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Title:
A METHOD AND AN APPARATUS FOR SEPARATING CHLORINE GAS FROM A GASEOUS ANODE OUTLET STREAM OF AN ELECTROCHEMICAL REACTOR
Document Type and Number:
WIPO Patent Application WO/2019/105955
Kind Code:
A3
Abstract:
The invention relates to a method for separating chlorine from a gaseous anode out- let stream mass flow of an electrochemical cell reactor. In a first aspect, the method makes use of an absorption step, wherein an anode outlet stream mass flow of the electrochemical cell reactor is exposed to an organic solvent being essentially immiscible with water for achieving an exergy-efficient separation of chlorine and hydrogen chloride. In a further aspect, the method makes use of absorption step, wherein the anode outlet stream mass flow is exposed to an ionic liquid, wherein the hydrogen chloride is dissolved in said ionic liquid, thereby forming a gas flow containing essentially chlorine and a solution mass flow comprising the ionic liquid and the hydrogen chloride. The hydrogen chloride is desorbed from the solution mass flow in a desorption step. In another aspect, the method makes use of a distillation step, wherein the anode outlet stream mass flow is separated at a static pressure of at least 2 bar for an exergy-efficient separation.

Inventors:
BECHTEL SIMON (DE)
VIDAKOVIC-KOCH TANJA (DE)
SUNDMACHER KAI (DE)
Application Number:
PCT/EP2018/082752
Publication Date:
July 11, 2019
Filing Date:
November 28, 2018
Export Citation:
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Assignee:
MAX PLANCK GESELLSCHAFT (DE)
International Classes:
B01D53/14; B01D53/00; C01B7/07; C25B1/26; C25B15/08
Foreign References:
EP0767138A11997-04-09
CA2579364A12008-08-20
US2398891A1946-04-23
US6063162A2000-05-16
EP2599770A12013-06-05
JP3193627B22001-07-30
DE102006023581A12007-11-22
US5580437A1996-12-03
Attorney, Agent or Firm:
GRAMM, LINS & PARTNER PATENT- UND RECHTSANWÄLTE PARTGMBB (DE)
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