Title:
METHOD FOR MANUFACTURING SULFUR-CONTAINING ORGANIC SILICON COMPOUND
Document Type and Number:
WIPO Patent Application WO/2018/101416
Kind Code:
A1
Abstract:
In the present invention, a sulfur-containing organic silicon compound is obtained by efficient hydrosilylation of an alkene having a sulfur functional group such as represented by formula (B-1) or formula (B-2) in the presence of an iridium complex. (In formulas (B-1) and (B-2), R4 represents a C1-20 alkyl group, a C3-20 cycloalkyl group, a C6-20 aryl group, a C1-20 acyl group, or a C1-20 acyloxy group, m represents an integer of 1-5, and n represents an integer of 1-20.)
Inventors:
NAKAJIMA YUMIKO (JP)
VENU SRINIVAS (JP)
SHIMADA SHIGERU (JP)
SATO KAZUHIKO (JP)
VENU SRINIVAS (JP)
SHIMADA SHIGERU (JP)
SATO KAZUHIKO (JP)
Application Number:
PCT/JP2017/043100
Publication Date:
June 07, 2018
Filing Date:
November 30, 2017
Export Citation:
Assignee:
AIST (JP)
International Classes:
C07F7/08; B01J31/22; C07F15/00; C07B61/00
Domestic Patent References:
| WO2015136913A1 | 2015-09-17 |
Foreign References:
| JPH0959290A | 1997-03-04 | |||
| JP2009215197A | 2009-09-24 |
Other References:
ORO, L. A. ET AL.: "Hydrosilylation of alkenes by iridium complexes", JOURNAL OF MOLECULAR CATALYSIS, vol. 37, no. 2-3, 1 October 1986 (1986-10-01), pages 151 - 156, XP055491663, Retrieved from the Internet
LEE, K. ET AL.: "NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes", ORGANOMETALLICS, vol. 31, no. 22, 26 November 2012 (2012-11-26), pages 7823 - 7826, XP055491667, Retrieved from the Internet
SRINIVAS, V. ET AL.: "IJSalicylaldiminato)NiIJII)-catalysts forhydrosilylation of olefins", CATALYSIS SCIENCE & TECHNOLOGY, vol. 5, no. 4, 10 March 2015 (2015-03-10), pages 2081 - 2084, XP055491671, Retrieved from the Internet
LEE, K. ET AL.: "NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes", ORGANOMETALLICS, vol. 31, no. 22, 26 November 2012 (2012-11-26), pages 7823 - 7826, XP055491667, Retrieved from the Internet
SRINIVAS, V. ET AL.: "IJSalicylaldiminato)NiIJII)-catalysts forhydrosilylation of olefins", CATALYSIS SCIENCE & TECHNOLOGY, vol. 5, no. 4, 10 March 2015 (2015-03-10), pages 2081 - 2084, XP055491671, Retrieved from the Internet
Attorney, Agent or Firm:
HIRAKAWA, Akira et al. (JP)
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