Title:
METAL COMPLEX AND SUPPORTED METAL COMPLEX HAVING DISILOXANE AS LIGAND, PREPARATION METHOD THEREFOR, AND SUPPORTED METAL CATALYST PREPARED USING SAME
Document Type and Number:
WIPO Patent Application WO/2014/142252
Kind Code:
A1
Abstract:
A metal complex represented by general formula (1). (In the formula, M represents palladium or platinum, L represents a ligand selected from carbon monoxide, an olefin compound, an amine compound, a phosphine compound, an N-heterocyclic carbene compound, a nitrile compound, and an isocyanide compound, n represents an integer from 0 to 2 representing the number of ligands, and R1-R4 represent an organic group.) The metal complex can be immobilized to an inorganic oxide while retaining the skeleton structure thereof to form a supported metal complex, and as a result, the supported metal complex is able to maintain the same level of catalytic activity provided in the original metal complex. In addition, by calcining a supported metal complex obtained in such a manner, it is possible to obtain a supported metal catalyst having catalytic activity which is greatly improved over conventional supported metal catalysts.
Inventors:
CHOI JUN-CHUL (JP)
FUKAYA NORIHISA (JP)
YASUDA HIROYUKI (JP)
FUKAYA NORIHISA (JP)
YASUDA HIROYUKI (JP)
Application Number:
PCT/JP2014/056716
Publication Date:
September 18, 2014
Filing Date:
March 13, 2014
Export Citation:
Assignee:
NAT INST OF ADVANCED IND SCIEN (JP)
International Classes:
C07F19/00; B01J31/22; B01J31/24; B01J37/08; C07B61/00; C07C5/03; C07C13/26; C07F7/21; C07F9/50; C07F15/00
Foreign References:
| US3625934A | 1971-12-07 |
Other References:
M.B.HURSTHOUSE ET AL.: "Cyclic cobaltadisiloxane compounds. Crystal structures of a pyridinolithium [bis(cyclosiloxy)cobalt] cobalt chloride and a bis (tetramethylethylenediaminolithium)-bis (cyclosiloxy)cobaltate", JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 381, no. 2, 1990, pages C43 - C46, XP055289970
J.BECKMANN ET AL.: "Strained Metallastannoxanes-Ring-Opening Polymerization versus Retention of Six-Membered-Ring Structure", ORGANOMETALLICS, vol. 18, no. 9, 1999, pages 1586 - 1595, XP055289972
CHEM. MATER., vol. 20, 2008, pages 6517
ACS CATAL., vol. 1, 2011, pages 1166
J. BECKMANN, APPL. ORGANOMETAL. CHEM., vol. 17, 2003, pages 52
C. T. KRESGE, NATURE, vol. 359, 1992, pages 710
See also references of EP 2975045A4
J.BECKMANN ET AL.: "Strained Metallastannoxanes-Ring-Opening Polymerization versus Retention of Six-Membered-Ring Structure", ORGANOMETALLICS, vol. 18, no. 9, 1999, pages 1586 - 1595, XP055289972
CHEM. MATER., vol. 20, 2008, pages 6517
ACS CATAL., vol. 1, 2011, pages 1166
J. BECKMANN, APPL. ORGANOMETAL. CHEM., vol. 17, 2003, pages 52
C. T. KRESGE, NATURE, vol. 359, 1992, pages 710
See also references of EP 2975045A4
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