Poly (tetra methylene ether glycol) is obtained by polymerization of tetrahydrofuran. This polymer is used as chain segments in polyurethanes and polyesters. Polyurethanes based on poly (tetra methylene ether glycol) soft-segment have improved hydrolytic stability, abrasion resistance and elastomeric properties. Other benefits include strength, toughness, durability, low compression set property, and high water vapor permeability. The largest end-use area is in spandex fibers for apparel.

The products containing poly (tetra methylene ether glycol) are used in wheels, high-speed rolls, automotive parts, bushings, specialty hose, cable sheathing and coating, pipeline liners, roof, and floor coatings. The 3-methyl-tetrahydrofuran monomer can be utilized as a comonomer for modifying poly (tetra methylene ether glycol) to yield better elastomeric properties.

In use of tetrahydrofuran as a solvent where lower volatility is desired, 3-methyl-tetrahydrofuran is advantageous because tetrahydrofuran boils at 66°C whereas 3-methyl-tetrahydrofuran boils at 86°C.

Processes for producing 3-methyl-tetrahydrofuran, by hydrogenation of an itaconic acid ester or a 3-formyl-2-methylpropionic acid ester, and by hydrogenation of a methyl-succinic ester are described in Japanese Patent Applications 219981/1994 and 217768/1996, respectively. Along with the objective 3-methyl-tetrahydrofuran, these reactions produce an alcohol, which has to be separated in a further step.

The 3-methyl-tetrahydrofuran forms an azeotropic mixture with most of the

lower alcohols, for example, with methanol having an azeotropic point at 64. 5°C, and an azeotropic composition consisting of 25% by weight of 3-methyl-tetrahydrofuran and 75% by weight of methanol. The azeotropic distillation requires energy for separating the two components. In particular, the 3-methyl-tetrahydrofuran which is employed for modifying poly (tetramethylene glycol) can tolerate an alcohol impurity of less than 0.2%.

A process for producing 3-methyl-tetrahydrofuran, by hydrogenation of beta-formylisobutyric acid ester with the following general formula is described in U. S. Patent No. 5,990, 324: ROOC-CH (CH3)-CH2-CHO, wherein, R is an alkyl group having 1 to 3 carbon atoms and the formyl group may be present as an acetal having an alkanol with 1 to 8 carbon atoms. In this process, the alcohol is separated from 2-methyl-gamma- butyrolactone in the second step of the three-step process. This separation can be effected by simple distillation. Azeotropic distillation is not required. However, a separation of the alcohol is still a necessary step in the process.

The present invention describes a two-step route to produce 3- methyl-tetrahydrofuran from alpha-methylene-gamma-butyrolactone, without any alcohol production or separation during the two steps.

SUMMARY OF INVENTION This invention relates to a continuous process for producing 3- methyl-tetrahydrofuran, which comprises the steps of: (a) subjecting the compound represented by the formula (I), alpha-methylene-gamma-butyrolactone, to hydrogenation to yield 2- methyl-gamma-butytrolactone (11) ; and (b) hydrogenating the 2-methyl-gamma-butytrolactone produced in step (a), to yield 3-methyl-tetrahydrofuran (III) as product.

DETAILED DESCRIPTION OF THE INVENTION By"alpha-methylene-gamma-butyrolactone"ismeantthe compound described in the formula below.

alpha-methylene-gamma-butyrolactone By"acid promoter"is meant a compound acidic in nature that is added to enhance the physical or chemical function of a catalyst.

By"metal promoter"is meant a metallic compound that is added to enhance the physical or chemical function of a catalyst.

This invention relates to synthesis of 3-methyl-tetrahydrofuran from alpha-methylene-gamma-butyrolactone reactant. More specifically, this invention relates to synthesis of 3-methyl-tetrahydrofuran in a two step continuous process from alpha-methylene-gamma-butyrolactone, which is free from an alcohol as a side product. The final product does not need separation or purification of alcohol. Owing to the high temperature of the catalytic reactions (greater than 150°C), previous attempts to directly convert alpha-methylene-gamma-butyrolactone to 3-methyl- tetrahydrofuran have resulted in the formation of a polymer of methylene- gamma-butyrolactone monomer. Therefore, an improved process to synthesize 3-methyl-tetrahydrofuran was desired.

A process for making 3-methyl-tetrahydrofuran from an acid- catalyzed, two-step hydrogenation of alpha-methylene-gamma- butyrolactone is disclosed. In a preferred embodiment, the hydrogenation of alpha-methylene-gamma-butyrolactone is carried out in two steps wherein first, alpha-methylene-gamma-butyrolactone is hydrogenated to 2- methyl-gamma-butyrolactone and second, 2-methyl-gamma-butyrolactone is further reduced/hydrogenated to final product.

In the first step of the process, the-methylene double bond of the alpha-methylene-gamma-butyrolactone reactant is hydrogenated to yield 2-methyl-gamma-butyrolactone as the intermediate product. This reaction is carried out under mild conditions to avoid the formation of poly (alpha-

methylene-gamma-butyrolactone). A metal catalyst, with or without a support may be present to effect the hydrogenation reaction. An acid material may optionally be used as a promoter to aid the reaction. A metal may also be optionally used as a promoter to aid the reaction.

In the second step of the process, the intermediate product, 2- methyl-gamma-butytrolactone is reduced by hydrogenation to yield 3- methyl-tetrahydrofuran, the desired product. This reaction is carried out at a higher temperature than the first hydrogenation step. A metal catalyst, with or without a support may be present to effect the reduction reaction.

An acid system may be used as a promoter to effect the reaction. A metal may also be optionally used as a promoter to aid the reaction.

The process of the present invention may be carried out in batch, sequential batch (i. e. , a series of batch reactors) or in continuous mode in any of the equipment customarily employed for continuous process. The condensate water is optionally removed from the reaction mass with the aid of an inert gas purge.

The temperature of the process is controlled in order to achieve a high yield of 2-methyl-gamma-butyrolactone in step (a) and a high yield of 3-methyl-tetrahydrofuran in step (b). Temperature range of from about 90°C to about 250° is employed in step (a) of the synthesis and temperature range of from about 100°C to about 250°C, in step (b). A temperature range of from about 135°C to about 165°C is preferred in step (a) of the synthesis and a temperature range of from about 200°C to about 250°C is preferred in step (b). Another preferred temperature range for step (a) is from about 215°C to about 240°C. A further preferred range for step (b) is from about 215°C to about 240°C.

A pressure range of from about 1.0 MPa to about 14.0 MPa is employed in step (a) of the synthesis and pressure range of from about 1.0 MPa to about 15 MPa, in step (b). Pressure range of from about 4.0 MPa to about 8.0 MPa is preferred in step (a) of the synthesis and pressure range of from about 8.0 MPa to about 10.0 MPa is preferred in step (b).

A catalyst is a substance that affects the rate of the reaction but not the reaction equilibrium, and emerges from the process, chemically unchanged. A chemical promoter generally augments the activity of a catalyst. The promoter may be incorporated into the catalyst during any step in the chemical processing of the catalyst constituent. The chemical

promoter generally enhances the physical or chemical function of the catalyst agent, but can also be added to retard undesirable side reactions.

Hydrogenation of alpha-methylene-gamma-butyrolactone to 2-methyl-gamma-butyrolactone as disclosed in step (a), is effected in presence of a catalytic metal. The principal component of the catalyst is selected from the group consisting of palladium, ruthenium, rhenium, rhodium, iridium, platinum, compounds thereof, and combinations thereof.

The metal catalyst used in step (a) of the process disclosed may be used as a supported or as an unsupported catalyst. A supported catalyst is one which in which the active catalyst agent is deposited on a support material by spraying, soaking or physical mixing, followed by drying, calcination, and if necessary, activation through methods such as reduction or oxidation. Materials frequently used as support are porous solids with high total surface areas (external and internal) which can provide high concentrations of active sites per unit weight of catalyst. The catalyst support may enhance the function of the catalyst agent. A catalyst which is not supported on a catalyst support material is an unsupported catalyst. A support material is selected from the group consisting of carbon, alumina, silica, silica-alumina, titania, and a combination thereof. Moreover, supported catalytic metal/s may have the same supporting material or different supporting material. A more preferred support is carbon. The carbon can be a commercially available carbon such as Calsicat C, Sibunit C, or Calgon C (under the trade name Centaur (R)).

A preferred catalytic metal content range of the supported catalyst is from about 0. 1% to about 15%. A more preferred catalytic metal content range is from about 1% to about 7%. A further preferred catalytic metal content range is from about 1% to about 5%.

Preferred combinations of catalytic metal and support system includes palladium on carbon, palladium on silica, ruthenium on carbon, ruthenium on alumina, rhodium on carbon, and rhodium on alumina.

An acid promoter may be used in step (a) of synthesis in the present invention. Suitable promoters include, those acids with a pKa less than about 4, preferably with a pKa less than about 2, including inorganic acids, organic sulfonic acids, heteropolyacids, perfluoroalkylsulfonic acids, and mixtures thereof. Also suitable are metal salts of acids with pKa less than about 4, including metal sulfonates, metal trifluoroacetates, metal triflates, and mixtures thereof including mixtures of salts with their

conjugate acids. Specific examples of promoters include sulfuric acid, fluorosulfonic acid, phosphoric acid, p-toluenesulfonic acid, benzenesulfonic acid, phosphotungtstic acid, phosphomolybdic acid, trifluromethanesulfonic acid, 1,1, 2, 2-tetrafluroethanesulfonic acid, 1,2, 3,2, 3, 3-hexapropanesulfonic acid, bismuth triflate, yttrium triflate, ytterbium triflate, neodymium triflate, lanthanum triflate, scandium triflate, and zirconium triflate. A preferred promoter is selected from Zn (BF4) 2 or CBV-3020 zeolite. The acid promoter is used in concentration of from 0. 1% to 5% by weight of the reactant. A preferred concentration range is 0.25% to 2.5% by weight of the reactant.

Suitable heterogeneous acid promoters are zeolites, fluorinated alumina, acid-treated silica, acid treated silica-alumina, acid treated clays, heterogeneous heteropolyacids and sulfate zirconia.

A metal promoter may be used optionally with the acid promoter in reaction of the present invention. Suitable metal promoters include tin, zinc, copper, gold, silver, and combinations thereof. The preferred metal promoter is tin. Reduction of 2-methyl-gamma-butyrolactone to 3-methyl- tetrahydrofuran product and water as disclosed in step (b), is effected in presence of a metal catalyst. The catalytic metal component of the catalyst is selected from the group consisting of metals of Group 7,8, 9, 1 O, of the Periodic Table, compounds of a metal of group 7,8, 9,10 of the Periodic Table,, compounds thereof, combinations thereof, copper, and copper compounds.

The catalytic metal used in step (b) of the process disclosed here may be used as supported or an unsupported catalyst. A support material is selected from the group consisting of carbon, alumina, silica, silica- alumina, titania, and a combination thereof. Moreover, supported catalytic metal/s may have the same supporting material or different supporting material. A more preferred support is carbon. The carbon can be a commercially available carbon such as Calsicat C, Sibunit C, or Calgon C (Centaur (R)).

A preferred catalytic metal content range is from about 0. 1% to about 25%. A more preferred catalytic metal content range is from about 1% to about 7%, and a further preferred catalytic metal content range is from about 1% to about 5%. Another preferred catalytic metal content is range is from about 18% to about 22%.

A preferred combination of catalytic metal and support system includes rhodium on carbon, rhenium on carbon, rhenium on alumina,

iridium on carbon, iridium on alumina, ruthenium on alumina, and a combination of (ruthenium + rhenium) on carbon.

An acid promoter may be used in step (b) of synthesis in the present invention. Suitable promoters include, those acids with a pKa less than about 4, preferably with a pKa less than about 2, including inorganic acids, organic sulfonic acids, heteropolyacids, perfluoroalkylsulfonic acids, and mixtures thereof. Also suitable are metal salts of acids with pKa less than about 4, including metal sulfonates, metal trifluoroacetates, metal triflates, and mixtures thereof including mixtures of salts with their conjugate acids. Specific examples of promoters include sulfuric acid, fluorosulfonic acid, phosphoric acid, p-toluenesulfonic acid, benzenesulfonic acid, phosphotungtstic acid, phosphomolybdic acid, trifluromethanesulfonic acid, 1,1, 2, 2-tetrafluroethanesulfonic acid,.

1,2, 3,2, 3, 3-hexapropanesulfonic acid, bismuth triflate, yttrium triflate, ytterbium triflate, neodymium triflate, lanthanum triflate, scandium triflate, and zirconium triflate. A preferred promoter is selected from group consisting of Zn (BF4) 2, zeolite CBV-1502, zeolite 20A, zeolite CBV 3020E, 13% Nafion (R), and methane sulfonic acid. The acid promoter is used in concentration of from 0. 1% to 5% by weight. A preferred concentration range is 0.25% to 2.5%.

Suitable heterogeneous promoters are zeolites, fluorinated alumina, acid-treated silica, acid treated silica-alumina, acid treated clays, heterogeneous heteropolyacids and sulfate zirconia.

A metal promoter may be used optionally with the acid promoter in reaction of the present invention. Suitable metal promoters include tin, zinc, copper, gold, silver, and combinations thereof. A preferred metal promoter is tin.

EXPERIMENTAL The following abbreviations are used in the Examples: ESCAT Series of catalysts provided by Engelhard Corp.

Calsicat Carbon Catalyst support from Engelhard Corp.

Sibunit Carbon Catalyst support from Inst. of Technical Carbon, Omsk, Russia JM-A11108 Carbon Catalyst support from Johnson Matthey, Inc.

Calgon Carbon Catalyst support from Calgon Corp. under the brand name of Centaur (R) CBV-3020E Type of Zeolite acid promoter

20-A Type of Zeolite acid promoter CBV-1502 Type of Zeolite acid promoter A commercially available support such as carbon, alumina, silica, silica-alumina, titania available from Engelhard Corp. (E. Windsor, CT) was impregnated by incipient wetness with a metal salt. The precursors used were NiC12. 6H20 (Alfa Chemical Co.), Re207 (Alfa Chemical Co. ), <BR> <BR> <BR> PdCl2 (Alfa Chemical Co. ), RuCl3. xH20 (Aldrich Chemical Co. ). H2PtCI6 (Johnson Matthey, Inc., W. Deptford, NJ), CrC13. 6H20 (Mallinckrodt Baker, Inc.), 5% Rh using RhCI3. xH20 (Alfa Chemical Co. ). The samples were dried and reduced at 300-450°C in H2 for 2 hours.

The carbon used was commercially available as Calsicat Carbon, Sibunit Carbon, or Calgon Carbon (Centaur (R)). Calsicat Carbon is lot S- 96-140 from Engelhard Corp. , Beachwood, OH. Sibunit Carbon is Sibunit- 2 from Institute of Technical Carbon, 5th Kordnaya, Omsk 64418, Russia.

Calgon Carbon is PCB Carbon from Calgon Corp. (under the registered trademark of Centaur (R)).

EXAMPLE-1 CATALYST PREPARATION 5% Pt on Acid Washed Calsicat Carbon In a 150 ml beaker, a solution was made up of 4.5 mi, 0.3 M H2PtCI6 with 4.0 ml deionized H20. To the beaker were added 4.75 g Calsicat Acid Washed Carbon (12x20 mesh, dried at 120°C overnight).

The slurry was allowed to stand at room temperature for 1 hr with occasional stirring and then dried at 120°C overnight with frequent stirring (until free flowing).

In an alumina boat, in a quartz lined tube furnace, the catalyst was purged with 500 SCCM N2 at room temperature for 15 min and then with 100 SCCM He at room temperature for 15 min. The catalyst was heated to 150°C and held at 150°C under He for 1 hr. At this point, 100 SCCM H2 were added and the sample was held at 150°C under He and H2 for 1 hr.

The temperature was increased to 300°C and the catalyst was reduced at 300°C under He-H2 for 8 hrs. The H2 was stopped, the sample was held at 300°C under He for 30 min and then cooled to room temperature in flowing He. The catalyst was finally passivated in 1.5% 02 in N2 at 500 SCCM for 1 hour at room temperature and weighed 4.93 grams when unloaded.

EXAMPLES 1-52: HYDROGENATION OF ALPHA-METHYLENE- GAMMA-BUTYROLACTONE TO 2-METHYL-GAMMA- BUTYROLACTONE-STEP (a) 50% alpha-methylene-gamma-butyrolactone in Dioxane (974.7 mg, 5.0 mmole) and an amount of catalyst with a support as indicated in Table 1, were added to a 2 ml batch reactor. The reactor was sealed and charged with pressure of H2 at 6.89 MPa for examples 1-8, and 23-26, 4.82 MPa for 14-22 and 27-52, and 1.38 MPa for 9-13, and heated to reaction temperature of 225°C for examples 1-8, and 23-26, and 150°C for 12-22 and 27-52, and 100°C for 9-11. The reaction was stopped after 2 hours for examples 1-7, and 23-52, and at 4 hours for examples 8-22 and rapidly cooled. An internal standard (2-methoxy ethyl ether) was added into the reaction mixture and GC analysis was performed on a HP- 6890 GC with a Chrompack column (CP-WAX 58,25 M x 0.25 MM). The following table lists the reaction conditions catalyst, acid promoter and conversion and selectivity of the reactant and products, respectively. All experiments were conducted with a 50% a-alpha-methylene-gamma- butyrolactone in dioxane.

Table 1 Ex. Time Temp H2 Catalyst/Support Acid a-MBL 2-Me-GBL 3-Me-THF No. (hrs) (°C) Pressure Conversio Selectivity Selectivity (MPa) n % % % 1. 2 225 6. 89 5% Pd/C (ESCAT140) 0 99. 21 83. 53 0. 23 2. 2 225 6. 89 5% Pd/C (ESCAT142) 0 85. 57 93. 72 0. 28 3. 2 225 6. 89 5% Pd/C (ESCAT143) 0 99. 49 96. 94 0. 19 4 2 225 6. 89 5% Pd/C (ESCAT148) 0 86. 71 97. 80 0. 33 5. 2 225 6. 89 5% Pd/C (ESCAT 149) 0 99. 92 94. 36 0. 14 6. 2 225 6. 89 5% Pd/C (ESCAT160) 0 95. 05 97. 80 0. 24 7. 2 225 6. 89 5% Pd/C (ESCAT162) 0 97. 87 88. 55 0. 15 8. 4 225 6. 89 5% Ru/Al203+5% 1r/0 98. 33 68. 52 0. 17 A) 203 9. 4 100 1. 38 5% Pd/C (JM-A11208- 0 100. 00 0. 00 0. 00 5) 10. 4 100 1. 38 5% Pd/C (JM-A11108- 0 56. 47 67. 70 0. 00 5) 11. 4 100 1. 38 5% Pd/C (JM-A11208- 0 65. 22 47. 97 0. 00 5) 12. 4 150 1. 38 5% Pd/C (JM-A11108- 0 48. 24 96. 37 0. 00 5) 13. 4 150 1. 38 5% Pd/C (JM-A11208- 0 53. 23 76. 40 0. 00 5) 14. 4 150 4. 82 5% Pd/C (JM-A11108- 0 86. 98 97. 46 0. 00 Ex. Time Temp H2 Catalyst/Support Acid #-MBL 2-Me-GBL 3-Me-THF No. (hrs) (°C) Pressure Conversio Selectivity Selectivity (MPa) n % % % 5) 15. 4 150 4.82 5%Pd/C(JM-A11208- 0 90.80 86.76 0.00 5) 16. 4 150 4.82 5%Pd/C(ESCAT 140) 0 99.32 94.44 0.00 17. 4 150 4.82 5%Pd/C(ESCAT 142) 0 98.66 90.84 0.00 18. 4 150 4.82 5%Pd/C(ESCAT 143) 0 98.76 91.10 0.00 19. 4 150 4.82 5%Pd/C(ESCAT 148) 0 94.99 89.87 0.00 20. 4 150 4.82 5%Pd/C(ESCAT 149) 0 99.94 86.35 0.00 21. 4 150 4.82 5%Pd/C(ESCAT 160) 0 96.16 84.32 0.00 22. 4 150 4.82 5%Pd/C(ESCAt 1620 0 99.64 86.08 0.00 23. 2 225 6.89 1%Ru/6%Re/C 0 99.44 90.27 0.16 24. 2 225 6.89 1.87%Ru/5.65%Re/0.7 0 83.75 7.10 0.00 7%Sn/C 25. 2 225 6.89 1.87%Ru/5.65%Re/0.7 Zn(BF4) 78.25 51.03 0.46 7%Sn/C 2 26. 2 225 6.89 1.87%Ru/%.65%Re/0.7 CBV- 97.76 1.14 0.06 7%Sn/C 3020 27. 2 150 4.82 5%Ru/Calsicat C 0 100.00 98.45 0.00 28. 2 150 4.82 5%RulAl2O3 0 100.00 96.77 0.00 29. 2 150 4.82 5%Ru/SiO2 0 70.47 77.90 0.00 30. 2 150 4.82 5%Rh/Calsicat C 0 100.00 95.24 0.00 31. 2 150 4.82 5%Rh/Al2O3 0 100.00 94.30 0.00 Ex. Time Temp H2 Catalyst/Support Acid #-MBL 2-Me-GBL 3-Me-THF No. (hrs) (°C) Pressure Conversio Selectivity Selectivity (MPa) n % % 32. 2 150 4.82 5%Rh/ SiO2 0 71.09 57.66 0.00 33. 2 150 4.82 5%Pd/Calsicat C 0 100.00 98.35 0.00 34. 2 150 4.82 5%Pd/Al2O3 0 87.66 94.31 0.00 35. 2 150 4.82 5%pd/SiO2 0 100.00 93.50 0.00 36. 2 150 4.82 5%lr/Calsicat C 0 60.94 66.85 0.00 37. 2 150 4.82 5%lr/Al2O3 0 68.01 58.23 0.00 38. 2 150 4.82 5%lr/ SiO2 0 65.92 66.74 0.00 39. 2 150 4.82 5%Pt/Sibunit C 0 91.57 93.37 0.00 40 2 150 4.82 5%Pt/Al2O3 0 59.61 88.22 0.00 41. 2 150 4.82 5%Pt/C ESCAT-248 0 74.49 97.88 0.00 42. 2 150 4.82 5%Pt/C ESCAT-268 0 79.67 98.05 0.00 43. 2 150 4.82 5%Pt/Al2O3 ESCAT- 0 43.30 94.61 0.00 294 44. 2 150 4.82 5%Pt/C JM-B21142-5 0 64.07 95.02 0.00 45. 2 150 4.82 5%Pt/C JM-B21142-5 0 68.64 99.88 0.00 46. 2 150 4.82 10%Pt/C 0 27.97 82.60 0.00 47. 2 150 4.82 5%Ru/Calsicat C 0 99.75 85.32 0.00 48. 2 150 4.82 5%Ru/Al2O3 0 100.00 78.08 0.00 49. 2 150 4.82 5%Rh/Calsicat C 0 100.00 82.62 0.00 50. 2 150 4.82 5%Rh/Ai2O3 0 100.00 74.50 0.00 51. 2 150 4.82 5%Pd/Calsicat C 0 100.00 79.99 0.00 52. 2 150 6.89 5%Pd/Al2O3 0 100.00 73.96 0.00

EXAMPLES 53-116: REDUCTION OF 2-METHYL-GAMMA- BUTYROLACTONE TO 3-METHYL-TETRAHYDROFURAN-STEP (b) 50% 2-methyl-y-butyrolactone in dioxane (970.0 mg, 4.84 mmole) and an amount of catalyst and support as indicated in Table 2 were added to a 2 ml batch reactor. The reactor was sealed and charged with 6.89 MPa of H2, and heated to 225°C, and then cooled rapidly. The reaction was stopped after 4 hours. An internal standard (2-methoxy ethyl ether) was added to the reaction mixture and GC analysis was performed on a HP-6890 GC with a Chrompack column (CP-WAX 58, 25 M x 0.25 MM). An acid promoter was not used for examples 53-85. An acid promoter was used for examples 86-116.

TABLE 2: EXAMPLES 53-85 Ex. Time Temp. H2 Catalyst/Acid 2-Me-GBL 3-MeTHF No. (hrs) (°C) Pressure Support Convers-Selecti- (MPa) ion (%) vity (%) 53.4 225 6.89 1 % Ru/6% Re/C 19. 56 49.12 54. 4 225 6. 89 5% Rh/Sibunit C 9. 21 12. 76 55.4 225 6.89 5%Pt/Sibunit C 2.12 29. 23 56.4 225 6. 89 5% Ru/Calsicat C 9. 87 77. 56 57.4 225 6. 89 5% Rh/Calsicat C 5. 12 91. 38 58. 4 225 6.89 5%Pd/Calsicat C 2.44 70. 21 59.4 225 6. 89 5% Re/Calsicat C 31. 24 97. 91 60 4 225 6.89 5%lr/Calsicat C 8.95 92. 01 61. 4 225 6. 89 5% Pt/Sibunit C 2. 40 82. 19 62 4 225 6.89 5%Ru/ Al2O3 1.60 95. 57 63. 4 225 6.89 5%Rh/ Al2O3 26.60 3.45 64.4 225 6. 89 5% Pd/Al2°3 88. 01 0. 80 65.4 225 6. 89 5% Re/ AI203 7. 33 97. 75 66.4 225 6. 89 5% 1r/Al203 2. 00 96.21 67.4 225 6.89 5%Pt/ Al2O3 10.62 24. 69 Ex. Time Temp. H2 Catalystl Acid 2-Me-GBL 3-MeTHF No. (hrs) (°C) Pressure Support Convers-Selecti- (MPa) ion (%) vity (%) 68. 4 225 6. 89 5% Ru/SiO2 5. 50 10. 01 69. 4 225 89 5% Rh/ Si 19. 51 1. 67 70. 4 225 6. 89 5% Pd/SiO2 31. 30 1. 23 71. 4 6. 89 5% Re/ Si02 8. 46 41. 56 72. 4 225 6. 89 5% lr/ Si02 1. 83 31. 17 ---2-5 5% Pt/ Si02- 73. 4 225 6. 89 5% PV SiO2 17. 41 3. 50 74. 4 225 6. 89 5% Re/Sibunit C 32. 87 53. 09 75. 4 on C 14. 50 31. 75 76. 4 225 6. 89 5% Re/Sibunit 42. 45 31. 39 C (400C) 77. 4 225 6. 89 5% Re/Sibunit 24. 33 46. 33 C (450C) 78. 4 225 6. 89 10% Re/Sibunit 36. 34 35. 26 C (400C) 79. 4 225 6. 89 10% Re/Sibunit 44. 95 30. 02 C (450C) 80. 4 6. 89 5% Re/Calsicat 36. 24 94. 20 C (400C) 81. 4 225 6. 89 5% Re/Calsicat 35. 77 91. 63 C (450C) 82. 4 225 6. 89 10% Re/Calsicat 46. 13 90. 11 C (400C) 83. 4 225 6. 89 10% Re/Calsicat 49. 41 91. 19 C (450C) _ 84. 4 225 6. 89 20% Re/Calsicat 64. 74 86. 26 C 400C 85. 4 225 6. 89 20% Re/Calsicat 72. 11 78. 25 C (450C) TABLE 3 : EXAMPLES 86-116 Ex. Time Temp Hz Catatyst Acid 2-Me-GBL 3-Me-THF No. (hrs) (°C) Pressure/Support Conver-Selecti- MPa sion (%) vity (%) 86. 4 225 6. 89 1 % Ru/6% Re/C Zn (BF4) 2 18. 68 80. 61 tt 225 6. 89 1 % Ru/6% Re/C CBV-10. 94 89. 96 1502 88. 4 225 6. 89 I% Ru/6% Re/C 20A 2. 70 48. 33 89. 4 225 6. 89 5% RhlSibunit Zn (BF4) 2 6. 15 6. 79 C Ex. Time Temp H2 Catalyst Acid 2-Me-GBL 3-Me-THF No. (hrs) (oC) Pressure/Support Conver-Selecti- (MPa) sion (%) vity (%) 90. 4 225 6. 89 5% Rh/Sibunit CBV-2. 21 40. 48 C 1502 91. 4 225 6. 89 5% Pt/Sibunit C Zn (BF4) 2 1. 37 31. 66 92. 4 225 6. 89 5% Pt/Sibunit C CBV-4. 83 6. 35 1502 93. 4 225 6. 89 5% Pd/Calsicat Zn (BF4) 2 10. 08 92. 06 C 94. 4 225 6. 89 5% Pd/Calsicat CBV-4. 75 8. 31 C 3020E 95. 4 225 6. 89 5% Pd/Calsicat 13% NAFI 1. 37 18. 57 C ON 96. 4 225 6. 89 5% Pd/Calsicat MSA 2. 48 11. 71 C 97. 4 225 6. 89 5% Ru/Calsicat Zn (BF4) 2 6. 90 86. 35 C 98. 4 225 6. 89 5% RulCalsicat CBV-3. 16 62. 88 C 3020E 99. 4 225 6. 89 5% RulCalsicat 13% NAFI 6. 11 57. 65 C ON (R) 100. 4 225 6. 89 5% Ru/Calsicat MSA 8. 59 32. 53 C 101. 4 225 6. 89 5% Re/Calsicat Zn (BF4) 2 4. 07 72. 97 C 102. 4 225 6. 89 5% Re/Calsicat CBV-8. 42 79. 78 C 3020E 103. 4 225 6. 89 5% Re/Calsicat 13% NAFI 10. 21 91. 35 C ON (R) 104. 4 225 6. 89 5% Re/Calsicat MSA 16. 03 92. 79 C 105. 4 225 6. 89 5% Rh/Calsicat Zn (BF4) 2 0. 69 57. 72 C 106. 4 225 6. 89 5% Rh/Calsicat CBV-1. 01 70. 50 C 3020E 107. 4 225 6. 89 5% Rh/Calsicat 13% NAFI 1. 14 42. 94 C ON (R) 108. 4 225 6. 89 5% Rh/Calsicat MSA 2. 34 38. 14 C 109. 4'225 6. 89 5% Pt/Sibunit C Zn (BF4) 2 2. 01 35. 66 110. 4 225 6. 89 5% Pt/Sibunit C CBV-0. 61 31. 75 3020E 111. 4 225 6. 89 5% Pt/Sibunit C 13% NAFI 2. 07 30. 65 ON 112. 4 225 6. 89 5% Pt/Sibunit C MSA 2. 67 24. 09 113. 225 6. 69 5% 1r/Calsicat C Zn (BF4) 2 1. 39 71. 80 Ex. Time Temp H2 Catalyst Acid 2-Me-GBL 3-Me-THF No. (hrs) (°C) Pressure/Support Conver-Selecti- (MPa) sion (%) vity (%) 114.4 225 6.89 5% lr/Calsicat C CBV- 2. 63 54.40 3020E 115. 4 225 6.89 5%lr/Calsicat C 13%NAFI 1.77 63. 55 ON (R) 116.4 225 6.89 5%lr/Calsicat C MSA 3.03 55.50