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Title:
METHOD FOR PRODUCING TRANSITION METAL-ISOCYANIDE COMPLEX
Document Type and Number:
WIPO Patent Application WO/2018/159599
Kind Code:
A1
Abstract:
This method is for producing a transition metal complex represented by formula (2), the method comprising reacting a compound containing a transition metal selected from V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, and Pt with an isocyanide compound represented by formula (1) in the presence of an alkali metal supported by a solid substance which is insoluble in an organic solvent. This production method can be used to easily and efficiently produce a transition metal complex that includes a predetermined transition metal having an oxidation number of 0 and that has the same or different isocyanide compounds, without using a compound harmful to the human body. (1): (CN)x-R1 {R1 represents a mono- to tri-valent organic group having 1-30 carbon atoms, and x represents an integer of 1-3}. (2): M1 a(L)b {M1 represents V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, or Pt, and is a zero-valent transition metal, L represents an isocyanide compound represented by formula (1), M1 and L may be the same or different from each other, "a" represents an integer of 1-8, and b represents an integer of 2-12}.

Inventors:
NAGASHIMA Hideo (NATIONAL UNIVERSITY CORPORATION 6-10-1, Hakozaki, Higashi-ku, Fukuoka-sh, Fukuoka 81, 〒8128581, JP)
SANAGAWA Atsushi (NATIONAL UNIVERSITY CORPORATION 6-10-1, Hakozaki, Higashi-ku, Fukuoka-sh, Fukuoka 81, 〒8128581, JP)
NODA Daisuke (Shin-Etsu Chemical Co. Ltd., 1-10, Hitomi, Matsuida-machi, Annaka-sh, Gunma 24, 〒3790224, JP)
SAKUTA Koji (Shin-Etsu Chemical Co. Ltd., 1-10, Hitomi, Matsuida-machi, Annaka-sh, Gunma 24, 〒3790224, JP)
Application Number:
JP2018/007216
Publication Date:
September 07, 2018
Filing Date:
February 27, 2018
Export Citation:
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Assignee:
KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION (6-10-1, Hakozaki Higashi-ku, Fukuoka-sh, Fukuoka 81, 〒8128581, JP)
SHIN-ETSU CHEMICAL CO., LTD. (6-1 Ohtemachi 2-chome, Chiyoda-ku Tokyo, 04, 〒1000004, JP)
International Classes:
C07F15/00; C07C291/10; C07F15/02; C07F15/04; C07F15/06
Foreign References:
JP4885730B22012-02-29
JPS5346986B21978-12-18
JP5385358B22014-01-08
JP5048503B22012-10-17
JP2016160487A2016-09-05
Other References:
BARYBIN, M.V. ET AL., J. AM. CHEM. SOC., vol. 121, no. 39, 1999, pages 9237 - 9238, XP055561144
BARYBIN, M.V. ET AL., J. AM. CHEM. SOC., vol. 129, no. 5, 2007, pages 1141 - 1150, XP055561166
MAUTZ, J. ET AL., EUR. J. INORG. CHEM., 2008, pages 1413 - 1422, XP055561174
MOKHTARZADEH, C. ET AL., DALTON TRANS., vol. 45, 2016, pages 14561 - 14569, XP055561177
J. M. WALTERS ET AL., J. MOLECULAR CATALYSIS, vol. 29, 1985, pages 201
H. NAGASHIMA ET AL., ORGANOMETALLICS, vol. 34, 2015, pages 2896
H. NAGASHIMA ET AL., J. AM. CHEM. SOC., vol. 138, 2016, pages 2480
M. S. WRIGHTON ET AL., J. ORGANOMET. CHEM., vol. 103, 1981, pages 975
M. S. WRIGHTON ET AL., J. AM. CHEM. SOC., vol. 128, 1977, pages 345
M. S. WRIGHTON ET AL., INORG. CHEM., vol. 19, 1980, pages 3858
A. J. CHALK ET AL., J. AM. CHEM. SOC., vol. 89, 1967, pages 1640
F. G. A. STONE ET AL., J. CHEM. SOC., DALTON TRANS., 1979, pages 1003
M. VIVANCO ET AL., ORGANOMETALLICS, vol. 11, 1992, pages 2734
Y. YAMAMOTO ET AL., INORG. CHEM., vol. 17, 1978, pages 3111
P. WOODWARD ET AL., J.CHEM. SOC., CHEM. COMMUN., 1977, pages 256
Y. YAMAMOTO ET AL., J. ORGANOMET. CHEM., vol. 282, 1985, pages 191
Y. YAMAMOTO ET AL., BULL. CHEM. SOC. JPN., vol. 57, 1984, pages 297
Y. YAMAMOTO ET AL., ORGANOMETALLICS, vol. 2, 1983, pages 1377
P. ESPINET ET AL., J. CHEM. SOC., DALTON TRANS., 1991, pages 2503
F. G. A. STONE ET AL., J. CHEM. SOC., CHEM. COMMUN., 1980, pages 489
N.J. COVILLE ET AL., J. CHEM. SOC., DALTON TRANS., 1982, pages 1069
Y. YAMAMOTO ET AL., J. ORGANOMET. CHEM., vol. 137, 1977, pages C31
M. MINELLI ET AL., INORG. CHEM., vol. 28, 1989, pages 2954
D. LENTZ ET AL., J. FLUORINE CHEM., vol. 89, 1998, pages 73
D. LENTZ, J. ORGANOMET. CHEM., vol. 377, 1989, pages 305
W. D. JONES ET AL., INORG. CHEM., vol. 26, 1987, pages 2120
J. E. ELLIS ET AL., J. AM. CHEM. SOC., 2000, pages 4678
T. W. TUMEY ET AL., J. CHEM. SOC., DALTON TRANS., 1976, pages 2021
S. OTSUKA ET AL., J. AM. CHEM. SOC., vol. 91, 1969, pages 6994
A. CHRISTOFIDES ET AL., J. ORGANOMET. CHEM., vol. 259, 1983, pages 355
J. S. FIGUEROA ET AL., INORG. CHEM., vol. 54, 2015, pages 5579
J. S. FIGUEROA ET AL., J. AM. CHEM. SOC., vol. 132, 2010, pages 5033
N.J. COOPER ET AL., J. AM. CHEM. SOC., vol. 116, 1994, pages 8566
W. E. BILLUPS ET AL., ANGEW. CHEM. INT. ED., vol. 46, 2007, pages 4486
J. E. ELLIS ET AL., J. AM. CHEM. SOC., vol. 129, 2007, pages 1141
ORGANOMETALLICS, vol. 23, 2004, pages 3976 - 3981
ORG. SYNTH., vol. 90, 2013, pages 358 - 366
TETRAHEDRON LETTERS, vol. 17, 1972, pages 1637 - 1640
Attorney, Agent or Firm:
PATENT PROFESSIONAL CORPORATION EI-MEI PATENT OFFICE (GINZA OHTSUKA Bldg. 2F, 16-12 Ginza 2-chome, Chuo-k, Tokyo 61, 〒1040061, JP)
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