Title:
METHOD FOR PRODUCING LITHIUM TRANSITION METAL OXIDE
Document Type and Number:
WIPO Patent Application WO/2011/002074
Kind Code:
A1
Abstract:
Disclosed is a novel method for producing a lithium transition metal oxide, which is capable of increasing the crystallite size, while suppressing oxygen defects. Specifically disclosed is a method for producing a lithium transition metal oxide, which comprises a step of mixing starting materials, a firing step, and a heat treatment step, and which is characterized in that the starting materials are fired in an atmosphere having an oxygen partial pressure of from 0.015 MPa to 0.15 MPa at a temperature not less than 850°C, and then the resulting material is heat-treated in an atmosphere having an oxygen partial pressure of not less than 0.03 MPa at a temperature that is the primary oxygen release temperature ± 50°C. Since the method is capable of suppressing oxygen defects while increasing the crystallite size, the strain is reduced and the lithium transition metal oxide has a strong skeleton. Consequently, when the lithium transition metal oxide is used as a positive electrode active material for a lithium secondary battery, the lithium secondary battery is able to have adequate output characteristics and adequate high-temperature cycle life characteristics at the same time.
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Inventors:
KAGEI SHINYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
Application Number:
PCT/JP2010/061308
Publication Date:
January 06, 2011
Filing Date:
July 02, 2010
Export Citation:
Assignee:
MITSUI MINING & SMELTING CO (JP)
KAGEI SHINYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
KAGEI SHINYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
International Classes:
C01G45/00; C01G49/00; C01G51/00; C01G53/00; H01M4/505
Foreign References:
JP2000211922A | 2000-08-02 | |||
JPH09259880A | 1997-10-03 | |||
JP2002075355A | 2002-03-15 | |||
JP2002175805A | 2002-06-21 | |||
JP2002316823A | 2002-10-31 | |||
JP2006252940A | 2006-09-21 | |||
JP2001335323A | 2001-12-04 | |||
JP2007149414A | 2007-06-14 |
Attorney, Agent or Firm:
TAKEUCHI, ICHIZAWA & ASSOCIATES (JP)
Patent business corporation Takeuchi and an Ichizawa international patent firm (JP)
Patent business corporation Takeuchi and an Ichizawa international patent firm (JP)
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