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Title:
LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, MG-CONTAINING LITHIUM TITANATE PARTICULATE POWDER AND PRODUCTION METHOD FOR SAME, NEGATIVE ELECTRODE ACTIVE MATERIAL PARTICULATE POWDER FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
Document Type and Number:
WIPO Patent Application WO/2012/029697
Kind Code:
A1
Abstract:
Provided are a lithium titanate particulate powder that displays excellent initial discharge capacity and a high discharge capacity maintenance rate as an active substance for a non-aqueous electrolyte secondary battery as well as having reduced gas emissions, a production method for same, and a Mg-containing lithium titanate powder. The present invention includes: a lithium titanate particulate powder with a spinel structure, wherein, when an index is applied by Fd-3m in XRD, the TiO2 volume by Reitveld analysis is 1.5% or less and the Li2TiO3 volume is 1%-6%, the Li4Ti5O12 volume is 94%-99%, and the BET specific surface area is 7-15m2/g; and a Mg-containing lithium titanate particulate powder with a composition indicated by LixMgyTizO4 (wherein x, z>0, 0.01≦y≦0.20, 0.01≦y/z≦0.10, and 0.5≦(x+y)/z≦1.0), a BET specific surface area of 5-50m2/g, a single-phase spinel type crystal structure, and a lattice constant (a) with a value indicated by 0.050y+8.3595

Inventors:
YAMAMOTO AKINORI (JP)
OKITA TOMOKO (JP)
YAMAMOTO HIROSHI (JP)
MORI KOHJI (JP)
KOGA KAZUMICHI (JP)
KAJIYAMA AKIHISA (JP)
Application Number:
PCT/JP2011/069407
Publication Date:
March 08, 2012
Filing Date:
August 29, 2011
Export Citation:
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Assignee:
TODA KOGYO CORP (JP)
YAMAMOTO AKINORI (JP)
OKITA TOMOKO (JP)
YAMAMOTO HIROSHI (JP)
MORI KOHJI (JP)
KOGA KAZUMICHI (JP)
KAJIYAMA AKIHISA (JP)
International Classes:
C01G23/00; H01M4/36; H01M4/485
Domestic Patent References:
WO2009146904A12009-12-10
WO2006106701A12006-10-12
WO2006106701A12006-10-12
Foreign References:
JP2009081049A2009-04-16
JP2011154928A2011-08-11
JP2001192208A2001-07-17
JP2001213622A2001-08-07
JPH09309727A1997-12-02
JP2010228980A2010-10-14
JP2006318797A2006-11-24
JP2003137547A2003-05-14
JPH11283624A1999-10-15
JPH06275263A1994-09-30
JP2001240498A2001-09-04
JP2005239460A2005-09-08
JP2005239461A2005-09-08
JP2001185141A2001-07-06
JP2001250554A2001-09-14
JP2000156229A2000-06-06
JP2004235144A2004-08-19
JPH10251020A1998-09-22
Other References:
See also references of EP 2612840A4
Attorney, Agent or Firm:
OKADA, KAZUHIKO (JP)
Kazuhiko Okada (JP)
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Claims: