Title:
METHOD FOR PRODUCING CYCLIC CONJUGATED POLYMER AND CATALYST FOR CYCLIC CONJUGATED POLYMER
Document Type and Number:
WIPO Patent Application WO/2012/165194
Kind Code:
A1
Abstract:
[Problem] To provide a method for producing a cyclic conjugated polymer, at the same yield as and having equivalent or superior stereoregularity and molecular weight distribution to conventional methods for producing cyclic conjugated polymers such as poly(3-substituted thiophenes), using inexpensive materials and production steps that are simple in that they do not require restricting the reaction temperature to the low-temperature region, and the like. [Solution] A method for producing a cyclic conjugated polymer whereby a monohalogenated cyclic conjugated compound having five-member to seven-member rings is deprotonated using a deprotonation catalyst formed from a secondary amine represented by Ｒ1ＮＨＲ2 (where R1 and R2 are the same or different branched or cyclic C1-15 alkyl group or phenyl group) and a Grignard reagent represented by Ｒ3ＭｇＸ(where X is a halogen atom selected from chlorine, bromine and iodine and R3 is a linear or branched C1-6 alkyl group), and the deprotonated monohalogenated cyclic conjugated compound is polymerized.
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Inventors:
OKAMOTO SYUJI (JP)
MEGURO HIKARU (JP)
MORI ATSUNORI (JP)
MEGURO HIKARU (JP)
MORI ATSUNORI (JP)
Application Number:
PCT/JP2012/062931
Publication Date:
December 06, 2012
Filing Date:
May 21, 2012
Export Citation:
Assignee:
SOKEN KAGAKU KK (JP)
NAT UNIV CORP UNIV KOBE (JP)
OKAMOTO SYUJI (JP)
MEGURO HIKARU (JP)
MORI ATSUNORI (JP)
NAT UNIV CORP UNIV KOBE (JP)
OKAMOTO SYUJI (JP)
MEGURO HIKARU (JP)
MORI ATSUNORI (JP)
International Classes:
C08G61/10; C08G61/12
Domestic Patent References:
| WO2012014844A1 | 2012-02-02 |
Other References:
TANAKA S ET AL.: "Generation of metalated thiophenes with Grignard reagent and catalytic secondary amine for the cross coupling reaction with aryl halides", TETRAHEDRON LETTERS, vol. 53, no. 9, 29 February 2012 (2012-02-29), pages 1173 - 1176
KRASOVSKIY,A. ET AL.: "Mixed Mg/Li amides of the type R2NMgCl-LiCl as highly efficient bases for the regioselective generation of funcionalized aryl and heteroaryl magnesium compounds", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION, vol. 45, no. 18, 2006, pages 2958 - 2961
PILLER,F.M. ET AL.: "Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes", ORGANIC LETTERS, vol. 11, no. 2, 2009, pages 445 - 448
KRASOVSKIY,A. ET AL.: "Mixed Mg/Li amides of the type R2NMgCl-LiCl as highly efficient bases for the regioselective generation of funcionalized aryl and heteroaryl magnesium compounds", ANGEWANDTE CHEMIE, INTERNATIONAL EDITION, vol. 45, no. 18, 2006, pages 2958 - 2961
PILLER,F.M. ET AL.: "Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes", ORGANIC LETTERS, vol. 11, no. 2, 2009, pages 445 - 448
Attorney, Agent or Firm:
SSINPAT PATENT FIRM (JP)
Patent business corporation SSINPAT (JP)
Patent business corporation SSINPAT (JP)
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