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Title:
LIVING RADICAL POLYMERIZATION INITIATOR, METHOD FOR PRODUCING POLYMER, AND POLYMER
Document Type and Number:
WIPO Patent Application WO/2016/035258
Kind Code:
A1
Abstract:
A living radical polymerization initiator represented by general formula (1), which uses a living radical polymerization initiator that comprises, as initiating groups for reactions, two halogen atoms different from each other in reactivity, and which enables different living radical polymerization reactions to proceed with respect to the respective initiating groups. In general formula (1), R1 represents an organic group which is linkable with two or more other organic groups, and which is selected from among an aliphatic group having 1-12 carbon atoms, an aromatic group, a carbonyl group, a sulfonyl group and an organic group obtained by combining two or more of these groups; each of R2, R3, R4 and R5 represents a hydrogen atom or an organic group selected from among an aliphatic group having 1-12 carbon atoms, an aromatic group, a carbonyl group, a carboxyl group and a sulfonyl group; each of X and Y represents a halogen atom; each of m and n represents an integer of 1 or more; and X and Y are different from each other in reactivity with a monomer.

Inventors:
GOTO ATSUSHI (JP)
MIYAMOTO MICHIHIKO (JP)
KOMATSU HIROTO (JP)
YAMAGUCHI YU (JP)
JITSUKAWA TAKUYA (JP)
Application Number:
PCT/JP2015/003991
Publication Date:
March 10, 2016
Filing Date:
August 07, 2015
Export Citation:
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Assignee:
UNIV KYOTO (JP)
GODO SHIGEN CO LTD (JP)
International Classes:
C08F4/00; C07C69/63; C07C69/65; C07C69/73; C08F293/00
Foreign References:
JP2010024263A2010-02-04
JP2013072069A2013-04-22
Other References:
YALING ZHU ET AL.: "New Dual Initiators To Combine Quasiliving Carbocationic Polymerization and Atom Transfer Radical Polymerization", MACROMOLECULES, vol. 43, 2010, pages 7048 - 7055, XP055416646
YALING ZHU ET AL.: "Effect of Structure on Cationic Initiation Efficiency of a Carbocatonic/ATRP Dual Initiator", MACROMOLECULES, vol. 45, 2012, pages 1217 - 1221, XP055416653
YALING ZHU ET AL.: "New Initiators to Combine Quasiliving Carbocationic Polymerization and Atom Transfer Radical Polymerization", POLYMER PREPRINTS, vol. 50, no. 2, 2009, pages 535 - 536, XP055416646
V. PERCEC ET AL.: "Metal-Catalyzed Living Radical Graft Copolymerization of Olefins Initiated from the Structural Defects of Poly(vinyl chloride", J. POLYM. SCI. PART A, vol. 39, 2001, pages 1120 - 1135, XP055416662
ATSUSHI GOTO: "Yuki Shokubai o Mochiita Living Radical Jugo no Kaihatsu to Tenkai", TOKAI SYMPOSIUM KOEN YOSHISHU, 2014, pages 1 - 8, XP009501040
MIHO TANISHIMA ET AL.: "Macromolecular Architectures Designed by Living Radical Polymerization with Organic Catalysts", POLYMERS, vol. 6, 2014, pages 311 - 326, XP055416669
ATSUSHI GOTO ET AL.: "Yuki Bunshi Shokubai o Mochiita Living Radical Jugo no Shokubai Sekkei", POLYMER PREPRINTS, JAPAN, vol. 63, no. 2, 2014, pages 4442 - 4443, XP009500893
LIN LEI ET AL.: "Systematic Study on Alkyl Iodide Initiators in living Radical Polymerization with Organic Catalysts", MACROMOLECULES, vol. 47, 2014, pages 6610 - 6618, XP055416672
ATSUSHI GOTO ET AL.: "Yoso o Mochiita Yuki Shokubai-gata Living Radical Jugo: Yoso no Tokusei o Katsuyo shita Kobunshi no Seigyo Gosei", SIS REPORT, 2014, pages 5 - 8, XP009500910
ATSUSHI GOTO ET AL.: "Living Radical Polymerization with Organic Catalysts under Thermal Heating and Photo Irradiation", JAPANESE JOURNAL OF POLYMER SCIENCE AND TECHNOLOGY, vol. 72, no. 5, 2015, pages 199 - 207, XP009500890
Attorney, Agent or Firm:
ABIKO, Gen (JP)
Yasuhiko Origin (JP)
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