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Title:
METHOD FOR PRODUCING HYDROCARBON LIQUID FUEL
Document Type and Number:
WIPO Patent Application WO/2017/208497
Kind Code:
A1
Abstract:
A method for producing a hydrocarbon liquid fuel by catalytically hydrocracking a feed oil in the presence of a catalytic hydrocracking catalyst by using a hydrogen supply pressure of 0.1-1.0 MPa, a liquid hourly space velocity for the amount of feed oil of 0.05-10.0 hr-1, and a hydrogen flow rate per liter of feed oil of 50-3000 NL, wherein, in the method for producing a hydrocarbon liquid fuel, the catalytic hydrocracking catalyst is prepared by a method comprising a step (step 1) for stirring a sulfur compound and a cracking catalyst in an aqueous medium and performing solid-liquid separation, a step (step 2) for stirring the solid obtained in step 1 and a metal component in an aqueous medium and performing solid-liquid separation, a step (step 3) for firing the solid obtained in step 2, and a step (step 4) for reducing the solid obtained in step 3 or performing sulfuration treatment after having reduced the solid obtained in step 3. The prevent invention makes it possible, using a predetermined procedure, to conduct catalytic hydrocracking of fats and oils and biomass retort oils, or feed oils such as hydrocarbons in petroleum, by supplying low-pressure hydrogen of approximately normal pressure.

Inventors:
TSUTO KEIICHI
AZUMA YUICHIRO
SHOJO DAISAKU
Application Number:
PCT/JP2017/003407
Publication Date:
December 07, 2017
Filing Date:
January 31, 2017
Export Citation:
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Assignee:
REVO INT INC (JP)
International Classes:
C10G47/12; B01J29/14; B01J37/16; C10G3/00
Domestic Patent References:
WO2013073528A12013-05-23
Foreign References:
JP2011148909A2011-08-04
JP2012532212A2012-12-13
JP2011148909A2011-08-04
Other References:
LIU, MURATA; INABA, TAKAHARA: "Shokubutsu-yu karano Baio-Keiyu (BHD) no Seizo (Production of Bio-Hydrogenated Diesel (BHD) from Vegetable Oils),'' (Independent Administrative Agency) the National Institute of Advanced Industrial and Technology (AIST", DAI-6-KAI SHIN ENERUGII SHINPOZIUMU (6TH NEW ENERGY SYMPOSIUM), 11 March 2011 (2011-03-11)
KOYAMA ET AL.: "Jidosha-Nenryo notameno Shokubutsuyu no Suisoka Shori Kotei (Hydrogenation Treatment Process of Vegetable Oils for Automobile Fuels)", SAE PAPER, 2007, pages 1 - 6
KIKUCHI ET AL.: "Atarashii Shokubai Kagaku (New Catalyst Chemistry", 1997, SANKYO SHUPPAN
H. HATTORI: "Bronsted acid of the solid acid (The Japan Society of Adsorption", ADSORPTION NEWS, vol. 25, no. 2, July 2011 (2011-07-01)
SHOKUBAI (CATALYST, vol. 45, 2003, pages 327
See also references of EP 3467076A4
Attorney, Agent or Firm:
HOSODA, Yoshinori (JP)
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