Title:
METAL-ORGANIC FRAMEWORK-BASED WATER ELECTROLYSIS CATALYST DERIVED FROM PRUSSIAN BLUE ANALOG COMPRISING THREE TRANSITION METALS AND COMPRISING SIZE-CONTROLLED PORES, AND METHOD OF PREPARING SAME
Document Type and Number:
WIPO Patent Application WO/2020/080637
Kind Code:
A1
Abstract:
Disclosed is a metal-organic framework-based water electrolysis catalyst prepared from a Prussian blue analog. The metal-organic framework-based water electrolysis catalyst comprises, as transition metals, Ni having an oxidation number of 2, Co having an oxidation number of 2, Co having an oxidation number of 3, Fe having an oxidation number of 2, and Fe having an oxidation number of 3, and comprises a coordination compound in which [Co(CN)6]3- complex ions are bonded to Ni2
+, a coordination compound in which [Fe(CN)6]3- complex ions are bonded to Ni2
+, and NiS produced by an ion-exchange reaction of the [Co(CN)6]3- complex ions and S2- ions.
Inventors:
AHN WOOK (KR)
PARK MOON GYU (KR)
PARK MOON GYU (KR)
Application Number:
PCT/KR2019/006681
Publication Date:
April 23, 2020
Filing Date:
June 03, 2019
Export Citation:
Assignee:
UNIV SOONCHUNHYANG IND ACAD COOP FOUND (KR)
International Classes:
B01J31/16; B01J35/10; B01J37/03; B01J37/08; B01J37/30; H01M4/88; H01M4/90
Other References:
YU , X. -Y.: "Formation of Nickel Sulfide Nanoframes from Metal-Organic Frameworks with Enhanced Pseudocapacitive and Electrocatalytic Properties", ANGEW. CHEM. INT. ED., 2015, pages 5331 - 5335, XP055703117
WIDMANN, A. ET AL.: "Structure, Insertion Electrochemistry, and Magnetic Properties of a New Type of Substitutional Solid Solutions of Copper, Nickel, and Iron Hexacyanoferrates/Hexacyanocobaltates", INORGANIC CHEMISTRY, 2002, pages 5706 - 5715, XP055703119
YAN, Y.: "A review on noble-metal-free bifunctional heterogeneous catalysts for overall electrochemical water splitting", JOURNAL OF MATERIALS CHEMISTRY A, 2016, pages 17587 - 17603, XP055703122
ZHANG, X.: "Ni3[Fe (CN) 6]2 nanocubes boost the catalytic activity of Pt to wards electrochemical hydrogen evolution", INORG. CHEM. FRONT., 14 May 2018 (2018-05-14), XP055703124
AHN, W.: "Hollow Multivoid Nanocuboids Derived from Ternary Ni-Co-Fe Prussian Blue Analog for Dual-Electrocatalysis of Oxygen and Hydrogen Evolution Reactions", ADV. FUNCT. MATER., 3 June 2018 (2018-06-03), pages 1 - 11, XP055703126
WIDMANN, A. ET AL.: "Structure, Insertion Electrochemistry, and Magnetic Properties of a New Type of Substitutional Solid Solutions of Copper, Nickel, and Iron Hexacyanoferrates/Hexacyanocobaltates", INORGANIC CHEMISTRY, 2002, pages 5706 - 5715, XP055703119
YAN, Y.: "A review on noble-metal-free bifunctional heterogeneous catalysts for overall electrochemical water splitting", JOURNAL OF MATERIALS CHEMISTRY A, 2016, pages 17587 - 17603, XP055703122
ZHANG, X.: "Ni3[Fe (CN) 6]2 nanocubes boost the catalytic activity of Pt to wards electrochemical hydrogen evolution", INORG. CHEM. FRONT., 14 May 2018 (2018-05-14), XP055703124
AHN, W.: "Hollow Multivoid Nanocuboids Derived from Ternary Ni-Co-Fe Prussian Blue Analog for Dual-Electrocatalysis of Oxygen and Hydrogen Evolution Reactions", ADV. FUNCT. MATER., 3 June 2018 (2018-06-03), pages 1 - 11, XP055703126
Attorney, Agent or Firm:
KIM, Tae Sun (KR)
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