Title:
METHOD FOR MANUFACTURING SUBSTITUTED ETHYNYL GOLD-NITROGEN CONTAINING HETEROCYCLIC CARBENE COMPLEX
Document Type and Number:
WIPO Patent Application WO/2010/008065
Kind Code:
A1
Abstract:
Disclosed is a method for manufacturing substituted ethynyl gold-nitrogen containing heterocyclic carbene complexes represented by general formula (3) that is characterized in that substituted ethylene represented by general formula (1) and a halogenated gold (I)-nitrogen containing heterocyclic carbene complex represented by general formula (2) are reacted in the presence of a base. A substituted ethynyl gold-nitrogen containing heterocyclic carbene complex can be obtained easily without requiring multiple steps.
Inventors:
FUJIMURA OSAMU
HONMA TAKASHI
HONMA TAKASHI
Application Number:
PCT/JP2009/062951
Publication Date:
January 21, 2010
Filing Date:
July 17, 2009
Export Citation:
Assignee:
UBE INDUSTRIES (JP)
FUJIMURA OSAMU
HONMA TAKASHI
FUJIMURA OSAMU
HONMA TAKASHI
International Classes:
C07F1/12
Domestic Patent References:
| WO2008050733A1 | 2008-05-02 |
Other References:
WANG, H.M. ET AL.: "Synthesis, Structure, and Spectroscopic Properties of Gold(I)-Carbene Complexes", ORGANOMETALLICS, vol. 18, no. 7, 1999, pages 1216 - 1223
SINGH, S. ET AL.: "A facile one-step synthesis of a lipophilic gold(I) carbene complex - X-ray crystal structures of LAuCl and LAuC=CH (L = 1,3-di-tert-butylimidazol-2-ylidene)", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no. 15, 2005, pages 3057 - 3062
SINGH, S. ET AL.: "A facile one-step synthesis of a lipophilic gold(I) carbene complex - X-ray crystal structures of LAuCl and LAuC=CH (L = 1,3-di-tert-butylimidazol-2-ylidene)", EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no. 15, 2005, pages 3057 - 3062
Attorney, Agent or Firm:
TSUKUNI, HAJIME (JP)
Hajime Tsukuni (JP)
Hajime Tsukuni (JP)
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