Title:
IMINE GUANIDINE DERIVATIVE CONTAINING FURAN SKELETON, AND PREPARATION AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2019/101160
Kind Code:
A1
Abstract:
Disclosed are an imine guanidine derivative containing a furan skeleton, the derivative comprising 2,5-furan diimine guanidine, an acceptable 2,5-furan diimine guanidine salt, and a solvate thereof. Also disclosed are a preparation method for 2,5-furan diimine guanidine, and the use thereof as an acidic gas absorbent and an anionic precipitant. The 2,5-furan diimine guanidine of the present invention can be conveniently regenerated and recycled after absorbing acidic gases, and the regenerating energy consumption thereof is low, the cost is reduced and the efficiency is improved, and the preparation method therefor is simple, the reaction conditions are mild, the reaction time is short, the yield is high, and the cost is low, and it is easy to realize large-scale preparation.
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Inventors:
ZOU YONG (CN)
LIU JIE (CN)
LUO XIANG (CN)
SHENG JIANFEI (CN)
SONG XIANHENG (CN)
WEI WENTAO (CN)
LI JIANHENG (CN)
LIU JIE (CN)
LUO XIANG (CN)
SHENG JIANFEI (CN)
SONG XIANHENG (CN)
WEI WENTAO (CN)
LI JIANHENG (CN)
Application Number:
PCT/CN2018/117144
Publication Date:
May 31, 2019
Filing Date:
November 23, 2018
Export Citation:
Assignee:
UNIV SUN YAT SEN (CN)
International Classes:
C07D307/52; B01D53/14
Domestic Patent References:
| WO2008068411A2 | 2008-06-12 | |||
| WO2006009600A2 | 2006-01-26 | |||
| WO2016089561A1 | 2016-06-09 | |||
| WO2018226368A1 | 2018-12-13 |
Foreign References:
| US20120027664A1 | 2012-02-02 | |||
| CN108003120A | 2018-05-08 | |||
| US20180134655A1 | 2018-05-17 |
Other References:
RADU CUSTELCEAN: "Aqueous Sulfate Separation by Sequestration of [(S04)2(H20)4]4-Clusters within Highly Insoluble Imine-Linked Bis-Guanidi- nium Crystals", CHEMISTRY - A EUROPEAN JOURNAL, vol. 22, no. 6, 8 December 2015 (2015-12-08), pages 1997 - 2003, XP055538220, ISSN: 0947-6539
SEIPP CHARLES A: "C02 Capture from Ambient Air by Crystallization with a Guanidine Sorbent", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 56, no. 4, 21 December 2016 (2016-12-21), pages 1042 - 1045, XP55613704, ISSN: 1433-7851
SEIPP CHARLES A: "C02 Capture from Ambient Air by Crystallization with a Guanidine Sorbent", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 56, no. 4, 21 December 2016 (2016-12-21), pages 1042 - 1045, XP55613704, ISSN: 1433-7851
Attorney, Agent or Firm:
GUANGZHOU HUAXUE INTELLECTUAL PROPERTY AGENCY CO., LTD. (CN)
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