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Title:
LUMINESCENT CYCLOMETALATING TRIDENTATE LIGAND-CONTAINING GOLD (III) COMPOUNDS WITH ARYL AUXILIARY LIGANDS FOR ORGANIC LIGHT-EMITTING DEVICES AND THEIR PREPARATION THEREOF
Document Type and Number:
WIPO Patent Application WO/2018/064974
Kind Code:
A1
Abstract:
A novel class of gold (III) compounds containing cyclometalated tridentate ligand and one aryl auxiliary ligand, both coordinated to a gold (III) metal center. (a) X is nitrogen or carbon; (b) Y and Z are independently nitrogen or carbon; (c) Ais cyclic structure (derivative) ofpyridine, quinoline, isoquinoline or phenyl group; (d) B and C are independently cyclic structures (derivatives) of pyridine, quinoline, isoquinoline or phenyl groups; (e) B and C can be identical or non-identical, with the proviso that both B and C are not 4-tert-butylbenzene; (f) R'is a substituted carbon, nitrogen, oxygen or sulfur donor ligand attached to the gold atom; (g) n is zero, apositive integer or a negative integer. wherein R'is selected from, but not limited to, aryl, substituted aryl, heteroaryl, substituted heteroaryl, heterocyclic aryl and substituted heterocyclic aryl, alkoxy, aryloxy, amide, thiolate, sulfonate, phosphide, fluoride, chloride, bromide, iodide, cyanate, thiocyanate or cyanide. Rings A, B and C are independently benzene or pyridine, or aryl (derivatives) or pyridyl, quinolyl, isoquinolyl (derivatives) with, but not limited to, one or more alkyl, alkenyl, alkynyl, alkylaryl, cycloalkyl, OR, NR2, SR, C (O) R, C (O) OR, C (O) NR2, CN, CF3, NO2, SO2, SOR, SO3R, halo, aryl, substituted aryl, heteroaryl, substituted heteroaryl or heterocyclic group, wherein R is independently alkyl, alkenyl, alkynyl, alkyaryl, aryl, or cycloalkyl.

Inventors:
YAM WING-WAH (CN)
TANG MAN CHUNG (CN)
CHAN MEI YEE (CN)
LEE CHIN HO (CN)
LI LOK KWAN (CN)
Application Number:
PCT/CN2017/105241
Publication Date:
April 12, 2018
Filing Date:
October 03, 2017
Export Citation:
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Assignee:
UNIV HONG KONG (CN)
International Classes:
C09K11/06; H05B33/14
Foreign References:
CN101098946A2008-01-02
CN101128507A2008-02-20
Other References:
CORBO, ROBERT ET AL.: "Access to the Parent Tetrakis(pyridine)gold(III) Trication, Facile Formation of Rare Au(III) Terminal Hydroxides, and Preliminary Studies of Biological Properties", INORGANIC CHEMISTRY, vol. 55, no. 6, 1 March 2016 (2016-03-01), pages 2830 - 2839, XP055476785
GIMENO, M. CONCEPCION ET AL.: "Synthesis, Photochemical, and Redox Properties of Gold(I) and Gold(III) Pincer Complexes Incorporating a 2, 2':6', 2''-Terpyridine Ligand Framework", INORGANIC CHEMISTRY, vol. 54, no. 22, 23 October 2015 (2015-10-23), pages 10667 - 10677, XP055476788
CORBO, ROBERT ET AL.: "Facile Formation of Homoleptic Au(III) Trications via Simultaneous", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 136, no. 35, 19 August 2014 (2014-08-19), pages 12415 - 12421, XP055476792
ZHANG, JING-JING ET AL.: "Organogold(III) Supramolecular Polymers for Anticancer Treatment", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 51, no. 20, 31 December 2012 (2012-12-31), pages 4882 - 4886, XP055476793
WONG, KAR-HO ET AL.: "Application of 2, 6-Diphenylpyridine as a Tridentate [L] Dianionic Ligand in Organogold(III) Chemistry. Structural and Spectroscopic Properties of Mono- and Binuclear Transmetalated Gold(III) Complexes", ORGANOMETALLICS, vol. 17, no. 16, 7 October 1998 (1998-10-07), pages 3505 - 3511, XP055476797
KUMAR, ROOPENDER ET AL.: "Evidence for Direct Transmetalation of AuIII-F with Boronic Acids", JACS, vol. 138, no. 42, 29 September 2016 (2016-09-29), pages 13790 - 13793, XP055476800
Attorney, Agent or Firm:
CHINA PATENT AGENT (H.K.) LTD. (CN)
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