Title:
METHOD FOR PRODUCING 100% PLANT-DERIVED SYNTHETIC PRODUCT FROM FURFURAL AND SYNTHETIC PRODUCT OF THE SAME
Document Type and Number:
WIPO Patent Application WO/2011/059013
Kind Code:
A1
Abstract:
Provided is technology for the efficient production of a plant-derived fumaric acid and/or a fumaric acid derivative using as the starting material furfural obtained from renewable plant-based resources that have grown as a result of absorbing the CO2 in the air. Also provided is technology for performing chemical synthesis in order to readily produce a synthetic product of (i) a 100% plant-derived succinic acid and/or a succinic acid derivative and (ii) a 100% plant-derived 1,4-butanediol for instance. A method for producing a plant-derived fumaric acid and/or a fumaric acid derivative by oxidation of a plant-derived furfural further comprises a product recovery process which includes: a step for removing the solid product from an oxidation reaction solution after oxidation; a step for subjecting the oxidation reaction solution from which the solid product has been removed to heating within a temperature range of 70ºC to less than the reaction solvent reflux temperature while at least a portion of the oxidation reaction solution is removed; and a step for cooling the oxidation reaction solution from which at least a portion thereof has been removed, and filtering and recovering the product.
Inventors:
MASUDA TAKASHI (JP)
KUNIOKA MASAO (JP)
FUNABASHI MASAHIRO (JP)
TACHIBANA YUYA (JP)
KUNIOKA MASAO (JP)
FUNABASHI MASAHIRO (JP)
TACHIBANA YUYA (JP)
Application Number:
PCT/JP2010/070057
Publication Date:
May 19, 2011
Filing Date:
November 10, 2010
Export Citation:
Assignee:
NAT INST OF ADVANCED IND SCIEN (JP)
MASUDA TAKASHI (JP)
KUNIOKA MASAO (JP)
FUNABASHI MASAHIRO (JP)
TACHIBANA YUYA (JP)
MASUDA TAKASHI (JP)
KUNIOKA MASAO (JP)
FUNABASHI MASAHIRO (JP)
TACHIBANA YUYA (JP)
International Classes:
C07C51/48; C07C29/149; C07C31/20; C07C51/31; C07C51/36; C07C55/10; C07C57/145; C07C57/15; C07C67/08; C07C67/303; C07C69/40; C07C69/60; C07D307/60; C07B61/00
Foreign References:
| JPH11240846A | 1999-09-07 |
Other References:
POSKONIN, V. V.: "Catalytic oxidation reactions of furan and hydrofuran compounds 9.* characteristics and synthetic possibilities of the reaction of furan with aqueous hydrogen peroxide in the presence of compounds of niobium (ii) and (v)", CHEMISTRY OF HETEROCYCLIC COMPOUNDS, vol. 45, no. 10, October 2009 (2009-10-01), pages 1177 - 1183
POSKONIN, V. V. ET AL.: "Catalytic oxidation of furan and hydrofuran compounds. 2. Oxidation of furfural in the hydrogen peroxide-vanadyl sulfate-sodium acetate system", CHEMISTRY OF HETEROCYCLIC COMPOUNDS, vol. 34, no. 6, 1998, pages 646 - 650
POSKONIN, V. V. ET AL.: "Catalytic oxidation of furan and hydrofuran compounds. 2. Oxidation of furfural in the hydrogen peroxide-vanadyl sulfate-sodium acetate system", CHEMISTRY OF HETEROCYCLIC COMPOUNDS, vol. 34, no. 6, 1998, pages 646 - 650
Attorney, Agent or Firm:
EBATA Toshio (JP)
Toshio Ebata (JP)
Toshio Ebata (JP)
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