3-one

To a solution of 0.92 g (3.50 mmol) of example 1.3 in 9 ml. cone, sulfuric acid was added 0.70 ml. of a 1 :1 mixture of cone, sulfuric acid and cone, nitric acid at -10°C dropwise. The mixture was stirred at 0°C for 2 hours and then carefully poured onto ice water. The mixture was extracted with ethyl acetat, the combined organic layer was washed with water and sat.

aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 0.51 g (1 .65 mmol, 47%) of the desired example 1 .4.

H-NMR (CDCIs, ppm): 8.00 (dd, J=9.62 Hz, J=6.48 Hz, 1 H); 7.66 (dd, J=10.80 Hz, J=5.89 Hz, 1 H); 7.06 (t, J=57.83 Hz, 1 H); 2.50 (s, 3 H).

[M+H] = 307.0; Rt = 1.017 min.

1 .5: Ethyl 2-[2-[5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro-2-nitro- phenoxy]phenoxy]acetate

To a solution of 0.75 g (2.45 mmol) of example 1 .4 in 10 ml. dimethyl formamide was added 0.68 g (4.90 mmol) Cs ₂ C0 ₃ followed by 0.53 g (2.70 mmol) ethyl 2-(2-hydroxyphenoxy)acetate (CAS: 99186-63-7) and the mixture was stirred at 70°C for 48 hours. The mixture was cooled to room temperature, water and ethyl acetate were added and the aqueous layer was extracted with ethyl acetate. The combined organic layer was washed with water and sat. aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure to obtain 0.54 g (1.12 mmol, 46%) of the desired compound (example 1 ). H-NMR (CDCI3, ppm): 7.90 (dd, J=9.60 Hz, J=0.48 Hz, 1 H); 7.24 - 7.14 (m, 3 H); 7.06 (ddd, J=8.13 Hz, J=7.41 Hz, J=1.45 Hz, 1 H); 6.98 (t, J=58.13 Hz, 1 H); 6.94 (dd, J=8.14 Hz, J=1.44 Hz, 1 H); 4.60 (s, 2 H); 4.16 (q, J=7.14 Hz, 2 H); 2.42 (s, 3 H); 1 .22 (t, J=7.14 Hz, 3 H).

[M+H] = 483.1 ; Rt = 1 .199 min.

Example 2:

Ethyl 2-[2-[2-amino-5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro- phenoxy]phenoxy]acetate

To a solution of 7.10 g (14.7 mmol) of example 1 in 50 mL ethyl acetate and 25 mL acetic acid was added 4.1 1 g (73.6 mmol) iron powder and the mixture was refluxed for 4 hours. The mixture was cooled to room temperature, fitered and the filter cake was rinsed with ethyl acetate. The filtrate was washed with water and sat. aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure. Toluene was added and the solvent was removed under reduced pressure until no odor of acetic acid was present which gave 6.82 g (15.1 mmol, 103%, contains acetic acid) of the desired example 2.

H-NMR (CDCIs, ppm): 7.06 (ddd, J=8.00 Hz, J=7.00 Hz, J=2.1 1 Hz, 1 H); 7.00 (t, J=58.33 Hz, 1 H); 7.00 - 6.89 (m, 3 H); 6.87 (d, J=6.99 Hz, 1 H);6.59 (d, J=1 1 .14 Hz, 1 H); 4.68 (s, 2 H); 4.34 (br. s., 2 H); 4.22 (q, J=7.14 Hz, 2 H); 2.41 (s, 3 H); 1 .26 (t, J=7.16 Hz, 3 H).

[M+H] = 453.0; Rt = 1 .126 min.

Example 3:

Ethyl 2-[2-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro- phenoxy]phenoxy]acetate

To a solution of 6.80 g (15.0 mmol) of example 2 in 60 mL acetonitrile was added 4.76 g (48.1 mmol) CuCI followed by portionwise addition of 5.64 g (48.1 mmol) isoamyl nitrite and 6.47 g (48.1 mmol) of CuC . The mixture was stirred at room temperature for 18 hours. The solvent was removed under reduced pressure, water was added and the mixture was extracted with ethyl acetate. The combined organic layer was washed with sat. aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 4.65 g (9.86 mmol, 66%) of the desired compound (example 3).

H-NMR (CDCIs, ppm): 7.36 (d, J=9.41 Hz, 1 H); 7.17 - 7.1 1 (m, 1 H); 7.05 - 6.83 (m, 5 H); 4.4 (s, 2 H); 4.20 (q, J=7.14 Hz, 2 H); 2.41 (s, 3 H); 1 .24 (t, J=7.14 Hz, 3 H).

[M+H] = 471.9; Rt = 1 .277 min.

Example 4:

Ethyl 2-[[3-[5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro-2-nitro-phenoxy]-2- pyridyl]oxy]acetate

To a solution of 2.62 g (8.56 mmol) of example 1 .4 in 34 mL tetrahydrofurane was added 2.37 g (17.1 mmol) Cs ₂ C0 ₃ followed by 2.03 g (10.3 mmol) ethyl 2-[(3-hydroxy-2-pyridyl)oxy]acetate (CAS: 353292-81 -6) and the mixture was refluxed for 4 hours. The mixture was cooled to room temperature, filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 2.36 g (4.89 mmol, 57%) of the desired example 4.

H-NMR (CDCIs, ppm): 8.00 (dd, J=4.94, J=1.65 Hz, 1 H); 7.91 (dd, J=9.46, J=0.51 Hz, 1 H); 7.48 (dd, J=7.76 Hz, J=1.63 Hz, 1 H); 7.27 (d, J=6.33 Hz, 1 H); 7.00 (dd, J=7.80 Hz, J=4.89 Hz, 1 H); 6.99 (t, J=58.04 Hz, 1 H); 4.88 (s, 2 H); 4.12 (q, J=7.14 Hz, 2 H); 2.43 (s, 3 H); 1 .21 (t, J=7.14 Hz, 3 H).

[M+H] = 484.1 ; Rt = 1 .191 min.

Example 5:

Ethyl 2-[[3-[2-amino-5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro-phenoxy]-2- pyridyl]oxy]acetate

To a solution of 0.36 g (0.75 mmol) of example 4 in 2.4 mL ethyl acetate and 1.2 mL acetic acid was added 0.21 g (3.73 mmol) iron powder and the mixture was refluxed for 5 hours. The mixture was cooled to room temperature, fitered and the filter cake was rinsed with ethyl acetate. The filtrate was washed with water and sat. aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure. Toluene was added and the solvent was removed under reduced pressure until no odor of acetic acid was present which gave 0.13 g (0.29 mmol, 39%) of the desired example 5.

H-NMR (CDCIs, ppm): 7.85 (dd, J=5.03 Hz, J=1.47 Hz, 1 H); 7.21 (dd, J=7.81 Hz, J=1.54 Hz, 1 H); 7.01 (t, J=58.30 Hz, 1 H);6.96 (d, J=6.92 Hz, 1 H); 6.87 (dd, J=7.68, J=4.90 Hz, 1 H); 6.61 (d, J=1 1 .06 Hz, 1 H); 4.99 (s, 2 H); 4.21 (q, J=7.17 Hz, 2 H); 2.42 (s, 3 H); 1 .26 (t, J=7.1 1 Hz, 3 H).

[M+H] = 454.3; Rt = 1.078 min.

Example 6:

Ethyl 2-[[3-[2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-1 ,2,4-triazol-1 -yl]-4-fluoro-phenoxy]-2- pyridyl]oxy]acetate

To a solution of 4.66 g (10.3 mmol) of example 5 in 50 mL acetonitrile was added 3.26 g (32.9 mmol) CuCI followed by portionwise addition of 3.85 g (32.9 mmol) isoamyl nitrite and 4.42 g (32.9 mmol) of CuC . The mixture was stirred at room temperature for 18 hours. The solvent was removed under reduced pressure, water was added and the mixture was extracted with ethyl acetate. The combined organic layer was washed with sat. aqueous NaCI, dried over MgSC , filtered and the solvent was removed under reduced pressure. The crude product was purified by column chromatography on silica (petrol ether/ethyl acetate) to give 1 .87 g (3.96 mmol, 39%) of the desired example 6.

H-NMR (CDCIs, ppm): 7.92 (dd, J=4.95, J=1.59 Hz, 1 H); 7.36 (d, J=9.35 Hz, 1 H); 7.25 (dd, J=7.84 Hz, J=1.69 Hz, 1 H); 7.10 (d, J=6.63 Hz, 1 H); 7.00 (t, J=58.07 Hz, 1 H); 6.92 (dd, J=7.77 Hz, J=4.93 Hz, 1 H); 4.92 (s, 2 H); 4.16 (q, J=7.16 Hz, 2 H); 2.42 (s, 3 H); 1 .22 (t, J=7.15 Hz, 3 H).

[M+H] = 473.1 ; Rt = 1.139 min.

The compounds listed below in tables 1 and 2 can be prepared similarly to the examples mentioned above.

R ⁶ is H, nd

R ^d are H

Table 1 no R ³ R ⁴ R ⁵ R ⁷ m/z [M+H] Rt [min]

7 F CI OCHs OCH2CH3 488 1 .241

8 CI CI H OCH2CH3 487 1 .316

8a F CN H OCH2CH3 482 1 .186

8b F C(S)NH ₂ H OCH2CH3 516 1 .157

wherein R ¹ is CHF ₂ , R ² is CH ₃ , R ⁶ is H, n is 1 , Q, W, X and Y are O, and

Z is Z ⁴ , wherein R ^a , R ^b and R ^d are H

Table 2

B Use examples The herbicidal activity of the phenyltriazolinones of formula (I) was demonstrated by the following greenhouse experiments:

The culture containers used were plastic flowerpots containing loamy sand with approximately 3.0% of humus as the substrate. The seeds of the test plants were sown separately for each species.

For the pre-emergence treatment, the active ingredients, which had been suspended or emulsified in water, were applied directly after sowing by means of finely distributing nozzles. The containers were irrigated gently to promote germination and growth and subsequently covered with transparent plastic hoods until the plants had rooted. This cover caused uniform germination of the test plants, unless this had been impaired by the active ingredients.

For the post-emergence treatment, the test plants were first grown to a height of 3 to 15 cm, depending on the plant habit, and only then treated with the active ingredients which had been suspended or emulsified in water. For this purpose, the test plants were either sown directly and grown in the same containers, or they were first grown separately as seedlings and transplanted into the test containers a few days prior to treatment.

Depending on the species, the plants were kept at 10 - 25°C or 20 - 35°C, respectively.

The test period extended over 2 to 4 weeks. During this time, the plants were tended, and their response to the individual treatments was evaluated. Evaluation was carried out using a scale from 0 to 100. 100 means no emergence of the plants, or complete destruction of at least the aerial moieties, and 0 means no damage, or normal course of growth. A good herbicidal activity is given at values of at least 70 and a very good herbicidal activity is given at values of at least 85.

The plants used in the greenhouse experiments were of the following species:

At an application rate of 16 g/ha, the compounds (examples) 3, 6, 7, 8, 10 and 1 1 applied by the post-emergence method, showed very good herbicidal activity against AMARE, CHEAL, ECHCG and SETVI.

At an application rate of 16 g/ha, the compound (example) 8a applied by the post-emergence method, showed very good herbicidal activity against AMARE, ECHCG and SETVI.

At an application rate of 16 g/ha, the compound (example) 9 applied by the post-emergence method, showed very good herbicidal activity against AMARE, ECHCG and SETVI, and good herbicidal activity against CHEAL. At an application rate of 16 g/ha, the compound (example) 12 applied by the post-emergence method, showed very good herbicidal activity against AMARE and SETVI, and good herbicidal activity against CHEAL.

Comparison examples

Comparison of the herbicidal activity of example 3 of the present invention and compound A known of US 5, 084, 085 at an application rate of 16 g/ha post emergence

Comparison of the herbicidal activity of example 3 of the present invention and compound A known of US 5, 084, 085 at an application rate of 16 g/ha pre-emergence

Table 5 Comparison of the herbicidal activity of example 3 of the present invention and compound B known of US 5, 084, 085 (table 1 , compound 44) at an application rate of 4 g/ha post emergence (greenhouse)

Comparison of the herbicidal activity of example 3 of the present invention and compound B known of US 5, 084, 085 (table 1 , compound 44) at an application rate of 16 g/ha pre-emergence (greenhouse)

The data disclosed in tables 3 to 6 clearly demonstrate the superior herbicidal activity of the inventive compounds of formula (I) of the present invention over the compounds known from the prior art.

The change of the substitution pattern corresponding to X and Q of the present invention from para- and meta-position as disclosed in US 5,084,085 (position of R ² ) to ortho-position according to the present invention (Z is attached to X and Q via vicinal carbon atoms) leads to a much better herbicidal activity as achieved by the compounds known from US 5,084,085, wherein the specifically mentioned compounds have either meta or para disubstituted groups corresponding to X and Q on the phenyl / pyridine ring.