Title:
METHOD FOR THE OXIDATION OF UNSATURATED HYDROCARBONS
Document Type and Number:
WIPO Patent Application WO2003059856
Kind Code:
A3
Abstract:
The invention relates to a method for the oxidation of unsaturated hydrocarbons, whereby an unsaturated hydrocarbon, an oxygen-comprising oxidation agent, a catalytic palladium complex, comprising a ligand of formula (I) where R = a saturated halogenated alkyl group with 1 to 20 C atoms and optional adjuncts are brought together in a liquid phase based on (a1) 10 to 100 wt. % of a protic polar solvent and (a2) 0 to 90 wt. % of an aprotic polar solvent, whereby the sum of the components (a1) and (a2) is 100 wt. %, at a temperature in a range from 30 to 300 DEG C and a pressure in a range from 1 to 200 bar, such as to give a liquid phase containing hydrocarbons comprising oxygen.
Inventors:
BUB GUENTHER (DE)
FORNIKA ROLAND (DE)
FISCHER BERTHOLD (DE)
GUSCHIN DIMITRII (DE)
MEYER TORSTEN (DE)
SHELDRICK WILLIAM (DE)
FORNIKA ROLAND (DE)
FISCHER BERTHOLD (DE)
GUSCHIN DIMITRII (DE)
MEYER TORSTEN (DE)
SHELDRICK WILLIAM (DE)
Application Number:
PCT/EP2003/000407
Publication Date:
December 18, 2003
Filing Date:
January 16, 2003
Export Citation:
Assignee:
STOCKHAUSEN CHEM FAB GMBH (DE)
BUB GUENTHER (DE)
FORNIKA ROLAND (DE)
FISCHER BERTHOLD (DE)
GUSCHIN DIMITRII (DE)
MEYER TORSTEN (DE)
SHELDRICK WILLIAM (DE)
BUB GUENTHER (DE)
FORNIKA ROLAND (DE)
FISCHER BERTHOLD (DE)
GUSCHIN DIMITRII (DE)
MEYER TORSTEN (DE)
SHELDRICK WILLIAM (DE)
International Classes:
B01J31/22; C07B61/00; C07C27/12; C07C27/16; C07C45/28; C07C45/34; C07C45/35; C07C49/08; C07C51/25; C07C51/275; C07C51/285; C07C57/045; C08F4/26; C08F120/00; (IPC1-7): C07C51/25; C07C45/35; C07C49/08; C07C57/04
Foreign References:
| US4738943A | 1988-04-19 | |||
| US4720474A | 1988-01-19 | |||
| US4310704A | 1982-01-12 | |||
| EP0145467A2 | 1985-06-19 |
Other References:
J. E. MCMURRY: "A method for the allylic oxidation of olefins", TETRAHEDRON LETTERS, vol. 25, no. 38, 1984, OXFORD GB, pages 4187 - 4190, XP002245213
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