[0001] This application claims priority fro U.S. Provisional Patent

Application No. 61/834,081 filed on June 12, 2013 entitled .T -CETLING LIQUID DESICCANT SYSTEM FOR DEHUMIDIFICATION, which is hereby incorporated by reference.

BACKGROUND

[0002] The present application relates generally to the use of liquid desiccant membrane modules to dehumidify and cool an air stream entering a space. More specifically, the application relates to the use of micro-porous membranes to separate the liquid desiccant from the air stream wherein the fluid streams (air, heat transfer fluids, and liquid desiccants) are made to flow turbulently so that high heat and moisture transfer rates between ihe fluids can occur. The application further reiaies to the application of such membrane modules to locally dehumidify spaces in buildings with the support of external cooling and heating sources by placing the membrane modules in or near suspended ceilings.

[0003] Liquid desiccants have been used in parallel to conventional vapor compression Ffv AC equipment to help reduce humidity in spaces, particularly in spaces that either require large amounts of outdoor air or that have large humidity loads inside the building space itself. Humid climates, such as for example Miami, FL require a large amount of energy to properly treat (dehumidify and cool) the fresh air that is required for a space's occupant comfort. Conventional vapor compression systems have only a limited ability to dehumidify and tend to overcool the air, oftentimes requiring energy intensive reheat systems, which significantly increases ihe overall energy costs because reheat adds an addiiional heat-load to the cooling coil or reduces the net-cooling provided to the space. Liquid desiccant systems have been used for many years and are generally quite efficient at removing moisture from the air stream. However, liquid desiccant systems generally use concentrated salt solutions such as solutions of LiCi, LiBr or CaC12 and water. Such brines are strongly corrosive, even in small quantities, so numerous attempts have been made over the years to prevent desiccant carry-over to the air stream that is to be treated. One approach - generally categorized as closed desiccant systems - is commonly used in equipment dubbed absorption chillers, places the brine in a vacuum vessel which then contains the desiccant. Since the air is not directly exposed to the desiccant, such systems do not ha v e any risk of carry-over of desiccant particles to the supply air stream. Absorpt on chillers however tend to be expensive both in terms of first cost and maintenance costs. Open desiccant systems allow a direct contact between the air stream and the desiccant, generally by flowing the desiccant o ver a packed bed similar to those used in cooling towers. Such packed bed systems suffer from other disadvantages besides still having a carry-over risk: the high resistance of the packed bed to the air stream results in larger fan power and pressure drops across the packed bed, thus requiring more energy. Furthermore, the dehuniidification process is adiabatic, since the heat of condensation that is released during the absorption of water vapor into the desiccant has no place to go. As a result both the desiccant and the air stream are heated by the release of the heat of condensation. This results in a warm, dry air stream where a cool dry air stream was desired, necessitating the need for a post-dehumidification cooling coil. Wanner desiccant is also exponentially less effective at absorbing water vapor, which forces the system to supply much larger quantities of desiccant to the packed bed which in turn requires larger desiccant pump power, since the desiccant is doing double duty as a desiccant as well as a heat transfer fluid. The larger desiccant flooding rate also results in an increased risk of desiccant carryover. Generally air flow rates in open desiccant systems need to be kept well below the turbulent region (at Reynolds numbers of less than -2,400) to prevent carry-over of desiccant to the air stream.

[0004] Modern multi-story buildings typically separate the outside air supply that is required for occupant comfort as well as air quality concerns from the sensible cooling or heating that is also required to keep the space at a required temperature. Oftentimes in such buildings the outside air is provided by a duct system in a suspended ceiling to each and every space from a central outside air handling unit. The outside air handling unit dehumidifies and cools the air, typically to a temperature slightly below room neutral temperatures (65--70F) and a relative humidity level of about 50% and delivers the treated outside air to each space. In addition, in each

9 space one or more fan-coil units (often called Variable Air Volume units) are installed that remove some air from the space, lead it through a water cooled or heated coils and bring it back into the space,

[0005] Between the outside air handling unit and the fan-coil units, the space conditions can usually be maintained at proper levels. However, it is well possible that in certain conditions, for example if outside air humidity is high, or if a significant amount of humidity is created within the space or if windows are opened allowing for excess air to enter the space, the humidity in the space raises to the point where the fan-coil in the suspended ceiling starts to condense water on the cold surfaces of the coil, leading to potential water damage and mold growth. Generally condensation in a ceiling mounted fan-coil is undesirable for that reason.

[0006] There thus remains a need for a system that provides a cost efficient, manufacturab!e and thermally efficient method to capture moisture from an air stream in a ceiling location, while simultaneously cooling such an air stream and while also eliminating the risk of condensation of such an air stream on cold surfaces.

Furthermore such a system needs to be compatible with existing building

infrastructure and physical sizes need to be comparable to existing fan-coil units.

BRIEF SUMMARY

[0007] Provided herein are methods and systems used for the efficient dehumidification of an air stream using a liquid desiccant. In accordance with one or more embodiments, the liquid desiccant flows down the face of a thin support plate as a falling film and the liquid desiccant is covered by a membrane, while an air stream is blown over the membrane. In some embodiments, a heat transfer fluid is directed to the side of the support plate opposite the liquid desiccant. In some embodiments, the heat transfer fluid is cooled so that the support plate is cooled which in turn cools the liquid desiccant on the opposite side of the support plate. In some embodiments, the cool heat transfer fluid is provided by a central chilled water facility. In some embodiments, the thus cooled liquid desiccant cools the air stream. In some embodiments, the liquid desiccant is a halide salt solution. In some embodiments, the liquid desiccant is Lithium Chloride and water. In some embodiments, the liquid desiccant is Calcium Chloride and water. In some embodiments, the liquid desiccant is a mixture of Lithium Chloride, Calcium Chloride and water. In some

embodiments, the membrane is a micro-porous polymer membrane. In some embodiments, the heat transfer fluid is heated so that the support plate is heated which in turn heats the liquid desiccant. in some embodiments, the thus heated liquid desiccani heats the air stream. In some embodiments, the hot heat transfer fluid is provided by a central hot water facility such as a boiler or combined heat and power facility. In some embodiments, the liquid desiccant concentration is controlled to be constant. In some embodiments, the concentration is held at a level so that the air stream o ver the membrane exchanges water vapor with the liquid desiccani in such a way that the air stream has a constant relative humidity. In some embodiments, the liquid desiccant is concentrated so that the air stream is dehumidified, in some embodiments, the liquid desiccant is diluted so that the air stream is humidified. In some embodiments, the membrane, liquid desiccani plate assembly is placed at a ceiling height location. In some embodiments, the ceiling height location is a suspended ceilmg. In some embodiments, an air stream is removed from below the ceiling height location, directed over the membrane/liquid desiccant plate assembly where the air stream is heated or cooled as the case may be and is humidified or dehumidified as the case may be and directed back to the space below the ceiling height location.

[0008] In accordance with one or more embodiments, the liquid desiccant is circulated by a liquid desiccani pumping loop. In some embodiments, the liquid desiccant is collected near the bottom of the support plate into a collection tank, in some embodiments, the liquid desiccant in the collection tank is refreshed by a liquid desiccani distribution system. In some embodiments, the heat transfer fluid is thermally coupled through a heat exchanger to a main building heat transfer fluid system. In some embodiments, the heat transfer fluid system is a chilled water loop system. In some embodiments, the heat transfer fluid system is a hot water loop system or a steam loop system.

[0009] In accordance with one or more embodiments, the ceiling height mounted liquid desiccant membrane plate assembly receives concentrated or diluted liquid desiccant from a central regeneration facility. In some embodiments, the regeneration facility is a central facility serving multiple ceiling height mounted liquid desiccani membrane plate assemblies. In some embodiments, the central regeneration facility also serves a liquid desiccani Dedicated Outside Air System (DOAS). In some embodiments, the DOAS provides outside air to the various spaces in a building. In some embodiments, the DOAS is a conventional DOAS not utilizing liquid desiccants.

[0010] In accordance with one or more embodiments, a liquid desiccani DOAS provides a stream of treated outside air to a duct distribution system in a building. In some embodiments, the liquid desiccant DOAS comprises several sets of liquid desiccant membrane plate assemblies with heat transfer fluids for removing or adding heat to the liquid desiccants. In some embodiments, a first set of liquid desiccant membrane plates receives a stream of outside air. In some embodiments, the first set of liquid desiccant membrane plates also receives a cold heat transfer Iluid. In some embodiments, the air stream leaving the first set of liquid desiccant membrane plates is directed to a second set of liquid desiccant membrane plates, which also receives a cold heat transfer fluid. In some embodiments, the second set of plates receives a concentrated liquid desiccant. In some embodiments, the concentrated liquid desiccant is provided by a central liquid desiccani regeneration facility. In some embodiments, the air treated by the second set of liquid desiccani membrane plates is directed towards a building and distributed to various spaces therein. In some embodiments, an amount of air is removed from said spaces and returned back to the liquid desiccani DOAS. In some embodiments, the return air is directed to a third set of liquid desiccant membrane plates. In some embodiments, the third set of liquid desiccant membrane plates receives a hot heat transfer fluid. In some embodiments, the hot heat transfer fluid is provided by a central hot water facility. In some embodiments, the central hot water facility is a boiler room, or a central heat and power facility. In some embodiments, the first set of liquid desiccant membrane plates receives a liquid desiccant from the third set of liquid desiccant membrane plates through a heat exchanger. In some embodiments, the liquid desiccant is circulated by a liquid desiccani pumping system, and utilizes one or more liquid desiccant collection tanks.

[001 1] In accordance with one or more embodiments, a liquid desiccant DOAS provides a stream of treated outside air to a duct distribution system in a building. In some embodiments, the liquid desiccant DOAS comprises several sets of liquid desiccant membrane plate assemblies with heat transfer fluids for removing or adding heat to the liquid desiccants. In some embodiments, a first set of liquid desiccant membrane plates receives a stream of outside air. In some embodiments, the air stream leaving the first set of liquid desiccant membrane plates is directed to a second set of liquid desiccant membrane plates, which receive a cold heat transfer fluid. In some embodiments, the second set of plates receives a concentrated liquid desiccant. In some embodiments, the concentrated liquid desiccant is provided by a central liquid desiccant regeneration facility. In some embodiments, the air treated by the second set of liquid desiccant membrane plates is directed towards a building and distributed to various spaces therein. In some embodiments, an amount of air is removed from said spaces and returned back to the liquid desiccant DOAS. In some embodiments, the return air is directed to a third set of liquid desiccant membrane plates. In some embodiments, the first set of liquid desiccant membrane plates receives a liquid desiccant from the third set of liquid desiccant membrane plates. In some embodiments, the first set of liquid desiccant membrane plates also receives a heat transfer fluid from the third set of plates. In some embodiments, the system recovers both sensible and latent energy from the return air stream entering the third set of liquid desiccant membrane plates. In some embodiments, the liquid desiccant is circulated by a liquid desiccant pumping system, and utilizes one or more liquid desiccant collection tanks. In some embodiments, the heat transfer fluid is circulated between the first set of liquid desiccant membrane plates and the third set of liquid desiccant membrane plates.

[0012] In accordance with one or more embodiments, a liquid desiccant DOAS provides a stream of treated outside air to a duct distribution system in a building. In some embodiments, the liquid desiccant DOAS comprises several sets of liquid desiccant membrane plate assemblies with heat transfer fluids for removing or adding heat to the liquid desiccants. In some embodiments, a first set of liquid desiccant membrane plates receives a stream of outside air. In some embodiments, the air stream leaving the first set of liquid desiccant membrane plates is directed to a second set of liquid desiccant membrane plates, which receive a cold heat transfer fluid. In some embodiments, the second set of plates recei v es a concentrated liquid desiccant. In some embodiments, the concentrated liquid desiccant is provided by a central liquid desiceant regeneration facility. In some embodiments, the air treated by the second sei of liquid desiceant membrane plates is directed towards a building and distributed to various spaces therein. In some embodiments, an amount of air is removed from said spaces and returned back to the liquid desiceant DOAS. In some embodimenis, this return air is directed to a third set of liquid desiceant membrane piaies. In some embodiments, the first set of liquid desiceant membrane plates receives a liquid desiceant from the third set of liquid desiceant membrane. In some embodiments, the first set of liquid desiceant membrane plates also receives a heat transfer fluid from the third set of plates. In some embodimenis, the system recovers both sensible and latent energy from the return air stream entering the third set of liquid desiceant membrane plates. In some embodiments, the air leaving the third set of liquid desiceant membrane plates is directed to a fourth set of liquid desiceant membrane plates. In some embodiments, the fourth set of liquid desiceant membrane plates receives a hot heat transfer fluid from a central hot water facility. In some embodiments, the hot heat transfer fluid received by the fourth set of liquid desiceant membrane plates is used to regenerate the liquid desiceani present in the fourth set of liquid desiceant membrane plates. In some embodiments, the concentrated liquid desiceant from the fourth set of liquid desiceant membrane plates is directed to the second set of liquid desiceant membrane plates by a liquid desiceant pumping system through a heat exchanger. In some embodiments, the liquid desiceant between the first and third set of liquid desiceant membrane plates is circulated by a liquid desiceant pumping system, and utilizes one or more liquid desiceant collection tanks. In some embodiments, a heat transfer fluid is circulated between the first and third set of liquid desiceant membrane plates so as to transfer sensible energy between the first and third set of liquid desiceant membrane plates,

[0013] In accordance with one or more embodiments, a liquid desiceant DOAS provides a stream of treated outside air to a duct distribution system in a building. In some embodiments, the liquid desiceant DOAS comprises several sets of liquid desiceani membrane plate assemblies and conventional cooling or heating coils with heat transfer fluids for removing or adding heat to the liquid desiccants and heating and cooling coils. In some embodiments, a first cooling coil receives a stream of outside air. In some embodiments, the first cooling coil also receives a cold heat transfer fluid in such a way as to condense moisture out of the outside air stream. In some embodiments, the air stream leaving the first set cooling coil is directed to a first set of liquid desiccant membrane plates, which also recei ve a cold heat transfer fluid. In some embodiments, the first set of liquid desiccant membrane plates receives a concentrated liquid desiccant. In some embodiments, the air treated by the first set of liquid desiccant membrane plates is directed towards a building and distributed to various spaces therein. In some embodiments, an amount of air is removed from said spaces and returned back to the liquid desiccant DOAS. In some embodiments, this return air is directed to a first hot water coil. In some embodiments, the first hot water coils receives hot water from a central hot water facility. In some embodiments, the hot water facility is a central boiler system. In some embodiments, the central hot water system is a combined heat and power facility, m some embodiments, the air leaving the first hot water coil is directed to a second set of liquid desiccant membrane plates. In some embodiments, the second set of liquid desiccant membrane plates also receives a hot heat transfer fluid from a central hot water facility. In some embodiments, the hot heat transfer fluid received by the second set of liquid desiccant membrane plates is used io regenerate the liquid desiccani preseni in the second set of liquid desiccant membrane plates. In some embodiments, the concentrated liquid desiccant from the second set of liquid desiccant membrane plates is directed to the first set of liquid desiccant membrane plates by a liquid desiccant pumping system through a heat exchanger. In some embodiments, the liquid desiccant between the first and second set of liquid desiccant membrane plate is circulated by a liquid desiccant pumping system, and utilizes one or more liquid desiccant collection tanks.

[0014] In accordance with one or more embodiments, a liquid desiccant DOAS is providing a stream of treated outside air to a duct distribution system in a building. In some embodiments, the liquid desiccant DOAS comprises a first and a second set of liquid desiccant membrane module assemblies and a conventional water-to-water eat pump system. In some embodiments, the water-to-water heat pump system is thermally coupled to a building's chilled water loops. In some embodiments, one of a first set of membrane modules is exposed to the outside air is also thermally coupled to the buildings chilled water loop. In some embodiments, the water-to- water heat pump is coupled so that it cools the building cooling water before it reaches the first set of membrane modules resulting in a lower supply air temperature from the membrane modules. In some embodiments, the water-to-water heap pump is coupled so that it cools the building cooling water after is has interacted with the first set of membrane modules resulting in a higher supply air temperature to the building. In some embodiments, the system is set up to control the temperature of the supply air to the building by controlling how the water from the building flows to the water-to-water heat pump and the first set of membrane modules. In accordance with one or more embodiments, the water- to -water heat pump provides hot water or hot heat transfer fluid to a second set of membrane modules. In some embodiments, the heat form the hot heat transfer fluid is used to regenerate a liquid desiccant in the membrane modules. In some embodiments, the second set of membrane modules receives return air from the building. In some embodiments, the second set of membrane modules receives outside air from the building. In some embodiments, the second set of membrane modules receives a mixture of return air and outside air. In some embodiments, the outside air directed to the first set of membrane modules is pre- treated by a first section of an energy recovery system and air directed to the second set of membrane modules is pre -treated by a second section of an energy recovery system. In some embodiments, the energy recovery system is a desiccant wheel, an enthalpy wheel, a heat wheel or the like. In some embodiments, the energy recovery system comprises a set of heat pipes or an air to air heat exchanger or any convenient energy recovery device. In some embodiments, the energy recovery is accomplished with a third and a fourth set of membrane modules wherein ihe sensible and/or the latent energy is recovered and passed between the third and fourth set of membrane modules.

[0015] In no way is the description of the applications intended to limit the disclosure to these applications. Many construction variations can be envisioned to combine the various elements mentioned above each with its own advantages and disadvantages. The present disclosure in no way is limited to a particular set or combination of such elements.

BRIEF DESCRIPTION OF THE DRAWINGS

[0016] FIG. 1 illustrates a multistory building wherein a central outside air- handling unit provides fresh air to spaces and a central chiller plant provides cold or hot water for cooling or heating the spaces. [0017] FIG. 2 shows a detailed schematic of a ceiling mounted fan-coil unit as used in FIG. 1.

[0018] FIG. 3 shows a 3-way liquid desiccant membrane module that is able to dehumidify and cool a horizontal air stream.

[0019] FIG. 4 iliusiraies a concepi of a single membrane plate structure in the liquid desiccant membrane module of FIG. 3.

[0020] FIG. 5 illustrates a liquid desiccant membrane dehumidification and cooling system in the prior art that is able to treat 100% outside air.

[0021 ] FIG. 6 illustrates a ceiling mounted membrane dehumidification module that is able to cool and dehumidify an air stream in a ceiling mounted location in accordance with one or more embodiments.

[0022] FIG. 7 shows how the system of FIG. 6 can be mounted in a multistory building simply by replacing the existing fan-coil units in accordance with one or more embodiments.

[0023] FIG. 8 shows a central air handling unit that uses a set of membrane liquid desiccant modules for energy recovery and a separate module for treating the outside air required for space conditioning in accordance with one or more embodiments.

[0024] FIG. 9 shows an alternate implementation of the system of FIG. 8 where only chilled water or hoi water needs to be provided but not both

simultaneously in accordance with one or more embodiments.

[0025] FIG. 10 sho ws an alternate implementation of the system of FIG. 8 where both cold water and hot water are used simultaneously in accordance with one or more embodiments.

[0026] FIG. 1 1 shows an alternate implementation of the system of FIG. 8 where the chilled water loop is used for pre-cooiing air going to the conditioner and the hot water loop is used for preheating air going to ihe regenerator in accordance with one or more embodiments. [0027] FIG. 12 illustrates an example process (psychrometric) chart of an energy recovery process using 3-way liquid desiccant modules in accordance with one or more embodiments,

[0028] FIG. 13 illustrates a way to provide integration of the central air handling units of FIGS. 8- 10 with an existing building cold water system, wherein the central air handling units use a local compressor system just generating heat for regeneration of liquid desiccant in accordance with one or more embodiments.

[0029] FIG. 14 illustrates the effect that the system of FIG. 13 has on the water temperatures in ihe building and air handling unit in accordance with one or more embodiments.

DETAILED DESCRIPTION

[0030] FIG. 1 depicts a typical implementation of an air conditioning system for a modern building wherein the outside air and the space cooling and heating are provided by separate systems. Such implementati ns are known in the industry as Dedicated Outside Air Systems or DOAS. The example building has two stories with a central air handling unit 100 on the roof 105 of the building. The central air handling unit 100 provides a treated fresh air stream 101 to the building that has a temperature that is usually slightly below room neutral conditions (65-70F) and has a relative humidity of 50% or so. A ducting system 103 provides air to the various spaces and can be ducted to the spaces directly or into a fan-coil unit 107 mounted in a suspended ceiling cavity 106. The fan-coil unit 107 draws air 109 from the space 1 10 and pushes it through a cooling or heating coil 1 15 mounted inside the fan-coil unit 107. The cooled or heated air 108 is then directed back into the space where it provides a comfortable environment for occupants. To maintain air quality some of the air 109 that is removed from the space and is exhaitsted through ducts 104 and directed back to ihe central air handling unit 100. Since the return air 102 to the air handling unit 100 is still relatively cool and dry (in summer or warm and moist in winter as the case may be), the central air handling unit 100 can be constructed so as to recover or use some of the energy present in the return air stream. This is oftentimes accomplished with total energy wheels, enthalpy wheels, desiccant wheels, air to air energy recovery units, heat pipes, heat exchangers and the like. [0031] The fan coils 1 15 in FIG. 1 also require cold water (for cooling operation) or warm water (for heating operation). Installing water lines in buildings is expensive and oftentimes only a single water loop is installed. This can cause problems in certain situations where some spaces may require cooling and other spaces may require heating. In buildings where a hot water- and a cold water loop are available at the same time, this problem can be solved by having some fan coil units 1 15 provide cooling where others are providing heating to the respective spaces. Spaces 1 10 can often be divided into zones by physical wails i l l or by physical separation of fan-coil units.

[0032] The fan coil units 107 thus utilize some form of hot and cold water supply system 1 12 as well as a return system 1 13. A central boiler and/or chiller plant 1 14 is usually available to provide the required hot and/or cold water to the fan-coil units.

[0033] FIG. 2 illustrates a more detailed view of a fan-coif unit 107. The unit includes a fan 201, which removes air 109 from the space below. The fan pushes air through the coil 202 which has a water supply line 204, a water return line 203. The heat in the air 109 is rejected to the cooling water 204 thereby producing colder air 108 and wanner water 203. If the air 109 entering the coil is already relatively humid, it is possible for condensation to occur on the coil since the cooling water is typically provided at temperatures of 50F or below. A. drain pan 205 is then required to be installed and condensed water is required to be drained so as to not create problems with standing water which can result in fungi, bacteria and other potentially disease causing agents such as legionnaires. Modern buildings are often much more air-tight than older buildings which can amplify the humidity control problem. Furthermore in modern buildings, internally generated heat is better retained resulting in a greater demand for cooling earlier in the season. The two effects combine to increase the humidity in the space and result in larger energy consumption than might have been expected.

[0034] FIG. 3 shows a flexible, membrane protected, counter-flow 3 -way heat and mass exchanger disclosed in U.S. Patent Application Publication No.

20140150662 meant for capturing water vapor from an air stream while

simultaneously cooling or heating the air stream. For example, a high temperature, high humidity air stream 401 enters a series of membrane plates 303 that cool and dehumidify the air stream. The cool, dry, leaving air 402 is supplied to a space such as, e.g., a space in a building. A desiccant is supplied through supply ports 304. Two ports 304 are provided on each side of the plate block structure 300 to ensure uniform desiccani distribution on the membrane plates 303. The desiccant film falls through gravity and is collected at the bottom of the plates 303 and exits through the drain ports 305. A. cooling fluid (or heating fluid as the case may be) is supplied through ports 405 and 306. The cooling fluid supply ports are spaced in such a way as to provide uniform cooling fluid flow inside the membrane plates 303. The cooling fluid runs counter to the air stream direction 401 inside the membrane plates 303 and leaves the membrane plates 303 through ports 307 and 404. Front/Year covers 308 and top/bottom covers 403 provide structural support and thermal insulation and ensure that air does not leave through the sides of the heat and mass exchanger,

[0035] FIG. 4 shows a schematic detail of one of the plate structures of FIG. 3. The air stream 251 flows counter to a cooling fluid stream 254. Membranes 252 contain a liquid desiccant 253 that falls along the wall 255 that contains a heat transfer fluid 254. Water vapor 256 entrained in the air stream is able to transition the membrane 252 and is absorbed inio ihe liquid desiccant 253. The heat of eondensaiion of water 2.58 that is released during the absorption is conducted through the wall 255 into the heat transfer fluid 254. Sensible heat 257 from the air stream is also conducted through the membrane 252, liquid desiccant 253 and wail 255 inio the heat transfer fluid 254.

[0036] FIG. 5 shows a new type of liquid desiccant system as shown in U.S. Patent Application Publication No. 20120125020. The conditioner 451 comprises a set of plate structures that are internally hollow. A cold heat transfer fluid is generated in cold source 457 and entered into the plates. Liquid desiccant solution at 464 is brought onto the outer surface of the plates and runs down the outer surface of each of the plates. In some embodiments -described further below- the liquid desiccani runs behind a thin membrane that is located between the air flow and the surface of the plates. Outside air 453 is now blown through the set of wavy plates. The liquid desiccant on the surface of the plates attracts the water vapor in the air flow and the cooling water inside the plates helps to inhibit the air temperature from rising. The plate structures are constructed in such a fashion as to collect the desiccant near the bottom of each plate. The treated air 454 is now put in the building directly without the need for any additional treatment,

[0037] The liquid desiccant is collected at the bottom of the wavy plates at 461 and is transported through a heat exchanger 463 to the top of the regenerator to point 465 where the liquid desiccant is distributed across the plates of the regenerator. Return air or optionally outside air 455 is blown across the regenerator plates and water vapor is transported from the liquid desiccant into the leaving air stream 456. An optional heat source 458 provides the driving force for the regeneration. The hot transfer fluid 460 from the heat source can be put inside the plates of the regenerator similar to the cold heat transfer fluid on the conditioner. Again, the liquid desiccant is collected at the bottom of the plates 452 without the need for either a collection pan or bath so that also on the regenerator the air can be vertical. An optional heat pump 466 can be used to provide cooling and heating of the liquid desiccant but can also be used to provide heat and cold as a replacement of cooler 457 and heater 458.

[0038] FIG. 6 illustrates an in-ceiling fan coil unit 501 in accordance with one or more embodiments that uses a 3 -way membrane liquid desiccant module 502 to dehumidify air in a space. Air 109 from the space is pushed by fan 503 through the 3- way membrane module 502 wherein the air is cooled and dehumidified. The dehumidified and cooled air 108 is then ducted to the space where it provides cooling and comfort. The heat that is released during the dehumidiflcation and cooling in the membrane module 502 is rejected to a circulating water loop 51 1, which circulates from the membrane module 502 to heat exchanger 509 and water pump 510, The heat exchanger 509 receives cold water from building chilled water loop 2.04, which ultimately rejects the heat of cooling and deliumidification. To achieve the dehumidiflcation function, a desiccant 506 is provided to the membrane module 502. The desiccant drains into a small storage tank 508. Desiccant from the tank 508 is pumped up to the membrane module 502 by liquid desiccant pump 507. Since ultimately the liquid desiccant gets further and further diluted by the dehumidiflcation process, a concentrated desiccant is added by a liquid desiccant loop 504. Dilute liquid desiccant is removed from the tank 508 and pumped through lines 505 to a central regeneration facility (not shown). [0039] FIG. 7 illustrates how the in-ceiling liquid desiccant membrane fan- coil unit of FIG. 6 can be deployed in the building of FIG. 1 where it replaces the conventional fan-coil units. As can be seen in the figure, fan-coil unit 501 containing the membrane module 502 is now replacing the conventional fan-coil units. Liquid desiccani distribution lines 504 and 505 a receiving liquid desiccant from a central regeneration system 601. Central liquid desiccant supply lines 602 and 603 can be used to direct liquid desiccant to multiple floors as well as to a roof based liquid desiccant DOAS. The air handling unit 604 can be a conventional non-liquid desiccant DOAS as well.

[0040] FIG. 8 illustrates an alternate embodiment of the DOAS 604 of FIG . 7 wherein the system uses liquid desiccant membrane plates similar to plates 452 shown in FIG. 6. The DOA S 701 of FIG. 8 takes outside 706 and directs it through a first set of liquid desiccant membrane plates 703 which are cooled internally by a chilled water loop 704 and dehumidified by a liquid desiccant in a loop 717. The air then proceeds to a second set of liquid desiccant membrane plates 702, which is also cooled internally by the chilled water loop 704. The air stream 706 has thus been dehumidified and cooled twice and proceeds as supply air 101 to spaces in the building as was shown in FIG. 7. The heat released by the cooling and

dehumidication processes is released to the chilled water 704 and the water return 705 to a central chiller plant is thus warmer than the incoming chilled water.

[0041 ] Return air 102 from the spaces in the building is directed over a third set of liquid desiccant membrane plates 720. These plates are internally heated by hot water loop 708. The heated air is directed to the outside where it exhausted as air stream 707. The liquid desiccant running over the membrane plates 720 is collected in a small storage tank 715, and is then pumped by pump 716 through loop 717 and liquid-to-liquid heat exchanger 718 to the first set of plates 703. The hot water inside plate set 720 helps to concentrate the desiccant running over the surface of the plate set 704. The concentrated desiccant can then be used to pre-dehumidify the air stream 706 on plate set 703, essentially functioning as a latent energy recovery device. A second desiccani loop 714 is used to further dehumidify the air stream 706 on the second plate set 702. The desiccant is collected in a second storage tank 712, and is pumped by pump 713 through loop 714 to plates 702. Diluted desiccant is removed through desiccant loop 71 1 and concentrated liquid desiccant is added to the tank 712 by supply line 710,

[0042] FIG. 9 illustrates another embodiment similar to the system of FIG. 8 wherein the hot water loop 708-709 has been omitted. Instead, a circulating water loop 802 provided by run-around pump 801 is used the transfer sensible heat from the incoming air stream. The system tints set up is able to remove moisture from the incoming air stream 706 in the membrane plate set 703 by the liquid desiccant loop 717 and add this moisture to the return air 102 in membrane plate set 704.

Simultaneously the heat of the incoming air 706 is moved by the run-around loop 802 and rejected to the return air stream 102. In this manner the system is able to recover both sensible and latent heat from the return air stream 102 and use it to pre-cool and pre-dehumidify the incoming air stream 706. Additional cooling is then provided by the membrane plate set 702 and fresh liquid desiccant is provided by supply line 710 as before.

[0043] FIG. 10 illustrates yet another embodiment similar to the systems of FIG. 8 and FIG. 9 wherein energ is recovered as was shown in FIG. 9 from the incoming air stream 706 and applied to the return air stream 102. As shown in FIG. 8 the remaining cooling and dehumidification is provided by membrane plate set 702 which is internally cooled by chilled water loop 704. However in this embodiment a fourth set of membrane plates 903 is employed which receives hot water from hot water loop 708. Liquid desiccant is provided by pump 901 and loop 902 and the concentrated liquid desiccant is returned to desiccant tank 712. This arrangement eliminates the need for the external liquid desiccant supply and return lines (710 and 71 1 in FIG. 8), since the membrane plates 903 function as an integrated regeneration system for the liquid desiccant.

[0044] FIG. 1 1 illustrates another embodiment of the previously discussed systems. In the figure, a pre-cooling coil 1002 is connected by supply 1001 to the chilled water loop 704. The incoming outside air 706 which is typically high in humidity will condense on coil 1002 and water will drain off the coil. The remaining cooling and dehumidification is then again perfonned by liquid desiccant membrane module 702. The advantage of this arrangement is that the water condensed on the coil does not end up in the desiccant and thus does not need to be regenerated. Also shown in the figure is a preheating coil 1003 supplied by lines 1004 from a hot water loop 708, The pre-heating coil 1003 increases the temperature of the return air stream 102. which enhances the efficiency of the regeneration membrane module 903 since the liquid desiccant 902 is not cooled as much by the air stream 102 as would otherwise be the case.

[0045] FIG. 12 illustrates the psychrometric processes typically involved with the energy recovery methods shown in the previous figures. The horizontal axis shows the dry-bulb temperature (in degrees Celsius) and the vertical axis shows the humidity ratio (in g/kg). Outside Air 1 101 (OA) at 35C and 1 8g/kg enters the system as does return air 1 102 (RA) from the space, which is typically at 26C, 1 lg/kg.

Latent energy reco very such as was shown in FIG. 8 reduces the humidity of the outside air to a lower humidity (and a somewhat lower temperature) at 1 105 (OA'). At the same time the return air absorbs the humidity (and some of the heat) at 1 104 (RA'). A sensible energy recovery system would have resulted in points 1 107 (OA'") and 1 108 (RA'"). Simultaneous latent and sensible recoveiy as was shown in FIG. 9 and 10 results in a transfer of both heat and moisture from the incoming air stream to the return air stream, points 1 106 (OA") and 1103 (RA").

[0046] In many buildings only a central cold water system is available and there may not be a simple source of hot water available for regeneration of the liquid desiccant. This can be solved by using a system shown in FIG. 13 similar to the central air handling systems of FIG. 8-10, but wherein the primary set of membrane modules 702 is coupled to a building cold water loop as before, but the regeneration is provided by an internal compressor system that is just there to provide heat for liquid desiccant regeneration in membrane modules 1215. It should be clear that like FIG. 8-10, another set of membrane modules 703 and 720 could be provided to provide latent or sensible energy recoveiy or both, from the leaving air 102 of the building. This is not shown in the figure so as to not overly complicate the figure. It should also be clear that such energy recovery could be provided by other more conventional means such as a desiccant- (enthalpy-) or heat wheels or a heat pipe system or other conventional energy reco very methods such as run-around water loops and air to air heat exchangers. Generally one portion of such an energy recovery system would be implemented in the air stream 102 before it enters the membrane modules 1215, and the other portion of the energy system would be implemented in the air stream 706 before it enters the membrane modules 702. In buildings where little or no return air 102. is available, the air stream 102 can simply be outside air.

[0047] In FIG. 13 the outside air stream 706 enters a set of 3 -way membrane plates or membrane modules 702. The membrane modules 702 receive a heat transfer fluid 1216 that is provided by liquid pump 1204 through water-to-water heat exchanger 1205. The heat exchanger 1205 is a convenieni way io provide pressure isolation between the usually higher (60-90 psi) building water circuit 704 and the low pressure heat transfer fluid circuit 1216/1217 which is generally only 0.5-2 psi. The heat transfer fluid 1216 is cooled down by the building water 704 in the heat exchanger 1205. The leaving building cooling water 1206 also is directed through a water-to-refrigerant heat exchanger 12.07 which is coupled to a conventional water-to- water heat pump. The cold heat transfer fluid 1216 provides cooling to the membrane modules 702 which also receive a concentrated liquid desiccant 714. The liquid desiccant 714 is pumped by pump 713 and absorbs water vapor from the air stream 706 and the air is simultaneously cooled and dehumidified as is discussed, e.g., in U.S. Patent Application Publication No. 2014-0150662, and is supplied to the building as supply air 101. The diluted liquid desiccant 1218 that leaves the membrane modules 702 is collected in desiccant tank 712. and now needs to be regenerated. A conventional compressor system (known in the HVAC industry as a water-to-water heat pump) comprising of compressor 1209, a iiquid-to- refrigerant condenser heat exchanger 1201, an expansion device 1212 and a liquid to refrigerant evaporator heat exchanger 1207. Gaseous refrigerant 1208 leaves the evaporator 1207 and enters the compressor 1209 where the refrigerant is compressed, which releases heat. The hot, gaseous refrigerant 1210 enters the condenser heat exchanger 1201 where the heat is removed and transferred into heat transfer fluid 1214 and the refrigerant is condensed to a liquid. The liquid refrigerant 121 1 then enters the expansion device 1212 where it rapidly cools. The cold liquid refrigerant 1213 then enters the evaporator heat exchanger 1207 where it picks up heat from the building water loop 704, thereby reducing the temperature of the building water. The thus heated heat transfer fluid 1214 creates a hot liquid heat transfer fluid 1202 which is directed to the regenerator membrane modules 1215 which are similar in nature to conditioner membrane modules 702 but could be sized differently to account for differences in air streams and temperatures. The hot heat transfer fluid 1202 now causes the dilute liquid desiecant 902 to release its excess water in the membrane modules 1215 which is exhausted into the air stream 102 resulting in a hot, humid air stream 707 leaving said membrane modules 1215. An economizer heat exchanger 1219 can be employed to reduce the heat load from the regenerator hot liquid desiecant 1220 to the cold liquid desiecant in the desiecant tank 712.

[0048] The hot heat transfer fluid is pumped by pump 1203 to the regenerator membrane modules 1215, and the cooler heat transfer fluid 1214 is directed back to the condenser heat exchanger 1201 where it again picks up heat. The advantage of the setup discussed above is clear: the local water-to-water heat pump is only used if liquid desiecant needs to be regenerated and thus can be used at times when electricity is inexpensive since concentrated liquid desiecant can be stored in tank 712 for use when needed. Furthermore, when the water-to-water heat pump is running, it actually cools the building water loop 704 down, thereby reducing the heat load on the central chilled water plant. Also when a building only has a cold water loop, which is commonly the case, there is no eed to install a central hot water system. And lastly the regeneration system could be made to work even if no return air is available, and if there is return air, an energy wheel or conventional energy recovery system can be added, or a separate set of liquid desiecant energy recovery modules such as shown in FIGS. 8- 10 can be added.

[0049] FIG. 14 illustrates the temperatures of the heat transfer fluid (often plain water) in the water lines of the system of FIG. 13. The building water 704 enters at temperature Twater,in into the evaporator heat exchanger 1207, The heat transfer fluid is cooled by the refrigerant in the evaporator 12.07 as discussed above resulting in the fluid leaving at temperature Twater,after evap. hx 1206. The heat transfer iluid then enters the conditioner heat exchanger 1205 where it picks up heat from the conditioner fluid loop 1216/1217. The run-around heat transfer loop 1216/1217 (indicated by temperature profile 1301 and 1302 in the heat exchanger 1205) is usually implemented in a counter-flow orientation resulting in a slightly wanner water temperature Twater, in cond. hmx that services the membrane modules 702. The heat transfer fluid then leaves the system at 705 and is returned to the central chiller plant (not shown) where it is cooled down. It should be obvious that the heat exchangers 1205 and 1207 can also be reversed in order or operated in parallel. The order of the heat exchangers makes little difference in operating energy, but will affect the outlet temperature for the supply air 701 : generally the supply air 701 will be colder if the building water enters heat exchanger 1207 first (as shown). Warmer air is provided if the building water enters heat exchanger 1205 first (as would happen if the flow from 704 to 705 is reversed). This obviously also can be used to provide a temperature control mechanism for the supply air.

[0050] The regeneration heat transfer fluid loop is also illustrated in FIG. 14. The heat transfer fluid (often water) having temperature Twater, in 1214 entering the condenser heat exchanger 1201 is first heated by the refrigerant resulting in temperature Twater, after cond.hx in 1202. The hot heat transfer fluid 1202 is then directed to the regenerator membrane module resulting in Twater, after regenerator in 1214. Since this is also a closed loop the water temperature is then the same as it was at the beginning of the graph as indicated by arrow 1303. For simplicity small parasitic temperature increases such as those caused by pumps and small losses such as those caused by pipe losses have been omitted from the figure,

[0051] Having thus described several illustrative embodiments, it is to be appreciated that various alterations, modifications, and improvements will readily occur to those skilled in the art. Such alterations, modifications, and improvements are intended to form a part of this disclosure, and are intended to be within the spirit and scope of this disclosure. While some examples presented herein involve specific combinations of functions or structural elements, it should be understood that those functions and elements may be combined in other ways according to the present disclosure to accomplish the same or different objectives. In particular, acts, elements, and features discussed in connection with one embodiment are not intended to be excluded from similar or other roles in other embodiments. Additionally, elements and components described herein may be further divided into additional components or joined together to form fewer components for performing the same functions. Accordingly, the foregoing description and attached drawings are by way of example only, and are not intended to be limiting.