BACKGROUND OF THE I VENTION

The subject invention relates to the fabrication of metal oxide patterns on a substrate adapted for use with thin film inductive transducers. The transducers, commonly referred to as thin film magnetic heads, are useful for recording and reading magnetic transitions on a moving magnetic recording medium.

Thin film recording heads are generally manufactured by an etching process wherein an electromagnet is formed on the surface of a substrate. More particularly, a magnetic material is deposited on a suitable substrate and is etched to the desired configuration. Thereafter, conductive layers are deposited on the magnetic material and etched to define the windings of the electromagnet. At least one additional

layer of magnetic material is deposited in a manner such that the rear ends of the magnetic materials are connected while the front ends thereof are separated to define a recording gap. An electric current may be passed through the windings of the conductor for recording.

The gap or pole tip region of the head is intended to fly in close proximity to the magnetic recording medium. In order to maximize the reading and writing ability of the thin film head, it is of critical importance to define the geometry of the pole tip region to within extremely precise tolerances. It has been found that read/write errors can be minimized when the pole tip regions of the electromagnet are formed with straight side walls.

In contrast, the side walls of the remaining portions of the magnetic head, which are spaced from the pole tip region need not be formed with a precise vertical geometry. In fact, when the lower pole of the head is provided with vertical side walls along- its entire length, problems arise relating to the deposition of the conductive layer used to define the windings of the electromagnet. As can be appreciated, . it -is relatively difficult to control the thickness of a layer which is being deposited on a surface having sharp, angular features. Thus, windings deposited on the magnetic material will frequently have u__desirable discontinuities particularly in regions havin sharp corners.

Accordingly, in the prior art, various methods have been developed to reduce the occurance of discontinuities

in the windings. One proposed solution is to bevel the side walls of the magnetic material to obtain a smooth, sloping surface thereby facilitating the deposition of the conductive layer over the magnetic material. However, it is important th only the rear portions of the magnetic material be beveled since the pole tip regions of the head must be provided with vertical side walls in order to minimize read/write errors.

Therefore, in the prior art, a method was developed wherein the degree of beveling of the side walls could be con- trolled such that the pole tip regions were provided with vert cal side walls, while the rear portions of the side walls were sloped to facilitate the deposition of the conductive windings The later method is disclosed in U.S. Patent Application Seria No. 311,968 filed October 16, 1981, assigned to the assignee as the subject invention. The_ latter method includes a new and improved multiple masking technique to achieve the unique and desired configuration of the magnetic material.

Various other solutions have been proposed to solve the problem of discontinuities in the conductive layer. One such solution, called "planarization", includes filling in the areas, adjacent the magnetic material, with a non-magnetic, non-metallic compound in a manner such that the top surface of the resulting structure is defined by a smooth plane. In this solution, the magnetic material is formed with vertical side walls throughout its construction. Further, since the upper surface of the magnetic material is co-planar with the non¬ magnetic filler material, additional layers may be accurately

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-it- deposited on the planar surface of the structure whereby discontinuities may be substantially diminished.

Unfortunately, in the prior art, no suitable method has been devised to produce the proposed planarized structure. The most obvious method would include a mechanical lapping operation. More particularly, in the latter method, the metall material is initially deposited on a substrate. Thereafter, a layer of non-metallic, non-magnetic filler material is deposite over the magnetic material. Using a mechanical grinder or lapping apparatus, the surface of the layers could be abraded until the desired planar configuration is achieved. However, due to the fragile nature and small size of thin film magnetic

. ^* . recording heads, ^" this method is impractical because it is both cumbersome and expensive. ~ Another proposed planarization method includes a thermal oxidation step, for equalizing the depth of the layers. Thermal -oxidation is a diffusion process which typically takes place at elevated temperatures in the range of 950 to 1200 degrees centigrade. This method is not adaptable t 0 present manufacuring requirements since the materials utilized ^• in forming the thin film magnetic -heads suffer se #v•ere degreda- tion, including recrystalization and strain, when subjected to temperatures over 400 degrees centigrade. Another possible method includes the use of liquified glasses, which can be 5 flowably formed on the substrate. However, as with thermal oxidation, most usable glasses melt at temperatures greater tha 400 degrees centigrade. The glasses which are found to melt at lower temperatures are not compatible with thin film processing

-5- because their thermal expansion and softening points are not satisfactory. Accordingly, it would be desirable to provide a new and improved method for planarizing the surface of the magnetic material of a thin film recording head such that succ sive layers may be readily deposited without discontinuities.

SUMMARY OF THE INVENTION Accordingly, it is an object of the subject inventio to provide a new and improved method for planarizing the upper surface of a structure which includes a magnetic material forming a portion of a thin film magnetic recording head. It is another object of the subject invention to provide a new and improved method for fabricating a thin film magnetic recording head wherein the pole tips thereof can be accurately manufactured with substantially vertical side walls to exact tolerances.

It is a further object of the subject invention to provide a new and improved method, for fabricating thin fil magnetic recording heads, which facilitates the depositing of - additional layers and diminishes the likelihood of the occurance of discontinuities.

In accordance with these and many other objects the subject invention relates to a method of fabricat _* ring the metallic magnetic pattern on a substrate for use with thin film recording heads. The metallic pattern and non-magnetic, non-conductive filler material are formed on the substrate in complimentary patterns such that the top surfaces of both materials are co-planar. By this arrangement, the deposition of additional layers is facilitated.

In accordance with the subject method, a layer of a non-conductive, non-magnetic material, formed fro ^a compound such as silicon dioxide, is applied to the substrate. A relatively thinner second layer is deposited over the non- e magnetic layer. The second layer is formed from a metal such as aluminum or chromium which is insoluable in a silicon dioxide etchant. A photoresist layer is placed on the top of the metal layer in a negative pattern with respect to the desired metallic magnetic pattern. By this arrangement, 0 a metal etchant can be used to remove the aluminum or other metal layer in a pattern corresponding to the metallic pattern.

In accordance with the subject invention, utilizing the etched aluminum layer.as a mask, the silicon dioxide layer 5 is plasma etched to define a cavity having a configuration corresponding to the desired metallic pattern. Due to the hig speed and directional nature of plasma etching, a cavity having relatively vertical side walls is produced. After the plasma etching step, any remaining portions of the aluminum 0 ^' -layer are removed. If l ₂ 0 ₃ is used Cr is the desired masking material and the 1 ₂ 0 ₃ can be etched in a mixture of HN0 ₃ , HF and H ₂ 0. The Al ₂ 0 ₃ can be deposited with . RF sputtering or reactive oxide sputtering and the deposition parameters are choosen to enhance the etch rate and form nearl 5 vertical side walls.

Using electron beam evaporation, another layer of aluminum or other suitable metal is deposited over the structure after the first aluminum layer has been stripped. A

discussed above, a layer, deposited over a structure having a sharp, angular configuration, tends to be uneven. Thus, the thickness of the newly deposited aluminum layer, along the sid walls of the cavity, is less than the thickness of the layer 5 along the horizontal portions of the structure. In the prior art, the resulting non-uniformity was considered a serious shortcoming since it often produced ^" discontinuities in the conductive windings. By contrast, in the subject invention, this non-uniform effect is utilized advantageously. More 0 particularly, the deposited aluminum layer is soft anodized to a depth sufficient to affect all of the aluminum formed on the side walls of the cavity. To obtain this result, the base of the cavity is electrically connected in a circuit and the anodizing step is continued until the aluminum on the side wall 5 is converted and the circuit is broken. The soft anodized portions of the aluminum are then removed by an etchant which does not attack either the unchanged aluminum or the dielectric By this arrangement, the aluminum formed on the bottom of the cavity is isolated from the aluminum. emaining on the surface o _Q " the dialectric. ' ^■

In the next step of the subject method, the aluminum located on top of the Si0 ₂ layer is hard anodized. This is accomplished electrochemically by linking the aluminum on the top portions in a circuit. Since the aluminum in the bottom of -5 the cavity is electrically isolated from the aluminum on the to surface of the SiO„, only latter will be hard anodized. Using the hard anodized aluminum as a mask, the remaining aluminum in the cavity can be etched using a phosphoric acid based solution

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Thereafter, using well known sputtering techniques, a layer of the magnetic metallic material is applied to the structure. Preferably, a Ni-Fe permalloy material is used. T permalloy is applied such that the cavity is filled while a 5 relatively thin layer is formed adjacent the upper edges of th cavity. The upper surface of the permalloy is then removed to depth sufficient to expose the aluminum layer adjacent the top edges of the cavity. The removal of the permalloy can be accomplished through well known sputter etching techniques.

10 After the aluminum has been exposed, the structure can be emersed in a bath of sodium hydroxide which functions to dissolve the aluminum. The removal of the intermediate aluminum layer functions to strip the excess permalloy from th structure resulting in a configuration wherein the cavity is

15 filled, while the top surface of the permalloy is co-planar with the Si0 ₂ layer. Accordingly, subsequent layers, includin the conductive windings may be readily applied to the planariz structure. Further, the permalloy is formed with vertical, or nearly vertical straight side walls for maximizing read/write

20. operations.

Further objects in advantage of the subject inventio will become apparent from the following detailed description

_* taken in conjunction with the -drawings in which;

BRIEF DESCRIPTION OF THE DRAWINGS 5 Figure 1 is side elevational view illustrating a substrate having layers formed thereon in accordance with the initial steps of the subject method.

Figures 2-10 are side elevational views, similar to Figure 1, illustrating subsequent steps of the new and improved method of the subject invention.

Figure 11 is a partial perspective view, of the stru ture including the bottom pole of a thin film recording head, made in accordance with the method of the subject invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

The subject invention relates to a method for fabri cating a metallic magnetic pattern on a substrate. The magne metallic pattern, formed from Ni-Fe permalloy material, defin the bottom pole of a thin film transducer. Figures 1-10 illustrate the steps of the subject method.

Thin film magnetic heads are formed on a non-magnet substrate 20. Typically, a plurality of magnetic recording heads will be placed in a spaced array, along the length of th substrate 20. In accordance with the subject invention, a fir layer of filler material 22 is applied to the substrate to a depth somewhat thicker than the desired thickness of the event " permalloy pattern, which generally ranges from approximately 3 microns. The filler material 22 is formed from a non-conducti non-metallic compound such as silicon dioxide. Other possible compounds include Si _{3 4} and Al ₂ 0 ₃ .

After the formation of the first layer 22, a relativ thinner, second, metal layer 24 is applied. The particular met of the second layer 24 is selected to have good ^* adhesion to th first layer material and to be insoluable in an etchant which

will attack the first material. Preferably, the metal 24 of t second layer is aluminum if Si0 ₂ is the first layer and Cr if 1 ₂ 0 ₃ is the first layer and has a thickness on the order of approximately .1 to 1 microns. The deposition of the two continuous layers 22, 24, upon the substrate 20, produces a structure as illustrated in Figure 1.

In the next step of the subject method, a layer (not shown) of photoresist material is applied to the upper surface of the metal layer 24. The photoresist must be etched to define ^' a negative pattern, complimentary to the desired patter of the permalloy. Typically, this is accomplished using a mas ing technique wherein the photoresist is selectively exposed t curing radiation. The non-cured portion may then be removed t define the negative pattern. A suitable etchant for metal is applied to the surface of the structure for removing the porti of the second aluminum layer 24 not masked by the remaining photoresist to achieve the configuration illustrated in Figure In accordance with the subject method, the layer 22 i then etched to define a cavity 30, having relatively vertical side walls 32 as illustrated in Figure 3. As described more fully below, side walls 32 of cavity 30 serve to define the desired side walls of the permalloy material. In order to produce the substantially vertical side walls 32, the silicon dioxide layer 22 is plasma etched, using the upper aluminum layer 24 as a mask. Plasma etching is a relatively high speed, directional operation which can provide the accuracy necessary for this removal step. Once the desired cavity 30 is formed.

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-li¬ the remaining layer 24 is removed to achieve the structure illustrated . in Figure 4. The photoresist layer may be remove ι' either prior to, or after the plasma etching step. When laye 24 is aluminum, it can be most readily removed by chemical etching.

In the next step of the subject method, another metal layer 36 is formed on the structure by, for example, electron beam evaporation. The metal is preferably aluminum. As illustrated in Figure 5, due to the sharp angular configur tion of the upper surface of the structure, layer 36 is not applied uniformly. More particularly, the thickness of the metal layer 36 is greater on the horizontal surfaces than alon the vertical side walls 32 of the cavity 30. As discussed above, in the prior art, a non-uniform layer, which is commonl formed over angular structures, was considered a shortcoming, since it often resulted in undesirable discontinuities in the layer. However, as will be discussed below, this effect is us advantageously in the subject invention. Preferably, the thickness of the metal layer 36, along the horizontal surfaces of the structure, is about twice as great as the thickness alo the side walls 32 thereof.

The aluminum layer 36 is then subjected to a soft anodizing step to form a thin porous alumina (aluminum oxide) film 38 on its surface. The method and apparatus used for anodizing are well known in the art and need not be described detail. Briefly, the structure is submersed in a electroly¬ tic anodizing solution and a potential is supplied between the aluminum layer and the solution. The anodizing step is contin

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to a depth sufficient to convert all of the aluminum on the sid walls 32 of the cavity to aluminum oxide. This result may be readily achieved because the electrical current will continue t flow through the conductive aluminum until the metal on the sid walls has been converted to non-conductive, aluminum oxide. Th length of time this step takes is a function of the thickness o the layer as well as the strength of the current supplied. The structure produced after this step is illustrated in Figure 6.

After the soft anodizing step, the aluminum oxide film 38 is dissolved. A suitable etchant is chosen which does not attack either the remaining aluminum layer 36 or the Si0 ₂ layer 22. The result of this dissolving step is to isolate the aluminum 36A in the base of the cavity 30 from the aluminum 36B remaining on the upper surface of the silicon dioxide layer 22 as illustrated in Figure 7. The upper surface of the aluminum portions 36B, on the top surface ςf the silicon dioxide layer 22, may then be hard anodized. Hard anodizing forms a non-porous or barrier alumina layer, as compared with the porous layer formed in the soft anodizing step. The hard anodizing step is carried out electrochemically wherein a bus is connected only to the aluminum portions 36B, located on the top surface of the silicon dioxide layer 22. Since the aluminum 36A disposed at the base of the cavity 30 is electric¬ ally isolated from the remaining aluminum 36B, only the latter portions will be anodized into alumina 40, as illustrated in Figure 8.

Using a suitable metal etchant, such as a phosphori acid based etchant, the aluminum 36A, remaining in the cavity 30 is removed, as illustrated in Figure 9. The hard anodized aluminua layer 40 masks the aluminum 36B underneath. The etchant is chosen such that it will not attack the silicon dioxide layer 22.

Cavity 30 may then be filled with the desired magne metallic material. Preferably, the magnetic material is form from a nickel-iron or permalloy compound. The permalloy layer 42 can be formed utilizing well known sputtering techniques. illustrated in Figure 10, the cavity 30 is filled while a relatively thin ^" layer is defined adjacent the top edges 44 of the cavity. As can be appreciated, since the cavity 30 is defined with accurate, vertical side walls, the permalloy in t cavity will be formed with similar, complimentary vertical sidewalls.

In accordance with the method of the subject inventi the permalloy layer 42 is then removed in a manner to expose t aluminum layer 36B adjacent the top edges 44 of the cavity 30. Preferably, the removal of the permalloy is accomplished by a back sputtering or sputter etching technique. Thereafter, aluminum layer 36B may be dissolved to release the excess permalloy 42. In the latter step, the structure is emersed in sodium hydroxide solution, which is capable of dissolving both aluminum and aluminum oxide. As can be appreciated, since the aluminum layers support the excess portions of the permalloy extending beyond the cavity, these portions of the permalloy a washed away in the solution. The sodium hydroxide solution

will dissolve either aluminum or the aluminum oxide such that the aluminum oxide layer 40 may be removed during this step. I the alternative, the aluminum oxide layer 40 can be removed prior to the addition of the permalloy layer 42. The removal of the aluminum layer, as well as the excess permalloy, functions to define a planarized structure as illustrated in Figure 11. The planarized structure is uniquely suited for the production of thin film magnetic heads. More particularly, since the side walls 32 of the permalloy material 42 are provided with accurate vertical side walls, the reading and writing ability of a recording head produced therefrom is maximized. In addition, the upper surface of the permalloy 42 is co-planar with the upper surface of the silicon dioxide laye 22. By this arrangement, additional layers may be uniformly deposited on the upper planar surface of the structure such tha discontinuities, prevalent in the prior art, are substantially reduced.

In summary, there is provided a new and improved method for producing metallic magnetic patterns on.a substrate " for use with thin film magnetic recording heads. In the subjec method, a permalloy pattern 42 is formed on the substrate. 'A non-magnetic, non-metallic material 22 is filled in around the side edges of the permalloy such that the top surface of the structure defines a plane. By this arrangement, addi- tional layers may be readily deposited on the structure, while permalloy pattern is defined which satisfies the strict geometr tolerance requirements necessary for accurate read/write operations.

While the subject invention has been described with reference to a preferred embodiment, it is to be underst that various other changes and modifications can be made ther by one skilled in the art, without varying from the scope and spirit of the subject invention as defined by the appended claims.