Title:
IMMOBILIZED CATALYST, PRODUCTION METHOD FOR IMMOBILIZED CATALYST, PRODUCTION METHOD FOR FORMATE, AND PRODUCTION METHOD FOR FORMIC ACID
Document Type and Number:
WIPO Patent Application WO/2023/163048
Kind Code:
A1
Abstract:
The present invention pertains to: an immobilized catalyst obtained by immobilizing a metal complex in a polymer, said immobilized catalyst including a polymer represented by general formula (1) set forth in the description; a production method for the immobilized catalyst; a production method for a formate in which, in the presence of a solvent, a catalyst is used to produce a formate by reacting hydrogen with at least one compound selected from the group consisting of carbon dioxide, bicarbonates and carbonates, said catalyst being the above-mentioned immobilized catalyst; and a production method for formic acid that includes a step in which a formate is produced according to the production method for a formate, and a step in which at least a portion of the formate is protonated to generate formic acid.
Inventors:
HIRANO MAKOTO (JP)
MATSUDA HIROKAZU (JP)
PIDKO EVGENY ALEXANDROVICH (NL)
FILONENKO GEORGY ALEXANDROVICH (NL)
REBREYEND CHRISTOPHE (NL)
TOSSAINT ALEX (NL)
MATSUDA HIROKAZU (JP)
PIDKO EVGENY ALEXANDROVICH (NL)
FILONENKO GEORGY ALEXANDROVICH (NL)
REBREYEND CHRISTOPHE (NL)
TOSSAINT ALEX (NL)
Application Number:
PCT/JP2023/006493
Publication Date:
August 31, 2023
Filing Date:
February 22, 2023
Export Citation:
Assignee:
NITTO DENKO CORP (JP)
International Classes:
B01J31/24; B01J37/04; C07B61/00; C07C51/00; C07C51/02; C07C53/06
Domestic Patent References:
| WO2015166935A1 | 2015-11-05 |
Foreign References:
| JP2022513283A | 2022-02-07 | |||
| JP2013185150A | 2013-09-19 | |||
| JP2016539793A | 2016-12-22 | |||
| KR20200111395A | 2020-09-29 |
Other References:
KONRATH, ROBERT ET AL.: "Preparation of a Series of Supported Nonsymmetrical PNP- Pincer Ligands and the Application in Ester Hydrogenation", C HEMISTRY-A EUROPEAN JOURNAL, vol. 25, 2019, pages 15341 - 15350, XP071850971, DOI: 10.1002/chem.201903379
ARASHIBA KAZUYA, ITABASHI TAKAYUKI, NAKAJIMA KAZUNARI, NISHIBAYASHI YOSHIAKI: "Synthesis and Catalytic Reactivity of Polystyrene-supported Molybdenum Pincer Complexes toward Ammonia Formation", CHEMISTRY LETTERS, CHEMICAL SOCIETY OF JAPAN,NIPPON KAGAKUKAI, JP, vol. 48, no. 7, 5 July 2019 (2019-07-05), JP , pages 693 - 695, XP093088120, ISSN: 0366-7022, DOI: 10.1246/cl.190193
ZHAO YAN, KIM SOOJIN, EOM YU KYUNG, VALANDRO SILVANO R., SCHANZE KIRK S.: "Polymer Chromophore–Catalyst Assembly for Photocatalytic CO 2 Reduction", ACS APPLIED ENERGY MATERIALS, vol. 4, no. 7, 26 July 2021 (2021-07-26), pages 7030 - 7039, XP093088122, ISSN: 2574-0962, DOI: 10.1021/acsaem.1c01100
ARASHIBA KAZUYA, ITABASHI TAKAYUKI, NAKAJIMA KAZUNARI, NISHIBAYASHI YOSHIAKI: "Synthesis and Catalytic Reactivity of Polystyrene-supported Molybdenum Pincer Complexes toward Ammonia Formation", CHEMISTRY LETTERS, CHEMICAL SOCIETY OF JAPAN,NIPPON KAGAKUKAI, JP, vol. 48, no. 7, 5 July 2019 (2019-07-05), JP , pages 693 - 695, XP093088120, ISSN: 0366-7022, DOI: 10.1246/cl.190193
ZHAO YAN, KIM SOOJIN, EOM YU KYUNG, VALANDRO SILVANO R., SCHANZE KIRK S.: "Polymer Chromophore–Catalyst Assembly for Photocatalytic CO 2 Reduction", ACS APPLIED ENERGY MATERIALS, vol. 4, no. 7, 26 July 2021 (2021-07-26), pages 7030 - 7039, XP093088122, ISSN: 2574-0962, DOI: 10.1021/acsaem.1c01100
Attorney, Agent or Firm:
EIKOH, P.C. (JP)
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