IONIC LIQUID AND METHOD OF REACTION USING THE SAME

Title:

IONIC LIQUID AND METHOD OF REACTION USING THE SAME

Document Type and Number:

WIPO Patent Application WO/2005/028446

Kind Code:

A1

Abstract:

A novel acidic ionic liquid which is useful as a catalyst for alkylation, nitration, Beckmann rearrangement, etc. and is stable to air and water. It is an ionic liquid represented by the following formula (1): (1) wherein X represents halogeno or hydroxy; Y^- represents CF₃SO₃^-, BF₄^-, PF₆^-, CH₃COO^-, CF₃COO^-, (CF₃SO₂)₂N^-, (CF₃SO₂)₃C^-, F^-, Cl^-, Br^-, or I^-; n is an integer of 2 to 16; and R represents methyl, allyl, or vinyl. This ionic liquid not only functions as a BrDnsted acid or a Lewis acid but is a liquid insoluble in many organic solvents. The liquid is hence useful as a catalyst or solvent for Friedel-Crafts reaction, nitration, and Beckmann rearrangement. It can be easily separated from the reaction mixture and reused.

Inventors:

YOKOYAMA CHIAKI (JP)
QIAO KUN (JP)

Application Number:

PCT/JP2004/013467

Publication Date:

March 31, 2005

Filing Date:

September 15, 2004

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Assignee:

SUMITOMO CHEMICAL CO (JP)
YOKOYAMA CHIAKI (JP)
QIAO KUN (JP)

International Classes:

C07C2/66; C07C205/06; C07D233/60; (IPC1-7): C07D233/60; C07C2/64; C07C13/12; C07C13/20; C07C15/44; C07C15/46; C07C205/06; C07C205/12

Domestic Patent References:

WO2003086605A2

2003-10-23

Foreign References:

JP2003313171A	2003-11-06
JP2002003478A	2002-01-09
JP2002025610A	2002-01-25

Attorney, Agent or Firm:

Naruse, Katsuo (TKK Nishishinbashi Bldg. 11-5, Nishi-shinbashi 2-chom, Minato-ku Tokyo 03, JP)

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