Title:
INSECTICIDES CONTAINING HYDRAZONE DERIVATIVES AS THE ACTIVE INGREDIENT AND NOVEL HYDRAZONE DERIVATIVES
Document Type and Number:
WIPO Patent Application WO/2003/059064
Kind Code:
A1
Abstract:
Insecticides containing as the active ingredient hydrazone derivatives represented by the general formula (I); and novel hydrazone derivatives: (I) wherein A and Q are each aryl or a heterocyclic group; W is oxygen, aminylene, alkylene, oxyalkylene, or alkyleneoxy; X1 and X2 are each hydrogen, alkyl, alkenyl, alkynyl, aryl, a heterocyclic group, formyl, acyl, alkoxycarbonyl, aryloxycarbonyl, heterocyle-oxycarbonyl, alkylsulfinyl, arylsulfinyl, heterocycle-sulfinyl, alkylsulfonyl, arylsulfonyl, or a heterocycle-sulfonyl; Y is oxygen or sulfur; and Z is hydrogen, halogeno, cyano, alkyl, alkenyl, alkynyl, amino, alkoxy, or alkylthio, with the proviso that each group may be substituted.
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Inventors:
KAWATA SHINJI (JP)
OKUI SHUKO (JP)
SUZUKI SHIGERU (JP)
FUKUCHI TOSHIKI (JP)
OKUI SHUKO (JP)
SUZUKI SHIGERU (JP)
FUKUCHI TOSHIKI (JP)
Application Number:
PCT/JP2003/000152
Publication Date:
July 24, 2003
Filing Date:
January 10, 2003
Export Citation:
Assignee:
NIHON NOHYAKU CO LTD (JP)
KAWATA SHINJI (JP)
OKUI SHUKO (JP)
SUZUKI SHIGERU (JP)
FUKUCHI TOSHIKI (JP)
SUWA AKIYUKI (JP)
KAWATA SHINJI (JP)
OKUI SHUKO (JP)
SUZUKI SHIGERU (JP)
FUKUCHI TOSHIKI (JP)
SUWA AKIYUKI (JP)
International Classes:
A01N37/18; A01N37/50; A01N43/08; A01N43/10; A01N43/40; A01N43/54; A01N43/58; A01N43/60; A01N43/78; A01N43/80; C07C251/76; C07C255/66; C07C257/02; C07C323/41; C07C323/48; C07D213/40; C07D213/61; C07D213/68; C07D213/74; C07D213/75; C07D213/77; C07D239/30; C07D237/12; C07D241/12; C07D261/10; C07D277/20; C07D277/30; C07D277/32; C07D277/82; C07D307/16; C07D307/52; C07D333/24; C07D333/28; C07D417/12; (IPC1-7): A01N37/28; A01N43/08; A01N43/10; A01N43/40; A01N43/54; A01N43/58; A01N43/60; A01N43/78; A01N43/80; C07C251/24; C07C259/06; C07C323/41; C07C323/48; C07D213/40; C07D213/76; C07D239/26; C07D277/82; C07D307/14; C07D307/52; C07D333/28; C07D413/12; C07D417/12
Domestic Patent References:
| WO2001001781A1 | 2001-01-11 |
Foreign References:
| US5304573A | 1994-04-19 | |||
| US5990171A | 1999-11-23 |
Other References:
DUBENKO R.G. ET AL.: "Fungicidal properties of arylhydrazones of glyoxylic acid substituted derivatives", FIZIOLOGICHESKI AKTIVNYE VESHCHESTVA, vol. 13, 1981, pages 33 - 37, XP002975382
CHEMICAL ABSTRACTS, vol. 98, no. 22, 30 May 1983, Columbus, Ohio, US; abstract no. 181105E, HAESSNER R. ET AL.: "Studies of the photochemical bleaching behavior of tautomeric monoazo dyes. III. Plotochemical degradation of malononitrile 2- and acetylacetone 3-phenylhydrazones and their derivatives in polymer matrix" page 79; XP002975383
CHEMICAL ABSTRACTS, vol. 135, no. 16, 15 October 2001, Columbus, Ohio, US; abstract no. 226967P, BEL'SKAYA N.P. ET AL.: "Reactions of 2-arylhydrazonoacetamides with orthoesters. Synthesis of new tetrahydro-1,2,4-triazines" page 821; XP002975384
YAGI YOSHIHARU: "Absorption spectra of azo dyes and their metal complexes. V. The electronic absorption spectra of metal-complexed hydroxyphenylazoacetoacetbenzylamides", BULL. CHEM. SOC. JAPAN, vol. 36, no. 5, 1963, pages 492 - 517, XP002975385
LOZINSKII M.O. ET AL.: "Condensation and cyclization of arylazochloroacetic acids. V. Chlorides, arylamides and acylhydrazides of arylazochloroacetic acids", ZH. ORGAN. KHIM., vol. 1, no. 11, 1965, pages 1976 - 1980, XP002975386
JANSEN A.B.A. ET AL.: "Synthesis of methyl benzylpenillonate", MONATSHEFTE FUER CHEMIE, vol. 98, no. 3, 1967, pages 1017 - 1027, XP002975387
CHEMICAL ABSTRACTS, vol. 98, no. 22, 30 May 1983, Columbus, Ohio, US; abstract no. 181105E, HAESSNER R. ET AL.: "Studies of the photochemical bleaching behavior of tautomeric monoazo dyes. III. Plotochemical degradation of malononitrile 2- and acetylacetone 3-phenylhydrazones and their derivatives in polymer matrix" page 79; XP002975383
CHEMICAL ABSTRACTS, vol. 135, no. 16, 15 October 2001, Columbus, Ohio, US; abstract no. 226967P, BEL'SKAYA N.P. ET AL.: "Reactions of 2-arylhydrazonoacetamides with orthoesters. Synthesis of new tetrahydro-1,2,4-triazines" page 821; XP002975384
YAGI YOSHIHARU: "Absorption spectra of azo dyes and their metal complexes. V. The electronic absorption spectra of metal-complexed hydroxyphenylazoacetoacetbenzylamides", BULL. CHEM. SOC. JAPAN, vol. 36, no. 5, 1963, pages 492 - 517, XP002975385
LOZINSKII M.O. ET AL.: "Condensation and cyclization of arylazochloroacetic acids. V. Chlorides, arylamides and acylhydrazides of arylazochloroacetic acids", ZH. ORGAN. KHIM., vol. 1, no. 11, 1965, pages 1976 - 1980, XP002975386
JANSEN A.B.A. ET AL.: "Synthesis of methyl benzylpenillonate", MONATSHEFTE FUER CHEMIE, vol. 98, no. 3, 1967, pages 1017 - 1027, XP002975387
Attorney, Agent or Firm:
Hanabusa, Tsuneo c/o Hanabusa, Patent Office (Shin-Ochanomizu Urban Trinity 2,
Kandasurugadai 3-chom, Chiyoda-ku Tokyo, JP)
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