Danker, George (26600 W. 106th Olathe, KS, 66061, US)
Campanella, David (Apartment #302 1708 N.E. Clubhouse Drive North Kansas City, MO, 64116, US)
| 1. | A fire resistant carpet backing formulation, comprising: a) a polyurethane dispersion; b) fire retardant components having at least a) ammonium polyphosphate, b) melamine, and c) a char former; c) solvents including water; d) filler, pigment and grinding aids; and e) surfactants. |
| 2. | A fire resistant carpet backing formulation according to claim 1, wherein the fire retardant components further comprises a flame poisoner. |
| 3. | A fire resistant carpet backing formulation according to claim 1, wherein the char former is a pentaeryritol. |
| 4. | A fire resistant carpet backing formulation according to claim 1, wherein the char former is a polysaccharide. |
| 5. | A fire resistant carpet backing formulation according to claim 1, wherein the polyurethane is selected from the group consisting of a polyurethane polyether, a polyurethane polyester and mixtures thereof. |
| 6. | A fire resistant carpet backing formulation according to claim 1, wherein the polyurethane is selected from the group consisting of an aliphatic polyurethane, an aromatic polyurethane and mixtures thereof. |
| 7. | A fire resistant carpet backing formulation according to claim 1, wherein the polyurethane dispersion is 1830% by weight. |
| 8. | A fire resistant carpet backing formulation according to claim 1, wherein the fire retardant components of part (b) are 3961% by weight. |
| 9. | A fire resistant carpet backing formulation according to claim 1, wherein the solvents of part (c) are 9 25% by weight. |
| 10. | A fire resistant carpet backing formulation according to claim 1, wherein the composition comprises by weight: Component % Range PR240 main dispersion 1830 Water 515 2Propanol 36 NMethyl2Pyrrolidone 14 CT131 dispersing agent 0.51.5 Lorama ECO R1 polysaccharide resin 49 Melamine 713 FR Cros 484 Ammonium polyphosphate 2535 Pentaerythritol 713 5099 black iron oxide 0.51.5 Dow Corning Antifoam"A"0.011.00 Surfynol 465 surfactant 0.11.0 4% aqueous dispersion of Rheox Bentone A. D. 26 11. A fire resistant carpet backing formulation according to claim 1, wherein the composition comprises by weight: resin 1 PR240 main dispersion 22.00 6 Lorama ECO R1 7.00 fire retardant components 7 Melamine 10.00 8 FR Cros 484 Ammonium polyphosphate30.00 9 Pentaerythritol (char former) 10.00 solvents for permitting flow of the composition 2 Water 8.75 3 2Propanol 4.00 4 NMethyl2Pyrrolidone 1.70 surfactants for the composition 11 Dow Corning Antifoam"A"0.05 12 Surfynol 465 surfactant 0.50 filles, pigments and antisettling and grinding aid 5 CT131 dispersing agent 1.00 10 5099 black iron oxide 1.00 13 4% aqueous dispersion of Rheox 4.00 12. A fire retardant nylon carpet having a backing component made from the fire resistant carpet backing formulation of claim 1. |
| 11. | 13 A fire retardant nylon carpet having a backing component made from the fire resistant carpet backing formulation of claim 10. |
| 12. | 14 A fire retardant nylon carpet having a backing component made from the fire resistant carpet backing formulation of claim 11. |
| 13. | 15 A fire retardant nylon carpet, comprising: a nylon carpet and backing thereon that meets the Airbus ATS 1000.001/ABD 0031 issue 5 smoke emission and toxic gas standards. |
Field of the Invention This invention relates to a fire retardant polyurethane resin formulation which is suitable for use as a carpet backing for nylon carpets.
Background of the Invention Aircraft carpeting can be made from a number of fibers. The two most commonly used for aircraft are wool and nylon. Nylon, in general, has become the preferred fiber for mechanical properties. Wool, historically, has been superior for fire safety.
The standards for fire safety purposes are imposed and monitored by governmental regulatory agencies such as FAA (United States-Federal Aviation Agency), CAA (Great Britain-Civil Aviation Authority-also recognized in parts of Europe), and JAA (Japan Aviation Authority).
These apply to all airline operators under their respective jurisdiction. Fire safety standards are additionally maintained by airframe manufacturers such as Boeing, Airbus, McDonnell Douglas and others, and apply to all aircraft they manufacture.
Fire safety regulations vary worldwide. In parts of the world, particularly Europe and Asia, wool has been the only fiber that was able to meet all fire safety regulations, such as vertical burn, smoke and toxic gas emission requirements. In the United States, where fire safety requirements for carpet do not include smoke and
toxicity standards, nylon dominates the market as the fiber of choice for aircraft carpet.
More specifically, it is mandatory that all carpet installed on any aircraft worldwide must pass the twelve second vertical burn test described in FAR 25.853 (a), Appendix F, Part 1, (a) (1) (ii) and incorporated herein by reference. This is the FAA version of the vertical burn regulation which is generally recognized worldwide and which appears essentially verbatim in CAA, JAA, and other regulatory agencies'documentation.
In contrast to vertical burn, smoke emission and toxic gas emission are regulated differently throughout various parts of the world. For instance, Boeing and Airbus, as airframe manufacturers serving worldwide markets, maintain standards for smoke and toxic gasses. These airline manufacturers provide Supplier Furnished Equipment (SFE) carpet which is selected and installed by Boeing or Airbus as original equipment on their aircraft. For smoke emission and toxic gas emission, this carpet must meet the airline manufacturer's standard, such as Boeing's BMS 8.237C, BSS 7236 and BSS 7238 standards and Airbus'ATS- 1000.001 ABD 0031 issue 5 standards, incorporated herein by reference.
These standards describe the smoke emission and toxicity test methods in detail. Generally, to meet the Airbus smoke emission and toxicity standards, a carpet sample (3"x 3") is burned for four minutes in a burn chamber under both flaming and non-flaming conditions. To meet the smoke emission standard, the specific optical density (Ds) of the resulting smoke cannot exceed 150. To meet the toxicity requirements for smoke gases, the smoke in the chamber is tested for the presence of the following six gases which cannot be present in more than the following listed quantities:
ppm w/in 4 minutes Hydrogen Fluoride (HF) 100 Hydrogen Chloride (HCL) 150 Hydrogen Cyanide (HCN) 150 Sulfur Dioxide (SO2 + H, S) 100 Carbon Monoxide (CO) 3500 Nitrous Gases (NO + NO2) 100 The Boeing standards for smoke emission and toxicity are less stringent, but similar to Airbus'standards.
Summary of the Invention Accordingly, it is an object of this invention to provide a backing for textiles, particularly nylon carpet which, when applied to these materials, produces a construction that exhibits lower smoke and toxic gas emissions than current products.
It is a further object of this invention to provide a composition for treating carpet or fabrics so they meet flammability, smoke generation and toxic gas emission requirements for aerospace, mass transportation and housing markets.
It is a further object of this invention to provide a fire retardant composition for carpets and fabrics which is agreeable to the manufacturing process, is environmentally safe, exhibits a very low level of volatile organic compounds (VOCs) and is a single-component material making it compatible with many existing commercial application processes.
It is a further object of this invention to provide a fire retardant composition for carpets and fabrics in a single package formulation which can be used without specialized application equipment being required, requires no mixing, and decreases worker exposure to isocyanates for increased worker safety.
It is a further object of this invention to provide a fire retardant composition for carpets and fabrics in a water-based formula with very low initial toxicity, with low VOCs, and with a non-flammable formula for increased fire safety.
It is a further object of this invention to provide a fire retardant composition for carpets and fabrics which is fire resistant and which meets governmental and industry fireworthiness regulations for use worldwide.
It is a further object of this invention to provide a fire retardant composition for carpets and fabrics which has high penetration and high adhesion to lock in carpet fibers, is tough to assure dimensional stability and provide long service life, and is an elastomeric formulation to eliminate concerns about shrinkage.
It is a further object of this invention to provide a fire retardant nylon carpet.
These and further objects of the invention will become apparent as the description of the invention proceeds.
These objects are attained by providing a fire resistant carpet backing formulation has been made having the following components: a) a polyurethane dispersion; b) fire retardant components having at least a) ammonium polyphosphate, b) melamine, and c) a char former; c) solvents including water; d) filler, pigment and grinding aids; and e) surfactants.
Preferred char formers are pentaerythritol and polysaccharides. The polyurethane dispersion is present in about 18-30% by weight, the fire retardant components of part (b) are present in about 39-61% by weight and the solvents of part (c) are present in about 9-25% by weight in the preferred embodiments. When this formulation is used to make a nylon carpet, the resulting carpet is fire retardant and meets the airline standards for fire safety.
Detailed Description of the Preferred Embodiments A carpet backing has been developed which enables nylon carpet to meet demanding fire safety requirements and thus permits European airline operators to enjoy the many benefits of nylon carpeting. The formula of this invention produces a backing for textiles, particularly nylon carpet which, when applied to these materials, produces a construction that exhibits lower smoke and toxic gas emissions than current products. Carpet or fabrics so treated meet flammability, smoke generation and toxic gas emission requirements for aerospace, mass transportation and housing markets. Additionally this product is environmentally safe, exhibiting very low VOCs and is a single-component material which makes it compatible with many existing commercial application processes.
The preferred formulation is set forth in Table 1 below. Each ingredient is numbered and a more detailed ingredient description as well as its function and source is given below the table.
Table 1 Preferred Formulation No. Component % by % range weight 1 PR-240 main dispersion 22. 00 18-30 2 Water 8. 75 5-15 3 2-Propanol 4. 00 3-6 4 N-Methyl-2-Pyrrolidone 1. 70 1-4 5 CT-131 dispersing agent 1. 00 0.5-0.5 6 Lorama ECO R1 polysaccharide resin 7. 00 4-9 7 Melamine 10. 00 7-13 8 FR Cros 484 Ammonium polyphosphate 30. 00 25-35 9 Pentaerythritol 10. 00 7-13 10 5099 black iron oxide 1. 00 0.5-1.5 11 Dow Corning Antifoam"A"0. 05 0.01-1.0 12 Surfynol 465 surfactant 0. 50 0.1-1.0 13 4% aqueous dispersion of Rheox 4. 00 2-6 Bentone A. D.
1. PR-240 is a proprietary solvent-free anionic aliphatic polyurethane dispersion in water. Typical resin solids are 38-42% with viscosity @ 25OC Ford Cup of 10-50 seconds, with a specific gravity of 1.06 gm/cm2, and a pH of 5-8. This is used as a binder for the nylon fibers of the carpet and to hold the other additives in place. This polyurethane dispersion exhibits low smoke and low toxicity
when burned. PR-240 is a product of Bayer Industrial Chemicals.
2. Water is used as a diluent and for viscosity control. When the backcoating cures the water evaporates and is no longer present.
3.2-Propanol is a commodity solvent used to reduce viscosity and adjust surface tension to help the polyurethane resin seek and bind to the nylon fibers. 2- Propanol evaporates during the curing and is not present in dried backing films.
4. N-Methyl-2-Pyrrolidone is a commodity solvent used to reduce viscosity and adjust surface tension to help the polyurethane resin seek and bind to the nylon fibers. N-Methyl-2-Pyrrolidone evaporates during curing and is not present in dried backing films.
5. CT-131 is a proprietary acetylenic, diol- based chemical used to enhance grinding and suspension of the additives. CT-131 is a product of Air Products and Chemicals Inc.
6. Lorama ECO R1 polysaccharide resin. This is a binder resin made of natural polysaccharides. It allows use of a wider range of polyurethane dispersions as a substitute for PR-240. It adds to fire resistance, it acts as an additional dispersing agent and it assists as a char former. Lorama ECO R1 is a product of Lorama Chemicals, Inc.
7. Melamine is a commodity chemical used as part of the fire retardant package. It is a spumescent that becomes gaseous when decomposed.
8. FR Cros 484 is a proprietary ammonium polyphosphate used as part of the fire retardant package.
It acts as a catalyst to extinguish the flame when burned.
FR Cros 484 is a product of Chemische Fabrik Budenheim.
9. Pentaerythritol is a commodity chemical used as part of the fire retardant package. It is used as a char former for flame extinguishing.
10.5099 black iron oxide is used as a shading pigment. 5099 black iron oxide is a product of Harcros Chemical.
11. Dow Corning Antifoam"A"is a de-foaming product of the Dow Corning Company.
12. Surfynol 465 is a proprietary ethoxylated 2,4,7,90-tetramethyl 5 decyn-4,7-diol used for surface tension modification. Surfynol 465 is a product of Air Products and Chemicals, Inc.
13. Premix of 4% Bentone A. D. and 96% water.
Bentone A. D. is a special clay filler that, when premixed with water, produces a gel-structured material that stabilizes the system, preventing settling without excessive thickening.
The polyurethane dispersion can be either a polyurethane polyether or a polyurethane polyester. The polyurethane can be either an aliphatic or aromatic polyurethane.
As seen from the ranges in the preferred compositions in Table 1, the polyurethane dispersion is present in about 18-30% by weight, the fire retardant components of part (b) are present in about 39-61% by weight and the solvents of part (c) are present in about 9-25% weight.
A further preferred composition is set forth in Table 2 where the various components or Table 1 are grouped by function.
Table 2 resin 1 PR-240 main dispersion 22.00 6 Lorama ECO RC1 7.00 fire retardant components 7 Melamine 10.00 8 FR Cros 484 Ammonium polyphosphate30.00 9 Pentaerythritol (char former) 10.00 solvents for permitting flow of the composition 2 Water 8.75 3 2-Propanol 4.00 4 N-Methyl-2-Pyrrolidone 1.70 surfactants for the composition 11 Dow Corning Antifoam"A"0.05 12 Surfynol 465 surfactant 0.50 fillers, pigments, anti-settling and grinding aid 5 CT-131 dispersing agent 1.00 10 5099 black iron oxide 1.00 13 4% aqueous dispersion of Rheox 4.00 Having described the basic aspects of the invention, the following examples are given to illustrate specific embodiments thereof.
Example 1 This example illustrates a preferred method of making a preferred formulation of the backing composition as basically set forth in Table 1.
In to a blending vessel with a high speed disperser such as a Cowles type dispersing blade for the deagglomeration of solids is added 22 parts by weight of PR- 240,6.0 parts water, 4.0 parts 2-propanol, 1.7 parts n- methyl-2-pyrrolidone, and 1.0 parts CT-131. The mixture is
then agitated and allowed to mix five minutes. Then, 10.00 parts melamine, 30.00 parts FR Cros 484,10.00 parts pentaerythritol, 1.00 parts black iron oxide pigment, 4.00 parts of a 4% aqueous dispersion of Rheox Bentone A. D. are added sequentially to the blending vessel. The resulting mixture is ground for 20 minutes to achieve the required dispersion.
Then, 0.05 parts Dow Corning Antifoam"A"and 0.5 parts Surfynol 465 surfactant are added and mixed for five minutes.
The viscosity is measured with a Brookfield RVT viscometer (spindle #4,10 RPM). The viscosity is reduced using up to 2.75% water. Finished viscosity is 1500-2500 centipoise at 25oC. The solids content by weight should be 62-66%.
The finished carpet can be fabricated by applying the liquid backing composition to unfinished carpet which is known as"soft"or"greige"goods. The wet back coating is then cured in an oven.
There are a number of methods used commercially to apply uniform amounts of wet coating to the unfinished carpet. An advantage of the present backing composition is that it is compatible with all common application methods and does not rely upon a unique or uncommon type of application equipment. The backing may be directly applied to the backside of the carpet as it travels inverted through the coating station. The back coating is made uniform and driven into the carpet with a doctor blade set at the gap angle to produce the applied weight and penetration desired.
The back coating may also be applied by a pan and roller method. In this method, the carpet travels through the conveying station in a right-side-up orientation.
The back coating is rolled into a reservoir pan in which a large cylindrical roller is mounted. The roller turns on an axle and picks up an amount of wet backing coating from the pan. The amount of pick-up is kept uniform by a scraping
blade. The greige carpet travels over this wetted roller and the back coating is transferred to the carpet. A combination of direct pressure, capillary action and scraping blades are used to achieve the applied weights and penetration desired.
The back coating may also be sprayed with commercially available airless spraying systems onto the soft goods. Scrapers, doctor blades and rollers can be used to control application weights and penetration of the back coating into the soft goods. In all application methods the back coating is cured by a combination of time, temperature, and air exchange. This is most often accomplished in ovens heated by either gas or electricity. Curing temperatures range from 100°-350°F and dwell time in ovens range from 5-30 minutes. The back coating can also be cured by infrared or microwave radiation, but this is not as common.
The formulation according to the present invention has many significant commercial advantages. It can be sold to the user in single package formulation so that no specialized application equipment required. This results in lower capitol cost and faster product introduction. No mixing is required which reduces labor costs and results in no mixing errors. Although it is a polyurethane formulation, workers are not exposed to isocyanates which increases worker safety.
Because the formulation is water based it has a very low initial toxicity and this provides for increased worker safety. It has low VOCs which reduces air pollution concerns, and the non-flammable formula results in increased fire safety. This fire resistance meets the FAA, CAA and JAA fireworthiness regulations so that nylon carpet can now be legally used worldwide. It also meets the Boeing and Airbus fireworthiness regulations, specifically the smoke and toxic gas requirements.
In designing a carpet backing formulation, difficulty exists in simultaneously meeting the vertical burn, smoke and toxicity provisions while additionally
maintaining mechanical, application, environmental and cost properties required for a commercially acceptable material.
This formulation successfully accomplishes this result by achieving vertical burn with a unique combination of materials and technology capable of delivering vertical burn performance without excessive smoke or toxicity characteristics.
The formulation has a high penetration ability when applied the nylon fibers and a high adhesion which locks in the carpet fibers. The formulation is tough, to assure dimensional stability and provide long service life. The formulation is also elastomeric so as to eliminate concerns about shrinkage.
It is understood that the foregoing detailed description is given merely by way of illustration and that many variations may be made therein without departing from the spirit of this invention.
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