Title:
METAL COMPLEX AND PRODUCTION METHOD THEREFOR, CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST FOR OLEFIN POLYMERIZATION CONTAINING METAL COMPLEX, AND METHOD FOR PRODUCING POLYMER AND COPOLYMER OF Α-OLEFIN USING CATALYST FOR OLEFIN POLYMERIZATION
Document Type and Number:
WIPO Patent Application WO/2018/021446
Kind Code:
A1
Abstract:
Provided are a novel catalyst component having superior polymerization activity for production of a polymer and a copolymer of an α-olefin, particularly a polymer having a high molecular weight, and a method for producing a polymer and a copolymer of an α-olefin using the catalyst component. Provided is a metal complex characterized by being obtained by causing a compound represented by general formula [I] or [II] to make contact with a transition metal compound containing a transition metal belonging to group 9, 10, or 11 in the periodic table. [In general formulae [I] and [II], R1, R2, R3, and R4 each independently represent (i) hydrogen, (ii) a halogen, (iii) a linear alkyl or the like having 1-30 carbon atoms and optionally having a group selected from the group consisting of heteroatoms, heteroatom-containing groups, etc., or (iv) OR9, etc. R5 and R6 each independently represent a linear alkyl group having 7-30 carbon atoms and optionally having a group selected from the group consisting of heteroatoms, heteroatom-containing groups, etc. E1 represents phosphorus, arsenic, or antimony. X1 represents oxygen or sulfur. In general formula [I], Z represents hydrogen or a leaving group, and m represents the valence of Z.]
Inventors:
NOZAKI KYOKO (JP)
ITO SHINGO (JP)
TAO WEN-JIE (JP)
KONISHI YOHEI (JP)
OHTAKI HISASHI (JP)
OHISHI YASUO (JP)
TANNA AKIO (JP)
TAYANO TAKAO (JP)
ITO SHINGO (JP)
TAO WEN-JIE (JP)
KONISHI YOHEI (JP)
OHTAKI HISASHI (JP)
OHISHI YASUO (JP)
TANNA AKIO (JP)
TAYANO TAKAO (JP)
Application Number:
PCT/JP2017/027134
Publication Date:
February 01, 2018
Filing Date:
July 26, 2017
Export Citation:
Assignee:
UNIV TOKYO (JP)
JAPAN POLYCHEM CORP (JP)
JAPAN POLYCHEM CORP (JP)
International Classes:
C07F15/04; C07F9/50; C08F4/70; C08F4/80; C08F10/00
Domestic Patent References:
| WO2013159229A1 | 2013-10-31 | |||
| WO2010050256A1 | 2010-05-06 |
Foreign References:
| JP2005307021A | 2005-11-04 | |||
| US6559326B1 | 2003-05-06 |
Other References:
DUBINSKY-DAVIDCHIK, INA ET AL.: "Selective Aryl-Fluoride Reductive Elimination from a Platinum (IV) Complex", ANGEWANDTE CHEMIE , INTERNATIONAL EDITION, vol. 54, no. 42, 2015, pages 12447 - 12451, XP 055457292, ISSN: 1433-7851
EMPSALL, H. DAVID ET AL.: "Complexes of Platinum and Palladium with Tertiary Dimethoxyphenylphosphines: Attempts to Effect 0- or C-Metallation", JOURNAL OF THE CHEMICAL SOCIETY , DALTON TRANSACTIONS : INORGANIC CHEMISTRY (1972-1999, vol. 3, 1978, pages 257 - 262, XP 002132764, ISSN: 0300-9246
EMPSALL, H. DAVID ET AL.: "Some Unusual Iridium Complexes formed from (2,6-Dimethoxyphenyl)- and (2,3-Dimethoxyphenyl)-di-t-butylphosphine: Crystal Structure of [2-Di-t-butylphosphino-3- methoxyphenoxo-OP] {2-[(2-hydroxy-6- methoxyphenyl)t-butylphosphino]-2- methylpropanato(2-)-ClP02}-(methyl isocyanide) iridium(III", JOURNAL OF THE CHEMICAL SOCIETY , DALTON TRANSACTIONS : INORGANIC CHEMISTRY (1972- 1999, vol. 9, 1978, pages 1119 - 1126, XP009511489, ISSN: 0300-9246
IONKIN, ALEX S. ET AL.: "Rare Organometallic Complex of Divalent, Four-Coordinate Iridium: Synthesis, Structural Characterization, and First Insights into Reactivity", ORGANOMETALLICS, vol. 23, no. 25, 2004, pages 6031 - 6041, XP 002455587, ISSN: 0276-7333
See also references of EP 3476858A4
EMPSALL, H. DAVID ET AL.: "Complexes of Platinum and Palladium with Tertiary Dimethoxyphenylphosphines: Attempts to Effect 0- or C-Metallation", JOURNAL OF THE CHEMICAL SOCIETY , DALTON TRANSACTIONS : INORGANIC CHEMISTRY (1972-1999, vol. 3, 1978, pages 257 - 262, XP 002132764, ISSN: 0300-9246
EMPSALL, H. DAVID ET AL.: "Some Unusual Iridium Complexes formed from (2,6-Dimethoxyphenyl)- and (2,3-Dimethoxyphenyl)-di-t-butylphosphine: Crystal Structure of [2-Di-t-butylphosphino-3- methoxyphenoxo-OP] {2-[(2-hydroxy-6- methoxyphenyl)t-butylphosphino]-2- methylpropanato(2-)-ClP02}-(methyl isocyanide) iridium(III", JOURNAL OF THE CHEMICAL SOCIETY , DALTON TRANSACTIONS : INORGANIC CHEMISTRY (1972- 1999, vol. 9, 1978, pages 1119 - 1126, XP009511489, ISSN: 0300-9246
IONKIN, ALEX S. ET AL.: "Rare Organometallic Complex of Divalent, Four-Coordinate Iridium: Synthesis, Structural Characterization, and First Insights into Reactivity", ORGANOMETALLICS, vol. 23, no. 25, 2004, pages 6031 - 6041, XP 002455587, ISSN: 0276-7333
See also references of EP 3476858A4
Attorney, Agent or Firm:
KISHIMOTO, Tatsuhito et al. (JP)
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