Title:
METAL COORDINATION COMPOUND AND ELECTROLUMINESCENCE DEVICE
Document Type and Number:
WIPO Patent Application WO/2003/000661
Kind Code:
A1
Abstract:
A metal coordination compound having a basic structure expressed by general formula MLmL’n (1) [wherein M represents a metal atom of Ir, Pt, Rh, or Pd, L and L’ represent mutually different bidentate ligands, m is 1, 2, or 3, n is 0, 1, or 2, and m &plus n is 2 or 3]. The basic structure includes a partial structure in which at least one bidentate ligand L is condensated through an alkylene group having 2−10 carbon atoms. An electroluminescence device having a cathode, an anode, and a plurality of organic thin films between the cathode and anode is also disclosed. At least one of the organic thin films is a luminescence layer made of a host material and luminance molecules of a metal coordination compound having a structure expressed by general formula (1) and mixed in the host material as a guest material. The electroluminescence device emits light at high efficiency and maintains a high luminance stably for a long term.
Inventors:
TAKIGUCHI TAKAO (JP)
TSUBOYAMA AKIRA (JP)
OKADA SHINJIRO (JP)
KAMATANI JUN (JP)
MIURA SEISHI (JP)
MORIYAMA TAKASHI (JP)
IGAWA SATOSHI (JP)
FURUGORI MANABU (JP)
MIZUTANI HIDEMASA (JP)
TSUBOYAMA AKIRA (JP)
OKADA SHINJIRO (JP)
KAMATANI JUN (JP)
MIURA SEISHI (JP)
MORIYAMA TAKASHI (JP)
IGAWA SATOSHI (JP)
FURUGORI MANABU (JP)
MIZUTANI HIDEMASA (JP)
Application Number:
PCT/JP2002/006001
Publication Date:
January 03, 2003
Filing Date:
June 17, 2002
Export Citation:
Assignee:
CANON KK (JP)
TAKIGUCHI TAKAO (JP)
TSUBOYAMA AKIRA (JP)
OKADA SHINJIRO (JP)
KAMATANI JUN (JP)
MIURA SEISHI (JP)
MORIYAMA TAKASHI (JP)
IGAWA SATOSHI (JP)
FURUGORI MANABU (JP)
MIZUTANI HIDEMASA (JP)
TAKIGUCHI TAKAO (JP)
TSUBOYAMA AKIRA (JP)
OKADA SHINJIRO (JP)
KAMATANI JUN (JP)
MIURA SEISHI (JP)
MORIYAMA TAKASHI (JP)
IGAWA SATOSHI (JP)
FURUGORI MANABU (JP)
MIZUTANI HIDEMASA (JP)
International Classes:
H01L51/50; C07D221/10; C07D221/16; C07F15/00; C09K11/06; G09F9/30; H01L27/32; H01L51/30; H05B33/14; H01L51/00; (IPC1-7): C07D221/10; C07D221/16; C09K11/06; H05B33/14; H05B33/12; C07F15/00
Domestic Patent References:
| WO2001041512A1 | 2001-06-07 | |||
| WO2000057676A1 | 2000-09-28 | |||
| WO2002044189A1 | 2002-06-06 | |||
| WO2000057676A1 | 2000-09-28 |
Foreign References:
| JP2001181617A | 2001-07-03 | |||
| EP1211257A2 | 2002-06-05 | |||
| JP2002105055A | 2002-04-10 | |||
| JP2001181616A | 2001-07-03 | |||
| US20010019782A1 | 2001-09-06 | |||
| JP2002175884A | 2002-06-21 | |||
| JP2001181617A | 2001-07-03 |
Other References:
CORNIOLEY-DEUSCHEL CHRISTINE ET AL.: "15. Complexes with a pincers. 2,6-diphenylpyridine as twofold-deprotonated (C-N-C) terdentate ligand in C,C-trans- and as mono-deprotonated (C-N) chelate ligand in chiral C,C-cis-complexes of platinum(II) and palladium(II)", HELV. CHIM. ACTA, vol. 1, 1988, pages 130 - 133, XP002955891
DEUSCHEL-CORNIOLEY CHRISTINE ET AL.: "A new type of 'square planar' platinum(II) complex showing helical chirality", J. CHEM. SOC., CHEM. COMMUN., vol. 2, 1990, pages 121 - 122, XP002955892
MAESTRI MAURO ET AL.: "Spectroscopic and electrochemical properties of pt(II) complexes with aromatic terdendate (C-N-C)cyclometallating ligands", J. PHOTOCHEM. PHOTOBIOL. A: CHEM, vol. 67, 1992, pages 173 - 179, XP002955893
LAMANSKY SERGEY ET AL.: "Synthesis and characterization of phosphorescent cyclometalated iridium complexes", INORG. CHEM., vol. 40, 26 March 2001 (2001-03-26), pages 1704 - 1711, XP002196399
LAMANSKY SERGEY ET AL.: "Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization and use in organic light emitting diodes", J. AM. CHEM. SOC., vol. 123, 9 May 2001 (2001-05-09), pages 4304 - 4312, XP002955894
JOLLIET PHILIPPE ET AL.: "Cyclometalated complexes of palladium(II) and platinum(II): cis-configured homoleptic and heteroleptic compounds with aromatic C-N ligands", INORG. CHEM., vol. 35, 1996, pages 4883 - 4888, XP002955895
OHSAWA Y. ET AL.: "Electrochemistry and spectroscopy of ortho-matalated complexes of Ir(III) and Rh(III)", J. PHYS. CHEM., vol. 91, 1987, pages 1047 - 1054, XP002955896
LAMANSKY ET AL.: "Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes", INORG. CHEM., vol. 40, 2001, pages 1704 - 1711
LAMANSKY ET AL.: "Highly Phosphorescent Bis-Cyclometalated Iridium Complexes: Synthesis, Photophysical Characterization, and Use in Organic Light Emitting Diodes", J. AM. CHEM. SOC., vol. 123, 2001, pages 4303 - 4312
JOLLIET ET AL.: "Cyclometalated Complexes of Palladium(II) and Platinum(II): cis-Configured Homoleptic and Heteroleptic Compounds with Aromatic CON Ligands", INORG. CHEM., vol. 35, 1996, pages 4883 - 4888
OHSAWA ET AL.: "Electrochemistry and Spectroscopy of Ortho-Metalated Complexes of Ir(III) and Rh(III", J. PHYS. CHEM., vol. 91, 1987, pages 1047 - 1054
See also references of EP 1400514A4
DEUSCHEL-CORNIOLEY CHRISTINE ET AL.: "A new type of 'square planar' platinum(II) complex showing helical chirality", J. CHEM. SOC., CHEM. COMMUN., vol. 2, 1990, pages 121 - 122, XP002955892
MAESTRI MAURO ET AL.: "Spectroscopic and electrochemical properties of pt(II) complexes with aromatic terdendate (C-N-C)cyclometallating ligands", J. PHOTOCHEM. PHOTOBIOL. A: CHEM, vol. 67, 1992, pages 173 - 179, XP002955893
LAMANSKY SERGEY ET AL.: "Synthesis and characterization of phosphorescent cyclometalated iridium complexes", INORG. CHEM., vol. 40, 26 March 2001 (2001-03-26), pages 1704 - 1711, XP002196399
LAMANSKY SERGEY ET AL.: "Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization and use in organic light emitting diodes", J. AM. CHEM. SOC., vol. 123, 9 May 2001 (2001-05-09), pages 4304 - 4312, XP002955894
JOLLIET PHILIPPE ET AL.: "Cyclometalated complexes of palladium(II) and platinum(II): cis-configured homoleptic and heteroleptic compounds with aromatic C-N ligands", INORG. CHEM., vol. 35, 1996, pages 4883 - 4888, XP002955895
OHSAWA Y. ET AL.: "Electrochemistry and spectroscopy of ortho-matalated complexes of Ir(III) and Rh(III)", J. PHYS. CHEM., vol. 91, 1987, pages 1047 - 1054, XP002955896
LAMANSKY ET AL.: "Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes", INORG. CHEM., vol. 40, 2001, pages 1704 - 1711
LAMANSKY ET AL.: "Highly Phosphorescent Bis-Cyclometalated Iridium Complexes: Synthesis, Photophysical Characterization, and Use in Organic Light Emitting Diodes", J. AM. CHEM. SOC., vol. 123, 2001, pages 4303 - 4312
JOLLIET ET AL.: "Cyclometalated Complexes of Palladium(II) and Platinum(II): cis-Configured Homoleptic and Heteroleptic Compounds with Aromatic CON Ligands", INORG. CHEM., vol. 35, 1996, pages 4883 - 4888
OHSAWA ET AL.: "Electrochemistry and Spectroscopy of Ortho-Metalated Complexes of Ir(III) and Rh(III", J. PHYS. CHEM., vol. 91, 1987, pages 1047 - 1054
See also references of EP 1400514A4
Attorney, Agent or Firm:
Yamada, Ryuichi (Hasegawa Bldg. 4F 7-7, Toranomon 3-chom, Minato-ku Tokyo, JP)
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