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Title:
METHOD FOR PRODUCING LITHIUM TRANSITION METAL OXIDE
Document Type and Number:
WIPO Patent Application WO/2011/002074
Kind Code:
A1
Abstract:
Disclosed is a novel method for producing a lithium transition metal oxide, which is capable of increasing the crystallite size, while suppressing oxygen defects. Specifically disclosed is a method for producing a lithium transition metal oxide, which comprises a step of mixing starting materials, a firing step, and a heat treatment step, and which is characterized in that the starting materials are fired in an atmosphere having an oxygen partial pressure of from 0.015 MPa to 0.15 MPa at a temperature not less than 850°C, and then the resulting material is heat-treated in an atmosphere having an oxygen partial pressure of not less than 0.03 MPa at a temperature that is the primary oxygen release temperature ± 50°C. Since the method is capable of suppressing oxygen defects while increasing the crystallite size, the strain is reduced and the lithium transition metal oxide has a strong skeleton. Consequently, when the lithium transition metal oxide is used as a positive electrode active material for a lithium secondary battery, the lithium secondary battery is able to have adequate output characteristics and adequate high-temperature cycle life characteristics at the same time.

Inventors:
KAGEI SHINYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
Application Number:
PCT/JP2010/061308
Publication Date:
January 06, 2011
Filing Date:
July 02, 2010
Export Citation:
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Assignee:
MITSUI MINING & SMELTING CO (JP)
KAGEI SHINYA (JP)
MIYANOHARA KEISUKE (JP)
HATA YOSHIMI (JP)
OCHI YASUHIRO (JP)
MITSUMOTO TETSUYA (JP)
International Classes:
C01G45/00; C01G49/00; C01G51/00; C01G53/00; H01M4/505
Foreign References:
JP2000211922A2000-08-02
JPH09259880A1997-10-03
JP2002075355A2002-03-15
JP2002175805A2002-06-21
JP2002316823A2002-10-31
JP2006252940A2006-09-21
JP2001335323A2001-12-04
JP2007149414A2007-06-14
Attorney, Agent or Firm:
TAKEUCHI, ICHIZAWA & ASSOCIATES (JP)
Patent business corporation Takeuchi and an Ichizawa international patent firm (JP)
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