METAL COMPLEX POLYMER AND APPLICATION THEREOF

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a metal complex polymer and its esterification and fermentation reactions. Diesel can be extracted by esterification and fermentation reactions of an oil product composed of a metal complex polymer, and a metal esterified enzyme or a biological enzyme can be used in an oil product for increasing the heat of combustion of a diesel solution. In the process of growing fungus and/or algae, an air/water and/or an oil phase dissolution equipment can be used for absorbing a gas or recycling a combusted gas, deriving a biological cell esterification to process a waste solution, processing an organic waste to produce fertilizers, feeds and food fermentations, as well as producing an organic gas (including a methane gas). 2. Description of the Related Art

In general, esterification is an important step in a chemical engineering process. As we all know, oils and alcohols can be converted and esterified, and oils and carboxyl compounds can be converted into fatty acid esters, and these reactions are known as esterification and polymerization. However, both esterification and polymerization require catalysis for conducting a reaction successfully. At early stage, the structure of catalysts for esterification was very complicated, and thus esterification was generally separated from other chemical engineering reactions. The present metal esterification enzyme or biological enzyme can be reacted altogether, and thus a highly stable oil or carboxyl compound can be reacted as well. Unlike a conventional process that requires high temperature and high pressure for the reaction and incurs high cost and investment, the present invention provides a simple way to achieve the same

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effect. Further, it is not common to have esterification or other reactions that include a metal esterification enzyme or a biological enzyme for processing and converting oils and carboxyl compounds into fatty acid esters. The symbiosis of fungus and marine algae produces a lichenized and/or algacultured mixture to be used for absorbing carbon dioxide and water in the air for the reaction, and absorbing nitrogen to produce saccharide, proteins, usnic acids and fatty acids (different substances are used for different applications, and thus some of the lichenized will produce more fatty acids) in a condensation reaction, and further carries out esterification and fermentation reactions or other esterifications, and such artificial diesel solution is rare. At early stage, there were processes for modifying oil products only, but none of these can directly increases the heat of combustion of the diesel solution, and the life expectancy of the reaction carrier at early stage is very short, but now an oil product composed of a metal complex polymer solution and made by a special fermentation reaction can improve and modify the quality of matters and develop a diesel solution with high efficiency, high density and high quality. It is not very common to see such application of using a metal complex polymer solution to produce an oil product and using a metal enzyme or biological enzyme to increase the modified oil products.

The shortcomings of the prior art demand immediate attentions and improvements, and related manufacturers spare no effort to find feasible solutions and develop appropriate designs to fulfill such long-felt needs.

In view of the existing shortcomings of the prior art, the inventor of the present invention based on years of experience in the product design of the related industry to conduct extensive researches and experiments, and finally developed and invented a method in accordance with the present invention to modify an oil product into a diesel and increases the heat of combustion of a bio- diesel, so as to improve the existing technologies and make the applications more

practical.

SUMMARY OF THE INVENTION

It is a primary objective of the present invention to overcome the shortcomings of the prior art and provide a method for modifying an oil product into a diesel and increasing the heat of combustion of a bio-diesel, so as to improve the quality and capability of modifying oil products.

Another objective of the present invention is to provide an oil product composed of a metal complex polymer solution that is applied in a technical area of a metal enzyme or a biological enzyme for improving the quality or modifying an oil product, and also in a technical area of an oil product composed of a metal complex polymer solution in the foregoing reaction for improving the quality of the biosynthesis of fungus and marine algae to produce a mixture similar to the lichenization and/or algaculture. A further objective of the present invention is to provide a method for modifying an oil product into a diesel and increasing the heat of combustion of a bio-diesel to make the applications more practical and improve the economic effects and the overall performance of the product.

Another further objective of the present invention is to provide a metal complex polymer solution applied for processing organic wastes into fertilizers and feeds, fermenting food and producing organic gases (including a methane gas) and their derived technological applications.

In a method of modifying an oil product into diesel and increasing the heat of combustion of a bio-diesel, the oil product and/or matter goes through a general growth or a fermentation, a lichenization and/or an algaculture and/or a metal esterase or a biological enzyme esterification (or a general esterification). If the oil product is composed of a metal complex polymer solution and gone through a

fermentation, a lichenization and/or an algaculture and/or an esterification and/or other applications, the properties and percentage composition of the oil product include an oil (including a fatty acid and/or its reversible matter): approximately 20-99% and/or water: approximately 0.1-99.87% and/or a R-COOH radical and/or its reversible matter: approximately 0.01-40%; a soluble saccharide (including sugar-metal) and/or its reversible matter such as starch: approximately 0.01-30%, and/or a polymer (including a polymer substance) having a hydroxyl radical or a hydroxyl radical with an amino radical and/or a carboxyl radical and/or a saccharide (including a polysaccharide-metal) and/or an usnic acid (in compliance with a saccharide) and/or other metal chelating agent (in compliance with a saccharide): approximately 0.01-30%, and/or a metal salt and/or an ore and/or a bone (including a sugar metal and/or excluding a polysaccharide-metal): approximately 0.01-30%, and an amino or amine matter and/or NH ₂ matter such as a protein reversed for several times: approximately 0.01-30%, or a combination of two or more of the aforementioned compositions such as a bean containing a fatty acid and a protein or a compound with a composition similar to the aforementioned composition: approximately 0.01-70%, and/or a bacteria or an enzyme or a cell producing a carboxyl acid and its reversible matter such as acetic acid bacteria, and its matter substituting carboxyl acids, and/or bacteria or an enzyme or a cell producing amino and or amine radicals, and its reversible matter substituting an amino or an amine matter and/or bacteria or an enzyme or a cell producing saccharides or a hydroxyl group polymer, and its reversible matter substituting saccharides or a hydroxyl group polymer, and/or bacteria or an enzyme or a cell producing fatty acid, and its reversible matter substituting fatty acid and/or bacteria or enzyme or cell producing and trapping metal or its reversible matter substituting a metal ion or a metal salt and/or a protease and/or bacteria and/or cell, stirred, heated and mixed evenly to produce a uniform

solution according to general methods. The oil product has the properties of protein fermentation and reproduction, wherein the R.COOH radical is an organic acid or an organic acid substance including one or more oil products composed of a metal complex polymer. In the foregoing oil product composed of metal complex polymer solution, the oil product is a fatty acid oil product, a pyrolyzed oil product, an oil product having plenty of OH radicals, or a mineral oil, etc. The ore is sand, rock, bone, and various different metal ores, ore soils, and ceramic tiles sintered by ore soils characterized in that fungus and/or algae and/or moss and/or tea cell and/or other microorganism or esterase and/or alcoholic enzyme and/or composite bacteria and/or functional bacteria produced according to the fermentation of a metal complex polymer solution are included. A metal complex polymer for the fermentation is made as a composite biological protein or a bacteria for an interface between a functional protein or an aerobic bacteria or an anaerobic bacteria, and said lichenized fungus and algae further includes a fungus or an algae or a moss or a tea cell or other microorganism or an esterification enzyme or an alcoholic enzyme.

In the aforementioned reaction process of an oil product composed of a metal complex polymer solution, the lichenized fungus and marine algae are biosynthesized and grown into various different lichens, and mosses, and the algacultured algae are grown into spinrulina, chlorella, and green algae.

In the aforementioned reaction process of an oil product composed of a metal complex polymer solution, the lichenized and/or algacultured and/or other botanic and/or culture medium for other applications are more suitable for humic acid (or other) metal complex polymer solution, and the food source includes air (including nitrogen gas and oxygen gas), organic and inorganic dusts, oil in the air, carbon dioxide (or carbonate ions, bicarbonate ions) and water, rock and ore

(coated in the equipment), bones, phosphate fertilizers, potash fertilizers, trace of ore soils for a qualitative titration and/or metal salts and/or inorganic salts and/or saccharides and/or carboxyl acids and/or urea and/or amino and/or amine matters and/or discarded protein matter or follows the foregoing oil product composed of metal complex polymer solution nutrient solution or the foregoing fermented oil product composed of metal complex polymer solution nutrient solution (applicable for plants such as EM bacteria) or follows the fertilizers as described in claim 11 plus carboxyl acid or amine matters and supplemented sufficiently with fungus and/or algae and/or other applied compositions to supplement the shortage of oil product composed of metal complex polymer solution for the breeding fermentation of fungus and/or algae and/or other botanic nutrition composition for the oil product composed of a metal complex polymer solution, and/or saw dusts, ceramic tiles sintered with ore soils, crop, sunlight (and/or illuminating device such as a light bulb). In the aforementioned reaction processes including a lichenization and/or a algaculture for an oil product composed of a metal complex polymer solution, the oil product can be applied in the areas of producing medicines, feeds, antibiotics, disinfectants, grass killers, dyes, purified algae, cultivated fatty acids, esterified diesel. In the aforementioned reaction process of an oil product composed of a metal complex polymer solution, the equipment used at a preliminary growth of a lichenized and/or algacultured and/or other photosynthetic plant is a front side air disinfection and/or a screening test program for purifying carbon dioxide/nitrogen gas, a general fluid dissolution or a whirl baffle equipment for dissolving and allowing air/water and/or an oil (substantially in an oil bubble form after adding, stirring and mixing the oil) to be arranged by condensing pipes, a rinsing tank that uses an air return and a flow guider to produce whirls of water and/or oil (which

also can be used for other fluid dissolution applications), a thermal exchange condenser that uses a condensation pipe for producing whirls to drive a fluid phase dissolution equipment and a photo-bioreactor, which could be any other illuminating device with circular pipes that are helical from top to bottom into a cylindrical pipeline type, a linear and curved pipe type with a multiple of branch pipes (a meshed multiple branch pipe arranged into a W-shaped linear and curved pipe), a linear and curved panel type (wherein a linear panel and a curved panel are connected in series with an interval apart from each other to form a "transverse W" shape) and made of a transparent material that can be a transparent and/or a semi-transparent material (for guiding and shading lights), a collection tank bundled with a circulator with the installation of a blender for blending, a pyrolysis machine for pyrolysis for a plant preliminary and/or mid- stage growth, and bundled with a stirring breeding fermentation storage tank (including a heat exchange heating pipe or a heating device), and adding the shortage of ingredients according to the nutrition proportion of the metal complex polymer solution, after the ingredients are blended and pyrolyzed, stirred and heated for a quick fermentation to produce and reproduce a large quantity of fungi, so that the bacteria can be grown constantly and repeatedly in the four steps: the carbon dioxide fluid dissolution, the photosynthetic production and culture, blending and mixing the circulated solution (for duplicating the new growth or requiring a blending and a pyrolysis), and the stirring breeding in a fermentation storage tank, and the equipments are shown in shown in FIGS. 1 to 5. The lichenization absorbs carbon dioxide to produce an usnic acid with a pH value of 3.5-7.5 (The pH value of the algae has a range of 6~11.5), and the solution in compliance with an air/water phase dissolution equipment absorbs a large quantity of carbon dioxide as shown in FIG. 7, for using the pH value to monitor and detect the reaction consumption of dissolved carbon dioxide, and

further controlling the quantity of wind flow, so that the thickness of dissolved carbon dioxide is consistent with the reaction consumption. The reaction consumption can be obtained from the speed of growth, and the intensity and quantity of lights for the photosynthesis can be changed by an internal illuminating device such as an LED lamp, an optical fiber light emission to adjust the speed of a circulated solution flow.

The aforementioned general fluid dissolution or an air/water and/or an oil phase dissolution equipment can absorb a large quantity of carbon dioxide, and titrate a carboxyl acid or amino or amine matter and/or a salt to make them acidic or alkaline and/or produce a whirling phase dissolution equipment and/or a front side equipment having a thermal exchange condenser (including a condenser) to promoting the dissolution of carbon dioxide and/or a temperature difference for stimulating the growth.

In the aforementioned reaction process of an oil product composed of a metal complex polymer solution, a lichenized and/or an algacultured and/or other botanic product is converted as an esterification for blending and pyrolysis, and/or mixed with a carboxyl acid and/or a saccharide and a disinfection processing at high temperature and in a radiation.

In the aforementioned reaction process of an product composed of a metal complex polymer solution, titanium (it is recommended to use other elements such as cobalt and/or aluminum or antimony for the complex metal ions) metal esterase (such as a lipase, and/or an esterase mixed with some alcoholic enzymes) or biological enzyme are used for the esterification or the esterification processing. In the aforementioned reaction process of an oil product composed of a metal complex polymer solution, the substance for esterification is an oil, a carboxyl compound, a fatty acid, a carboxyl acid, a weak ester acid, a saccharide

going through an alcoholic catalysis or an alcohol or a general alcohol, and the esterification process can timely add a gas with oxygen anions O ^"2 , O ^2" or nascent oxygen for enhancing the modified ester solvent.

The aforementioned reaction process for an oil product composed of a metal complex polymer solution, the equipment used for the esterification fermentation can be a fermentation equipment having a stirring function and/or an aerating function as shown in FIG. 6, that goes through a quick-dissolving setting agent for a coagulation separation (in solvent and non-solvent phases) or an evaporation separation. The aforementioned oil product composed of a metal complex polymer solution is characterized in that after a metal salt and/or a metal ore is added into the complex polymer solution, an amino radical is added to change the polymer solution into NH ₂ reversed for several times, such as a protein, and then grounded and/or dissolved and/or pyrolyzed and/or reacted with an enzyme (including a bacteria for hydrolysis) and a fermentation protein to produce an amine and amino acid, and/or adding a small quantity of ammonia as a fermentation starter for the foregoing solution, or a saccharide or a carboxyl acid or a fatty acid or a metal salt which is grounded and/or dissolved and/or pyrolyzed and/or converted by an enzyme for its use and/or adding a small quantity of converted matter as a fermentation starter for the foregoing solution.

The aforementioned grounding and/or dissolution and/or pyrolysis used for culturing and growing a plant is applicable for an algae and/or a lichen and/or other photosynthetic plant at a preliminary and/or a middle growing period.

In the aforementioned reaction process and reaction equipment and reaction solution of an oil product composed of a metal complex polymer, a disinfection factor similarly to the production of algae and/or lichen and/or other photosynthetic plant and/or other culture medium and/or the purification and

prevention of bacteria pollution is added to promote reproduction.

In the aforementioned processing of an oil product composed of a metal complex polymer solution (which is added according to the shortage of ingredients of an oil product composed of a metal complex polymer solution), an organic waste (which is solidified or liquefied) and/or a fertilizer, a feed, a food fermentation and/or producing a culture medium (such as a metal complex polymer including a hydrolysis to produce hydrogen, an ethanoic acid and methane and a bacteria) and a nutrient substance (according to the composition of the metal complex polymer as recited in claim 9 excluding the bacteria), and it is recommended to use nickel or molybdenum produced by mixing both substances, an organic gas (including methane gas) for the complex metal ions.

In the aforementioned applications in oxidation-condensation, condensation reaction, biochemical reaction for fermentation, metal enzyme biological enzyme, bacteria culture medium and storage system, food and medicare, chemical matter production of plant, oil product processing application, nano filter, nano inorganic matter, nano material for fermentation, nano plastics, nano fibers, manufacture of nano ceramic materials, manufacture of liquid crystals and semiconductors for an oil product composed of a metal complex polymer solution.

Compared with the prior art, the present invention has many advantages and beneficial effects. To achieve the objectives of the present invention, the technical characteristics of the present invention are given as follows:

The present invention provides an oil product composed of a metal complex polymer solution, and the inventor of the present invention also filed No. PCT/CN2005/000132 patent application entitled "A SOLUTION OF METAL- POLYMER CHELATE(S) AND APPLICATIONS THEREOF" related to an oil product application for further improvements. As we known from the prior art, an oil product composed of a metal complex polymer solution is preferably made of

an oil (fatty acid), a mineral (metal ion), a protein (source of amino radical), an enzyme, a saccharide, an acid matter (carboxyl organic acid) for constituting a fatty acid-M-NH ₂ -protease-sugar fermentation system, and the lichen (fungus and marine algae are biosynthesized, grown and lichenized), and its biosynthetic matter produces a fatty acid, a saccharide, a protein, an usnic acid, an acid etched ore, an acid etched rock, a fungus and a marine algae biosynthetic bacteria, and similar to a fatty acid-M-protein -protease-sugar, If there is a change (fermented and/or grounded and/or dissolved and/or pyrolyzed to convert a protein into an amine and an amino acid) and the foregoing fatty acid-M-NH ₂ - protease-sugar fermentation system is the same, the preliminary growth will be very easily for quick reproduction and fast growth, and the algae photosynthesis absorbs air (including nitrogen gas), organic dusts, inorganic dusts, carbon dioxide and water, and uses the air phase dissolution equipment for the illumination reaction fermentation, and produces a saccharide, a protein, a fungus and absorbs a marine algae to produce saccharide, oxygen gas, organic salt from rock, and water to produce dissolved usnic acid from the rock. There are also nutrient sources of weak ester acids, fatty acids, and saccharides to support the production of fatty acids, such that if a cane sugar is added for the fermentation to enhance the growth and promote the fermentation, and the fatty acid includes plenty of nutrient sources. The lichen can be a solvent for dissolving oil, and the usnic acid is chelated and grounded and the lichen is dissolved in soil (or metal) to become an usnic acid metal complex polymer solution, or the usnic acid (or other metal chelating agent) is separated in compliance with the saccharide and a carboxyl acid and a substance having an amino radical are added. All of the above can be used for the next step of fermentation repeatedly, and the method of using natural air for producing energy is definitely a breakthrough for the energy crisis.

Firstly, after the metal complex polymer solution is composed, lichen (fungus and marine algae biosynthetic bacteria) is added for the fermentation and culture, and the air /water dissolution chemical engineering equipment as disclosed in U.S. Pat. Application No. 11/503,086 entitled "Chemical engineering equipment with baffle structure for producing whirl liquid flow or whirl combustion flow and dissolving air/water" and filed by the inventor of the present invention inputs air while using a water loop through an air whirl baffle to produce whirls for the mixing, such that when air is mixed with the raw material in a fermentation, the sunlight can promote the reproduction. To achieve the objectives of the present invention, the technical measures taken by the invention are described below. The method in accordance with the present invention modifies oil product to diesel and increases the heat of combustion of bio-diesel, and the metal complex polymer solution is consisted of oil and/or water and/or a R-COOH radical, a saccharide (including sugar-metal) molecules and/or a polymer having a hydroxyl radical or a hydroxyl radical with an amino radical and/or a carboxyl radical and/or a saccharide (including polysaccharide-metal), and/or a metal salt and an amino or amine matter, wherein the percentage compositions have the following ranges: oil: 20-99% water: 0.1- 99.87%; R-COOH: 0.01-40%; saccharide (including sugar-metal) molecules and/or a polymer having a hydroxyl radical or a hydroxyl radical with an amino radical and/or a carboxyl radical and/or a saccharide (including polysaccharide- metal): 0.01-30%; a metal salt: 0.01-30%; and an amino or amine matter is added, stirred or heated, wherein the R.COOH is an organic acid or an organic acid substance, which is more suitable at the early stage to use humic acid and metal complex polymer solution for the basic solidified carrier for the fermentation, and the black solution can absorb lights easily, and the peat and lichen so produced is piled into a peat-like substance, and this system can be

used for the fermentation, new growth and reproduction.

The objectives and technical solutions of the present invention can be achieved by the following technical measures.

Firstly, an experiment is performed to extract some mosses, and a rice sugar solution is mixed, grounded, and stirred evenly, and coated onto a stone including a peat soil, and water is sprinkled frequently. The moss (including a fatty acid) will be grown again very soon (without adding oil for the dissolution). Another experiment is performed to extract some mosses, oils and oil meals, and a rice sugar solution is mixed, dissolved, grounded, and stirring evenly, and then coated on a stone including a peat soil, and water is sprinkled frequently, and the moss (whose structure is very similar to a fatty acid-M-NH ₂ -protein-sugar structure) will be grown again very soon. These experiments show that the moss with a nutrition composition is mixed, grounded or dissolved or pyrolyzed, and stirred evenly, and then coated onto a stone, and then the moss will be grown again very soon. The nutrition composition is suitable for a cultivation system (such as a fatty acid-M-NH ₂ -protease-sugar fermentation system), that can culture a bacteria and a bacterial strain. In the design of the present invention, the machine according to the foregoing principle absorbs natural air (that can pass through air disinfection such as ultraviolet rays) or uses a film filter technology to purify the required carbon dioxide and other gases, continuously loop the nutrient solution for the photosynthesis and a continual reproduction, wherein the air phase dissolution equipment has the stirring and mixing functions, and the titrate carboxyl acid such as citric acid can absorb carbon dioxide easily, and the oil in the stirred and mixed state is in the form of oil bubbles, and the photo-bioreactor allows the lichen to be in contact with water at a time and in contact with air at another time, since the pipe includes air with an environment closer to that for the natural growth of lichens, and the reproduction will be quicker. The nutrient

solution is photosynthesis and lichenized into an usnic acid for absorbing carbon dioxide to a produce a solution with a pH value of approximately 3.5 to 7, and the lichenized meal has a alkalinity suitable for the acidic system, and the acidic system comes with a pH value below 3.5 and the efficiency for dissolving carbon dioxide can be up to 100% in compliance with the dissolution of air/water and/or oil (and becomes colder after going through an heat exchange of the stirring breeding fermentation storage tank). The colder the temperature, the larger is the quantity of absorbed carbon dioxide, so as to provide an acidic solution, and give poor dissolution of usnic acid in water. However, the dissolved oil, solvent and usnic acid are acidic and dissolved on the rock for absorbing carbon dioxide, and the pH value is used for monitoring the reaction consumption of dissolved carbon dioxide by the photo-bioreactor and controlling the quantity of wind flow, such that the thickness of dissolved carbon dioxide will be consistent with the reaction consumption. The lichenization only requires a mid-level of light intensity, and we can know from the reaction consumption that if the growth rate is slow, then the light required by the photosynthesis can be provided by an illuminating device such as an LED lamp, an optical fiber light emission, an optical fiber and a light guide in the equipment for adjusting and supplementing the light. The performance of the nutrient solution for the photosynthesis is a key factor for determining the reproduction, and the lichen in the nature grows slowly, but the speed can be faster by using a culture medium composed of a nutrient solution, a fermentation bacterial strain at preliminary growth in compliance with a metal complex polymer solution, and a nutrition absorption system for the fermentation, and thus the photosynthesis uses all these for expediting the culture and reproduction at this stage, and the reproduction can imitate the nature with its growth and shower at the stone or tile or carrier, or sealed pipe type, flat panel type or semi-closed type or according to embodiment or other photo-bioreactor,

and thus saw dusts can be added to places wherein bacterial strains are attached. All of the above can be used for a qualitative titration of a trace of soil and/or a metal salt and/or an inorganic salt and/or a carboxyl acid such as citric acid and/or a cane sugar and/or an urea and/or an amino and/or amine matter and/or a discarded protein matter or a nutrient solution composed of a metal complex polymer solution or fermented nutrient solution (suitable for plant) composed of metal complex polymer solution or a carboxyl acid such as citric acid matter is added previously and a lichen nutrition composition is added to meet the requirement and storage of an oil composed of a metal complex polymer solution oil for promoting growth, and the reaction time depends on the photosynthetic rate of the synthetic saccharides and carbon dioxide, and the lichen in the nature are exposed in the air, therefore half of the pipeline of the photo-bioreactor includes air, to facilitate a convection of oxygen and carbon dioxide, algae absorbs carbon dioxide and has nitrogenase and chlorophyll, and the fungus absorbs oxygen gas, and thus the photo-bioreactor for the circulated solution in this section is given with sufficient reaction time, and the flow speed of the circulated solution an be controlled accordingly. If the photosynthetic rate of the synthetic saccharides become slower, the flow speed will be retarded. If the photosynthetic rate becomes faster, then the flow speed will be accelerated. The nutrient solution dissolved in air /water and/or oil can dissolve and absorb a large quantity of carbon dioxide, and the pH value before the solution passes through the photo-bioreactor is used for monitoring the acidity, and the acidity of the circulated solution after the solution passes through the photo-bioreactor. The change of acidity can be used for calculating the reaction consumption of carbon dioxide, and the photosynthetic rate of the synthetic saccharides can be used for adjusting the flow speed of the circulated solution or dimming a light or changing the speed of wind.

The circulated solution flows to a collection tank, and the collection tank bundled with a circulator installs a blender for blending and pyrolyzing a moss, and a lichen (such that the protein is decomposed into amines and amino acids), and a fungus and marine algae reproduction cell carried by the circulated solution are blended, pyrolyzed and mixed into a state of the nutrient solution (or a culture medium) and flowed into a stirring, breeding and fermentation storage tank, and then returned to the previous air /water and/or oil dissolution reaction apparatus for the next duplication (asexual reproduction), so that the four steps including bacteria to be absorbed and dissolved in carbon dioxide, a photosynthetic production and a duplication, a circulated solution to be blended and mixed, and a stirring breeding fermentation storage tank are used for the new growth repeatedly, and thus the plant has a temperature difference for stimulating its growth, and it is not necessary to lichenize, blend and mix the circulated solution each time. Such processes depend on the time of the circulation (approximately three days or more) and the lichen duplicated for a new growth requires the blending and mixing processes, and a stirring, breeding and fermentation storage tank for the blending and pyrolysis to quickly cultivate a large quantity of fungi, and stirring and heating appropriately (the temperature of bacteria is slightly high for a quicker duplication), and the heating can be obtained from the heat source of an air/water and/or oil dissolution reaction apparatus, and appropriately supplement and comply with the shortage of ingredients in the fermentation system (according to the nutrition composition of the metal complex polymer solution). Now, lichen is added and the pH value is about 6.5, so that the fungus can be reproduced in tens of millions of times, and the fungus fermentation and reproduction take at least three days, and thus twice as much of an inventory is needed for the reaction of the nutrient solution. Then, the foregoing air/water and/or oil dissolution reaction apparatus can meet the

requirements for the foregoing procedure, and photosynthetic production and duplication (asexual reproduction) can be carried out for the culture, which is not a subculture method (but also can be a subculture), and the culture time is similar to that of a traditional way, but the first-generation reproduced fungus is grown and tens of millions of times of the original quantity will be produced, the production is fast and huge. If the thickness of the circulated solution is getting increasingly larger, the thickness will approach to a saturation, and the newly grown are blended and pyrolyzed (or not blended and pyrolyzed for other use), the flowing out portion is used for esterification processing (but this process does not use a stirring, breeding and fermentation storage tank), and the remaining portion is added with bacteria-free water and/or oil, and humic acid metal complex polymer solution is added (or not added) for diluting the basic elements for the fermentation, and entering the stirring breeding fermentation storage tank for the next duplication. The cultured algae include lichen since it has antibiotic matter for purifying and preventing any contamination of the algae, and the solidified (immobile) green algae of the lichen can be cultured safely (for the green algae culture system), and various culture systems are provided for the metal complex polymer solution as a nutrition absorption system for the fermentation, culture and reproduction, and miscellaneous bacteria are controlled by the foregoing method in compliance with a disinfection factor such as a trace of chlorine for preventing miscellaneous bacteria, without affecting the fermentation, culture and reproduction by using the metal complex polymer solution as the reproduction system. Since we only need a system with a duplication capability larger than the disinfection factor of the disinfection capability to achieve the effects of purifying and preventing contamination and providing a strong reproduction.

The culture method of separate algae is similar to this system that adopts a fatty acid-M-NH ₂ -protease-sugar and/or cane sugar-M-NH2-protease fermentation

system for both proprietary operation and/or joint operation, and the preliminary growth is easy and the reproduction is quick. The fast growth and algae photosynthesis absorbs air (including nitrogen gas), organic dusts, inorganic dusts, carbon dioxide and water, cane sugar, carboxyl acid, metal salt, amino and/or amine matters, and use the air phase dissolution equipment for the illuminating reaction and fermentation to produce saccharides, proteins, fatty acids, minerals. The features of products reside on that the protein usually does not have any carboxyl acid. After the algae are blended and pyrolyzed in compliance with cane sugar, a carboxyl acid and a matter having an amino radical can be added for carrying out the next step of fermentation, and thus a trace of cane sugar and more carboxyl acids are added for the fermentation and duplication of fungus to enhance the growth and promote the fermentation, and a portion of the proteins is decomposed into amines and amino acids and a matter containing plenty of amino radicals (In a photo-bioreactor, the cane sugar and carboxyl acid will become a carbon algae nutrient source). When the metal complex polymer solution is added to the marine algae bacteria at the early stage for the reproduction, fermentation and culture, the solution is placed in the air filter and air/water dissolution chemical engineering equipment for inputting air while using a water loop to go through an air whirl baffle for producing, whirling, and mixing the solution. If air is mixed, stirred and fermented with the raw materials, the sunlight promotes the reproduction. More preferably, the humic acid metal complex polymer solution is used as a basic solidified carrier for the fermentation, and the black solution can absorb lights easily. In this system, fermentations, new growths, and reproductions can be achieved. Air (going through air disinfection such as ultraviolet rays) is circulated continuously, and the photosynthesis for the nutrient solution can be conducted for the reproduction, wherein the air phase dissolution equipment has the stirring and mixing functions. The air phase

dissolution equipment adds an alkaline (including caustic potassium) and/or an amine matter such as urea in compliance with the metal salt in the nutrient solution for the reaction for absorbing carbon dioxide and producing carbonate ions, bicarbonate ions and ionic amino radicals and salts, and the pH value of the solution is about 6.5 to 11.5, and the algae (such as spinrulina) are suitable for an alkaline system, and the alkaline system comes with a pH value of 8.5 or below 10.5 and uses dissolved carbon dioxide for various different carbonate ions and each can have a maximum of 100% or 50%, in compliance with air/water (that becomes colder when going through a heat exchange of the stirring, breeding and fermentation storage tank) to be dissolved. The colder the temperature, the larger is the quantity of absorbed carbon dioxide, and thus giving a strong alkaline. The pH value is used for monitoring the reaction consumption of dissolved carbon dioxide of the photo-bioreactor and for controlling the quantity of wind flow, such that the thickness of dissolved carbon dioxide is consistent with the reaction consumption. When the nutrient solution conducts photosynthesis, the algae only require a mid-level of light intensity. From the reaction consumption, we can know that the growth speed become slower. By then, the light required for the photosynthesis can be provided by an illuminating device such as an LED lamp, an optical fiber light emission, an optical fiber and a light guide in the equipment for adjusting and supplementing the light source. The performance for the nutrient solution to conduct photosynthesis is a key factor for determining its reproduction, and when the algae is composed for each time by the culture medium composed of a nutrient solution, the fermentation bacterial strains at preliminary growth are in compliance with the metal complex polymer solution and the nutrition absorption system for the fermentation, and its speed can be fast, and thus the photosynthesis uses this period for expediting the culture and reproduction, and the reproduction can imitate the growth and shower

in the nature by a carrier, or a sealed pipe type, a flat panel type or a semi-closed type or the method according to the embodiments or other typed photo- bioreactor. All of the above can follow the nutrient requirements of the algae including a qualitative titration with a trace of metal salt and/or inorganic salt and/or carboxyl acid such as acetic acid, citric acid and/or cane sugar and/or urea and/or amino and/or amine matters and/or discarded protein matter or a nutrient solution composed of a metal complex polymer solution, or a nutrient solution composed of a fermented metal complex polymer solution (suitable for plant) or a previously added amine matter and supplemented by an algae nutrition composition to supplement the shortage of an oil product composed of a metal complex polymer solution for promoting the reaction, and the reaction time depends on the photosynthetic rate of the synthetic saccharides in carbon dioxide, and the algae in the nature are exposed in the air, and thus half of the pipeline of the photo-bioreactor includes air to facilitate the release of oxygen, and the algae absorbs carbon dioxide and includes nitrogenase and chlorophyll, so that the circulated solution at this section provides sufficient time for the photo- bioreactor, and the flow speed of the circulated solution can be controlled accordingly. If the photosynthetic rate of the synthetic saccharides becomes slower, the flow speed will be retarded. If the photosynthetic rate becomes faster, the flow speed will be accelerated. The nutrient solution dissolved in air /water and/or oil can dissolve and absorb a large quantity of carbon dioxide, and the pH value before the solution passes through the photo-bioreactor is used for monitoring the acidity, and the acidity of the circulated solution after the solution passes through the photo-bioreactor. The change of acidity can be used for calculating the reaction consumption of carbon dioxide, and the photosynthetic rate of the synthetic saccharides can be used for adjusting the flow speed of the circulated solution or dimming a light or changing the speed of wind.

The circulated solution flows to a collection tank, and the collection tank bundled with a circulator installs a blender for blending, pyrolyzing an algae (for decomposing a protein into an amine and an amino acid), and the marine algae reproduction cells carried in the circulated solution goes through a blender for blending, pyrolyzing and mixing a synthetic nutrient solution (a culture medium) to a stirring, breeding and fermentation storage tank and returns to the previous air/water dissolution reaction apparatus for the next duplication (asexual reproduction), so that the four steps includes the absorption and dissolution of bacteria in carbon dioxide, the photosynthetic production and duplication, blending and mixing the circulated solution by the stirring, breeding and fermentation storage tank for a new growth constantly. Therefore, the plant having a temperature difference for stimulating its growth, and it is not necessary to blend and mix the algae in a circulated solution every time, and the blending and mixing processes depend on the time of circulation (approximately three days or more). If the algae have been duplicated for a new growth, then it will require the blending and mixing processes. After the blending and pyrolysis are preformed, a stirring breeding fermentation storage tank is provided for quickly culturing the fungus, and stirring and appropriate heating (the temperature of bacteria is slightly higher for a quicker duplication), and the heating can be obtained from a heat source of the heat exchange of the air/water dissolution reaction apparatus, which is suitable for supplement the shortage of ingredients in the fermentation system (according to the nutrient composition of the metal complex polymer solution). By then, the algae are added, and the pH value of the solution is approximately 7, such that the fungi can be reproduced in tens of millions of times, and the fungi can be fermented and reproduced quickly that takes at least three days, and thus one time or more inventor is needed for the reaction of the nutrient solution. The foregoing procedure requires an air /water

dissolution reaction apparatus, and the photosynthetic production and duplication (asexual reproduction) for the culture which is not a subculture method (but also can be a subculture). The thicker the circulated, the closer is the saturation, and the solution for the new growth has been blended and pyrolyzed (or not blended and pyrolyzed for other uses), and the discharging portion is used for the esterification processing (and this case does not use a stirring, breeding and fermentation storage tank), and the bacteria-free water is added and the humic acid metal complex polymer solution can be added (or not added) for diluting the basic elements for the fermentation and entering the stirring breeding and fermentation storage tank for the next duplication. Similarly, this method can be applied for the production of other photosynthetic plants.

The flowing out portion the foregoing fungus and/or algae is used for the disinfection processing, and it also can be used for other purpose for the next step of esterification processing, and cane sugar is mixed and a carboxyl acid is mixed in the fresh culture medium, and oil can be added or not added for supplementing the shortage of fungi and/or algae nutrition composition to meet the requirements and shortage of an oil composed of a metal complex polymer solution. If a titanium soil is added into the usnic acid metal complex polymer solution in the section of the air/water and/or oil phase dissolution equipment, the solution will become a titanium metal complex polymer solution, such that after the esterase is fermented, the titanium (or other metal such as cobalt and/or aluminum or antimony is recommended for the complex metal ion and the metalesterase such as a lipase and/or an esterase mixed with some alcoholic enzyme) biological enzyme is used for the esterification nutrient solution (and the moss is disinfected), and the esterified substances include oil, carboxyl compound, fatty acid, carboxyl acid, weak ester acid, saccharide, alcohol or general alcohol going through the alcoholic enzyme, and the esterification

process can timely add oxygen anions O ^"2 , O ² Or nascent oxygen for enhancing the modification, and the product is a solvent such as a fatty acid ester, and the equipment used for esterification and fermentation has the stirring and/or aerating fermentation function, and the stirring and reaction by the chemical engineering equipment can separate the solution into two phases (solvent phase and non- solvent phase). The titanium esterase or biological enzyme is used for esterification and the nutrient solution is not necessary a solid catalyst, since the fermentation and catalyst are provided for the reaction without requiring high temperature, and the esterification is mixed with some alcoholic enzyme, such that the saccharide can be converted into alcohol to facilitate the conversion of fatty acid and alcohol into fatty acid ester, and the quick-dissolving setting agent such as ferric chloride breaks down the fatty acid-M-NH ₂ -protease-sugar structure, and finally the solution is separated into two phases. The solvent such as the fatty acid ester floats and the water and protein and precipitate does not necessarily require distillation.

A thin film evaporator connected in series with a scraping thin film evaporator may be used for separating rough rocks, esters, methanol, water and any substance with a low boiling point. The scraping thin film evaporator is used for separating fatty acid, and bio-diesel. After the method is used for separating the methyl ester I the product, the quantity of methyl ester is larger than 96%, and the recycle percentage is larger than 85%. The separated product shows indexes in compliance with Germany bio-diesel production standards, and it can be produced in a quick and good manner, and definitely a breakthrough for the energy recycling. Similarly, the esterification of pure fatty acid adds material in compliance with the fatty acid-M-NH ₂ -protease~sugar structure (metal complex polymer solution), and the metalesterase (such as a lipase and/or an esterase mixed with some

alcoholic enzyme) biological enzyme used for the esterification and emulsion of oil, such as a fatty acid and water and vinegar and cane sugar and titanium sulfate and ammonia water mixed evenly, and after the lipase or esterase mixed with some alcoholic enzyme is fermented, the catalyst is mixed into the fatty acid for stirring and aerating reactions to produce the fatty acid ester.

In another application, the fatty acid-M-Nhb-protease-sugar structure in the discarded substance processing such as food leftover processing, and the leftover is spread out for its nutrition composition which is incompliance with the nutrition composition of the foregoing fatty acid-M-NH ₂ -protease-sugar structure, and thus ingredients are added to comply with the foregoing nutrition composition of the fatty acid-M-NH ₂ -protease-sugar structure, such as oil-mineral-protein- decomposed food leftover bacteria or enzymes-saccharides further include animal and plant oils, leave vegetables, nits and minerals such as fish meat, egg, shrimp, seafood protein, decomposed food leftover bacteria or enzymes such as EM bacteria - rice, noodle, potato, yam, starch and saccharide in compliance with a carboxyl acid matter such as onion, lemon, plum, or a carboxyl acid used for processing food leftovers. From the foregoing shortage of which kind of substance, we can add similar chemical material to supplement the shortage. After the supplements are added, stirred and mixed, the food leftover bacteria or enzyme are decomposed for an easy fermentation. The general fermentation requires heating to promote the reaction, but the method of adding, stirring mixing a small quantity of ammonia while the ammonia gas has not escaped from the ammonia solution, the aforementioned solution fermentation starter can be added similarly for other types of ingredients. It is only necessary to compose and stir according to the composition of different ingredient types to achieve a quick fermentation reaction, process the discarded substance in food leftover which is a substance other than those with the fatty acid-M-NH ₂ -protease-sugar structure, or

an ingredient or similar matter with the fatty acid-M-NH ₂ -protease-sugar structure can be fermented successfully, For example, water, wet grass, (dipped in water for several days, and including carboxyl acid) mixed with the leftover rice (starch and saccharide), cane sugar (accelerating agent for a direct fermentation), and oil meals (with or without oil), a gypsum (mineral), a bean dreg (protein including amino acid), urine (NH ₂ and enzyme) are stirred and mixed (and grounded into powder for any solid substance) for the fermentation to produce fertilizers. In this natural organic agricultural method, a metal complex polymer solution composed of natural matters is added for absorbing ionic matters which is suitable for the fermentation of bacteria and plant by the enzymes, but the combination state of the ionic matters of the metal complex polymer solution can accelerate the enzyme system in the plant (wherein the plant has more antibiotics), and thus this method is developed rapidly for the fast growth, and used for fertilizers. In addition, the inventor of the present invention filed No. PCT/CN2005/000132 patent application, entitled "A SOLUTION OF METAL-POLYMER CHELATE(S) AND APPLICATIONS THEREOF" which teaches the foregoing method for processing organic wastes by using other fungus, and the solidification or liquefaction are adopted for other applications. The present invention provides a metal complex polymer solution applied for processing organic wastes and producing fertilizers. Further, stools from buildings or residence are used for fertilizer and the discarded substance are processed and deodored. All these human wastes including stool and urine are inputted directly, and the organic hydrocarbon gases of stools and the ammonia gas of the urine can be processed by the metal complex polymer solution and the cane sugar-M-NH ₂ -protease system and/or other fermentation system. Firstly, the bacteria that produces carboxyl acids and its matters such as acetic acid bacteria and its substitute for carboxyl acids and/or bacteria that produce saccharide for its substitute to

decompose organic hydrocarbon compounds of stools and ammonia of urine. Such fermentation system makes it easy to process the metal ion urine, and bacteria for the deodoration or bacteria for other functions such as methane bacteria is added, and the number of bacteria for the main reactions in the system is greater than the number of other bacteria and deodoration bacteria (methane bacteria), and thus the fermentation and reproduction can be maximized. The principle of using the metal complex polymer solution and composite bacteria for the fermentation can deodor or produce gases, which is an application of using a metal complex polymer solution for processing organic wastes and deodoring or producing gases.

The inventor of the present invention filed No. PCT/CN2005/000132 patent application entitled "A SOLUTION OF METAL-POLYMER CHELATE(S) AND APPLICATIONS THEREOF" which teaches a method for processing feeds without requiring a fermentation, but simply using a nutrient composition to convert each matter of a protein for decomposing protein into amino radical for a self fermentation, and such metal complex polymer solution is applied in the feeds.

In another application, a fatty acid-M-NH ₂ -protease -sugar fermentation system is used for producing food such as a stinky bean curb, and the beans are added into a protein including fatty acid and water, acetic acid and cane sugar added, and finally gypsum is added into the hydrolysis enzymes of the protein for producing a large quantity of fermentation enzymes (which is good for human bodies). If the protein is decomposed into amino radicals, the main fermentation enzyme will be produced during the fermentation. Further, soy milk is mixed with a meat sauce to substitute NH ₂ and promote the fermentation, and the aforementioned substances are mixed with the soy milk and the aforementioned matters are mixed with the oil for the fermentation. Unlike traditional

fermentations, oil is used. The fermentation of bread is used for the illustration, and flour plus water, oil, sugar, acetic acid, trace of gypsum, mushroom sauce or meat sauce or protein (including some of the human protein hydrolysis enzymes) are mixed evenly, and main fermentation enzymes (which is good to human bodies) are added for the fermentation, and such fermentation method is very different from the traditional fermentation of breads. Salt-free soy sauce is used for another illustration, and a general soy sauce will be fermented in a salt-free condition, and the fermentation involves several complicated procedures, but the salt-free soy sauce can use soy beans including fatty acids, proteins, cane sugars, acetic acid bacteria (to substitute carboxyl acids), wild vegetable juices (minerals) or a trace of gypsum for the fermentation to produce some acetic acid, and a salty soy sauce is added for culturing synthetic enzymes for the fermentation, and the salty soy sauce comes with a taste of a soy sauce but without any salt. Therefore, the fatty acid-M-NH ₂ -protease-sugar or fatty acid-M- protein-protease-sugar system can be applied for food fermentations.

In another application, the fatty acid-M-NH ₂ -protease-sugar and/or cane sugar-M-NH ₂ -protease system and/or other fermentation system can be applied for producing organic gases. For example, the foregoing method for processing discarded substances by adding hydrolytic bacteria to produce hydrogen and ethanoic acid bacteria and methane bacteria, such that the hydrolytic bacteria can decompose the protein into a polypeptide and an amino acid, and the fatty acid into a glycerin and chained fatty acid, and the polysaccharide into a monosaccharide and a bisaccharide and further produces hydrogen and ethanoic acid, such that after the fermentation matures, the bacteria will attach chemical matters other than the fatty acid-M-NH ₂ -protease-sugar or cane sugar-M-Nhb- protease structure, and the anaerobic fermentation will continue, and the methane will be produced continuously. This method can be applied for

producing a methane gas. From the description above, the bacteria culture medium and nutrient substance (produced according to the composition of the foregoing method, but the -NH2 bridging portion can be substituted by -NH2 converting matter such as protein, and composed according to different ingredient types and stirred evenly and water is added, so as to provide a specific bacteria function for the decomposition and fermentation to produce methane gas until all of the ingredients are consumed completely. If the nutrient substance is a fatty acid-M~protein-(without adding protease)-sugar or a cane sugar-M-protein- (without adding protease) structure, the protein can be substituted by NH ₂ . If the protease has not been added to the -NH2, the ionic bacteria in the environment still can be absorbed easily for the fermentation, and thus fermentations will not take place easily by adding a protein as the substitute without adding the protease. Once if the bacteria culture medium including methane bacteria come from the hydrolytic bacteria, the protein will be decomposed into amines and amino acids, and the -NH2 together with the methane bacteria will be fermented. Therefore, we can design a product like a portable coal gas (powder) package which is divided into two packs, one for the bacteria culture medium if a fermented hydroxypropyl methyl cellulose system is adopted, and another one is for a nutrient substance stirred evenly and made according to the composition different ingredient types (undecayed matter with a high stability is used for freezing, drying and vacuuming the bacteria-free package. If it is necessary to produce a coal gas, two packs are mixed with bacteria-free water and placed in a coal gas culture can. The sealed culture can can be opened and comes with a ventilation hole connected to a coal gas pipeline (the shorter, the better, since the pressure in the culture can is not too large) and the coal gas stove can be ignited for the combustion until the coal gas is exhausted. After the combustion is completed, the minerals are remained. If a pack of nutrient substances is

designed for a combustion of 10 minutes, and it is necessary to cook food for 20 minutes, then a pack of bacteria culture medium can be added to two packs of nutrient substances and some bacteria-free water are mixed in the coal gas culture can, the culture medium and nutrient substance may adopt nickel or molybdenum for the complex metal ions. Due to the catalysis, methane can be produced quickly, and such method can be designed as an automatic machine for converting coal gas and producing coal gas in a factory or a coal gas electric generation plant, and the coal gas producing machine can install a device for preventing leak and explosion, so that the used methane gas can be converted into carbon dioxide by the active bacteria in the moss and discharged quickly. Such method for generating energy and producing other organic gas can imitate the same processing, and the metal complex polymer solution of this invention can be used for producing organic gas (including methane gas).

In another application for the fermentation used in the biochemical reaction, R-metal ion-NH ₂ -protease of each fermentation system can be changed into R- metal ion-protein-protein bacteria as the hydrolytic bacteria. Since the hydrolytic bacteria decomposes the protein into amines and amino acids, and the -NH2 substitutes the protein, and the disinfection eliminates the hydrolytic bacteria and it is necessary to add protease and/or bacteria and/or cell for fermentations for other purposes.

In another fermentation system or hydroxypropyl methyl cellulose fermentation system, the R-metal ion-NH ₂ -protease can be substituted by the R- metal ion-protein-protein bacteria as the hydrolytic bacteria for the link status, since the hydrolytic bacteria decomposes the protein into amines and amino acids, and the -NH ₂ protein bacteria fermentation entering into the metal complex system will become an organic metal, and the solution is pulled and pushed by an attraction and a repulsion respectively to miniaturize the metal ions into a nano

scale. In the nano metal complex polymer solution (which is a fatty acid-M- protein-protease-sugar in this system), an unfermented unit of the original mixture and plastic polymer (or a resin such as Amberlite IRC-50 including carboxyl radicals) or its monomer is stirred and combined, and fermentation is performed (including protein hydrolysis enzymes for decomposing protein into amino radical) and the foregoing dispersion method (fermentation without interference) or fermentation with polymerization or condensation polymerization or crosslinking solidification (referring to a fermentation without interference), and heating and a mixed synthetic type of evaporation for a metal complex polymer solution (which is a fatty acid-M-protein-protease-sugar in this system) and a fermentation (by adding protein hydrolysis enzymes for decomposing protein into amino radical) are performed to achieve the nano metal and ceramic. The fermented metal complex polymer solution can be added in the sintering process to obtain the nano-scale composite ceramics. As described above, the protein is decomposed into an amino radical and there will be no problem for the nano fermentation or adding a plastic, fiber or ceramic material for the fermentation. A metal complex polymer solution can be applied in different technical areas for the oxidation- condensation and condensation reaction, biochemical reaction for fermentations, metal enzyme or biological enzyme, bacteria culture medium and storage system, food and medicare, production of chemical matters in a plant, oil product processing application, nano filter, production of nano materials for fermentation, production of liquid crystals and semiconductors, nano plastics and fibers, nano inorganic matters and ceramic materials. (Similarly, the foregoing protein can be a NH ₂ matter reversed for several times such as a protein decomposed into an amino radical, and an amino radical composed of amino acids and a protein, or a saccharide or a carboxyl acid or a fatty acid grounded and/or dissolved and/or pyrolyzed and/or converted by enzymes or acetic acid bacteria and its matter to

substitute the carboxyl acid or other bacteria and its substitute can be applied in each embodiment of the present invention and each embodiment as disclosed in No. PCT/CN2005/000132 patent application).

Compared with the prior art, the present invention has the following advantages:

1. In the process of producing bio-diesel solution in accordance with the present invention, carbon dioxide gas can be dissolved in the solution very quickly, and it is not necessary to add any carbonates, but simply imitate the normal state in the nature to grow and reproduce the lichen and/or algae, and thus saving tremendous cost, labor and efforts, and resulting in good economic benefits.

2. The diesel solution in accordance with the present invention comes with a high safety, and the production process does not require any high-temperature pyrolysis or involve industrial safety. The invention provides a novel photosynthetic device and culture system without occupying much farming land, and thus the invention can be applied in large-scale automatic control culture.

3. The novel lichenization and/or algaculture and/or esterification in accordance with the present invention provides an application for producing diesel, and processing carbon dioxide. The coal gas (powder) package can be stored for a long time and the way of producing methane is very convenient and capable of overcoming the difficulty of fertilizers for the fermentation.

4. The present invention provides a novel metal complex polymer solution for processing discarded substances, producing fertilizers and feeds, and applying the food fermentation in organic gas (including methane). 5. The present invention provides a novel biochemical reaction applied in different technical areas for fermentations, and fermentations for producing nano materials, nano plastics and fibers, nano inorganic matters and nano ceramic

materials.

The present invention will now be described in more detail hereinafter with reference to the accompanying drawings that show various embodiments of the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view of air/water and/or oil phase dissolution equipment;

FIG. 2 is a side view of a circular pipe of a photo-bioreactor being a pipeline circling around a cylindrical post downward;

FIG. 3 is a schematic view of straight and curved pipes with several branches of a photo-bioreactor;

FIG. 4 is a schematic view of straight and curved panels of a photo- bioreactor; FIG. 5 is a schematic view of collection tank, blender (having a pump function

), pyrolysis machine, stirring breeding fermentation storage tank, heat exchange heating pipe (or heating device), loop pipeline (including heat pipe );

FIG. 6 shows stirring and/or aerating esterification fermentation chemical engineering equipment; and FIG. 7 shows a table of percentages of carbonate radical, bicarbonate radical and carbon dioxide in water solutions of different pH values.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Referring to a machine designed according to the aforementioned principle by the inventor of the present invention, a windmill 5 absorbs natural air from a gas inlet 11 and the air passes through an air disinfection and/or a film fitter 9 such as ultraviolet rays and circulates continuously, and the nutrient solution 7

goes through a photosynthesis 8 for its continuous reproduction, wherein an air phase dissolution equipment 10 has the stirring and mixing functions, such that the nutrient solution 7 from a qualitative titration apparatus 25 can be adjusted to an acidity and an alkalinity in compliance with the air/water and/or oil phase dissolution equipment 10 (becoming colder after passing through a thermal exchange condenser 16 between the stirring breeding fermentation storage tanks 40) and dissolved. The colder, the larger quantity of carbon dioxide is absorbed. The phase dissolution equipment is driven by the spiral baffle to produce a swirl air, and the air and gas are gathered at the water whirl portion and guided regularly that will cause a whirling effect for the water vapor current, and the temperature and pressure of the whirl are used to promote the exchanged of cold and hot air at the plurality of condensing pipes composed of whirl baffles 15, and a coldness reserving device 17 is disposed outside, and in such stage, the condensing pipe composed of whirl baffles 15 is used for the heat exchange, such that more are dissolved at a colder temperature. In the coming stages, whirl air/water and/or oil rinsing tank 13 is used for the whirl dissolving reaction, since the air turns at a sharp angle and the whirls produced by the flow guider 131 are large, and another wave of fluid dissolution effects will occur. A pump 18 for such dissolution reaction apparatus going through a dissolution reaction apparatus loop pipeline 44 can be returned repeatedly to the air/water and/or oil phase dissolution equipment 10 and water is sprinkled (or discharged to the photo- bioreactor 19), until the dissolved carbon dioxide is saturated to meet the requirements, and then the process is stopped or the nutrient solution 7 is discharged to the photo-bioreactor 19, and air at the top of the whirl air/water and/or oil rinsing tank 13 is passed through a mist eliminator 14 and then discharged from the gas outlet 12 to the atmosphere. The inventor of the present invention filed a U.S. Pat. Application No. 11/503086 entitled "Air/water phase

dissolution equipment with a baffle structure for producing whirl liquid flow or whirl combustion flow" for an improved application as shown in FIG. 1. The nutrient solution performs photosynthesis 8, and its performance determines its reproduction, and the key factor resides on the photo-bioreactor 19 having a circular pipe with an upwardly helical and cylindrical pipeline, a linear and curved pipe with a multiple branch pipes, or a linear and curved panel. The pipeline type photo-bioreactor 19 having an upwardly helical cylindrical pipe is described below:

The transparent pipeline circular pipe made of transparent resin including a plastic or a transparent plastic material is an upwardly helical circular pipe 1 to define a stack of circles, and the circumference of the circle can fix the three surfaces or four surfaces of the support stand 3 on the ground. The three surfaces of the support rod 2 can be inserted into a gap between the upper circle and the lower circle for an enhanced fixture to define a cylindrical pillar for installing an illuminating device 4, such as an LED lamp, an optical fiber light emission, an optical fiber or a guide light for adjusting and supplementing the light. The light pipe includes an assisting opening aligned with its top portion provided for the qualitative titration apparatus 25 to introduce the culture solution, adjust the pressure in the transparent pipeline, or rinse the transparent pipeline. Similarly, the application can be used for producing other photosynthetic plants as shown in FIG. 2.

The linear and curved pipe of the multiple branch pipes is described as follows:

In the photosynthetic pipeline, a transparent pipeline made of a transparent resin such as glass or acrylic is used for introducing the culture solution therein. The photosynthetic pipeline includes a main pipe 20 interconnected with a plurality of linear pipes 21 and a plurality of curved pipes 22 to form a meshed shape or rectangular or square pipeline, and the linear pipes and the curved pipes

are connected in series with an interval apart to form rows of continuous opposite oblique "transverse W" shape 19, and the three-dimensional multiple branch pipes transparent pipeline allow the culture solution to circulate and flow down to sufficiently absorb lights for the photosynthesis, or an illuminating device 4 can be used. The light pipeline includes an assisting opening aligned with its top portion, for a qualitative titration apparatus 25 to introduce the culture solution, adjust the pressure in the transparent pipeline, or rinse the transparent pipeline as shown in FIG. 3.

The linear and curved panel type can be used for producing other photosynthetic plants as above:

The photosynthetic pipeline includes a branch pipe interconnected with a linear panel 23 and a curved panel 24 to form a rectangular or square panel, and the panel is hollow inside, and the linear panel and curved panel are connected with an interval in between to form a row of continuous oblique "transverse W- shape 19, and the three-dimensional multi-panel transparent pipeline allows the culture solution to circulate and flow downward to fully absorb lights to perform photosynthesis, and includes an illuminating device 4 therein. The light pipeline has an assisting opening aligned with its top portion for allowing a qualitative titration apparatus 25 to introduce the culture solution, adjust the pressure in the transparent pipeline, or rinse the transparent pipeline as shown in FIG. 4.

The photosynthetic pipeline flowing into the collection tank 27 with a funnel- shape facilitates collecting a fungus and/or an algae or removing a heavier precipitate, and whirls can be produced by the design of a lateral flow 54. If the algae requires to discharge oxygen, the gas can be discharged easily (when the lichen is cultured, a small quantity of oxygen can be flowed in directly from the top 54), and air is discharged from an upper side of the air outlet, and the adjustable opening can be used for discharging air to maintain the pressure in the level

adjusting device, and the collection tank bundled with a circulator 28 is generally connected to the collection tank loop pipeline 45 and also to the air/water and/or oil phase dissolution equipment 10 for the whirl water and/or an oil rinsing tank 13, and the blender (having a pump function) 29 is installed below the collection tank 27. When not blended, a control valve 47 can be used for a direct discharge, and the blender (having a pump function) 29 is connected to a pyrolysis machine 30, such that after the pyrolysis is completed, the solution can be sent to the stirring, breeding and fermentation storage tank 40 that installs a heat exchange heating pipe (or heating device) 42 from the condenser 16 therein, and a heat reserving device 43 disposed outside the stirring, breeding and fermentation storage tank 40, so as to maintain it at a higher temperature. If the fermentation is matured, or the next loop of culture starts again, the stirring, breeding and fermentation storage tank 40 bundled with a circulator 41 will be started and an electric switch valve 47 will be adjusted, such that the stirring, breeding and fermentation storage tank loop pipeline (including heat pipe) 46 for sending the nutrient solution 7 to a whirl water and/or an oil rinsing tank 13 of the air/water and/or oil phase dissolution equipment 10 as shown in FIG. 5.

After air/water and/or oil phase dissolution equipment 10a for dissolving the nutrient solution 7 absorbs a large quantity of carbon dioxide as shown in FIG. 7, a pH meter 6 is used for monitoring the acidity and alkalinity of the circulated solution 26 which has not passed through a position before the photo-bioreactor 19, and also monitoring the acidity and alkalinity of the circulated solution 26 which has passed the photo-bioreactor 19. From the decrease of acidity or alkalinity of the circulated solution before and after it passes through the photo- bioreactor 19, we can obtain the reaction consumption of carbon dioxide and also can know the photosynthetic rate of the synthetic saccharide for adjusting the flow speed of the circulated solution 26, and the foregoing nutrient solution 7 can carry

out a photosynthesis 8, and a pH meter 6 is used for monitoring the reaction consumption of dissolved carbon dioxide for the photo-bioreactor 19 to control the wind quantity (windmill rotating speed), such that the thickness of the dissolved carbon dioxide is consistent with the reaction consumption, and the photosynthesis 8 only requires a mid-level of light intensity. From the reaction consumption, we can obtain the growth speed. The required quantity of light can be adjusted and supplemented by an illuminating device such as an LED lamp, an optical fiber light emission, an optical fiber, and a light guide in the photo- bioreactor 19, so as to adjust the wind speed and the dimming. In summation of the description above, the present invention can be applied similarly to the production of other photosynthetic plant as well.

After a portion of nutrient solution 7 flowing out from a collection tank 27 below the photo-bioreactor 19 passes through the disinfection machine 48, the disinfected nutrient solution 7 can be used for other purpose, and in the next step of stirring esterification processing reaction 49, a sealed reaction bucket is opened, and the stirring machine is installed in the middle and an inlet 54 is disposed on the lateral side for pouring in the nutrient solution 7 and also discharging air. The cane sugar and carboxyl acid are mixed into a fresh culture medium to supplement the fungus and/or algae nutrition to comply with the shortage of metal complex polymer solution. After the esterase 50 is added to the titanium metal complex polymer solution, the titanium (or other metal, but it is recommended to use cobalt and/or aluminum or antimony for the complex metal ion) metal esterase (such as lipase or and/or esterase mixed with some alcoholic enzyme) or biological enzyme as the esterification nutrient solution 7, and the esterification process can timely add oxygen anions O ^'2 , O ^2' or nascent oxygen 51 for enhancing the modification, and the product includes a solvent such as fatty acid ester, and the equipment for esterification fermentation includes a

stirring and/or aerating fermentation chemical engineering equipment 52 for the stirring reaction, after a two-phase separation (solvent phase and non-solvent phase ). If a quick-dissolving setting agent such as ferric oxide is added, the fatty acid-M-NH ₂ -protease-sugar structure will break down, and finally separated into two phases. The solvent phase such as the fatty acid ester will be floated and extracted from the lateral sides, and water and protein and precipitates will flow out from the bottom, and it is not necessary to be distilled as shown in FIG. 6.

The embodiments of the present invention disclose that oil product (including fatty acid) and/or leftover rice (starch ), cane sugar, cellulose powder 1-4% are put into 1-4% grass (oxalic acid) or other acid (including organic and/or inorganic matter having a -COOH carboxyl acid) and mixed with 97-88% of water solution. At 2OD, a thick slurry is produced, and such slurry and 1-4% gypsum, bone powder, acidified or chlorinated or hydroxyl or inorganic polymer of a monovalent, bivalent or trivalent metal ions and algae protein powder fermentation and/or grounded and/or dissolved and/or pyrolyzed protein is converted into an amine and an amino acid, and sufficiently stirred and mixed, and the stirring speed is 200 rpm. The fermentation reaction solution and other reaction solution are given in the following embodiments.

In a first preferred embodiment of the present invention, lichen is cultured (which can be used similarly for the production of other photosynthetic plants as well).

In the method of absorbing nutrition from the air to culture lichens, a metal complex polymer solution composed of humic acid, calcium oxide and ammonia water together with 150 cc of culture medium are contained in a 500 cc oscillating bottle, and an appropriate quantity of 3-4-5 cc of lichen is added into the culture medium. The solution is oscillated and cultured at a room temperature of 25D and projected with a light continuously for two days. The speed for the

fermentation and duplication of lichen can be expedited to produced tens of millions of lichen cells, and the titrated carboxyl acid such as citric acid can easily absorb carbon dioxide and they are stirred powerfully to add carbon dioxide gas to make them acidic, and a light with an intensity of 4800 luxes and a rotating speed of 120 rpm are used for the photosynthetic culture, and then titrated to meet the shortage of a metal complex polymer solution composed of an oil product (excluding the previously added carboxyl acid such as citric acid), and the dosages of cane sugar, amino or amine, metal salt, and oil are approximately the same as acid. A spectrophotometer with a wavelength of 680 nm is used for measuring the growth of lichen and the optical degree for measuring the lichen cells, and the optical density of the lichen is measured once every 24 hours to obtain the cell density. After the lichen grows to a late logarithmic phase, the next culture can be performed.

New humic acid, metal complex polymer solution, culture medium are added into another oscillating bottle, and then a portion of lichen cells is absorbed, grounded, and/or dissolved and/or pyrolyzed to convert the protein into an amine and an amino acid, and other ingredients are converted. A small quantity of cane sugar and carboxyl acid are mixed in the fresh culture medium to supplement the lichen nutrition such that the composition can suffice the shortage of metal complex polymer solution, and the fermentation is diluted by 100 times, and similarly the same culture conditions are used for the culture, and then the nutrient solution is added and titrated to citric acid and/or cane sugar and/or inorganic salt and/or metal salt and/or urea and/or amino and/or amine matters and/or discarded protein matter or a metal complex polymer solution with a nutrient solution as recited in claim 1 or a fermented (such as EM bacteria suitable for plant) metal complex polymer solution with a nutrient solution as recited in claim 1 for promoting the reaction. The solution is mixed evenly for

three days, and the lichen cells will grow to a late logarithmic phase again, so as to repeatedly perform the next culture.

In a second preferred embodiment of the present invention, algae are cultured (similarly, it can be used for the production of other photosynthetic plants).

Algae (such as spinrulina) are cultured by a proprietary operation and/or a joint operation (such as producing a metal complex polymer solution by humic acid, calcium oxide and ammonia water and adding 150 cc of culture medium into a 500 cc vibrating bottle and an appropriate quantity of 3~4.5 cc of algae is added into the culture medium and oscillated and cultured at the room temperature of 25 D, and projected continuously by a light for two days, such that the algae can be fermented and duplicated into tens of millions of algae cells quickly, and then titrated by potassium hydroxide and/or an amine matter such as urea, and stirred powerfully to introduce carbon dioxide gas to produce carbonate ions, bicarbonate ions and potassium chloride and ionic amino radicals substantially alkaline and a light with an intensity of 4800 luxes and a rotating speed of 120 rpm are used for the photosynthetic culture, and then a titration is performed to supplement the shortage of an oil product composed of a metal complex polymer solution (excluding the previously added amine matter such as urea), and the dosages of cane sugar, acetic acid and metal salt are approximately equal to that of the amine, and a phosphate fertilizer and a trace of potassium are added timely, and a spectrophotometer with a wavelength of 680 nm is used for measuring the optical degree of the growing algae to test the algae cells. The optical density of the algae is measured once for every 24 hours, and the cell density of algae is measured. If the cells of the algae are grown to a late logarithmic phase, the next culture can be conducted.

New humic acid, metal complex polymer solution, and culture medium are

poured into another oscillating bottle, and a portion of algae cells is absorbed and a protein is grounded and/or dissolved and/or pyrolyzed into an amine and an amino acid, and other ingredients are converted, and a cane sugar is mixed and a carboxyl acid is added into a fresh culture medium, so that the algae nutrition composition can be supplemented to comply with the shortage of the metal complex polymer solution, and the solution is diluted by 100 times for the fermentation, and the same culture conditions are used for the culture, and then a nutrient solution is added for the titration, and the citric acid, acetic acid and/or cane sugar and/or inorganic salt and/or metal salt and/or urea and/or amino and/or amine matters and/or discarded protein matter or a nutrient solution of a metal complex polymer solution according to claim 1 or a fermented nutrient solution of a metal complex polymer solution according to claim 1 for promoting the reaction after the solution is mixed evenly for three days, and the algae cells will be grown again to a logarithmic with phase, so as to repeat the culture. In a third preferred embodiment of the present invention, the embodiment includes an oil product of a fungus and/or an algae and/or a method for producing diesel by esterification and fermentation, and the fungus and/or algae cell is blended and pyrolyzed, and a cane sugar is mixed, and a carboxyl acid is added (and it is perfectly alright for adding or not adding oil, such that the fungus and/or algae nutrition composition can be supplemented for the shortage of an oil product composed of a metal complex polymer solution. For example, 1 liter of lichen includes different ingredients of approximately 2%, and 1 % of cane sugar and 1 % of citric acid are added to produce a titanium metal complex polymer solution, and 0.1% of an esterase (such as a lipase and an esterase mixed with some alcoholic enzymes 0.01%) is used for fermentation, and then the titanium esterase or biological enzyme us used as an esterification nutrient solution. After the esterification and fermentation, the solution is stirred and some oxygen anions

O ^"2 , O ^2" or nascent oxygen are added to enhance the modification, aerating, fermentation and stirring for the separation, and a scraping board type thin film evaporator is used for the separation into a fatty acid and a methyl ester which is a bio-diesel. In a fourth preferred embodiment of the present invention, the pure fatty acid for esterification and fermentation is an embodiment for the diesel method that adds the fatty acid to comply with the fatty acid-M-NH ₂ -protease-sugar structure (or a metal complex polymer solution), and mixed into an oil emulsion having a percentage composition of: Bacteria-free water 30%

Vinegar (including carboxyl acids) 10%

Fatty acid (or pyrolyzed industrial oil) 20%

Titanium sulfate 10%

Ammonia water 10% Cane sugar 20%

Lipase or esterase mixed with some alcoholic enzyme Trace

The fatty acid, water, vinegar, cane sugar, titanium sulfate, and ammonia solution are mixed evenly, and then the lipase or esterase mixed with some alcoholic enzyme is fermented. After a catalyst is mixed into the fatty acid and stirred/aerated, a fatty acid ester will be formed.

In a fifth preferred embodiment of the present invention, a metal complex polymer solution applied for processing organic wastes and producing fertilizers is composed of:

Oil meal (which can be either nutritious or not nutritious) 2% Grass (Tartaric acid) 2%

(or saw dust and its acetic acid bacteria mixed with lactobacilli and yeasts)

Leftover rice (starch) and cane sugar 3%

Water 90%

Gypsum and bone powder 2%

Urine (NH2 starter), Meat leftover (NH ₂ matter reversed for several times)

2% Other food leftover (minerals) 1 %

Fermentation enzyme (good for human body and plant) After being fermented for a week, a metal complex polymer solution can be formed more quickly, and finally stacked into a fertilizer, and this method does not require high-temperature fermentations for the quick formation. In a sixth embodiment of the invention, a metal complex polymer solution applied for feeds is composed of: Oil 1%

Grass (Valeric acid) 2% Corn starch 3% Water... 90%

Wild vegetables (minerals) 2%

Algae protein powder 2% (NH ₂ matter reversed for several times) Thus, fermentation and catalysis are conducted automatically in the body. In a seven embodiment of the present invention, a metal complex polymer solution applied in food fermentation is consisted of: Soy milk 2%

Acetic acid (which can be substituted by a fermented acetic acid bacteria

1 %

Cane sugar powder 3% Water 90%

Gypsum 1%

Trace of ammonia water as a starter, and a meat source (NH ₂ matter

reversed for several times) 2%

Main fermentation enzyme (good for human body) 1 % In an eighth preferred embodiment of the present invention, a metal complex polymer solution used as a nutrient substance for producing an organic gas (including a methane gas) is composed of: South-east Asian sour fruit powder 2% Cane sugar powder 3%

Water ... 90%

Nickel 1 % Algae protein powder 2% (NH ₂ matter reversed for several times)

Oil 2%

The foregoing ingredients are packed by a frozen dry vacuum bacteria-free package.

The bacteria culture medium is composed of: Bacteria-free water 94%

Vinegar including carboxyl acids 2%

Hydroxypropyl methyl cellulose 2%

Nickel sulfate 2%

Ammonia water 2% The hydrolytic bacteria produce trace of oxygen, ethanoic acid bacteria, and methane bacteria. A pack of bacteria culture medium is added to a pack of nutrient substance, and bacteria-free water is mixed into a coal gas culture can. It is recommended to use nickel for the complex metal ions in the culture medium and nutrient substance due to the catalysis. Two packs of bacteria culture medium can expedite the production of methane in the coal gas culture can interconnected with a coal gas stove.

In a ninth preferred embodiment of the present invention, a metal complex

polymer solution fermented for the applications in the technical areas of biochemical reaction, nano filter, nano inorganic matter, fermentation for producing nano material, producing liquid crystals and semiconductors, nano plastics, nano fibers, nano ceramic materials is composed of: The R-metal ion-NH ₂ -protease converts R-metal ion-protein-protein bacteria as hydrolytic bacteria.

Bacteria-free water 86%

Vinegar including carboxyl acids 2% (Acetic acid bacteria and its matter such as sugar can be used to substitute the carboxyl acids) Hydroxypropyl methyl cellulose 2%

Titanium sulfate 10%

Ammonia water converted into a protein 2% (NH ₂ matter reversed for several times)

Hydrolytic bacteria Trace The hydrolytic bacteria decomposes the protein into amino radicals, and the foregoing fermented nano metal complex polymer solution is condensed into a coagulation state, and cast into a titanium oxide green to be sintered at 600D.

Similarly, other oxidation-condensation and condensation reaction, biochemical reaction for fermentation, metal enzyme or biological enzyme, bacteria culture medium and storage system, food and medicare, chemical matter for the production of plant, oil product processing application, nano filter, nano inorganic matter, nano material for fermentation, liquid crystals and semiconductors, nano plastics, nano fibers adopt the aforementioned hydrolysis enzyme for decomposing protein into amino radicals (or saccharides or carboxyl acids or fatty acids by grounding and/or dissolution and/or pyrolysis and/or enzyme) or an acetic acid bacteria and its matter to substitute carboxyl acids or other bacteria and its substitute, and all of the above methods and substances

can be used for the fermentation purpose, and applied in different embodiments as illustrated in patent application No. PCT/CN2005/000132, but it is to be understood that the invention is not limited thereto. To the contrary, it is intended to cover various modifications and similar arrangements and procedures, and the scope of the appended claims therefore should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements and procedures.