Title:
METHOD FOR PRODUCING QUANTUM DOT, AND ORGANIC PHOSPHINE
Document Type and Number:
WIPO Patent Application WO/2018/084262
Kind Code:
A1
Abstract:
The purpose of the present invention is to provide a method whereby it becomes possible to produce a quantum dot having a narrow grain size distribution with high reproducibility even when an amino-substituted organic phosphine precursor is used in the synthesis of the quantum dot. The method for producing a quantum dot according to one aspect of the present invention comprises a step of mixing a Group-IIIB precursor with an organic phosphine precursor to produce a precursor mixture and a step of heating the precursor mixture to produce a solution of a Group-IIIB phosphide quantum dot, wherein the organic phosphine precursor has one or multiple amino substituents, and at least one of parent amines for the amino substituents has a boiling point of 160ºC or higher under the standard atmospheric pressure.
Inventors:
MORIYAMA TAKAFUMI (US)
NOVET THOMAS E (US)
SCHUT DAVID M (US)
NOVET THOMAS E (US)
SCHUT DAVID M (US)
Application Number:
PCT/JP2017/039807
Publication Date:
May 11, 2018
Filing Date:
November 02, 2017
Export Citation:
Assignee:
SHOEI CHEMICAL IND CO (JP)
International Classes:
C01B25/08; B82Y20/00; B82Y40/00; C07F9/24; C09K11/70
Domestic Patent References:
| WO2016146719A1 | 2016-09-22 |
Foreign References:
| JP2000290268A | 2000-10-17 | |||
| JP2002284774A | 2002-10-03 | |||
| JP2003238579A | 2003-08-27 | |||
| JP2014015549A | 2014-01-30 | |||
| US6576291B2 | 2003-06-10 |
Other References:
JANARTHANAN GOPALAKRISHNAN, APPL. OR-GANOMETAL. CHEM., vol. 23, 2009, pages 291 - 318
MICKAEL D. TESSIER, CHEM. MATER., vol. 27, 2015, pages 4893 - 4898
TAICHI MATSUMOTO, CHEMISTRY LETTERS, vol. 33, no. 11, 2004
"Aminophosphines: A Double Role in the Synthesis of Colloidal Indium Phosphide Quantum Dots", J. AM. CHEM. SOC., vol. 138, no. 18, 2016, pages 5923 - 5929
"Synthesis and Characterization of InP, Gap, and GaInP2 Quantum Dots", J. PHYS. CHEM., vol. 99, 1995, pages 7754 - 7759
"Nano Letters", vol. 2, 2002, AMERICAN CHEMICAL SOCIETY, pages: 1027 - 1030
"Strongly Luminescent InP/ZnS Core - Shell Nanoparticles", CHEMPHYSCHEM, 2001
"Highly Efficient Cadmium-Free Quantum Dot Light-Emitting Diodes Enabled by the Direct Formation of Excitons within InP@ZnSeS Quantum Dots", ACS NANO, vol. 7, no. 10, 2013, pages 9019 - 9026
"InP@ZnSeS, Core@Composition Gradient Shell Quantum Dots with Enhanced Stability", CHEM. MATER., vol. 23, no. 20, 2011, pages 4459 - 4463
"Highly Luminescent InP/GaP/ZnS Nanocrystals and Their Application to White Light-Emitting Diodes", J.AM.CHEM.SOC., vol. 134, 2012, pages 3804 - 3809
JOUNG ET AL.: "Facile synthesis of uniform large-sized InP nanocrystal quantum dots using tris (tertbutyldimethylsilyl) phosphine", NANOSCALE RESEARCH LETTERS, vol. 7, 2012, pages 93
See also references of EP 3536663A4
MICKAEL D. TESSIER, CHEM. MATER., vol. 27, 2015, pages 4893 - 4898
TAICHI MATSUMOTO, CHEMISTRY LETTERS, vol. 33, no. 11, 2004
"Aminophosphines: A Double Role in the Synthesis of Colloidal Indium Phosphide Quantum Dots", J. AM. CHEM. SOC., vol. 138, no. 18, 2016, pages 5923 - 5929
"Synthesis and Characterization of InP, Gap, and GaInP2 Quantum Dots", J. PHYS. CHEM., vol. 99, 1995, pages 7754 - 7759
"Nano Letters", vol. 2, 2002, AMERICAN CHEMICAL SOCIETY, pages: 1027 - 1030
"Strongly Luminescent InP/ZnS Core - Shell Nanoparticles", CHEMPHYSCHEM, 2001
"Highly Efficient Cadmium-Free Quantum Dot Light-Emitting Diodes Enabled by the Direct Formation of Excitons within InP@ZnSeS Quantum Dots", ACS NANO, vol. 7, no. 10, 2013, pages 9019 - 9026
"InP@ZnSeS, Core@Composition Gradient Shell Quantum Dots with Enhanced Stability", CHEM. MATER., vol. 23, no. 20, 2011, pages 4459 - 4463
"Highly Luminescent InP/GaP/ZnS Nanocrystals and Their Application to White Light-Emitting Diodes", J.AM.CHEM.SOC., vol. 134, 2012, pages 3804 - 3809
JOUNG ET AL.: "Facile synthesis of uniform large-sized InP nanocrystal quantum dots using tris (tertbutyldimethylsilyl) phosphine", NANOSCALE RESEARCH LETTERS, vol. 7, 2012, pages 93
See also references of EP 3536663A4
Attorney, Agent or Firm:
SAKAI, Masami et al. (JP)
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