Title:
IMMOBILISED LIGANDS DERIVED FROM ETHYLENEDIAMINE
Document Type and Number:
WIPO Patent Application WO2004014551
Kind Code:
A3
Abstract:
An immobilised nitrogen-containing ligand is described comprising the reaction product of a compound of formula (I) wherein R<5>, R<6>, R<7> and R<8> are independently hydrogen, a saturated or unsaturated C1-C10 alkyl group, an aryl group, a urethane group, a sulphonyl group or form an imine group, R<1>, R<2>, R<3> , and R<4> are independently hydrogen, a saturated or unsaturated C1-C10 alkyl group or an aryl group and at least one of R<1>, R<2>, R<3> and R<4> is functionalised with a functional group, and a solid support having a site capable of reacting with said functional group. The nitrogen-containing ligand is useful for preparing immobilised catalysts for performing e.g. asymmetric catalysis.
Inventors:
HEMS WILLIAM PATRICK (GB)
XIAO JIANLIANG (GB)
CHEN WEIPING (GB)
XIAO JIANLIANG (GB)
CHEN WEIPING (GB)
Application Number:
PCT/GB2003/003306
Publication Date:
June 17, 2004
Filing Date:
July 30, 2003
Export Citation:
Assignee:
JOHNSON MATTHEY PLC (GB)
HEMS WILLIAM PATRICK (GB)
XIAO JIANLIANG (GB)
CHEN WEIPING (GB)
HEMS WILLIAM PATRICK (GB)
XIAO JIANLIANG (GB)
CHEN WEIPING (GB)
International Classes:
B01J31/16; B01J31/18; C07B53/00; C07B61/00; C07C29/145; C07C33/18; C07C209/42; C07C211/27; C07C211/29; C07C213/02; C07C217/56; C07C217/64; C07C247/10; C07C251/02; C07D301/03; B01J31/24; (IPC1-7): B01J31/16; B01J31/18; C07B53/00; C07C29/136; C07C211/10; C07C251/02; C07C209/42; C07C5/02; C07B37/04; C07D301/03; C07D301/19; C07D301/32; C07D203/06; C07B37/12; C07C247/06
Domestic Patent References:
| WO2001044153A1 | 2001-06-21 |
Other References:
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BIGI, FRANCA ET AL: "Heterogeneous enantioselective epoxidation of olefins catalysed by unsymmetrical (salen)Mn(III) complexes supported on amorphous or MCM-41 silica through a new triazine-based linker", CHEMICAL COMMUNICATIONS (CAMBRIDGE, UNITED KINGDOM) (2002), (7), 716-717, 21 March 2002 (2002-03-21), XP002265073
ALLEN ANNIS D ET AL: "POLYMER-SUPPORTED CHIRAL CO(SALEN) COMPLEXES: SYNTHETIC APPLICATIONS AND MECHANISTIC INVESTIGATIONS IN THE HYDROLYTIC KINETIC RESOLUTION OF TERMINAL EPOXIDES", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL SOCIETY, LONDON, GB, vol. 121, no. 17, 1999, pages 4147 - 4154, XP001019176, ISSN: 0368-1769
ADIMA A ET AL: "CHIRAL ORGANIC-INORGANIC SOLIDS AS ENANTIOSELECTIVE CATALYTIC MATERIALS", JOURNAL OF MATERIALS CHEMISTRY, THE ROYAL SOCIETY OF CHEMISTRY, CAMBRIDGE, GB, vol. 7, no. 12, 1 December 1997 (1997-12-01), pages 2331 - 2333, XP000736603, ISSN: 0959-9428
FERRAND A ET AL: "Hydrophilic diamine ligands for catalytic asymmetric hydrogenation of C@?O bonds", TETRAHEDRON: ASYMMETRY, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 13, no. 13, 19 July 2002 (2002-07-19), pages 1379 - 1384, XP004374310, ISSN: 0957-4166
"Organic Reactions vol. IV", 1948, WILEY, NEW YORK US, XP009023049
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; LI, TING-YOU ET AL: "Studies on the stereoselectivity of pinacol coupling reaction mediated by TiCl4-Mg", XP002265075, retrieved from STN Database accession no. 134:193158
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; SCHNEIDER, HANS JOERG ET AL: "1,2- Diphenyl - 1, 2 - diaminoethane derivatives as scissors shaped allosteric receptors", XP002265076, retrieved from STN Database accession no. 117:7579
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; OGRETIR, CEMIL ET AL: "Reaction of 3,4-diformyl-2,5-dimethylpyrrole with 1,2-(substituted) diphenyl - 1, 2 - diaminoethanes", XP002265077, retrieved from STN Database accession no. 129:175629
KARL, JOHANN ET AL: "Ring-substituted [1,2-bis(4-hydroxyphenyl)ethylenediamine]dichloropl atinum(II) complexes: compounds with a selective effect on the hormone-dependent mammary carcinoma", JOURNAL OF MEDICINAL CHEMISTRY (1988), 31(1), 72-83, XP002265074
BIGI, FRANCA ET AL: "Heterogeneous enantioselective epoxidation of olefins catalysed by unsymmetrical (salen)Mn(III) complexes supported on amorphous or MCM-41 silica through a new triazine-based linker", CHEMICAL COMMUNICATIONS (CAMBRIDGE, UNITED KINGDOM) (2002), (7), 716-717, 21 March 2002 (2002-03-21), XP002265073
ALLEN ANNIS D ET AL: "POLYMER-SUPPORTED CHIRAL CO(SALEN) COMPLEXES: SYNTHETIC APPLICATIONS AND MECHANISTIC INVESTIGATIONS IN THE HYDROLYTIC KINETIC RESOLUTION OF TERMINAL EPOXIDES", JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL SOCIETY, LONDON, GB, vol. 121, no. 17, 1999, pages 4147 - 4154, XP001019176, ISSN: 0368-1769
ADIMA A ET AL: "CHIRAL ORGANIC-INORGANIC SOLIDS AS ENANTIOSELECTIVE CATALYTIC MATERIALS", JOURNAL OF MATERIALS CHEMISTRY, THE ROYAL SOCIETY OF CHEMISTRY, CAMBRIDGE, GB, vol. 7, no. 12, 1 December 1997 (1997-12-01), pages 2331 - 2333, XP000736603, ISSN: 0959-9428
FERRAND A ET AL: "Hydrophilic diamine ligands for catalytic asymmetric hydrogenation of C@?O bonds", TETRAHEDRON: ASYMMETRY, ELSEVIER SCIENCE PUBLISHERS, AMSTERDAM, NL, vol. 13, no. 13, 19 July 2002 (2002-07-19), pages 1379 - 1384, XP004374310, ISSN: 0957-4166
"Organic Reactions vol. IV", 1948, WILEY, NEW YORK US, XP009023049
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; LI, TING-YOU ET AL: "Studies on the stereoselectivity of pinacol coupling reaction mediated by TiCl4-Mg", XP002265075, retrieved from STN Database accession no. 134:193158
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; SCHNEIDER, HANS JOERG ET AL: "1,2- Diphenyl - 1, 2 - diaminoethane derivatives as scissors shaped allosteric receptors", XP002265076, retrieved from STN Database accession no. 117:7579
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; OGRETIR, CEMIL ET AL: "Reaction of 3,4-diformyl-2,5-dimethylpyrrole with 1,2-(substituted) diphenyl - 1, 2 - diaminoethanes", XP002265077, retrieved from STN Database accession no. 129:175629
KARL, JOHANN ET AL: "Ring-substituted [1,2-bis(4-hydroxyphenyl)ethylenediamine]dichloropl atinum(II) complexes: compounds with a selective effect on the hormone-dependent mammary carcinoma", JOURNAL OF MEDICINAL CHEMISTRY (1988), 31(1), 72-83, XP002265074
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