Title:
METHOD FOR PRODUCING 1,6-HEXANEDIOL BY HYDROGENATION OF OLIGO- AND POLYESTERS
Document Type and Number:
WIPO Patent Application WO/2010/115759
Kind Code:
A3
Abstract:
The invention relates to a method for the hydrogenation of oligo- and/or polyesters which can be obtained by the esterification of a dicarboxylic acid solution with a diol or diol mixture, the hydrogenation being carried out in the presence of a catalyst, the precursor of said catalyst containing copper oxide, aluminum oxide and at least one oxide of lanthanum, iron, tungsten, molybdenum, titanium or zirconium. The invention also relates to a method for producing 1,6-hexanediol by the catalytic hydrogenation of ester mixtures which contain oligo- and polyesters of the adipic acid and 6-hydroxycaproic acid as the main components and which can be obtained by the esterification of a dicarboxylic acid solution with diols and especially 1,6-hexanediol or diol mixtures.
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Inventors:
ABILLARD OLIVIER (DE)
PINKOS ROLF (DE)
TEBBEN GERD-DIETER (DE)
SIRCH TILMAN (DE)
URBANCZYK DANIEL (DE)
URTEL HEIKO (DE)
TOMPERS ROLF (DE)
PINKOS ROLF (DE)
TEBBEN GERD-DIETER (DE)
SIRCH TILMAN (DE)
URBANCZYK DANIEL (DE)
URTEL HEIKO (DE)
TOMPERS ROLF (DE)
Application Number:
PCT/EP2010/054114
Publication Date:
January 13, 2011
Filing Date:
March 29, 2010
Export Citation:
Assignee:
BASF SE (DE)
ABILLARD OLIVIER (DE)
PINKOS ROLF (DE)
TEBBEN GERD-DIETER (DE)
SIRCH TILMAN (DE)
URBANCZYK DANIEL (DE)
URTEL HEIKO (DE)
TOMPERS ROLF (DE)
ABILLARD OLIVIER (DE)
PINKOS ROLF (DE)
TEBBEN GERD-DIETER (DE)
SIRCH TILMAN (DE)
URBANCZYK DANIEL (DE)
URTEL HEIKO (DE)
TOMPERS ROLF (DE)
International Classes:
C07C29/149; B01J23/76; C07C31/20; C08J11/16
Domestic Patent References:
WO2004085356A1 | 2004-10-07 |
Foreign References:
EP0922688A1 | 1999-06-16 | |||
EP0721928A2 | 1996-07-17 | |||
US3524892A | 1970-08-18 | |||
US3933930A | 1976-01-20 | |||
DE1255650B | 1967-12-07 |
Attorney, Agent or Firm:
BASF SE (67056 Ludwigshafen, DE)
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