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Title:
LITHIUM SILICATE COMPOUND, METHOD FOR PRODUCING SAME, POSITIVE ELECTRODE ACTIVE MATERIAL AND POSITIVE ELECTRODE FOR SECONDARY BATTERIES, AND SECONDARY BATTERY
Document Type and Number:
WIPO Patent Application WO/2013/084396
Kind Code:
A1
Abstract:
This lithium silicate compound is represented by general formula Li2-a+bAaMn(1-x-y)CoxMySiO4+αClβ (wherein A represents at least one element that is selected from the group consisting of Na, K, Rb and Cs; M represents at least one element that is selected from the group consisting of Mg, Ca, Al, Ni, Fe, Nb, Ti, Cr, Cu, Zn, Zr, V, Mo and W; and the subscripts respectively satisfy 0 ≤ a < 0.2, 0 ≤ b < 1, 0 < x < 1, 0 ≤ y ≤ 0.5, -0.25 ≤ α ≤ 1.25 and 0 ≤ β ≤ 0.05). This lithium silicate compound is used as a positive electrode active material for secondary batteries, which has a high discharge average voltage and is capable of absorbing and desorbing lithium ions.

Inventors:
KOJIMA AKIRA (JP)
KOJIMA TOSHIKATSU (JP)
TABUCHI MITSUHARU (JP)
SAKAI TETSUO (JP)
MIYUKI TAKUHIRO (JP)
NIWA JUNICHI (JP)
KAWASUMI KAZUHITO (JP)
MURASE MASAKAZU (JP)
Application Number:
PCT/JP2012/006559
Publication Date:
June 13, 2013
Filing Date:
October 12, 2012
Export Citation:
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Assignee:
TOYOTA JIDOSHOKKI KK (JP)
NAT INST OF ADVANCED IND SCIEN (JP)
International Classes:
C01B33/32; H01M4/58
Domestic Patent References:
WO2010089931A12010-08-12
Foreign References:
JP2007335325A2007-12-27
JP2010257592A2010-11-11
Attorney, Agent or Firm:
OHKAWA, HIROSHI (JP)
Okawa 宏 (JP)
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Claims: