METHOD FOR PRODUCING GLYCOSIDE HAVING PHENOL AS AGLYCONE THEREOF

WIPO Patent Application WO/2013/073659

A1

Provided is a method for producing a glycoside having a phenol as the aglycone thereof, which is a method that: does not require an expensive catalyst or enzyme; does not require following a complex synthesis pathway; is a method for directly producing a glycoside having a phenol as the aglycone thereof from a monosaccharide or a saccharide chain; and is characterized by reacting a monosaccharide or a saccharide chain with a phenol represented by formula (1), while in the presence of supercritical or subcritical carbon dioxide and a lower alcohol. Ar-OH (1) (In formula (1), Ar is one aromatic ring, and may optionally include a substituent.)

JPS57122039	TETRASUBSTITUTED BENZENE DERIVATIVES
JP4164383	Compounds, their manufacturing methods and uses

MOTOKUCHO SUGURU (JP)
INOUE TOSHIO (JP)

PCT/JP2012/079757

May 23, 2013

November 16, 2012

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UNIV NAGASAKI (JP)
JX NIPPON OIL & ENERGY CORP (JP)

C07H15/203; C08B33/04; C08B35/04

JP2010053038A	2010-03-11
JP2005336163A	2005-12-08

MANOHAR,B. ET AL.: "Amyloglucosidase catalyzed syntheses of bakuchiol glycosides in supercritical carbon dioxide", BULLETIN OF THE KOREAN CHEMICAL SOCIETY, vol. 30, no. 8, 2009, pages 1760 - 1766
HINOU,H. ET AL.: "Microwave effect for glycosylation promoted by solid superacid in supercritical carbon dioxide", INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, vol. 10, no. 12, 2009, pages 5285 - 5295

MORITA, NOBUYUKI (JP)
Yoriyuki Morita (JP)

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