Title:
METAL-ORGANIC FRAMEWORK MATERIAL SEPARATION MEMBRANE, PREPARATION METHOD THEREFOR, AND USE THEREOF
Document Type and Number:
WIPO Patent Application WO/2022/077562
Kind Code:
A1
Abstract:
Provided are a metal-organic framework material separation membrane and a method for preparing a metal-organic framework material separation membrane. The metal-organic framework material separation membrane comprises a base membrane and a metal-organic framework material functional layer, and the structure of the metal-organic framework material functional layer comprises an inter-embedded polyhedral structure. The preparation method for the metal-organic framework material separation membrane comprises: (1) preparing a solution containing a first organic solvent, an organic ligand, a metal compound and an auxiliary agent; (2) subjecting a base membrane to a pretreatment, involving introducing, on the surface of the base membrane, metal atoms from the metal compound of step (1); and (3) mixing the pretreated base membrane of step (2) with the solution of step (1) to obtain a first mixture, and then heating the first mixture for a reaction, so as to prepare a metal-organic framework material separation membrane. An organic gas separation membrane prepared from the present invention has the properties of a high separation coefficient, a large flux, adhesion resistance, pollution resistance, etc. during an application process.
Inventors:
WU CHANGJIANG (CN)
WEI XIN (CN)
LI HESHENG (CN)
ZHANG XINMIAO (CN)
SUN JIE (CN)
WANG CHENGHONG (CN)
WANG YUJIE (CN)
MENG FANNING (CN)
WEI XIN (CN)
LI HESHENG (CN)
ZHANG XINMIAO (CN)
SUN JIE (CN)
WANG CHENGHONG (CN)
WANG YUJIE (CN)
MENG FANNING (CN)
Application Number:
PCT/CN2020/124309
Publication Date:
April 21, 2022
Filing Date:
October 28, 2020
Export Citation:
Assignee:
CHINA PETROLEUM & CHEM CORP (CN)
BEIJING RES INST CHEMICAL IND CHINA PETROLEUM & CHEMICAL CORP (CN)
BEIJING RES INST CHEMICAL IND CHINA PETROLEUM & CHEMICAL CORP (CN)
International Classes:
B01D53/00; B01D71/06; B01D53/22; B01D67/00; B01D69/08; B01D71/26; B01D71/30; B01D71/36; B01J20/22; B01J20/30; C07C7/144; C08G83/00
Domestic Patent References:
| WO2015171970A1 | 2015-11-12 |
Foreign References:
| CN106492651A | 2017-03-15 | |||
| CN108939958A | 2018-12-07 | |||
| CN106278368A | 2017-01-04 | |||
| US20180272274A1 | 2018-09-27 | |||
| CN202011101303A | 2020-10-15 | |||
| CN110052185A | 2019-07-26 |
Other References:
SHAN BOHAN, JAMES JOSHUA B., ARMSTRONG MITCHELL R., CLOSE EMILY C., LETHAM PORTIA A., NIKKHAH KASSANDRA, LIN Y. S., MU BIN: "Influences of Deprotonation and Modulation on Nucleation and Growth of UiO-66: Intergrowth and Orientation", THE JOURNAL OF PHYSICAL CHEMISTRY C, AMERICAN CHEMICAL SOCIETY, US, vol. 122, no. 4, 1 February 2018 (2018-02-01), US , pages 2200 - 2206, XP055922194, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.7b11012
WU FEICHAO; LIN LU; LIU HAIOU; WANG HUANTING; QIU JIESHAN; ZHANG XIONGFU: "Synthesis of stable UiO-66 membranes for pervaporation separation of methanol/methyl tert-butyl ether mixtures by secondary growth", JOURNAL OF MEMBRANE SCIENCE, ELSEVIER BV, NL, vol. 544, 15 December 2017 (2017-12-15), NL , pages 342 - 350, XP085230538, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2017.09.047
HE CHUNHONG: "Study on separation of organic vapor/nitrogen system through composite hollow fiber membrane", 2005, TIANJIN UNIVERSITY
WU FEICHAO; LIN LU; LIU HAIOU; WANG HUANTING; QIU JIESHAN; ZHANG XIONGFU: "Synthesis of stable UiO-66 membranes for pervaporation separation of methanol/methyl tert-butyl ether mixtures by secondary growth", JOURNAL OF MEMBRANE SCIENCE, ELSEVIER BV, NL, vol. 544, 15 December 2017 (2017-12-15), NL , pages 342 - 350, XP085230538, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2017.09.047
HE CHUNHONG: "Study on separation of organic vapor/nitrogen system through composite hollow fiber membrane", 2005, TIANJIN UNIVERSITY
Attorney, Agent or Firm:
YUHONG INTELLECTUAL PROPERTY LAW FIRM (CN)
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