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Title:
METHINE DYE AND DYE-SENSITIZED PHOTOELECTRIC CONVERSION ELEMENT
Document Type and Number:
WIPO Patent Application WO/2015/037676
Kind Code:
A1
Abstract:
 The present invention pertains to the development of a dye having a specific structure, a photoelectric conversion element having high optical durability and being sensitized using the dye, and a solar cell comprising the photoelectric conversion element and being capable of maintaining high conversion efficiency. A methine dye represented by formula (1) (in formula (1), m represents an integer 1 to 5, l and n represent an integer 0 to 6, and j represents an integer 0 to 3. X1 and Y1 each independently represent a carboxyl group, a cyano group, or the like. Z1 and Z2 each independently represent an oxygen atom, a sulfur atom, or the like. A1, A2, A3, A5, and A6 each independently represent a hydrogen atom, an aromatic residue, an aliphatic hydrocarbon residue, a cyano group, or the like. A4 represents a hydrogen atom, an aliphatic hydrocarbon residue, a cyano group, or the like. A7 and A 8 each independently represent a hydrogen atom, an aliphatic hydrocarbon residue, a cyano group, or the like. R1 and R2 each independently represent a specific aromatic residue, a heterocyclic residue, or the like.)

Inventors:
KANEKO MASAYOSHI (JP)
SHIGAKI KOICHIRO (JP)
Application Number:
PCT/JP2014/074133
Publication Date:
March 19, 2015
Filing Date:
September 11, 2014
Export Citation:
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Assignee:
NIPPON KAYAKU KK (JP)
International Classes:
C09B23/00; H01G9/20
Domestic Patent References:
WO2010147427A22010-12-23
Foreign References:
CN102675898A2012-09-19
KR20100125717A2010-12-01
JP2013041747A2013-02-28
JP2003282165A2003-10-03
Other References:
ZHANG, W. ET AL.: "Synthesis and photovoltaic properties of functional dendritic oligothiophenes", JOURNAL OF POLYMER SCIENCE , PART A: POLYMER CHEMISTRY, vol. 49, no. 8, 2011, pages 1865 - 1873
FISCHER, M. K. R. ET AL.: "D-n-A Sensitizers for Dye-Sensitized Solar Cells", LINEAR VS BRANCHED OLIGOTHIOPHENES, CHEMISTRY OF MATERIALS, vol. 22, no. 5, 2010, pages 1836 - 1845
THOMAS, K. R. J. ET AL.: "2,3-Disubstituted Thiophene-Based Organic Dyes for Solar Cells", CHEMISTRY OF MATERIALS, vol. 20, no. 5, 2008, pages 1830 - 1840
LIN, R. Y.-Y. ET AL.: "Y-shaped metal-free D-n- (A)2 sensitizers for high-performance dye- sensitized solar cells, Journal of Materials Chemistry A", MATERIALS FOR ENERGY AND SUSTAINABILITY, vol. 2, no. 9, 2014, pages 3092 - 3101
Attorney, Agent or Firm:
ASAMURA PATENT OFFICE, p. c. (JP)
Patent business corporation Asamura patent firm (JP)
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