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Title:
METHOD FOR PRODUCING TRICYCLO[5.2.1.02,6]DECANE-2-CARBOXYLIC ACID ESTERS
Document Type and Number:
WIPO Patent Application WO/2019/159906
Kind Code:
A1
Abstract:
The method for producing tricyclo[5.2.1.02,6]decane-2-carboxylic acid esters of the present invention is a method for producing tricyclo[5.2.1.02,6]decane-2-carboxylic acid esters by reacting the tricyclo[5.2.1.02,6]deca-3-ene in a dilute solution containing tricyclo[5.2.1.02,6]deca-3-ene with carbon monoxide in the presence of an acid catalyst and then reacting with an alcohol, wherein the dilute solution contains 100 mass parts or more of a tricyclo[5.2.1.02,6]decane isomer mixture per 100 mass parts of the tricyclo[5.2.1.02,6]deca-3-ene, the tricyclo{5.2.1.02,6]decane isomer mixture contains endo-tricyclo[5.2.1.02,6]decane (endo-form of TCD) and exo-tricyclo[5.2.1.02,6]decane (exo-form of TCD), and the composition ratio thereof (endo-form of TCD/exo-form of TCD) is greater than 1.0.

Inventors:
SHINAGAWA SHIORI (JP)
KITAMURA MITSUHARU (JP)
NAGAO SHINICHI (JP)
SUGITO KEN (JP)
Application Number:
PCT/JP2019/004910
Publication Date:
August 22, 2019
Filing Date:
February 12, 2019
Export Citation:
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Assignee:
MITSUBISHI GAS CHEMICAL CO (JP)
International Classes:
C07C67/14; C07C69/753; C07B61/00
Foreign References:
JP2005089399A2005-04-07
JP2006248957A2006-09-21
JP2005089400A2005-04-07
JPS6140658A1986-02-26
JPS611014A1986-01-07
JPS6253499A1987-03-09
JP2680069B21997-11-19
JP2005089399A2005-04-07
JP2018026132A2018-02-15
Other References:
See also references of EP 3753919A4
Attorney, Agent or Firm:
INABA, Yoshiyuki et al. (JP)
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