Title:
MACROSCOPIC ARRAY ELECTRODE AND PREPARATION METHOD THEREFOR AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2023/245868
Kind Code:
A1
Abstract:
The present invention relates to the technical field of electrocatalysis and electrode design and manufacturing, and in particular, to a macroscopic array electrode and a preparation method therefor and a use thereof. The present invention provides a macroscopic array electrode, comprising a conductive substrate and a wettability regulation and control layer deposited on the surface of the conductive substrate. The conductive substrate comprises a base and a cone array on the surface of the base, and the cone array is composed of cones; an included angle between each cone and a vertical direction of the base is 0-85°; and the wettability regulation and control layer is composed of nanoparticle aggregates. In the present invention, the cone and the vertical direction of the base in the array electrode have a certain angle, and good bubble traction force is provided under the combined action of the Laplace force caused by a shape gradient and a buoyancy component; and the wettability regulation and control layer enables the array electrode to have a gasophobic surface in an adhesive state, and the array electrode provided in the present invention is used for performing a gas evolution reaction, so that according to the electrode, bubbles generated by the gas evolution reaction can be directionally transported.
Inventors:
SUN XIAOMING (CN)
LUO LIANG (CN)
YANG YINGZE (CN)
LUO LIANG (CN)
YANG YINGZE (CN)
Application Number:
PCT/CN2022/116536
Publication Date:
December 28, 2023
Filing Date:
September 01, 2022
Export Citation:
Assignee:
UNIV BEIJING CHEM TECH (CN)
International Classes:
C25B11/054; C25B11/02; C25D5/10
Foreign References:
| CN114959763A | 2022-08-30 | |||
| CN113215604A | 2021-08-06 | |||
| CN112853392A | 2021-05-28 | |||
| CN114134528A | 2022-03-04 | |||
| CN114177961A | 2022-03-15 | |||
| CN111188056A | 2020-05-22 | |||
| DE4039018A1 | 1992-06-11 |
Other References:
CUNMING YU ET AL.: "Spontaneous and Directional Transportation of Gas Bubbles on Superhydrophobic Cones", ADVANCED FUNCTIONAL MATERIALS, vol. 26, no. 19, 30 March 2016 (2016-03-30), pages 3236 - 3243, XP072411397, ISSN: 1616-301X, DOI: 10.1002/adfm.201505234
XUE XIUZHAN, YU CUNMING, WANG JINGMING, JIANG LEI: "Superhydrophobic Cones for Continuous Collection and Directional Transportation of CO 2 Microbubbles in CO 2 Supersaturated Solutions", ACS NANO, AMERICAN CHEMICAL SOCIETY, US, vol. 10, no. 12, 27 December 2016 (2016-12-27), US , pages 10887 - 10893, XP093119239, ISSN: 1936-0851, DOI: 10.1021/acsnano.6b05371
YINGJIE LI ET AL.: "Under-Water Superaerophobic Pine-Shaped Pt Nanoarray Electrode for Ultrahigh-Performance Hydrogen Evolution", ADVANCED FUNCTIONAL MATERIALS, vol. 25, no. 11, 10 February 2015 (2015-02-10), pages 1737 - 1744, XP072292072, ISSN: 1616-301X, DOI: 10.1002/adfm.201404250
ZHAO YAN, ZHANG YALI: "Advances in Nano-array Electrode Research", DAXUE HUAXUE, vol. 19, no. 5, 31 October 2004 (2004-10-31), pages 1 - 7, XP009551284, ISSN: 1000-8438
SHENG JINHUA; XU WENWEN; LU ZHIYI; SUN XIAOMING: "Recent Progress in the Use of Superwetting Nano Array Electrodes for Gas-Involved Electrocatalysis", JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY (NATURAL SCIENCE EDITION), BEIJING HUAGONG DAXUE, CN, vol. 45, no. 5, 29 October 2018 (2018-10-29), CN , pages 54 - 63, XP009551314, ISSN: 1671-4628, DOI: 10.13543/j.bhxbzr.2018.05.007
XUE XIUZHAN, YU CUNMING, WANG JINGMING, JIANG LEI: "Superhydrophobic Cones for Continuous Collection and Directional Transportation of CO 2 Microbubbles in CO 2 Supersaturated Solutions", ACS NANO, AMERICAN CHEMICAL SOCIETY, US, vol. 10, no. 12, 27 December 2016 (2016-12-27), US , pages 10887 - 10893, XP093119239, ISSN: 1936-0851, DOI: 10.1021/acsnano.6b05371
YINGJIE LI ET AL.: "Under-Water Superaerophobic Pine-Shaped Pt Nanoarray Electrode for Ultrahigh-Performance Hydrogen Evolution", ADVANCED FUNCTIONAL MATERIALS, vol. 25, no. 11, 10 February 2015 (2015-02-10), pages 1737 - 1744, XP072292072, ISSN: 1616-301X, DOI: 10.1002/adfm.201404250
ZHAO YAN, ZHANG YALI: "Advances in Nano-array Electrode Research", DAXUE HUAXUE, vol. 19, no. 5, 31 October 2004 (2004-10-31), pages 1 - 7, XP009551284, ISSN: 1000-8438
SHENG JINHUA; XU WENWEN; LU ZHIYI; SUN XIAOMING: "Recent Progress in the Use of Superwetting Nano Array Electrodes for Gas-Involved Electrocatalysis", JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY (NATURAL SCIENCE EDITION), BEIJING HUAGONG DAXUE, CN, vol. 45, no. 5, 29 October 2018 (2018-10-29), CN , pages 54 - 63, XP009551314, ISSN: 1671-4628, DOI: 10.13543/j.bhxbzr.2018.05.007
Attorney, Agent or Firm:
BEIJING LINGZHUAN INTELLECTUAL PROPERTY AGENCY CO., LTD (CN)
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