MECHANICALLY EMBOSSED SINGLE PLY ROOFING MEMBRANE FOR ANTI-ROLL BLOCKING

BACKGROUND OF THE INVENTION

1. Field of the Invention This invention relates to a single ply roofing membrane having a top layer and a bottom layer for covering industrial and commercial flat and pitched roofs. More particularly, the invention relates to a single ply reinforced roofing membrane in which the bottom layer is embossed to improve roll blocking without sacrificing the heat seaming performance of the roofing membrane.

2. Reported Developments

Single ply roofing membranes to cover flat and pitched roofs are known in the art of commercial roofing membranes. Some membranes comprise bottom and top polyolefin-based sheets with a fiber reinforcement scrim sandwiched between the sheets. To promote adhesion between the scrim and the polyolefm sheets, a highly flowable, functional-polyolefin is incorporated into one or both sheets as disclosed in U.S. Patent No. 6,544,909.

Other membranes of the prior art consist of materials based on atactic polypropylene (APP) modified bitumen. Still other membranes consist primarily of materials based on styrene-butadiene-styrene (SBS) modified bitumen. Attachment of these membranes to underlying roof decks are accomplished with adhesives and/or screws. To adhere one membrane to another membrane to render the roof covering waterproof, the selvage edge of one membrane is overlapped with the selvage edge of the next membrane. A torch is then used to soften the membranes at their overlapped portions to achieve a seam sufficient to withstand weather conditions.

U.S. Patent No. 6,134,856 discloses a roll roof membrane , and a method for its preparation, which obviates the use of a torch to achieve a seam between the overlapped portions of the membranes. The roof membrane comprises a support sheet having bonded on the top and bottom surfaces thereof layers comprising APP modified bitumen, a first selvage edge disposed in the top APP modified bitumen layer along one side of the membrane, a second selvage edge disposed in the bottom APP modified bitumen layer along the opposite side of the membrane, and wherein each of the selvage edges have a series of embossed ridges and valleys adopted to accept adhesives, the valleys extending substantially through the APP modified bitumen layers to the support sheet.

The method of preparing the roll roof membrane includes the steps of: a roll of support sheet is unwound and passed through an accumulator; the unwound sheet is dip coated by immersion in a coating vat containing molten compounded APP, asphalt, and one or more fillers and fire retardants; while the coatings are in a molten state, the selvage edges on opposite sides and opposite surfaces of the membrane are contacted with top side embosser and bottom side embosser; the APP modified bitumen layers are cooled and solidified by floating the membrane in a water bath and the membrane is wound into a roll. A suitable liquid parting agent, such as a coconut oil, can be added to the bottom surface of the membrane to reduce the tendency for the membrane to stick during winding and subsequent handling.

We have observed that roll blocking tends to occur with single ply membranes of the prior art. As the membranes are produced, they are wound into rolls, stored in roll configurations and delivered to the site of installation. Since the membrane is smooth, portions thereof tend to stick and adhere to each other thereby hindering the unwinding process. Embossment of selvage edges on opposite sides and opposite surfaces of the membrane does not appear to solve the roll blocking problem: while the embossed portions of the membrane easily unwind, the remaining portions constituting the majority of the surface area tend to stick and adhere to each other.

We have now discovered that the roll blocking problem can be greatly reduced by the complete embossment of the bottom layer of the single ply membrane.

SUMMARY OF THE INVENTION

In accordance with the present invention, there is provided a single ply roofing membrane for covering industrial and commercial flat and pitched roofs. The single ply roofing membrane comprises: a bottom layer and a top layer wherein the layers are permanently bound together, and the bottom layer is embossed with various patterns to increase the surface area of the membrane.

In a preferred embodiment of the present invention the single ply roofing membrane comprises: a top layer of a polyolefin, a bottom layer of a polyolefin, and a fibrous reinforcing scrim sandwiched between the top and bottom layers wherein the bottom layer is embossed with various patterns. Suitable polyolefins are polymers including polyethylene, polypropylene, terpolymers of ethylene, propylene and diene monomers, ethylene-propylene copolymers, ethylene-butane copolymers, ethylene- hexane copolymers, ethylene-octane copolymers, propylene-C4-8 alpha olefin copolymers, and metallocene polyolefms. In order to improve adhesion between top and bottom layers and the reinforcing scrim, a small amount, preferably about 0.5- 20% w/w, and more preferably about 1-10% w/w, and most preferably about 1-5% w/w of a highly-flowable, functional polyolefin is incorporated into one or both polyolefin layers. A maleic anhydride-modified polyolefin (CK Witco), an epoxy- modified polyethylene (Elf Atochem) and methacrylate terpolymers thereof (Elf Atochem) are preferred. The thickness of the membrane preferably ranges from 0.1 to 5 mm (4 to 200 mils), and more preferably from 0.6 to 2.5 mm (25 to 100 mils).

The fibrous reinforcing scrim is preferably of fiberglass and/or polyester. However, woven or non-woven fabrics may also be used. The tenacity of the scrim can range from about 100 to 3000 denier, preferably 500 to 1500, and most preferably 1000 denier. Preferred support scrims have a tensile strength greater than about 14 KN per meter (80 pounds force per inch).

The bottom layer of the single ply roofing membrane is embossed with various patterns which includes: a polyhedron with a polygonal base and triangular faces meeting in a common vertex, such as a pyramidal base; a cone configuration having a circular or ellipsoidal configurations; and random pattern configurations. The depth of the embossments can be about 0.01 to 2 mm (0.4 to 80 mils), preferably 0.025 to 0.5 mm (1 to 20 mils), and most preferably 0.05 to 0.25 mm (2 to 10 mils). BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of a single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 2 is a bottom plan view of the single ply roof membrane depicted in FIG. 1 showing the bottom layer embossed with a rectangular base pyramidal configuration;

FIG. 3 is a side view of the single ply roof membrane depicted in FIG. 1 showing the unembossed top layer and the embossed bottom layer in profile;

FIG. 4 is a perspective view of another single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 5 is a bottom plan view of the single ply roof membrane depicted in FIG. 4 showing the bottom layer embossed with a hexagonal base pyramidal configuration;

FIG. 6 is a side view of the single ply roof membrane depicted in FIG. 4 showing the unembossed top layer and the embossed bottom layer in profile;

FIG. 7 is a perspective view of still another single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 8 is a bottom plan view of the single play roof membrane depicted in FIG. 7 showing the bottom layer embossed with a cone-shaped, circular base configuration;

FIG. 9 is a side view of the single ply roof membrane depicted in FIG. 7 showing the unembossed top layer and the embossed bottom layer in profile; FIG. 10 is a perspective view of another single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 11 is a bottom plan view of the single ply roof membrane depicted in FIG. 10 showing the bottom layer embossed with random longitudinally running designs;

FIG. 12 is a side view of the single ply roof membrane depicted in FIG. 10 showing the unembossed top layer, and the embossed bottom layer in profile;

FIG. 13 is a perspective view of another single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 14 is a bottom plan view of the single ply roof membrane depicted in FIG. 13 showing the bottom layer embossed with random transversely running designs;

FIG. 15 is a side view of the single ply roof membrane depicted in FIG. 13 showing the unembossed top layer, and the embossed bottom layer in profile;

FIG. 16 is a perspective view of another single ply roof membrane showing the embossed bottom layer in profile, and the unembossed top layer;

FIG. 17 is a bottom plan view of the single ply roof membrane depicted in FIG. 16 showing the bottom layer embossed with random interwoven basket-weave designs; and

FIG. 18 is a side view of the single ply roof membrane depicted in FIG. 16 showing the unembossed top layer, and the embossed bottom layer in profile. DETAILED DESCRIPTION OF THE INVENTION

The invention being described is with reference to the preferred embodiments described in the Summary of the Invention with respect to the top and bottom layers and the scrim sandwiched between the layers. However, the invention also finds utility with other scrims or support sheets made of papers and film. In the description that follows like numerals denote like components.

FIGS. 1-3 illustrate a single ply roof membrane 10 comprising a scrim or support sheet 12, top layer 14, and a bottom layer 16 which layers sandwich the scrims or support sheet therebetween. The bottom layer is embossed with a rectangular base pyramidal configuration 18 having a series of ridges 22 and valleys 20.

FIGS. 4-6 illustrate another single ply roof membrane 1OA comprising a scrim or support sheet 12 A, a top layer 14A, and a bottom layer 16A which layers sandwich the scrim or support sheet therebetween. The bottom layer is embossed with a hexagonal base configuration 24 having a series of ridges 26 and valleys 28.

FIGS. 7-9 illustrate still another single ply roof membrane 1OB comprising a scrim or support sheet 12B, a top layer 14B, and a bottom layer 16B which layers sandwich the scrim or support sheet therebetween. The bottom layer is embossed with a cone-shaped, circular base configuration 30 having a series of ridges 32 and valleys 34.

FIGS. 10-12 illustrate a further single ply roof membrane 1OC comprising a scrim or support sheet 12C, a top layer 14C, and a bottom layer 16C which layers sandwich the scrim or support sheet therebetween. The bottom layer is embossed with random thread-like filaments 36 randomly spaced from each other and running longitudinally on the single ply roof membrane having a series of ridges 38 and valleys 40. FIGS. 13-15 illustrate still another single ply roof membrane 1OD comprising a scrim or support sheet 12D, a top layer 14D, and a bottom layer 16D which layers sandwich the scrim or support sheet therebetween. The bottom layer is embossed with random thread-like filaments 42 randomly spaced from each other and running transversely on the single ply roof membrane having a series of ridges 44 and valleys 46.

FIGS. 16-18 illustrate a still further single ply roof membrane 1OE comprising a scrim or support sheet 12E, a top layer 14E, and a bottom layer 16E which layers sandwich the scrim or support sheet therebetween. The bottom layer is embossed with basket-weave patterns 48 randomly spaced from each other having a series of ridges 50 and valleys 52.

In addition to the random patterns shown in FIGS. 10-18, other random patterns of embossments may be used including the geometrical shapes shown in FIGS. 1-9 wherein the shapes are randomly spaced from each other. In all embodiments of the present invention it is important that the various patterns of embossments increase the surface area of the membrane thereby decreasing the roll blocking tendency of the membrane.

In preparing the single ply roofing membrane conventional equipment and methods are used which are well known in the prior art. Such methods include extrusion coating and calendaring. The embossing rolls useful herein are known in the art and/or modified as described herein.

The single ply roll membranes typically have a width of about 1 to 5 meters (3 to 15 feet), while the length of the membranes may be about 15 meters (50 feet) or more. The single ply roofing membranes are used with an appropriate adhesive which is painted or sprayed on the unfolded membrane prior to the installation; or can be mechanically attached using techniques well known to those skilled in the art. Ia both systems, the membranes are rolled out prior to the installation. Blocking tests were conducted on the embossed membranes of the present invention in roll forms, and on unembossed membranes of the prior art in roll forms as control based on ASTM D-751 method. The control samples showed 100% blocking while the membranes of the present invention showed about 25% blocking. LIST OF PARTS

Singly ply roof membrane, generally designated 10, 1 OA, 1OB, 1OC, 10D, 1OE

Support scrim or sheet 12, 12 A, 12B, 12C, 12D, 12E

Top layer 14, 14A, 14B, 14C, 14D, 14E

Bottom layer 16, 16A, 16B, 16C, 16D, 16E

Rectangular based pyramidal configuration 18 Valleys in the rectangular based pyramidal configuration 20 Ridges in the rectangular based pyramidal configuration 22 Hexagonal based pyramidal configuration 24 Ridges in the hexagonal based pyramidal configuration 26 Valleys in the hexagonal based pyramidal configuration 28 Cone-shaped, circular based configuration 30 Ridges in cone-shaped, circular based configuration 32 Valleys in cone-shaped, circular based configuration 34 Filaments running longitudinally 36 Ridges in filaments embossment 38 Valleys in filaments embossment 40 Filaments running transversely 42 Ridges in filaments embossment 44 Valleys in filaments embossment 46 Basket-weave pattern 48 Ridges in basket- weave design 50 Valleys in basket-weave design 52 The invention has been described with reference to certain preferred embodiments thereof, however, it is to be understood that variations and modifications can be effected within the spirit and scope of the invention.