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Title:
MANUFACTURING METHOD OF A STEEL PRODUCT
Document Type and Number:
WIPO Patent Application WO/2022/180427
Kind Code:
A1
Abstract:
A method to manufacture a steel product in a steelmaking plant comprising several different tools, the method including the definition of at least two manufacturing routes using different tools and the calculation of the expected level of CO2 emissions associated to each of this defined manufacturing routes.

Inventors:
DA GAMA CAMPOS HUGO (GB)
VAN DER HOEVEN JEAN-MARTIN (LU)
Application Number:
PCT/IB2021/051614
Publication Date:
September 01, 2022
Filing Date:
February 26, 2021
Export Citation:
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Assignee:
ARCELORMITTAL (LU)
International Classes:
C21B13/00
Other References:
SONG JIAYUAN ET AL: "Comparison of Energy Consumption and CO2 Emission for Three Steel Production Routes-Integrated Steel Plant Equipped with Blast Furnace, Oxygen Blast Furnace or COREX", METALS, vol. 9, no. 3, 21 March 2019 (2019-03-21), pages 364, XP055840776, DOI: 10.3390/met9030364
RYMAN CHRISTER ET AL: "Reduction of CO2 Emissions from Integrated Steelmaking by Optimised Scrap Strategies: Application of Process Integration Models on the BF-BOF System", 12 December 2006 (2006-12-12), pages 1 - 7, XP055844347, Retrieved from the Internet [retrieved on 20210924]
RAMMER BARBARA ET AL: "Comparing the CO2Emissions of Different Steelmaking Routes", BHM. BERG UND HUETTENMAENNISCHE MONATSHEFTE, SPRINGER, VIENNA, AU, vol. 162, no. 1, 5 January 2017 (2017-01-05), pages 7 - 13, XP036140025, ISSN: 0005-8912, [retrieved on 20170105], DOI: 10.1007/S00501-016-0561-8
WANG C ET AL: "Potential CO"2 emission reduction for BF-BOF steelmaking based on optimised use of ferrous burden materials", INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, ELSEVIER, AMSTERDAM, NL, vol. 3, no. 1, 1 January 2009 (2009-01-01), pages 29 - 38, XP025851048, ISSN: 1750-5836, [retrieved on 20080715], DOI: 10.1016/J.IJGGC.2008.06.005
Attorney, Agent or Firm:
PLAISANT, Sophie (FR)
Download PDF:
Claims:
CLAIMS

1) A method of manufacturing a steel product P in a steelmaking plant S comprising several manufacturing tools Tx, the method including the following steps:

- Defining 100 at least two different manufacturing routes MRi using tools Tx allowing to manufacture the product P,

- Calculating 110, for each defined manufacturing route MRi, an expected level of C02 emissions Eexpi to manufacture the steel product P according to manufacture route MRi, such calculation being done considering all CO2 contributions associated to raw materials, energy sources and processes used for manufacturing the steel product according to each manufacture route MRi,

- producing the steel product P using tools Tx according to the manufacturing route MRi having the lowest calculated expected level of C02 emissions Eexpi. 2) Method according to claim 1 including a first step of target definition wherein a maximum level of C02 emissions Emax is predefined for the manufacturing of the steel product P and the producing step 100 is performed only if Eexpi is inferior or equal to Emax, otherwise new manufacturing routes MRi are defined and new associated expected level of C02 emissions Eexpi are calculated. 3) Method according to claim 1 or 2 wherein raw material are chosen among scrap, iron ore, coal, coke, sinter feed, pellets, gases

4) Method according to claim 3 wherein scrap is of different types and is chosen among old scrap, new scrap, prime scrap, home scrap, pit scrap, shredded, plates and structure scrap, heavy melting scrap, cast scrap, coil scrap or busheling scrap. 5) Method according to anyone of the previous claims wherein energy sources are chosen among renewable electricity, electricity produced by internal recycling of exhaust gas from the steel manufacturing process or by capture of heat released by products from the steel manufacturing process. 6) Method according to anyone of the previous claims wherein processes are chosen among direct reduction processes, hydrogen-based ironmaking, steel electrolysis, blast furnace with top-gas recycling, blast furnace with top-gas conversion, electric-arc-furnace steelmaking, converter steelmaking, scrap melting. 7) Method according to anyone of the previous claims including a step, after the production step, of establishing a certificate for the manufactured steel indicated the level Eexpi of C02 emissions associated to its manufacturing route.

8) Method according to anyone of the previous claims wherein the tools Tx are chosen among a coking plant, a sintering plant, a direct-reduction plant, a blast furnace, an electric — arc furnace, a converter, a ladle, a H2 production plant, a chemical plant, a biotech plant, a power plant, a ladle, a furnace, a casting plant, a rolling plant, gas cleaning devices, heat recovery devices, hot stoves.

Description:
Manufacturing method of a steel product

[001] The invention is related to a method of manufacturing steel.

[002] Steel industry, like many other human activities, is a source of C02 emission in the atmosphere. Many technologies are implemented or under development to decrease those C02 emissions at different levels of the production, through for example recycling of blast furnace, coke oven or converter top gas. This recycling may be performed, after appropriate treatments, by injection into another steelmaking device or use as syngas for other productions. [003] These technologies aim to decrease direct C02 emissions of the manufacturing of steel products.

[004] However, customer of such steel products, such as car makers, also have to reduce the carbon footprint of their products and to do so request steel products fulfilling all their usual standards in terms of physical properties and quality, but also in terms of carbon footprint. This C02 carbon footprint is not limited to the direct emissions of the manufacturing process itself.

[005] There is so a need for a method allowing to determine and reduce the C02 footprint of steel products.

[006] This problem is solved by a method according to the invention wherein a steel product is to be manufactured in a steelmaking plant comprising several manufacturing tools, the method including the steps of defining at least two different manufacturing routes using tools allowing to manufacture the steel product, calculating, for each defined manufacturing route, an expected level of C02 emissions to manufacture the steel product according to each manufacture route, such calculation being done considering all C02 contributions associated to raw materials, energy sources and processes used for manufacturing the steel product according to each manufacture route, and producing the steel product using the tools according to the manufacturing route =having the lowest calculated expected level of C02 emissions.

[007] The method of the invention may also comprise the following optional characteristics considered separately or according to all possible technical combinations:

- the method further comprises a first step of target definition wherein a maximum level of C02 emissions is predefined for the manufacturing of the steel product and the producing step is performed only if the lowest expected level of emissions is inferior or equal to the predefined maximum level, otherwise new manufacturing routes are defined and new associated expected level of C02 emissions are calculated.

- raw materials are chosen among scrap, iron ore, coal, coke, sinter feed, pellets, gases - scrap is of different types and is chosen among old scrap, new scrap, prime scrap, home scrap, pit scrap, shredded, plates and structure scrap, heavy melting scrap, cast scrap, coil scrap or busheling scrap.

- energy sources are chosen among renewable electricity, electricity produced by internal recycling of exhaust gas from the steel manufacturing process or by capture of heat released by products from the steel manufacturing process.

- processes are chosen among direct reduction processes, hydrogen-based ironmaking, steel electrolysis, blast furnace with top-gas recycling, blast furnace with top- gas conversion, electric-arc-furnace steelmaking, converter steelmaking, scrap melting.

- the method further includes a step, after production step of establishing a certificate for the manufactured steel indicated the level Eexpi of C02 emissions associated to its manufacturing route.

- the tools are chosen among a coking plant, a sintering plant, a direct-reduction plant, a blast-furnace, an electric — arc furnace, a converter, a ladle, a H2 production plant, a chemical plant, a biotech plant, a power plant, a ladle, a furnace, a casting plant, a rolling plant, gas cleaning devices, heat recovery devices, hot stoves.

[008] Other characteristics and advantages of the invention will emerge clearly from the description of it that is given below by way of an indication and which is in no way restrictive, with reference to the appended figures in which:

Figure 1 is a flowchart of a method, according to the invention, for manufacturing steel

[009] Figure 1 represents a flowchart of a method to manufacture a steel product according to the invention. A steel product P is to be manufactured into a steelmaking plant S comprising several manufacturing tools T x . A manufacturing tool maybe a combination of several equipment. For example, a blast furnace with top-gas recycling is one tool, even if it comprises a blast furnace, gas treatment devices and gas heating devices. The tools T x may be chosen among a coking plant, a sintering plant, a direct-reduction plant, a blast furnace, an electric — arc furnace, a converter, a ladle, a H2 production plant, a chemical plant, a biotech plant, a power plant, a ladle, a furnace, a casting plant, a rolling plant, gas cleaning devices, heat recovery devices, hot stoves. [0010] In a first step 100, at least two different manufacturing routes MRi allowing to manufacture the product P and using tools Tx are defined. For example, i=3, MRi uses tools T 1 , T 2 , T 3 which are respectively a blast furnace with top gas recycling, a steelmaking unit with a converter and a continuous caster, MR 2 uses tools T 2 , T 3 and T , T being a hydrogen- based blast furnace, MR 3 uses tools T 5 , T 6 and T 3 wherein T 5 is an electric arc furnace and T 6 is a secondary metallurgy unit.

[0011] In a second step 110, an expected level of C02 emissions Eexp, to manufacture the steel product P according to each manufacture route MR, is calculated considering all C02 contributions associated to raw materials, energy sources and processes used for manufacturing the steel product according to each manufacture route MRi.

[0012] Raw materials may be of different types. They may include coal, coke, iron ore, biomass, sintered ore, agglomerates, pellets, direct-reduced iron (DRI), scrap, mineral additions, such as limestone or dolomite, alloying elements but also gases such as oxygen or hydrogen. Scrap maybe of different typologies among, notably, old scrap, new scrap, prime scrap, home scrap, pit scrap, shredded, plates and structure scrap, heavy melting scrap, cast scrap, coil scrap or busheling scrap. In a preferred embodiment, raw materials are selected among biomass, cold-bonded pellets, direct-reduced iron, scrap, mineral additions, alloying elements, oxygen and hydrogen.

[0013] By considering all C02 contributions linked to raw materials, it is meant that all C02 emissions linked to the production of those raw materials before they are used into the steel manufacturing process is taken into account. For example, when considering iron ore, all C02 emissions related to the mining extractions and ore processing have to be included into the calculation. Same for the scrap, even it is the recycling of an existing product, it has a C02 footprint coming from its former life which has to be considered into the calculation. Depending on its typology, C02 footprint may differ from one scrap to another.

[0014] Energy sources may also be various. They include electricity coming from renewable energy, such as from solar panels or windmills, but also electricity produced by power plant, which may use gases resulting from the steelmaking process, such as blast furnace gases or converter gases. It also includes any fuel, either gaseous or solid, fossil or organic, which may be used into the steel manufacturing process. In a preferred embodiment energy sources are chosen among renewable electricity, electricity produced by internal recycling of exhaust gas from the steel manufacturing process or by capture of heat released by products from the steel manufacturing process.

[0015] In order the calculation to be the most accurate it is important to not count a C02 impact twice. For example, if coke is considered as a raw material to the converter process and its impact included into the raw materials impact, it must not be considered as a fossil fuel and included into the energy sources impact.

[0016] Processes include all different processes performed along the manufacturing route and their associated C02 emissions. It includes pig iron production, liquid steel production and finishing processes. Pig iron production includes coking, sintering, pelletizing, blast furnace process, but also direct reduction and shaft furnace processes. Liquid steel production covers decarburization, dephosphorization and all secondary metallurgy or ladle treatments allowing to turn pig iron into liquid steel and adjust the composition of the liquid steel for further steps, it also includes the electric-arc-furnace steelmaking process. Finishing processes include notably casting, heating, rolling, cooling, coiling, shaping, levelling, welding, coating. When considering C02 impact of a process, all by-products recycling or emission reduction technologies applied to said process has to be taken into account for the calculation. For example, blast furnace process without top-gas recycling does not have the same C02 impact as the same blast furnace process wherein top-gas is not released to the atmosphere but rather re-injected into.

[0017] In a preferred embodiment, processes are chosen among direct reduction processes, hydrogen-based ironmaking, steel electrolysis, blast furnace with top-gas recycling, blastfurnace with top-gas conversion, electric-arc-furnace steelmaking, converter steelmaking, scrap melting. By hydrogen-based ironmaking it is meant any ironmaking process, such as a direct-reduction process or a blast-furnace process wherein the reducing gas is mainly composed of hydrogen. Blast-furnace wit top-gas recycling means a blast furnace process wherein top-gas exhausting from the blast furnace is at least partly re injected into the blast furnace after appropriate treatments. Blast furnace with top-gas conversion means a blast furnace process wherein top-gas exhausting from the blast furnace is at least partly used to produce a syngas which is then further used in chemical, biochemical or power plants

[0018] Once this expected level of C02 emissions Eexp, is calculated, all Eexp, are compared and the product P is manufactured 120 into the steelmaking unit according to the manufacturing route MR, having the lowest expected level of emissions Eexp,.

[0019] The method may also comprise an additional step 130, after the manufacturing step 120, of establishing a certificate for the manufactured steel indicated the level Eexp, of C02 emissions associated to its manufacturing route.

[0020] With the method according to the invention it is thus possible to produce the steel product P with a reduced carbon footprint and to determine said carbon footprint.