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Title:
METHOD FOR PRODUCING TRISPHENOLS AND MONOESTER DERIVATIVES THEREOF, AND 4-ACYLARALKYLPHENOL DERIVATIVES
Document Type and Number:
WIPO Patent Application WO/2010/134559
Kind Code:
A1
Abstract:
Provided are a method for industrially easily producing trisphenols, which are useful as starting materials for polymer compounds such as epoxy resins and polycarbonate resins and starting materials or additives for photoresists, at a high purity and high yield, and 4-acylaralkylphenol derivatives. Specifically, provided are: a method for producing a trisphenol represented by general formula (1) [wherein R1 to R4 independently represent a hydrogen atom, an alkyl group, an alkoxyl group, an aromatic hydrocarbon group, a halogen atom, an acyloxy group or a hydroxyl group; R5 and R6 independently represent a hydrogen atom or an alkyl group; R7 represents a hydrogen atom or an alkyl group; R0 represents an alkyl group, an alkoxyl group or a halogen atom; n represents 0 or an integer of 1 to 4, provided that in the case where n is 2 or greater, R0's may be either the same or different; and R9 to R11 independently represent a hydrogen atom, an alkyl group, an alkoxyl group, an aromatic hydrocarbon group, a halogen atom or a hydroxyl group], which comprises using, as a starting material, a 4-aralkylphenol derivative represented by general formula (2) [wherein R1 to R4, R5 and R6, R0 and n are each as defined in general formula (1); and X represents a hydrogen atom or a leaving group which can be substituted by a hydrogen atom, provided that in the case where n is 1 or greater, R0 does not attach to the 4-position of the phenyl group]; and a 4-acylaralkylphenol derivative.

Inventors:
OJIRI AKIHIKO (JP)
TSUJIGAMI TAKAFUMI (JP)
TANBA KOUICHI (JP)
Application Number:
PCT/JP2010/058476
Publication Date:
November 25, 2010
Filing Date:
May 19, 2010
Export Citation:
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Assignee:
HONSHU CHEMICAL IND (JP)
OJIRI AKIHIKO (JP)
TSUJIGAMI TAKAFUMI (JP)
TANBA KOUICHI (JP)
International Classes:
C07C37/20; C07C39/15; C07C45/65; C07C49/83; C07C67/29; C07C69/157
Foreign References:
JP2008191413A2008-08-21
Other References:
FUJIMOTO, K. ET AL.: "Synthesis and molecular recognition properties of a self-assembling molecule consisted of a porphyrin core and two hydrogen-bonding moieties", MATERIALS SCIENCE & ENGINEERING, C: BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, vol. 27, no. 1, 2007, pages 142 - 147, XP005805818, DOI: doi:10.1016/j.msec.2006.04.002
Attorney, Agent or Firm:
HASEBE, Zentaro et al. (JP)
Zentaro Hasebe (JP)
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Claims: