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Title:
METHOD FOR HOMOPOLYMERIZATION AND RANDOM COPOLYMERIZATION OF PROPYLENE
Document Type and Number:
WIPO Patent Application WO/2019/090882
Kind Code:
A1
Abstract:
Disclosed is a method for the homopolymerization and the random copolymerization of propylene, comprising: (1) subjecting a liquid phase propylene comprising a polymerization catalyst to a prepolymerization of propylene, to obtain a feedstock slurry liquid containing a propylene prepolymer, wherein the polymerization temperature is 40ºC-50ºC, the prepolymerization pressure is 3.2-3.9 MpaG, and the olefin polymerization catalyst is 0.04-0.06% wt% of the liquid phase propylene; (2) mixing the feedstock slurry liquid, recovered liquid phase propylene and recovered and recycled hydrogen gas into a liquid phase polymeric raw material; (3) subjecting the liquid phase polymeric raw material to a liquid phase homopolymerization of propylene, or a liquid phase copolymerization with ethylene, continuously introducing the resulting slurry liquid into a gas phase polymerization reactor for a gas phase homopolymerization of propylene or a gas phase copolymerization of propylene with ethylene, to obtain a propylene homopolymer or a random copolymer.

Inventors:
LI ZEMIN (CN)
LIU LIXIN (CN)
CHEN HONG (CN)
LIU LIYAN (CN)
WU XIA (CN)
ZHANG YI (CN)
Application Number:
PCT/CN2017/115397
Publication Date:
May 16, 2019
Filing Date:
December 11, 2017
Export Citation:
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Assignee:
BEIJING HUAFU ENG CO LTD (CN)
International Classes:
C08F2/00; C08F10/06; C08F110/06; C08F210/06
Foreign References:
CN102272166A2011-12-07
CN103788258A2014-05-14
CN103772571A2014-05-07
Attorney, Agent or Firm:
RUNPING & PARTNERS (CN)
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